Honors Chemistry Page 1 of 8 I Want to Be Like You-oo-oo!! Oh, oobee-doo I wanna be like you-u-u I wanna walk like you Talk like you, to-oo-oo-oo You'll see it's true An element like me-e-e Can learn to be a gas….like you toooo-oo (badly modified from Disney’s ‘Jungle Book’) https://www.youtube.com/watch?v=9JDzlhW3XTM Group IA metals (alkali metals) 1.1. Write the electron Configurations for the following elements: Alkali metals Li: Na: K: Rb: Cs: Fr: Noble Gases He: Ne: Ar: Kr: Xe: Rn: 1.2. Procedure: Go to the Open Learn Science website and make observations of the physical and chemical changes that occur during the demonstration http://www.open.edu/openlearn/science-maths-technology/science/chemistry/alkali-metals 1.3. Observations: 1.4. Reaction Equations: Honors Chemistry Page 2 of 8 1.5. Based upon your review of the above website, what do you observe is the order of reactivity for each of the alkali metals? 1.6. What do you think might account for those differences-It’s an atom ‘thing’? Group IIA Metals (Alkaline Earth Metals) pH and Conductivity Preparation: Alkaline earth metal chlorides Testing Solutions: A 50 ml solution of 0.1 M, Magnesium hydroxide solution Mg(OH)2 A 50 ml solution of 0.1 M, Calcium hydroxide solution Ca(OH)2 100 ml graduated cylinder 100 ml beakers Measuring solutions Transfer and test with pH and conductivity probes 2.1. Before you conduct the next investigation, think about your first set of observation. Based upon what you observed, what do you hypothesize will be the differences between the pH and conductivity of IIA hydroxide solutions? Honors Chemistry Page 3 of 8 2.2.Test the pH and conductivity of each solution using the Vernier pH and conductivity probes pH Conductivity Mg(OH)2 _______________________ _______________________ Ca(OH) ________________________ _______________________ 2.3.How would you compare your results to what you predicted about the pH and conductivity of IIA metal solutions? 2.4.What do you think might account for those differences? Solubility Preparation: Alkaline earth metal chlorides Testing Solutions: a. b. c. d. e. f. g. h. Barium chloride solution, 0.1 M, BaCl2, Ammonium oxalate solution, 0.25 M, (NH4)2C2O4 Calcium chloride solution, 0.1 M, CaCl2 Potassium iodate solution, 0.2 M, KIO3 Magnesium chloride solution, 0.1 M, MgCl2 Sodium carbonate solution, 1 M, Na2CO3 Strontium chloride solution, 0.1 M, SrCl2 Sodium sulfate solution, 1 M, Na2SO4 Honors Chemistry Page 4 of 8 8 disposable pipets 1 testing plate i. Fill each pipet with the soln’s, invert pipet and store in a beaker Follow steps i and ii, look for the production of a precipitate Add several (approximately 5) drops of an alkaline earth metal chloride solution to each well in a horizontal row, as follows (see Figure 1): • magnesium chloride to wells A1–A5 • calcium chloride to wells B1–B5 • strontium chloride to wells C1–C5 • barium chloride to wells D1–D5 ii. Add several drops of testing solution to each well in a vertical column, as follows (see Figure 1): • potassium iodate to wells A1–D1 • sodium sulfate to wells A2–D2 • ammonium oxalate to wells A3–D3 • sodium carbonate to wells A4–D4 iii. Record results on the following table. If a solid appears, record as ‘ppt’ in the circle. Honors Chemistry Page 5 of 8 3.1. Based upon your observations, where the any patterns that emerged between the elements. 3.2. What do you think might account for those differences? Group VIIA Nonmetals (The halogens): 4.1.First, compare the visible physical properties of the three elements Cl2, Br2, and I2, which are displayed in bottles on the side shelf. Be sure to notice the colored vapors above the liquid and solid. Element Physical State Color Cl2 ________________ ________________ Br2 ________________ ________________ I2 __________________ __________________ 4.2.Which of these three elements is most volatile (most easily vaporized)? ___________ 4.3. How does the volatility of the elements vary with the atomic mass of the Cl2, Br2, and I2 molecules? Honors Chemistry Page 6 of 8 4.4.In 50 ml beakers, measure the conductivity of the aqueous solutions of the 0.1 M sodium halides using the conductivity probe (use the 0-20,000 toggle setting). Solution Conductivity 20 ml. NaCl(aq) __________________ 20ml NaBr(aq) __________________ 20 ml. NaI(aq) __________________ 5.2. Based upon your observations, where there any patterns that emerged between the VIIA elements. 5.3. What do you think might account for those differences? Solubility 5.1. Preparation of Solutions: a. Chlorine Water: To prepare 100 mL of chlorine water, mix 13 mL of 5% sodium hypochlorite solution (bleach) with 30 mL of 1 M hydrochloric acid. Dilute to 100 mL with distilled water and stir to mix. Store in a labeled glass bottle or stoppered flask until needed. Work with chlorine water in the hood. Honors Chemistry Page 7 of 8 b. Bromine Water: To prepare 100 mL of bromine water, mix 30 mL of 1 M sodium bromide solution with 30 mL of 1 M hydrochloric acid. Add 15 mL of 5% sodium hypochlorite solution (bleach) followed by 25 mL of distilled water and stir well to mix. Store in a labeled glass bottle or stoppered flask until needed. Work with bromine water in the hood. c. Iodine Solution: _______________________________ 5.1. Procedure I. Label six square glass bottles 1–6 II. Using a graduated cylinder, measure and add 5 mL of chlorine water to each bottle 1 and 2. Cap the bottles. III. Draw a line to mark the level of liquid in bottles 1 and 2, and mark off a line at the same height in each bottle 3–6. IV. Add bromine water to the 5-mL line in each bottle 3 and 4. V. Add iodine solution to the 5-mL line in each bottle 5 and 6. VI. Record the color of each aqueous halogen solution in Data Table A. VII. Using a clean graduated cylinder, measure and add approximately 10 mL of hexane to each test tube 1–6. VIII. Place a stopper in each test tube and carefully invert each tube several times to mix the liquids. There should be two layers—the top organic layer (hexane), and the bottom aqueous layer (water). IX. For each aqueous halogen/hexane mixture, record the colors of the upper and lower liquid layers in Data Table A. X. Add 5 mL of sodium bromide solution to the chlorine mixture in bottle 1. Cap the bottle and carefully invert several times to mix the liquids. Observe any reaction that occurs— look for changes in color to either layer. Record all observations in Data Table B. If no change is apparent, write no reaction (NR) in the data table. XI. Using the information in the following chart, repeat step 10 for all of the possible halogen– sodium halide combinations in bottles 2–6. XII. Record detailed observations as each solution is added. Complete Data Table B. Test Tube 1 2 3 4 5 6 Halogen Cl2 Cl2 Br2 Br2 I2 I2 Sodium Halide Solution NaBr NaI NaCl NaI NaCl NaBr Honors Chemistry Page 8 of 8 5.2. Based upon your observations, where there any patterns that emerged between the VIIA elements. 5.3. What do you think might account for those differences?