PRODUCT SAFETY DATA SHEET 1- PRODUCT AND COMPANY IDENTIFICATION Product: Rizo-oil M Chemical name: Soybean oil methyl esters CAS Number: not applicable (mixture) Type of product: Anti evaporation - Penetrating SENASA N°: 37.022 Manufacturer: Rizobacter Argentina S. A. Telephone No: 02477 – 409400 Fax Nº: 02477 – 432893 2- RISKS CLASSIFICATION Flammability: flammable, 3 class Toxicological classification: Class IV – Generally non-hazardous product 3- COMPOSITIÓN/INFORMATIÓN OF THE INGREDIENTS Chemical composition: Soybean oil methyl esters: 82 % 4- FIRST AID MEASURES Inhalation: If inhaled and exposure has been excessive, take the patient to fresh air. Skin: Wash with abundant water and soap. Wah the contaminated clothing before reusing. Eyes: Flush with water jets. Call a physician if irritation persists. Ingestion: Do not induce vomiting. Call a physician in case of ingestion. 5- FIREFIGHTING MEASURES Extinguishing media: water spray, regular foam, dry chemical, carbon dioxide. Specific control procedures: Use self contained breathing apparatus. Use special protective clothing for firefighters. Page 1 of 4 6- ACCIDENTAL RELEASE MEASURES Locate the vehicle off the road and divert traffic. Immediately notify Rizobacter Argentina S.A., Police and Firefighters. Absorb with sawdust, wood chips or sand. Collect all the material in polyethylene bags and inform Rizobacter Argentina S.A 7- HANDLING AND STORAGE Personal precautionary measures: Observe handling standard precautions appropriate for pesticide products. Storage: store in a fresh, dry and well ventilated place, in its original container. 8- EXPOSURE CONTROL/PERSONAL PROTECTION Wear safety glasses, pvc gloves, rubber boots, NIOSH approved filters mask for respiratory protection and proper protective clothing. 9- PHYSIC AND CHEMICAL PROPERTIES Physical appearance: EC (liquid) Color: 1235 C (translucient orange) – Pantone scale Odor: Characteristic Vapor pressure: It does not correspond Melting point: It does not correspond Boiling point: It does not correspond Solubility in water at 20°C: It does not correspond. Decomposition temperature: Flammable 3° Class – Flash point: 43°C 10- STABILITY AND REACTIVITY Stability: stable. Reactivity: non reactive. 11- TOXICOLOGICAL INFORAMTION Page 2 of 4 Inhalacion: Little hazardous Eyes: Minimally irritant Skin: Non irritant Ingestion: Pulmonary aspiration hazard, if swallowed or vomited. Acute toxicity - Oral DL 50: > 5.000 mg/Kg – Class IV - Dermal DL 50: > 4.000 mg/Kg – Class III - Inhalation LC 50: > 2,25 mg/L - Skin irritation: NON IRRITANT - Skin sensitization: NOT SENSITIZING - Eyes irritation: MÍNIMALLY IRRITANT. Subacute toxicity: NO Chronic toxicity: NO Mutagenicity: Non mutagenic 12- ECOLOGICAL INFORMATION Toxicity to fish: > 100 mg/L: PRACTICALLY NON TOXIC Toxicity to birds: > 2.000 mg/Kg: PRACTICALLY NON TOXIC Persistence in soil: It does not correspond Control effect: It does not correspond 13- DISPOSAL CONSIDERATIONS Absorb spill with suitable material (sand, sawdust) and place in container for disposal. Disposal: using locally qualified specialist companies. 14- TRANSPORT INFORMATION Land: No regulated by ADG Sea: Not regulated by IMDG Air: No regulated by IATA 15- REGULATORY INFORMATION Toxicity Classification as Legislation Argentina: Class IV - Product that usually is not hazardous. Green band (Key: Care) 16- OHER INFORMATION Contact in case of poisoning: NATIONAL POISON CENTER - Hospital Nacional "Prof. Alejandro Posadas " Page 3 of 4 Av. Presidente Illia y Marconi CP 1684 – El Palomar – Province of Buenos Aires TEL: 0-800-333-0160 (011) 4654-6648 (011) 4658-7777 Type of assistance: personal and telephone within 24 hours. Toxicology Unit - Hospital de Niños "Dr. Ricardo Gutiérrez " Gallo 1330 CP 1425 - Ciudad Autónoma de Buenos Aires TEL: (011) 4962-2247 / 6666 Type of assistance: personal and telephone within 24 hours. T.A.S. - Toxicology Consulting and Services CP 1544 Tucumán 2000 - Rosario - Santa Fe Province of TEL: (0341) 424-2727 448-0077 Type of assistance: personal and telephone within 24 hours. Toxicology Service - Hospital Escuela "José de San Martín" Paraguay 2201 CP 1120 - Ciudad Autónoma de Buenos Aires TEL: (011) 5950-8804 / 8806 Type of assistance: personal and telephone within 24 hours. CIQUIME - Chemistry Information Center for Emergencies TEL: 0800-222-2933 (011) 4613-1100 Type of Assistance: Call 24 hours. Toxicology Service - Municipal Emergency Hospital Catamarca 441 CP 5000 – Córdoba TEL: (0351) 4276200 Type of assistance: personal and telephone within 24 hours. OBSERVATIONS: Rizobacter Argentina S.A. assumes no implicit or explicit responsibility for damages of any nature, arising from a use other than indicated on the product label or if the recommended precautions have not been observed or if it was not kept under normal conditions of storage. Page 4 of 4