AP Chemistry Semester Final Item Analysis Multiple Choice- 30 MC Questions. 2 Points each. Hybridization- identifying hybridization given a structure Lewis structures- VSEPR geometry with exceptions to octet rule Determine sigma and pi bonds given structures Writing Mass Action Expressions- Keq ICE tables to determine equilibrium concentrations from initial concentrations Le Chatelier’s Principle- concentration, temp, pressure, Keq Graphically interpret what happens when a stress is applied to a reaction at equilibrium What happens to rate when concentration changes based on rate law Boltzman’s distribution and the relationship b/w kinetic energy and activation energy Reaction mechanisms- identifying catalysts and intermediates Rate determining step- what is it? How is it identified? Labeling reaction coordinates Reaction coordinates- difference b/w endothermic and exothermic reactions Determine molar solubility from the solubility of one of the ions of a compound Determine the Ksp if given the molar solubility of a compound Net ionic equations of ppct reactions Common Ion- identify which ions will shift the equilibrium of a dissolution equation Identify the solubility product expression for a dissolution equation AP Chemistry Semester Final Item Analysis Multiple Choice- 30 MC Questions. 2 Points each. Hybridization- identifying hybridization given a structure Lewis structures- VSEPR geometry with exceptions to octet rule Determine sigma and pi bonds given structures Writing Mass Action Expressions- Keq ICE tables to determine equilibrium concentrations from initial concentrations Le Chatelier’s Principle- concentration, temp, pressure, Keq Graphically interpret what happens when a stress is applied to a reaction at equilibrium What happens to rate when concentration changes based on rate law Boltzman’s distribution and the relationship b/w kinetic energy and activation energy Reaction mechanisms- identifying catalysts and intermediates Rate determining step- what is it? How is it identified? Labeling reaction coordinates Reaction coordinates- difference b/w endothermic and exothermic reactions Determine molar solubility from the solubility of one of the ions of a compound Determine the Ksp if given the molar solubility of a compound Net ionic equations of ppct reactions Common Ion- identify which ions will shift the equilibrium of a dissolution equation Identify the solubility product expression for a dissolution equation Free Response- Address 3 out of 5 FR. 15 points each. I. Bonding/ Lewis Structures/Intermolecular forces Draw Lewis Structures for organic compounds ID Structural Isomers of an organic molecule Intermolecular forces comparison for different organic compounds Hybridization given a structure Bond angles based on hybridization present II. Kinetics Write a rate law expression from data Calculate rate constant Rate of formation or consumption a specific substance within a reaction Rate mechanism based on reaction mechanism Kinetics Rate law from data Rate constant with units Determine the initial rate of disappearance based on rate law Calculate initial concentration of a substance given rate law Equilibrium Mass action expression/ equilibrium constant expression Calculate equilibrium concentrations using ICE table Calculate equilibrium constant Le Chatelier’s Principle Factors that increase yield based on Le Chatelier’s Principle Equilibrium Mass action expression Determine equilibrium concentrations using an ICE table Reaction quotient (Q) calculation- determine the direction the reaction is heading III. IV. V. Free Response- Address 3 out of 5 FR. 15 points each. VI. Bonding/ Lewis Structures/Intermolecular forces Draw Lewis Structures for organic compounds ID Structural Isomers of an organic molecule Intermolecular forces comparison for different organic compounds Hybridization given a structure Bond angles based on hybridization present VII. Kinetics Write a rate law expression from data Calculate rate constant Rate of formation or consumption a specific substance within a reaction Rate mechanism based on reaction mechanism Kinetics Rate law from data Rate constant with units Determine the initial rate of disappearance based on rate law Calculate initial concentration of a substance given rate law Equilibrium Mass action expression/ equilibrium constant expression Calculate equilibrium concentrations using ICE table Calculate equilibrium constant Le Chatelier’s Principle Factors that increase yield based on Le Chatelier’s Principle Equilibrium Mass action expression Determine equilibrium concentrations using an ICE table Reaction quotient (Q) calculation- determine the direction the reaction is heading VIII. IX. X.