Chemistry 2 Structure and bonding 1. What is ionic bonding? 2. Between which groups on the periodic table does it occur? 3. What does the receiver form? 4. What does the giver form? 5. How are they held together? 6. Give an example of a giant ionic lattice 7. Why is a lot of energy required to break up a giant ionic structure? 8. In the liquid state, molten or dissolved in water they can do what? 9. Complete this: solid ionic compounds are ….. in a …… They vibrate but ….. move around so ….. conduct …… 10. Complete this: ………. Ionic Compounds are where high ….. provide …. to overcome strong ….between ions. They can …… so ….. electricity 11. Ionic compounds in a …… separate away from the …… because of ….moleculees, enabling them to ……around the ……. 12. How are covalent bonds formed? 13. Between which groups does it occur? 14. What are simple molecules? Give three examples 15. Why don’t they conduct electricity? 16. What are giant covalent structures? 17. What is diamond? Describe its structure 18. What is graphite? Describe its structure? 19. What is silicon dioxide? 20. What are giant metallic structures? 21. why are they malleable? 22. What are alloys? 23. How do they affect the properties in terms of atoms? 24. How does liquid nitrogen cool metals? What can they be used for? 25. When did chemists discover carbon cages? 26. What are they called? 27. State three things that have been made up of (answer to 26) 28. What is nanoscience? 29. State four ways that nanoscience can be used to improve every day lives. 30. What are monomers? 31. How are low density polymers formed? 32. How are high density polymers formed? 33. What are thermosoftening polymers? 34. What are thermosetting polymers? Rates of Reaction 35. How can the rate of chemical reaction be found? 36. What equation can be use to represent this? 37. When do chemical reactions occur? 38. What is activation energy? 39. If the reactants produce a gas what happens to the mass? 40. What can measure the volume of gas evolved? 41. If a cloud precipitate is formed what is timed? 42. What will happen to particles if temperature is increased? 43. What will happen to particles if pressure increases? 44. What happens to collisions if there is an increase in surface area? 45. Draw a graph showing A) a farily slow reacition b) a quicker reaction but the same initial amounts c) more product and an increased rate 46. What are catalysts? 47. Give three examples of different catalysts used in industry – not enzymes. 48. What happens to the surroundings in an endothermic reaction? Why? 49. Give three examples of an endothermic reaction 50. What happens to the surroundings in an exothermic reaction? Why? 51. Give three examples of an exothermic reaction 52. Show a reversible reaction of copper sulphate Atoms and Quantitative Chemistry 53. What is a positive particle in an atom’s nucleus? What is its mass? 54. What is a neutral particle in an atom’s nucleus? What is its mass? 55. What is a negative subatomic particle in an atom’s energy shell called? What is its mass? 56. What is the atomic number? 57. What is the mass number? 58. What is meant by the relative atomic mass? 59. What are the relative atomic masses of a) hydrogen, b)helium, c)nitrogen, d)oxygen, d)iron 60. What is the relative formula/molecular mass of a compound? 61. What is the relative formula mass of ammonia? 62. What is a mole? 63. What is 1 mole of a) carbon, b)oxygen atom, c)iron, d)potassium, e)calcium, f)argon 64. What is half a mole of a)water, b)carbon dioxide, c)ammonia, d)potassium chloride? 65. What is the formula for working out the total number of moles? 66. What is the formula for working out the percentage of an element in a compound? 67. What is the formula for working out percentage yield? 68. What is meant by the term ‘isotope’ 69. Why isn’t it always possible to obtain calculated amounts? 70. What is the empirical formula? 71. Use the empirical formula to work out a) copper oxide, b)sodium hydroxide c)water 72. What is a reversible reaction? 73. What is gas chromatography? 74. How does it work? 75. Why do compounds in a mixture dissolve better than ones in a solvent? 76. What are the advantages and disadvantages of instrumental analysis? Acids and Alkalis 77. Give four examples of an acid 78. Give four examples of a base 79. Give three examples of neutral solutions 80. If a substance is dissolved in water what is it called? 81. What are soluble hydroxides known as? 82. What do acids form when added to water? 83. What do soluble hydroxides form when added to water? 84. Is pH higher further up the scale or lower? 85. Which indicator is used for showing this? 86. An acid + metal forms what? Give an example using magnesium chloride and hydrogen 87. An acid+base forms what? Give an example using sulphuric acid and magnesium oxide 88. An acid+alkali forms what? Give an example using nitric acid and sodium hydroxide 89. An acid+carbonate forms what? Give an example using hydrochloric acid and calcium carbonate 90. What do some acids and alkalis form when they react? 91. Ammonium nitrates are formed by what? 92. What are ammonia salts used for and how are they made? 93. If two solutions of soluble salts are added to water what is formed? 94. In the example lead nitrate + potassium iodide which are the isoluble salts? Electrolysis 95. What is electrolysis? 96. What are electrodes? 97. To which electrode does a) cation b)anion move to? Why? 98. Upon heating what happens to an ionic substance? 99. Why may products vary? 100. What is oxidation? Give an example 101. What is reduction? Give an example 102. In an aqueous solution if two elements can be produced at an electrode will the more reactive or less reactive element from? 103. At a positive electrode hydroxide ions are usually discharged to form what? 104. When is this not the case? 105. What is electroplating? 