NOMENCLATURE OF INORGANIC COMPOUNDS OBJECTIVE: Students will be able to correctly write formulas for, and name, inorganic compounds. As we cover nomenclature, we will follow a progression. As you master each of the skills listed below, check it off. Note that only the last two apply to covalent compounds. Memorization of the polyatomic and metal ions (“Flashcard Central”) Charges of simple monatomic ions (using the Periodic Table) “All compounds are ___________________ ____________________.” Formulas of simple ionic compounds (Metal ions limited to: group 1, group 2, Al+3, Zn+2, and Ag+1) Naming simple ionic compounds Naming other metal ions (Stock system, etc.) Determining the charge of metal ions in compounds (simple oxidation numbers) Nomenclature including all metal ions Nomenclature with polyatomic ions The “-ite” ions The “hydrogen _____________” ions Oxidation numbers Nomenclature of acids The seven diatomic elements Prefixes used in naming covalent compounds Nomenclature of covalent compounds FORMULA WRITING AND COMPOUND NAMING 1. Atoms of oxygen have ___ valence electrons. To be stable, these atoms must have ___ valence electrons. Therefore, atoms of oxygen will _____________ ___ electrons, forming oxide ions. Oxide ions have a charge of ___ because they have _____________ ___ electrons. Atoms of sodium have ___ valence electrons. To be stable, these atoms must have ___ valence electrons. Therefore, these atoms _____________ ___ electrons, forming ions. These ions have a charge of ___ because they have ___________ ___ electrons, and are called ______________ _____. Atoms of calcium have ___ valence electrons. To be stable, these atoms must have ___ valence electrons. Therefore, these atoms _____________ ___ electrons, forming ions. These ions have a charge of ___ because they have ___________ ___ electrons, and are called ______________ _____. Atoms of fluorine have ___ valence electrons. To be stable, these atoms must have ___ valence electrons. Therefore, these atoms _____________ ___ electrons, forming ions. These ions have a charge of ___ because they have ___________ ___ electrons, and are called ______________ _____. 2. Write the electron dot structure for the following atoms: Na S F Mg Cl N 3. Write the electron dot equations to form the following ions: A. O-2 B. Br-1 C. Ca+2 4. Write the symbols and charges for the following ions: A. oxide ion _______ B. chloride ion _______ C. sodium ion _______ D. bromide ion _______ E. calcium ion _______ F. aluminum ion _______ G. phosphide ion _______ H. sulfide ion _______ 5. Name the following ions: A. O-2 B. Br-1 C. Ca+2 D. F-1 E. P-3 F. Al+3 G. Na+1 H. S-2 6. ALL COMPOUNDS ARE ______________________________!!!!!!! 7. Indicate whether each of the following is a correct formula for a compond, THEN EXPLAIN!. A. NaCl B. CaBr C. Na2S D. AlF2 E. Ca3N2 F. MgO 8. Write the correct formulas for the following compounds: A. potassium fluoride B. lithium oxide C. strontium iodide D. aluminum sulfide E. zinc phosphide F. calcium oxide G. magnesium nitride NOMENCLATURE A (complete after #8) REMEMBER: All compounds are __________________ _________________!!!!! 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23* 24* 25* barium chloride sodium oxide calcium sulfide Aluminum bromide lithium carbide Potassium phosphide Strontium nitride sodium iodide Aluminum oxide barium carbide sodium sulfide francium nitride Aluminum chloride lithium phosphide Potassium fluoride Strontium iodide sodium sulfide Aluminum fluoride lithium selenide Potassium carbide lithium nitride cesium sulfide iron(III) chloride lithium carbonate nickel(II) sulfate 9. Write the symbols and charges for the following ions: A. iron (II) ion _______ B. copper (I) ion _______ C. zinc ion _______ D. lead (IV) ion _______ E. chromium (III) ion _______ F. mercury (II) ion _______ G. gold (I) ion _______ H. titanium (IV) ion _______ 10. Name the following ions: A. Co+2 B. Ba+2 C. Sr+2 D. Fe+3 E. Pb+4 F. Al+3 G. Ni+2 H. U+3 11. Name