Ders Tanıtım Bilgileri (İngilizce) 1 DERS TANITIM BİLGİLERİ (İNGİLİZCE) Course Information Course Name Petroleum Refining Engineering Prequisites Course Language Course Type Mode of Delivery (face to face, distance learning) Learning and Teaching Strategies Instructor(s) Course Objective Learning Outcomes Course Content Code Semester CEAC 577 Autumn Theory Application (Hours/Week) (Hours/Week) 3 0 Laboratuary (hours/week) National Credit ECTS 0 3 7.5 English Elective Face to Face Lecture, Discussion, Question and Answer Department members To familiarize students with petrochemical processes to describe existing and innovative emerging technologies for the production of synthesis gas, olefins, aromatics and their derivatives including industrial polyolefins and polyesters. To apply fundamental chemical engineering knowledge to industrial processes, such as steam reforming, steam cracking and catalytic reforming etc. The course makes close references to TUPRAŞ and PETKIM Petrochemicals Co. operations as well as to mega-size applications in the Middle East Region. Depending on the interests of the participants, emphasis can be shifted to either (i) detailed chemistry and technology or (ii) engineering and design (including technology assesment and economic evaluation) of petrochemical processes including downstreaming. Explain the chemistry of petroleum and its characterization Teach principles of fractional distillation: Atmospheric and vacuum distillations Explain energy integration in a refinery: Pumparounds and side slips Explain the need for basic noncatalytic and catalytic conversion processes: Principles of heterogeneous catalysis Charges and products and yield estimation techniques of a refinery Explain thermodynamics of steam cracking of ethane and naphtha: Hot and cold sections of olefin plants Teach principles of catalytic reforming: Dual-site catalysis Teach principles of aromatics production, conversion and separation proceses Teach trends in downstream processing Teach use of process simulators (such as ASPEN Hysis) in refining and petrochemical plants Introduction to Petroleum Refining and Petrochemical Industries - Major refinery operations including conversions: “Chemical Refinery” concept - Overall view of first and second generation petrochemical intermediates September, 2014 (E.Alper) Ders Tanıtım Bilgileri (İngilizce) 2 manufacture: Principles of basic “building block” processes Steam Cracking and Olefins Production -Physicochemistry of the pyrolysis of saturated hydrocarbons (ethane and light straight run naphta) -Thermodynamic considerations -Kinetic characteristics -Steady state rate-based simulation of an industrial steam cracker by MATLAB -Effects of operating variables of steam cracking (from industry and by simulations) -Reaction temperature -Residence time -Hydrocarbon partial pressure and the role of steam -Analysis of kinetic severity factor (KSF) concept -Primary fractionation and separation and purification of cracked products Emerging Technologies for olefin production (such as methanol to olefins (MTO), partial oxidation, dehydrogenation, metathesis) Catalytic Reforming and Aromatics (BTX) Production -Physicochemistry of catalytic reforming -Modelling of reforming reactions and principles of dual site catalysis -Thermodynamic and kinetics considerations -Industrial catalytic reforming and main types of installation -Operating conditions -Average reforming performance concept (UOP factor) C8 aromatics -Separation -Isomerisation -Hydrodealkylation and disproportination Aromatics from pyrolysis gasoline and other sources Aromatics production from lower alkanes (Z-forming) Steam Reforming and related processes -Thermodynamics and kinetics of reforming and shift reactions -Hydrogen, synthesis gas, methanol production and their derivatives -Industrial CO2 removal References Ethylene Derivatives Propylene Derivatives C4 olefins derivatives Benzene derivatives Toluene and Xylene derivatives Textbook: Course notes with problems and exercises will be distributed which are based on following references. References: 1. A.Chauvel and Gilles Lefebvre, Petrochemical Processes: Technical and Economic Characteristics, Vol.1: Synthesis Gas Derivatives and Major Hydrocarbons; Vol.2: Major Oxygenated, Chlorinated and Nitrated Derivatives, IFP Publications, Gulf Publishing Co.,TECHNIPS Edn., (1989). 