Q 1. The smallest matter particle that can take part in chemical reaction is: (a) atom (b) molecule (c) both (d) none Q 2. Matter is anything which occupies A and .......... ... B .......... ... has Here A and Bare: (a) density and mass (b) volume and mass (c) space and mass (d) none of these Q 3. The solid like conducting state of gases with free electrons is called: (a) sol state (b) gel state (c) plasma state (d) all of these Q 4. An example of homogeneous mixture is: (a) mixture of soil and water (c) sugar solution (b) mixture of salt and sand grains (d) none of the above The density of water is equal to: (a) 10-3 kg/m3 (b) 10 kg/m3 (c) 103 kg/m3 Q 5. Q 6. Q 7. (d) 106 kg/m3 Which one of the following is not the unit of time ? (a) parallactic second (b) solar day (c) lunar month (d) leap year 0.003924 have …………. significant figures. (a) 6 (b) 4 (c) 3 (d) 7 Q 8. In multiplication and division the significant figures of answer must be same as that in the quantity with …………… no. of significant figures. (a) maximum (b) 3 (c) 2 (d) minimum Q 9. The answer of the calculation (a) 3.579 2.568 5.8 in significant figures will be: 4.168 (b) 3.570 (c) 3.57 (d) 3.6 Q 10. How many significant figures are there in (respectively)? (1) 73.000 g (2) 0.0503 g and (3) 2.001 sec. (a) 3, 3, 4 (b) 3, 4, 5 (c) 2, 5, 4 (d) 5, 3, 4 11 Q 11. The sample with largest number of atoms is : (a) 1 g of O2(g) (b) 1 g of Ni (s) (c) 1 g of B(s) (d) 1 g of N2 (g) Q 12. A sample of ammonium phosphate (NH4)3 PO4 contains 6.36 mol of hydrogen atoms. The number of moles of oxygen atom in the sample is: (atomic mass of N = 14.04, H =1, P = 31, 0=16) (a) 0.265 (b) 0.795 (c) 2.12 (d) 4.14 Q 13. A sample of copper sulphate pentahydrate contains 8.64 g of oxygen. How many g of Cu present in this sample ? (Atomic mass : Cu = 63.6, S = 32.06, O = 16) (a) 0.952 g (b) 3.809 g (c) 3.782 g (d) 8.64 g Q 14. What volume of hydrogen gas, at 273 K and 1 atm? Pressure will be consumed in obtaining 21.6 g of elemental boron (atomic mass = 10.8) from the reduction of BCl3 by hydrogen: (a) 22.4 L (b) 89.6 L (c) 67.2 L (d) 44.8 L Q 15. Cortisone is a molecular substance containing 21 atoms of carbon per molecule. The molecular weight of cortisone is 360.4. What is the percentage of carbon in cortisone? (a) 59.9% (b) 75% (c) 69.98% (d) None of these Q 16. How many moles of MgIn2S4 can be made from 1 g each of Mg, In and S ? (atomic mass : Mg = 24, In = 114.8, S = 32) (a) 6.47 × 10 (b) 3.0×10-1 (c) 9.17×10-2 (d) 8.7×10-3 Q 17. The number of atoms present in a 0.635 g of Cu piece will be: (a) 6.023 × 10-23 (b) 6.023 × 1023 (c) 6.023 × 1022 (d) 6.023 × 1021 Q 18. Calculate the number of moles left after removing 1021 molecules from 200 mg of CO2 : (a) 0.00454 (b) 0.00166 (c) 2.88 × 10-3 (d) none of these Q 19. Volume occupied by 1 mole of a diatomic gas at NTP will be: (a) 67.2 L (b) 22.4 L (c) 11.2 L (d) none of these Q 20. The number of sulphate ions in 1000 mL of 0.001 M H2SO4 is: (a) 6.023 × 1023 (b) 6.023 × 1022 (c) 6.023 × 1021 (d) 6.023 ×1020 Q 21. The molecular weight of air will be: (the components of air given as N2-78% Or – 21%, Ar - 0.9% and CO2 – 0.1%) (a) 18.64 (b) 24.968 (c) 28.964 (d) 29.864 Q 22. Number of atoms in 560 g of Fe is: (given atomic mass of Fe = 56 g/mol) (a) twice that of 70 g nitrogen (c) both are correct (b) half that of 20 g hydrogen (d) none is correct Q 23. In an experiment equal weights of iron and sulphur (1.00 g) are heated together and react to form FeS. What fraction of original weight is left unreacted? (Fe = 55.85 g/mol; S = 32.10 g/mol) (a) 0.250 (b) 0.579 (c) 8.75 × 10-1 (d) 4.25 × 10-1 Q 24. 