Molecular Shape: Hybridization
Major concepts
 Although VSEPR is a good way to predict molecular shape, the physical basis for the shapes of
molecules can be described in terms of stable orbitals for valence electrons
 Bonds can be described in terms of orbital overlap regions
 Using a qualitative model of orbitals, we can describe an atom in terms of its hybridization,
which tells us about molecular geometry and stability of electrons.
Vocabulary
 Orbitals
 Hybridization
 Stability of electrons
Students should be able to:
 Explain what is meant by “hybridization” and “orbital”
 Given the hybridization of atoms, be able to draw orbital overlap pictures of simple molecules
and ions
 Apply both the concepts of VSEPR and hybridization to explain the shape of molecules and the
stability of electrons
Daily Problems
1. Assuming that there is no conjugation in these molecules and ions, predict the hybridization of each
carbon, oxygen, and nitrogen atom:
2. Draw an orbital picture for carbon that is sp3 hybridized, sp2 hybridized, and sp hybridized. Indicate
the angles between each orbital.
3. The carbon atom in CH3+ is sp2 hybridized. Draw an orbital overlap picture for this ion.
4. According to VSEPR, what should the bond angles be for CH3+.? Does this match your orbital overlap
picture from problem 3?
5. The nitrogen atom in NH3 is sp3 hybridized. Draw an orbital overlap picture for this molecule.
6. According to VSEPR, what should the bond angles be for NH3.? Does this match your orbital overlap
picture from problem 5?
Cumulative problems
7. Draw an orbital overlap picture for ethanal.
8. Draw an orbital overlap picture for ethene.
9. Indicate which of the following lone pairs is more stable, and explain with a physical justification.
(Physical justifications include comparing resonance stabilized vs. non-resonance stabilized structures,
comparing relative stability of orbitals (sp > sp2 > sp3), or electrons on a more vs. less electronegative
atom.)
Extension problems
10. Which of these structures conveys more information? Explain.
11. Using models, explain one way in which these two compounds are the same, and one way in which
they are different.