Chemistry 30 Unit 1 Chemistry 20 Review 1. Fact File Timeline and More A. Democritus (460 to 370 BC) -Atoms are impenetrable and have a density proportional to their volume B. Lavoisier (1743-1794) – Found the Law of Conservation of Mass C. John Dalton (1766-1844) – Proposed the Atomic Theory in 1803 D. J.J.Thompson (1856 – 1940) – the first to discover the electron in 1895 and then the first to split an atom in 1905 E. Ernst Rutherford (Aug. 30, 1871 to Oct. 19, 1937) – in 1910 showed that there must be an inner structure in the atom, later named the nucleus F. Robert Millikan (March 22, 1868 to Dec. 19, 1953) – Began working in 1909 to prove the charge of electons G. Niels Bohr (Oct. 7, 1885 to Nov. 18, 1962) – Using concepts from the Quantum Theory, he presented a picture of atom H. James Chadwick (Oct. 20, 1891 to July 24, 1974) – Discovered the neutron in 1932 I. Louis de Broglie (1892 to 1987) – In 1924 he introduced the wave particle duality theory which united the energy of a wave with the movement of the particle which helped create quantum mechanics Assignment #4: Atomic Scientists Bohr was the first to propose this idea of energy levels. Using the Internet, check up on the history of his work and answer the following questions: 1. What problems with Rutherford's theory was Bohr trying to explain? The first problem was that the atom was very unstable because electrons that continually change direction, speed, etc. would constantly be using up their energy ending in them spiraling into the nucleus. The second problem was that his model did not explain that in some gasses the electrons emitted a light at certain discrete distances, not at random areas. 2. The work of several men was used as the basis for Bohr's theory. Describe the contribution of the following men to Bohr's theory: o Max Planck Determined Planck’s constant which helped to measure the distribution of energy in the full spectrum of radiation. This helped Bohr to explain how electrons absorbed or emitted energy. o John Palmer 3. The study of light is central to Bohr's theory. Define the following terms as they relate to light: o Wavelength - distance between successive peaks or troughs o Frequency - number of complete wavelengths that pass a given point in 1 second o Photons - the smallest increment of radiant energy Emission spectrum – a spectrum containing radiation of only specific wavelengths 4. Explain how Bohr's theory explains the emission spectrums of elements like hydrogen using the terms above in question #3 o Typical light consists of radiation that is composed of several wavelengths. When these wavelengths are split into their different components, an emission spectrum is formed. Assignment 11 Chemical Families Info taken from: http://www.chemicalelements.com/groups/alkali.html The alkali metals, found in group 1 of the periodic table (formerly known as group IA), are very reactive metals that do not occur freely in nature. These metals have only one electron in their outer shell. Therefore, they are ready to lose that one electron in ionic bonding with other elements. As with all metals, the alkali metals are malleable, ductile, and are good conductors of heat and electricity. The alkali metals are softer than most other metals. Cesium and francium are the most reactive elements in this group. Alkali metals can explode if they are exposed to water. The Alkali Metals are: Lithium Sodium Potassium Rubidium Cesium Francium The alkaline earth elements are metallic elements found in the second group of the periodic table. All alkaline earth elements have an oxidation number of +2, making them very reactive. Because of their reactivity, the alkaline metals are not found free in nature. The Alkaline Earth Metals are: Beryllium Magnesium Calcium Strontium Barium Radium The halogens are five non-metallic elements found in group 17 of the periodic table. The term "halogen" means "salt-former" and compounds containing halogens are called "salts". All halogens have 7 electrons in their outer shells, giving them an oxidation number of -1. The halogens exist, at room temperature, in all three states of matter: Solid- Iodine, Astatine Liquid- Bromine Gas- Fluorine, Chlorine The Halogens are: Fluorine Chlorine Bromine Iodine Astatine The Oxygen Family, also called the Chalcogens, consists of the elements found in Group 16 of the periodic table and is considered part of the Main Group elements. It consists of the elements oxygen, sulfur, selenium, tellurium and polonium. The group is named after its first member, oxygen, however the individual elements very quite widely due to the changing metallic properties as one descends down the group. They can be found in nature in both free and combined states. Properties and Periodic Trends All elements of the Oxygen family have 6 electrons in their outermost shell, with a valence electron configuration of ns2np4, which accounts for the similar chemical properties between the elements. As one moves down the group, metallic character increases, with tellurium being a metalloid and polonium a metal. Melting point, boiling point, density, atomic radius, and ionic radius all increase going down the group. Ionization energy decreases going down the group. The most common oxidation state is -2, however sulfur can also exist at a +4 and +6 state and +2, +4, and +6 oxidation states are possible for Se, Te, and Po. http://chemwiki.ucdavis.edu/Inorganic_Chemistry/Descriptive_Chemistry/Main_Group_E lements/Group_16:_The_Oxygen_Family Assignment #12: Types of Chemical Bonds Using any or all of the following sources of information to answer the following questions. http://users.senet.com.au/~rowanb/chem/chembond.htm http://www.okstate.edu/jgelder/bondpage3.html#cen http://members.aol.com/profchm/bonding.htm http://www.woodrow.org/teachers/chemistry/links/chem1/Chapter5.html 1. What are the three types of chemical bonds? Ionic, Covalent and Metallic 2. Describe what happens to the atoms when each type of bond forms. Ionic – large electronegative difference and the one or more valence electrons are moved to the other atom Covalent – valence electrons are shared between the atoms, can be polar if the sharing is not equal Metallic – valence electrons shared between two metallic atoms 3. What types of elements (metal or nonmetal) form each type of bond? Metallic (metal) 4. What is a molecule? A molecule is the smallest particle of a substance that retains its chemical properties and is made up of at least two atoms 5. What types of bonds form molecular substances? Covalent Bonds 6. List 4 properties of these types of substances? Melting/Boiling Point, Solubility, Electrical Conductivity 7. What is the difference between polar and nonpolar covalent bonds? Polar means that there is a charge because the electrons are not shared evenly within the bond, so one end is + and one end appears to be -. Nonpolar means that the electrons are shared evenly. 8. How does this differences between the two types of covalent bonds affect the properties of the molecules that contain these bonds ? Polar molecules are dipole, a + end and a negative end.