106. Why is it done? 107. Describe the process of manufacturing aluminium 108. What can sodium hydroxide and chlorine be used for? Chemistry 3 Periodic table 1. Who was John Dalton? 2. In which year did John Newlands build on Dalton’s ideas? 3. Why was Newland’s theory flawed? Give two reasons 4. Who was Dimitri Mendeleev and what did he do? 5. Whose idea is the modern periodic table based on? 6. How are they different? 7. How are elements organised? 8. What are group 1 elements known as? 9. What charged ions do they form? 10. What are their four properties? 11. Where are the transition elements found? 12. What are their densities like compared to group 1 elements? 13. What are their properties like compared to group 1 elements? 14. Give an example of a coloured compound 15. Which elements in this section can form different ions? 16. What are group 7 elements known as? 17. What charged ions do they form? 18. What are their four properties? Water 19. What does soft water form when combined with soap? 20. What does hard water form when combined with soap? 21. What is scale? 22. What is scum? 23. Do soapless detergents form scum and scale? 24. Which ions does hard water contain? 25. What is gypsum? 26. Is calcium carbonate soluble in water? 27. Is calcium carbonate soluble in slightly acidic water? 28. If these ions are removed what can soap form? 29. What else does hard water cause problems in? What are the effects? 30. What is temporary hardness? 31. How can it be removed? 32. Why can’t permanently hard water be softened by boiling? 33. How can it be softened? 34. What is ion exchange resin? 35. What are the advantages and disadvantages of hard water? 36. What does the solubility of a solute in water depend on? 37. What is a substances solubility? 38. What is wrong with drinking distilled water? 39. Describe the process of sedimentation 40. Describe the process of filtration 41. Describe the process of disinfection 42. What is a home filter jug used for? 43. Discuss the advantages and disadvantages of using fluoride ions in water treatment? Energy from Reactions 44. How can the relative amount of energy released when a substance burns be measured? 45. What does each letter stand for in the formula Q=MxCxΔT 46. How can energy transfer be reduced in a polystyrene cup? 47. In an exothermic reaction are products at a lower energy level than the surroundings or a higher energy level? Why? 48. In an endothermic reaction are products at a lower energy level than the surroundings or a higher energy level? Why? 49. Does a catalyst increase or decrease activation energy? 50. If energy change = Δproducts – Δreactants, work out the answer of N2 (g) + 3H2 (g) – 2NH3 (g) 51. What can be used as an alternative to fuel? 52. What can fuel cells be fed with to produce water and energy to power vehicles? 53. What needs to be matched to compare these fuels with petrol? Titrations 54. What are added together in a conical flask in a neutralisation reaction with phenolphthalein insulator? 55. Why is a biuret used? 56. 1dm3 = how many cm3? 57. What is the formula for the number of moles ina solution? 58. In which areas of industry are unknown substances needed to be analysed? Give at least three 59. What colour do the metal ions in a flame of a) lithium b) sodium c) potassium )d) calcium e)borium f)magnesium turn? 60. Precipitation reactions of sodium hydroxide turn a) aluminium ions b) calcium ions c) magnesium ions d) iron 2+ ions e) iron 3+ ions f) copper ions into what? 61. What do carbonate ions react with to form carbon dioxide? 62. Sulphate ions in……produce a ….. precipitate in ….. chloride in ……hydrochloric…… 63. Halide ions in a solution produce what with silver nitrates in the presence of what? what colour does a)silver chloride b)silver bromide c)silver iodide turn? 64. If the concentration of the reactant is unknown, how can the results be found out? Ammonia 65. What is equilibrium? 66. Where does equilibrium occur? 67. What is a closed system? 68. Are the reactions still taking place? 69. In a reversible reaction what does the position of equilibrium depend on? 70. If temperature is raised what will happen to the a)endothermic b)exothermic reaction yield? 71. If temperature is lowered what will happen to the a)endothermic b)exothermic reaction yield? 72. If pressure is raised will the reaction which produces less volume or more volume be encouraged? 73. If pressure is lowered will the reaction which produces less volume or more volume be encouraged? 74. What happens to a reaction if a catalyst is added? 75. What are the raw materials for the Haber process and how are they obtained? 76. What type of catalyst is needed for the Haber process? 77. What are the ideal conditions? 78. Do higher pressures favour the forward or backward reaction? 79. Why is pressure set as high as possible, but why is temperature not? 80. What is the problem with lower temperatures? 81. Why is 450® chosen? 82. What would happen to the reaction without the catalyst? Alcohols, esters and carboxylic acids 83. What is the general formula for the structure of an alcohol? 84. What are the first three homologous alcohols? 85. What are their properties? 86. They dissolve in water to form what? 87. How is ethanol produced and what is its most popular use? 88. Whare are methylated spirits used for? 89. If there is more ethanol in a fuel is there more or less pollution formed? 90. How can ethanol be oxidised? State two ways 91. What is the general formula for the structure of a carboxylic acid? 92. When dissolved in water they form what? 93. Why are they known as weak acids? 94. What is the difference between strength and concentration? 95. What can carboxylic acids with longer chains form? 96. How are esters formed and what is their functional group? 97. What are their properties? 98. Complete this example: ethanol+ethanoic acid - …. 99. What are they commonly used for? 100. Why do some esters cause ethical issues?