CH 115 Fall 2014 Mock Exam 2 Multiple Choice 1. Aluminum (III) sulfite is an ionic compound. What is the correct way to represent the formula of this compound? a). AlSO3+ b). Al(SO3)2c). Al3+SO32d). Al2(SO3)3 e). Al7(SO3)11 2. VSEPR theory serves to do which of the following? a). To minimize electron-pair collisions b). To minimize electron-pair repulsions c). To maximize electron-pair collisions d). To maximize electron-pair repulsions 3. In the best possible Lewis structure for carbonic acid (H2CO3), which of the following is true? I. The carbon is sp3 hybridized. II. Each of the oxygen atoms has tetrahedral electronic geometry. III. The orbitals that form the sigma bond between the O and H are 1s and sp3. a). I only b). II only c). I and II only d). III only e). I, II, and III 4. The electronic and molecular geometries, respectively, for XeF4 are a). trigonal bipyramidal, square planar b). octahedral, square pyramidal c). octahedral, square planar d). tetrahedral, tetrahedral 5. What is the formal charge on the central atom in the best Lewis structure of ClO4-? a). +3 b). +2 c). 0 d). -1 6. How many resonance structures are possible for the nitrite ion? a). 1 b). 2 c). 3 d). 4 e). 5 CH 115 Fall 2014 Mock Exam 2 7. What is the predicted O-N-O bond angle in the nitrate ion? a). 109.5o b). 45o c). 90o d). 180o e). 120o 8. Acetic acid, CH3COOH, has ____ sigma bonds and _____ pi bonds. a). 1,7 b). 2,6 c). 6,2 d). 7,1 e). 8,0 9. Which of the following trends in electronegativity is correct? a). B>C>N>O>F b). F>Cl>Br>I>At c). Tl>In>Ga>Al>B d). Al>Si>P>S>Cl 10. In the compound CS2, the carbon-sulfur bonds are ____________ and the molecule has a net _______ dipole moment. a). Nonpolar, zero b). Nonpolar, non-zero c). Polar, zero d). Polar, non-zero 11. Which of the following intermolecular interactions are present in CH3CN? I. London dispersion forces II. Dipole-dipole forces III. Hydrogen bonds a). I only b). II only c). I and II only d). I and III only e). I, II, and III 12. How many atoms of carbon are there in 0.56 moles of ethanol (CH3CH2OH)? OMIT a). 3.4 x 1023 b). 6.7 x 1023 c). 9.3 x 10-25 d). 1.9 x 1022 CH 115 Fall 2014 Mock Exam 2 13. For which of the following molecules/ions does the oxygen atom have the positive end of the dipole moment? a). H2O b). NO2 c). OF2 d). OHShort Answer 14. Answer the following questions pertaining to the figure below. Lone pairs and all carbon atoms may not be shown. CH3 N NH NH O a). How many sigma bonds and pi bonds are present? 15 sigma, 2 pi b). What is the hybridization and electronic geometry of the oxygen atom? Sp2, trigonal planar c). How many of the atoms in this molecule are sp2 hybridized? 4 15. Fill in the table below. Name Arsenic trichloride Aluminum oxalate 2,3,6-trimethyloctane Copper (II) nitride CH3 H3 C H3 C What is the name of this line structure? 4-ethylheptane Formula AsCl3 Al2(C2O4)3 C11H24 Cu3N2 C9H20 Ionic or Molecular? molecular Ionic Molecular Ionic molecular CH 115 Fall 2014 Mock Exam 2 16. Draw all the possible Lewis structures for each of the following molecules or ions. Indicate the bond angles around the central atom and the formal charge of the central atom for each structure. a). H2SeO3 less than 109.50, formal charge = +1 b). SO42- 109.50, formal charge = +2