PRODUCT SAFETY DATA SHEET 1- PRODUCT AND COMPANY IDENTIFICATION Product: Rizospray Súper Chemical name: Not applicable CAS Number: Not applicable Use: Adjuvant Chemical composition: Monobranched fatty alcohol ethoxylated: 3% w/w Registration number SAGP y A - SENASA : 34709 Manufacturer: Rizobacter Argentina S. A. Telephone Nº: 02477 - 409400 Fax Nº: 02477 – 432893 2- RISKS CLASSIFICATION Flammability: Not flammable Toxicological information: Class IV – Generally non-hazardous product 3- PHYSICO-CHEMICAL PROPERTIES Physical state: Solid Color: Yellow Odor: Characteristic Relative density at 20 ºC: 1,128 g.cm3 pH: 4,8 Solubility in water at 20ºC: soluble 4- FIRST AIDS Skin: Wash with abundant water and soap the exposed parts. Eyes: Rinse with clean water for at least 15 minutes. Ingestion: Provide water and induce vomiting. Inhalation: Lay the patient down in a fresh place and avoid heat loss. In all cases provide medical assistance immediately; symptomatic treatment. Page 1 of 4 5- FIREFIGHTING MEASURES Extinguishing media: water spray, regular foam, dry chemical, carbon dioxide. Specific control procedures: Use self contained breathing apparatus. Use special protective clothing for firefighters. 6- HANDLING AND STORAGE Personal precautionary measures: Ventilation: storage area: general ventilation Work place: provide proper ventilation Respiratory protection: avoid inhalation Protective gloves: impermeable gloves (rubber, pvc) Storage: Store in a fresh, dry abd well ventilated place in its original container. 7- STABILITY AND REACTIVITY Stability: Stable under normal conditions. Reactivity: Non reactive. 8- TOXICOLOGICAL INFORMATION DL50 - Oral: > 2000 mg.Kg-1 (rat) DL50 - Dermal: > 2000 mg.Kg-1 (rat) CL50 - Inhalation: > 12,08 mg.L-1 (rat) Primary dermal irritation index: 0 (rabbit) – Non irritant product Eye irritation index: 6,66 (rabbit) – Minimally irritant product Dermal non-sensitizing (albino guinea pigs) 9- ECOTOXICOLOGICAL INFORMATION Page 2 of 4 Slightly toxic product to birds Practically non toxic product to fish Virtually non toxic product to bees 10- EMERGENCY ACTIONS Spillages: absorb the spill with suitable material (sand, sawdust) and place in container for disposal. Fire: Use extinguishers. Extinguish fire (downwind). Wear the protective equipment. Disposal: using locally qualified specialist companies. 11- TRANSPORT INFORMATION ONU Number. MERCOSUR agreement: Not classified product Land: Not classified product Air: Not classified product Sea: Not classified product 12 – OTHER INFORMATION Contact in case of poisoning: NATIONAL POISON CENTER - Hospital Nacional "Prof. Alejandro Posadas " President Illia and Marconi Av CP 1684 - El Palomar - Province of Buenos Aires TEL: 0-800-333-0160 (011) 4654-6648 (011) 4658-7777 Type of assistance: personal and telephone within 24 hours. Toxicology Unit - Hospital de Niños "Dr. Ricardo Gutiérrez " Gallo 1330 CP 1425 - Ciudad Autónoma de Buenos Aires TEL: (011) 4962-2247 / 6666 Type of assistance: personal and telephone within 24 hours. T.A.S. - Toxicology Consulting and Services CP 1544 Tucumán 2000 - Rosario - Santa Fe Province of TEL: (0341) 424-2727 448-0077 Type of assistance: personal and telephone within 24 hours. Toxicology Service - Hospital Escuela "José de San Martín" Paraguay 2201 CP 1120 - Ciudad Autónoma de Buenos Aires TEL: (011) 5950-8804 / 8806 Type of assistance: personal and telephone within 24 hours. CIQUIME - Chemistry Information Center for Emergencies TEL: 0800-222-2933 (011) 4613-1100 Type of Assistance: Call 24 hours. Toxicology Service - Municipal Emergency Hospital Catamarca 441 CP 5000 – Córdoba TEL: (0351) 4276200 Type of assistance: personal and telephone within 24 hours. Page 3 of 4 OBSERVATIONS: Rizobacter Argentina S.A. assumes no implicit or explicit responsibility for damages of any nature, arising from a use other than indicated on the product label or if the recommended precautions have not been observed or if it was not kept under normal conditions of storage. Page 4 of 4