30 mL of a gaseous hydrocarbon requires 90 mL of O2 for complete combustion and 60 mL of CO2 is formed in the process. The molecular formula of hydrocarbon will be: (a) C2H2 (b) CH4 (c) C2H4 (d) C2H6 Q 25. A sample of a mixture of CaCl2 and NaCI weighing 4.22 g was treated to precipitate all the Ca as CaCO3. This CaCO3 is then heated and quantitatively converted into 0.959 g of CaO. Calculate the percentage of CaCl2 in the mixture: (Atomic mass of Ca=40,O=16, C=12, and Cl=35.5) (a) 31.5% (b) 21.5% (c) 45.04% (d) 68.48% Q 26. About a gaseous reaction xX + yY lL + mM Which statement is wrong ? (a) x litre of X combines with y litre of Y to give L and M (b) x mole of X combines with y moles of Y to give L and M (c) x number of molecules of X combine with y number of molecules of Y to form L and M (d) x g of X combines with y g of Y to gives M and L Q 27. For the reaction X + 2Y Z 5 moles of X and 9 moles of Y will produce: (a) 5 moles of Z (b) 8 moles of Z (c) 14 moles of Z (d) 4 moles of Z Q 28. A metal oxide is reduced by heating it in a stream of hydrogen. It is found that after complete reduction, 3.15 g of oxide yielded 1.05 g of metal. From the above data we can say that: (a) the atomic weight of metal is 8 (b) the atomic weight of metal is 4 (c) the equivalent weight of metal is 4 (d) the equivalent weight of metal is 8 Q 29. Two elements X (at. wt. 75) and Y (at. wt. 16) combine to give a compound having 75.8% of X. The formula of compound will be: (a) XY (b) X2Y (c) XY3 (d) X2Y3 Q 30. If 0.5 mole of BaCl2 is mixed with 02 mole of Na3PO4 The maximum number of moles of Ba3(PO4)2 that can be formed is: (a) 0.7 (b) 0.5 (c) 0.03 (d) 0.10 Q 31. Which of the following pairs contain equal number of atoms? (a) 11.2 cc (STP) of nitrogen and 0.015 g of nitric oxide (b) 22.4 litre (STP) of nitrous oxide and 22.4 litres of nitric oxide (c) 1 milhimole of HC1 and 0.5 millimole of H2S (d). 1 mole of H2O2 and 1 mole of N2O4 Q 32. The haemoglobin from RBCs of mammals contains 0.33% of iron by weight. The physical measurements indicate the mol. wt, of haemoglobin is 7000. The no. of iron atoms in each molecule of haemoglobin is: (atomic weight of Fe = 56) (a) 2 (b) 3 (c) 4 (d) 5 Q 33. Cyclohexanol is dehydrated to cyclohexene on heating with conc. H2SO4 The cyclohexene obtained from 100 g cyclohexanol will be: (if yield of reaction is 375%) (a) 61.5 g (b) 75.0 g (c) 20.0 g (d) 41.0 g Q 34. The ratio of volumes of H2 evolved if same amount of Zn to treated with excess of H2SO4 and NaOH separately : (a) 1:2 (b) 2:1 (c) 1:1 (d) 9:4 Q 35. The composition of residual mixture will be if 30 g of Mg combines with 30 g of oxygen: (a) 40g MgO + 20g O2 (b) 45g MgO + 15g O2 (c) 50g MgO + 10g O2 (d) 60g MgO only Answers 1. 8. 15. 22. 29. a d c c d 2. 9. 16. 23. 30. c d c d d 3. 10. 17. 24. 31. c d d c a 4. 11. 18. 25. 32. c b b c c 5. 12. 19. 26. 33. c c c d a 6. 13. 20. 27. 34. a c d d c 7. 14. 21 28 35. b c c c c 5. 12. c c 6. 13. a c 7. b Answers 1. 8. a d 2. 9. c d 3. 10. c d 4. 11. c b