Graphing Periodic Trends - Waterford Public Schools

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Graphing the Periodic Trends

Background

The Periodic Table is arranged according to Periodic Law. The Periodic Law states that when elements are arranged in order of increasing atomic number, their physical and chemical properties show a periodic pattern. These patterns can be discovered by examining the changes in properties of elements on the Periodic Table. The properties that will be examined in this lesson are: atomic size, ionic radius, electronegativity, and ionization energy.

Procedure

1.

Define the following terms on a separate sheet of paper: period, group (Family), atomic radius, electronegativity, first ionization energy

2.

Graph 1 - For elements 1-36 make a graph of atomic radius as a function of atomic number. Plot atomic number on the X-axis and the atomic radius on the Y-axis. Use a colored pen or pencil to draw a vertical line that represents the beginning of each period.

3.

Graph 2 - For elements 1-36, make a graph of the ionization energy. Plot atomic number on the X-axis and ionization energy on the Y-axis. Use a colored pen or pencil to draw a vertical line that represents the beginning of each period.

4.

Graph 3 - For elements 1-36, make a graph of the ionic radius. Plot atomic number on the X-axis and the ionic size on the Y-axis. Use a colored pen or pencil to draw a vertical line that represents the beginning of each period.

5.

Graph 4 - For elements 1-36, make a graph of the electronegativity. Plot atomic number on the X-axis and the electronegativity on the Y-axis. Use a colored pen or pencil to draw a vertical line that represents the beginning of each period.

Computer Directions

1.

Turn on computer, log onto the network, start the program Microsoft Excel.

2.

Create column headings for the data to be listed. Enter the data from the periodic table into columns. Enter the data for elements 1-36. If any of the elements are missing data, simply leave them blank-do not enter zero-and

continue down the list.

3.

Select the data in the column to be graphed first by clicking on the top cell and dragging down to the bottom of the cell. Click on the graph (chart) wizard button to produce a graph.

4.

Copy the atomic radius numbers from the data table next to (right‐hand side) the atomic numbers in the table

(first column = X variable, second column = Y variable).

5.

Highlight both columns (atomic number – atomic radius) and go to Insert on the toolbar and select Chart.

6.

You will be given a number of choices. Choose X-Y (scatter), and select the fourth option from the left (Straight

Marked Scatter).

7.

A chart should appear. You may need to resize it by dragging the corner. We now need to title and label the axes of the graph.

8.

If the toolbox is not currently open select Toolbox at the top or go to the toolbar and select View and

Formatting Palette.

9.

Choose Chart Options on the Formatting Palette.

10.

You should see a drop down menu under Titles that you can use to label your graph. Apply the correct labels with units where appropriate. When finished, print the graph.

11.

Repeat this process for the remaining three properties: 1st ionization energy, electron affinity, and electronegativity.

12.

Staple all four graphs to the lab with your completed Analysis Questions.

Data Table

Element

Symbol

Mn

Fe

Co

Ni

Sc

Ti

V

Cr

Cl

Ar

K

Ca

Al

Si

P

S

Cu

Zn

Ga

Ge

As

Se

Br

Kr

H

He

Li

Be

B

C

N

O

F

Ne

Na

Mg

Atomic

Radius (pm)

184

176

171

166

161

156

152

149

118

111

98

88

79

71

243

194

145

142

136

125

114

103

94

88

53

31

167

112

87

67

56

48

42

36

190

145

Atomic

#

25

26

27

28

21

22

23

24

17

18

19

20

13

14

15

16

29

30

31

32

33

34

35

36

4

5

6

7

1

2

3

8

9

10

11

12

633

659

651

653

717

762

760

737

577

786

1011

999

1251

1520

419

590

Ionization

Energy

(kJ/mol)

1311

2371

520

899

800

1086

1402

1313

1680

2080

496

737

745

906

579

762

944

941

1139

1350

Electronegativity *

(Pauling Scale)

Ionic

Radius*

(pm)

60

31

20

15

171

140

136

95

65

50

41

212

184

181

72

72

96

88

62

53

222

198

195

133

99

106

96

88

81

75

74

1.36

1.54

1.63

1.66

1.55

1.83

1.88

1.91

1.61

1.90

2.19

2.58

3.16

0.82

1.00

1.90

1.65

1.81

2.01

2.18

2.55

2.96

3.00

2.20

0.98

1.57

2.04

2.55

3.04

3.44

3.98

0.93

1.31

Questions

A trend is an observation, NOT an explanation! It is fine to state the trend itself, but you must also go further by explaining what causes the observed trend. Remember, these trends emerge as a result of a pattern in element properties. Think hard about the change in atomic structure as one moves across and down the Periodic Table!

Please answer all questions on a separate sheet of paper. Write complete sentences to receive full credit.

1.

Based on your graphs, what is the trend in atomic radius across a period? Down a family? Using your knowledge of atomic structure, what is the explanation for this trend?

2.

Based on your graphs, what is the trend in ionization energy across a period? Down a family? Using your knowledge of atomic structure, what is the explanation for this trend?

3.

Based on your graph, what is the trend in electronegativity across a period? Down a family? Using your knowledge of atomic structure, what is the explanation for this trend?

4.

Based on your graph, what is the trend in ionic radius across a period? Down a family?

5.

Compare the graphs for ionic and atomic radii. a.

In general, what happens to metals when they form an ion? b.

What happens to nonmetals when they form an ion? c.

How does this information support the trends you see?

6.

For each Periodic Table trend explored in this activity, hypothesize the element that has the greatest value and the smallest value.

Justify your answers.

7.

Using an activity series, what can you deduce about the relationship between ionization energy and reactivity of metals? Why do you think the relationship you see in the graph is contradictory to what you understand about the activity series?

8.

For each property, write a summary below the title of your graph that explains the trend as you move across a period and down a group. Be sure to include the explanation for the observations you wrote in #1-4!

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