PRODUCT SAFETY DATA SHEET 1- IDENTIFICATION OF THE PRODUCT AND COMPANY Product: Rizospray Extremo Chemical name: methyl esters of soybean oil CAS Number: not applicable (mixture) Product Type: Adjuvant SENASA No: 37.021 Manufacturer: Rizobacter Argentina S.A. Telephone No: 02477-409400 Fax N°: 02477-432893 2 - CLASSIFICATION OF RISKS Flammability: Flammable 4 ° Category. Toxicological Classification: Class IV - Product that usually is not hazardous. 3 - COMPOSITION / INFORMATION OF INGREDIENTS Chemical composition: methyl esters of vegetable oils: 70% w/v 4 - FIRST AID MEASURES · Inhalation: If inhaled, and exposure has been excessive, transfer the patient to fresh air. · Skin: Wash with soap and water. Wash contaminated clothing before reuse. · Eyes: Flush with water jets. Call a physician if irritation persists. · Ingestion: If small amounts enter through the mouth, rinse with water until no residual taste. Do not induce vomiting. Call your doctor right away if there were swallowed. 5 - MEASURES FIRE FIGHTING · Extinguishing Media: Water spray (fog), foam, dry chemical, carbon dioxide. · Specific control procedures: Wear self-contained breathing equipment. Use special protective clothing for firefighters. 6 - ACCIDENTAL RELEASE MEASURES · Locate the vehicle off the road and divert traffic. · Immediately notify Rizobacter Argentina S.A., Police and Fire. · Absorb with sawdust, wood chips or sand. · Collect all the material in polyethylene bags and advise Rizobacter Argentina S.A. 7 - HANDLING AND STORAGE · Personal Precautions: Observe normal precautions appropriate to handling pesticides. Page 1 of 3 · Storage: Store in a cool, dry, well ventilated, in its original container. 8 - EXPOSURE CONTROL / PERSONAL PROTECTION Safety glasses, gloves, PVC, rubber boots, masks with filters certified (NIOSH) for respiratory protection and protective clothing. 9 - PHYSICAL AND CHEMICAL PROPERTIES · Physical appearance: EC (liquid) · Color: 106 C (Yellow) - Pantone Scale · Smell: Characteristic · Vapor Pressure: Not applicable · Melting point: Not applicable · Boiling point: Not applicable · Solubility in water at twenty degrees centigrade (20 ° C): Not applicable · Decomposition temperature: Flammable 4 ° Category - Flash point: 70 ° C 10 - STABILITY AND REACTIVITY Stability: Stable. Reactivity:Not reactive. 11- TOXICOLOGICAL INFORMATION · Inhalation: Slightly hazardous · Eyes: Minimally irritating · Skin: Not irritating · Ingestion: Risk of pulmonary aspiration if swallowed or vomited. · Acute toxicity - Oral LD 50:> 5,000 mg / kg - Category IV - Dermal LD 50:> 2,000 mg / kg - Category III - Inhalation LC 50 (4 hs):> 2.87 mg / L - Skin irritation: Not irritating - Skin Sensitization: not sensitizing DERMAL - Eye Irritation: Minimally irritating. · Subacute: NO · Chronic toxicity: NO · Mutagenicity: No mutagenic. 12 - ECOLOGICAL INFORMATION · Toxicity to fish:> 100 mg / L: PRACTICALLY NON-TOXIC · Toxicity to birds:> 2,000 mg / Kg: PRACTICALLY NON-TOXIC · Persistence in soil: Not applicable · Effect of control: Not applicable 13 - DISPOSAL CONSIDERATIONS Absorb spill with suitable material (sand, sawdust) and place in container for disposal. Disposal: using locally qualified specialist companies. Page 2 of 3 14 - TRANSPORT INFORMATION · ADG: Not classified as dangerous · IMDG: Not classified as dangerous · IATA: Not classified as dangerous 15 - REGULATORY INFORMATION Toxicity Classification as Legislation Argentina: Class IV - Product that usually is not hazardous. Green band (Key: Care) 16 - OTHER INFORMATION CONTACT IN CASE OF POISONING: · NATIONAL POISON CENTER - Hospital Nacional "Prof. Alejandro Posadas " President Illia and Marconi Av CP 1684 - El Palomar - Province of Buenos Aires TEL: 0-800-333-0160 (011) 4654-6648 (011) 4658-7777 Type of assistance: personal and telephone within 24 hours. · Toxicology Unit - Hospital de Niños "Dr. Ricardo Gutiérrez" Gallo 1330 CP 1425 - Ciudad Autónoma de Buenos Aires TEL: (011) 4962-2247 / 6666 Type of assistance: personal and telephone within 24 hours. · T.A.S. - Toxicology Consulting and Services CP 1544 Tucumán 2000 - Rosario - Santa Fe Province of TEL: (0341) 424-2727 448-0077 Type of assistance: personal and telephone within 24 hours. · Toxicology Service - Hospital Escuela "José de San Martín" Paraguay 2201 CP 1120 - Ciudad Autónoma de Buenos Aires TEL: (011) 5950-8804 / 8806 Type of assistance: personal and telephone within 24 hours. · CIQUIME - Chemistry Information Center for Emergencies TEL: 0800-222-2933 (011) 4613-1100 Type of Assistance: Call 24 hours. · Toxicology Service - Municipal Emergency Hospital Catamarca 441 CP 5000 - Córdoba TEL: (0351) 4276200 Type of assistance: personal and telephone within 24 hours. COMMENTS: Rizobacter Argentina S.A. assumes no implicit or explicit responsibility for damages of any nature, arising from a use other than indicated on the product label and not recommended precautions have been observed or not to keep it under normal conditions of storage. Page 3 of 3