SUPPLEMENTARY INFORMATION Supplementary Table 1: Compiled literature and cruise collected δ13CPOC values Name Year Month Ocean Type of Sample Reference Sackett, 1965 1964 Apr-Jun Pacific and Atlantic Plankton net [W M Sackett et al., 1965] Degens, 1968 1966 Apr Pacific Plankton net [E T Degens et al., 1968] Eadie Jeffry, 1973 1967-71 all months Southern Filter Fontugne Duplessy 1978 1976 Jun-Jul Indian Plankton net [B J Eadie and L M Jeffrey, 1973] [M Fontugne and J C Duplessy, 1978] Fisher 1997 1978 Sept-Nov Atlantic Plankton net [G Fischer et al., 1997] Fontugne Duplessy 1981 1977 Jul N. Atlantic, Indian Plankton net [M R Fontugne and J C Duplessy, 1981] Jeffrey 1983 1979-80 Apr-May, Feb-Mar Pacific and Atlantic Filter [A W A Jeffrey et al., 1983] Rau 1982 ? ? ? Filter [G H Rau et al., 1982] Wada 1987 1983-84 Dec-Jan Southern Filter [E Wada et al., 1987] Rau 1989 1989 Apr-May Atlantic Filter [G H Rau et al., 1989] Rau 1991 1986 Mar-Apr Atlantic Filter [G H Rau et al., 1991] AMT3 1996 1996 Sept-Nov Atlantic Filter unpublished Popp 1999 1994 Jan Southern Filter [B N Popp et al., 1999] AMT18 2008 2008 Sept-Nov Atlantic Filter unpublished AMT19 2009 2009 Sept-Nov Atlantic Filter unpublished Icechaser 2010 2010 Jun-Jul N. Atlantic Filter unpublished References Degens, E. T., R. R. L. Guillard, W. M. Sackett, and J. A. Hellebust (1968), Metabolic fractionation of carbon isotopes in marine plankton—I. Temperature and respiration experiments, Deep Sea Research and Oceanographic Abstracts, 15(1), 1-9. Eadie, B. J., and L. M. Jeffrey (1973), δ13C analyses of oceanic particulate organic matter, Marine Chemistry, 1(3), 199-209. Fischer, G., R. Schneider, P. J. Müller, and G. Wefer (1997), Anthropogenic CO2 in Southern Ocean surface waters: evidence from stable organic carbon isotopes, Terra Nova, 9(Journal Article), 153-157. Fontugne, M., and J. C. Duplessy (1978), Carbon isotope ratio of marine plankton related to surface water masses, Earth and Planetary Science Letters, 41(3), 365-371. Fontugne, M. R., and J. C. Duplessy (1981), Organic carbon isotopic fractionation by marine plankton in the temperature range - 1 to 31oC, Oceanologica Acta, 4(1), 8590. Jeffrey, A. W. A., R. C. Pflaum, J. M. Brooks, and W. M. Sackett (1983), Vertical trends in particulate organic carbon 13C:12C ratios in the upper water column, Deep Sea Research Part A.Oceanographic Research Papers, 30(9), 971-983. Popp, B. N., et al. (1999), Controls on the carbon isotopic composition of Southern Ocean phytoplankton, Global Biogeochemical Cycles, 13(4), 827-843. Rau, G. H., R. E. Sweeney, and I. R. Kaplan (1982), Plankton 13C:12C ratio changes with latitude: differences between northern and southern oceans, Deep Sea Research Part A.Oceanographic Research Papers, 29(8), 1035-1039. Rau, G. H., T. Takahashi, and D. J. D. Marais (1989), Latitudinal variations in plankton [delta]13C: implications for CO2 and productivity in past oceans, Nature, 341(6242), 516-518. Rau, G. H., P. M. Froelich, T. Takahashi, and D. J. Marais (1991), Does sedimentary organic delta 13C record variations in quaternary ocean [CO2(aq)]?, Paleoceanography, 6(3), 335-347. Sackett, W. M., W. R. Eckelmann, M. L. Bender, and A. W. H. Bé (1965), Temperature Dependence of Carbon Isotope Composition in Marine Plankton and Sediments, Science, 148(3667), 235-237. Wada, E., M. Terazaki, Y. Kabaya, and T. Nemoto (1987), 15N and 13C abundances in the Antartic Ocean with emphasis on the biogeochemical structure of the food web, Deep Sea Research Part A. Oceanographic Research Papers, 34(5-6), 829-841.