2. Peter Wiseman, Petrochemicals, UMIST Series in Science and technology, John Wiley & Sons (1986). September, 2014 (E.Alper) Ders Tanıtım Bilgileri (İngilizce) 3 3. The Chemistry of Methane, Ethylene,Propylene, C4 Olefins,Benzene, Toluene Xylenes, Workshop Notes, CHEM SYSTEMS (1999). 4. Bilsen Beşergil, Hampetrolden Petrokimyasallara: El Kitabı, Tükelmat A.Ş.,İzmir (2007). 5. James H. Gary, Glenn E.Handwerk & Mark J.Kaiser, Petroleum Refining: Technology and Economics, Fifth Edn., CRC Press (2007). 6. T.Alsahaf and M.Fahim, Fundamentals of Petroleum Refining, Elsevier (2010) Weekly Course outline Weeks 1. Week 2. and 3. Weeks Topics Introduction to Petroleum Refining and Petrochemical Industries Steam Cracking and Olefins Production Pre-study Lecture Notes Lecture Notes 4. and 5. Weeks Catalytic Reforming and Aromatics (BTX) Lecture Notes Production 6. Week 7. and 8. Weeks MIDTERM I C8 aromatics -Separation -Isomerisation -Hydrodealkylation and disproportination Aromatics from pyrolysis gasoline and other sources Aromatics production from lower alkanes (Zforming) 9. and 10. Weeks Steam Reforming and related processes Lecture Notes 11. and 12. Weeks Ethylene Derivatives Propylene Derivatives C4 olefins derivatives Project Presentations-1 Benzene derivatives Toluene and Xylene derivatives Project Presentations-2 FINAL EXAMINATION Lecture Notes 13. Week 14. Week 15. Week 16. Week Assessment methods September, 2014 (E.Alper) Lecture Notes Lecture Notes Ders Tanıtım Bilgileri (İngilizce) Course Activities Number Percentage % 5 20 1 20 1 1 20 40 100 60 40 100 Attendance Laboratory Application (Quizzes) Field Activities Specific Practical Training (if any) Assignments Presentation Projects Seminars Midterm Final Exam Total Percentage of semester activities contributing grade success Percentage of final exam contributing grade success Total Course Category Core Courses Major Area Courses x Supportive Courses Media and Management Skills Courses Transferable Skill Courses Workload and ECTS Calculation Activities Number Duration (Hours) Total Work Load Course Duration (x16) Laboratory Application (Quizzes) Specific practical training (if any) Field Activities Study Hours Out of Class (Preliminary work, reinforcement, ect) Presentation / Seminar Preparation Projects Homework assignment Midterm ( Study duration ) Final ( Study duration ) Total Workload 16 3 48 16 3 48 1 1 2 1 1 20 20 15 18 40 20 20 30 18 40 224 September, 2014 (E.Alper) 4 Ders Tanıtım Bilgileri (İngilizce) 5 Matrix of the Course Learning Outcomes Versus Program Outcomes Program Outcomes 1. An ability to access, analyze and evaluate the knowledge needed for the solution of advanced chemical engineering and applied chemistry problems. 2. An ability to self-renewal by following scientific and technological developments within the philosophy of lifelong learning. 3. An understanding of social, environmental, and the global impacts of the practices and innovations brought by chemistry and chemical engineering. 4. An ability to perform original research and development activities and to convert the achieved results to publications, patents and technology. 5. An ability to apply advanced mathematics, science and engineering knowledge to advanced engineering problems. 6. An ability to design and conduct scientific and technological experiments in lab- and pilot-scale, and to analyze and interpret their results. 7. Skills in design of a system, part of a system or a process with desired properties and to implement industry. 8. Ability to perform independent research. 9. Ability to work in a multi-disciplinary environment and to work as a part of a team. 10. An understanding of the professional and occupational responsibilities. 1: Lowest, 2: Low, 3: Average, 4: High, 5: Highest September, 2014 (E.Alper) Contribution Level* 1 2 3 4 5 x x x x x x x x x x