PRODUCT SAFETY DATA SHEET 1- PRODUCT AND COMPANY IDENTIFICATION Product: RizoCarb 50 Chemical name: not applicable CAS Number: not applicable (mixture) Type of product: Fungicide. Concentrate suspension. SENASA N°: 33.158 Manufacturer: Rizobacter Argentina S. A. Telephone No: 02477 – 409400 Fax No: 02477 – 432893 2- RISKS CLASSIFICATION Flammability: Not flammable (aqueous based suspension). Toxicological classification: Class III – Little hazardous product. 3- COMPOSITION/INFORMATIÓN OF THE INGREDIENTS INGREDIENT Carbendazim Moisturizing, dispersing and inert Nº CAS 10605 – 21 – 7 % 50 csp 100 4- FIRST AID MEASURES Inhalation: Lay the patient in a cold and fresh place to avoid heat loss. Skin: Wash with abundant water and soap the parts that have been in contact with the product. Eyes: Rinse with clean water for at least 15 minutes. Ingestion: Induce vomiting giving to drink water with salt. Symptomatic treatment. In all cases seek medical assistance immediately. 5- FIRE FIGHTING MEASURES Extinguishing media: water spray, regular foam, dry chemical, carbon dioxide. Specific control procedures: use self-contained breating apparatus. Use special protective clothing for firefighters. 6- ACCIDENTAL RELEASE MEASURES Page 1 of 4 Locate the vehicle off the road. Immediately notify Rizobacter Argentina S.A., Police and Firefighters. Absorb with sawdust, wood chips or sand. Collect all material in polyethylene bags and inform Rizobacter Argentina S.A. 7- HANDLING AND STORAGE Handling: avoid inhalation and skin contact. Storage: store in original container, in a ventilated, fresh and dry place and away from heat sources. 8- EXPOSURE CONTROL/PERSONAL PROTECTION Respiratory protection: Avoid inhalation. Protective gloves. 9- PHYSICAL AND CHEMICAL PROPERTIES Physical state: Concentrate suspension. Color / Odor:Chalk white opaque/putrid. Carbendazim melting point: > 266 º C Carbendazim vapor pressure: < 1.16 x 10- 4 Pa a 50 º C Solubility in water: It does not correspond. Decomposition temperature: Estable a STP 10- STABILITY AND REACTIVITY Stability: Stable. Reactivity: Not reactive. 11- TOXICOLOGICAL INFORMATION Acute in rats. DL50 = >3000 mg/Kg Acute dermal in rats. DL50 = >2000 mg.kg-1 Acute inhalation in rats. CL50 = Not available Primary irritation in rabbits skin: Slighyly irritant. Eye irritation in rabbits: Slightly irritant. Dermal sensitization in albino guinea pigs: Non sensitizing. 12- ECOLOGICAL INFORMATION Toxicity to birds: Practically non toxic. Toxicity in fish: Slightly toxic. Toxicity in bees: Virtually non toxic. Page 2 of 4 13- DISPOSAL CONSIDERATIONS Absorb spill with suitable material (sand, sawdust) and place in container for disposal. Disposal: using locally qualified specialist companies. 14- TRANSPORT INFORMATION Land (ADR-RID):UN N° 2902 Risk number: 60 Class: 6.1 Packaging type: III Air (ICAO/IATA):UN N° 2902 Risk number: 60 Class: 6.1 Packaging type: III Marítimo (IMDG):UN N° 2902 Risk number: 60 Class: 6.1 Packagung type: III 15- REGULATORY INFORMATION Toxicity classification according to Argentine legislation: III Little hazardous product. Blue color band (Legend: Careful) 16- OTHER INFORMATION NATIONAL POISON CENTER - Hospital Nacional "Prof. Alejandro Posadas " President Illia and Marconi Av CP 1684 - El Palomar - Province of Buenos Aires TEL: 0-800-333-0160 (011) 4654-6648 (011) 4658-7777 Type of assistance: personal and telephone within 24 hours. Toxicology Unit - Hospital de Niños "Dr. Ricardo Gutiérrez " Gallo 1330 CP 1425 - Ciudad Autónoma de Buenos Aires TEL: (011) 4962-2247 / 6666 Type of assistance: personal and telephone within 24 hours. T.A.S. - Toxicology Consulting and Services CP 1544 Tucumán 2000 - Rosario - Santa Fe Province of TEL: (0341) 424-2727 448-0077 Type of assistance: personal and telephone within 24 hours. Toxicology Service - Hospital Escuela "José de San Martín" Paraguay 2201 CP 1120 - Ciudad Autónoma de Buenos Aires TEL: (011) 5950-8804 / 8806 Type of assistance: personal and telephone within 24 hours. CIQUIME - Chemistry Information Center for Emergencies Page 3 of 4 TEL: 0800-222-2933 (011) 4613-1100 Type of Assistance: Call 24 hours. Toxicology Service - Municipal Emergency Hospital Catamarca 441 CP 5000 - Córdoba TEL: (0351) 4276200 Type of assistance: personal and telephone within 24 hours. OBSERVATIONS: Rizobacter Argentina S.A. assumes no implicit or explicit responsibility for damages of any nature, arising from a use other than indicated on the product label or if the recommended precautions have not been observed or if it was not kept under normal conditions of storage..