the following componds: A. LiCl B. ZnBr2 C. Cu2S D. AlF3 E. Co3N2 F. CaO G. TiO2 H. CuS I. ScF3 J. Sn3P2 K. MoCl3 L. MnO2 12. Write the correct formulas for the following compounds: A. potassium chloride B. lithium nitride C. iron(III) iodide D. iron(III) nitride E. copper(I) phosphide F. osmium(III) oxide G. Tin(II) sulfide H. copper(II) selenide I. bismuth(III) nitride 13. Name the following compounds: A. LiOH B. Zn(NO3)2 C. Cu2SO4 D. NH4F E. CaCO3 F. CuSO4 G. Mg(CN)2 H. Pb(CH3COO)2 I. NH4OH J. AgOH K. Ni(NO3)2 L. Na2SO4 M. NH4Cl N. FeSO4 O. Mg(OH)2 P. Cr(CH3COO)3 Q. MoS2 R. Cr2(SO4)3 14. Write the correct formulas for the following compounds: A. potassium nitrate B. lithium carbonate C. iron(III) hydroxide D. iron(II) hydroxide E. copper(I) phosphate F. ruthenium(III) oxide G. Tin(II) sulfate H. cobalt(III) nitride I.chromium(III) cyanide J. iron(II) acetate K. copper(II) sulfate L. ammonium carbonate M. chromium(III) oxide N. Tin(IV) sulfide O. chromium(II) sulfate P. gold(I) cyanide Q. lead(II) acetate R. copper(I) sulfate S. ammonium hydroxide T. ferrous nitrate U. uranium(V) oxide 15. The “-ite” ions. general rule: Complete the following examples, then write the ___________ sulfate ion ___________ nitrate ion ___________ sulfite ion ___________ nitrite ion General rule: 16. Additional examples: __CLO3-1___ chlorate ion ___________ phosphite ion ___________ chlorite ion 17. The “hydrogen ___________” ions. The hydrogen ion (_______) important in acid/base chemistry. These positive ions will often negative ions. If this forms a neutral molecule, it is an ACID. though, we also want to discuss the formation and naming of other is very join with Here ions. For instance, sulfate ions (_______) can join singly with hydrogen ions (______), to form “hydrogen sulfate ions” (__________). OR, phosphate ions (_______) can join with two hydrogen ions (______), to form “dihydrogen phosphate ions” (__________). 18. Additional examples: hydrogen carbonate ion _________ 19. hydrogen phosphate ion_________ Name the following compounds: A. KHCO3 B. Na3PO3 C. CuHSO3 20. Write the formulas: A. Calcium nitrite B. Magnesium hydrogen carbonate C. lithium sulfite NOMENCLATURE C Name______________________________Date___________Pd.______ NAME FORMULA NAME FORMULA Sulfuric acid _________ Calcium acetate _________ Chromium (II) fluoride _________ Nitric acid _________ Lead (II) iodide _________ Potassium peroxide _________ Antimony (III) chlorate _________ Copper (I) oxide _________ Mercury (I) sulfide _________ Ammonium phosphate _________ Iron (III) sulfate _________ Chromium (III) nitrate _________ Nickel (II) phosphide _________ Antimony (V) nitride _________ Barium nitride _________ Tin (II) hydrogen sulfate _________ Manganese (II) bromide _________ Magnesium phosphate _________ Cobalt (III) chlorite _________ Acetic acid _________ Sodium carbonate _________ _______________________ CuSO4 Hydrochloric acid _________ _______________________ Pb(ClO3)2 Zinc permanganate _________ _______________________ Sn(OH)2 Hydrogen cyanide _________ _______________________ Na2C2O4 Aluminum oxalate _________ _______________________ Ca(C2H3O2)2 Lithium hydride _________ _______________________ CrI3 Aluminum thiosulfate _________ _______________________ LiCN Ammonium dichromate _________ Potassium thiocyanate KSCN Copper (II) perchlorate _________ _______________________ Sb(NO3)3 Mercury (II) nitrate _________ _______________________ Mg3N2 Phosphoric acid _________ _______________________ FeCl3 Tin (IV) hypochlorite _________ _______________________ (NH4)2CO3 Cadmium (I) hydroxide _________ _______________________ AlPO4 Silver sulfite _________ _______________________ HgO Lead (II) sulfide _________ _______________________ BaCrO4 Formula Compound Name Formula Compound Name LiF aluminum chloride Na2O iron(III) nitrate SrTe ferric oxide Ag2S zinc sulfide Zn3P2 gold(I) bromide MoF2 strontium sulfide PbBr4 potassium arsenide CrP calcium carbide FeN manganese(IV) oxide MgCl2 radium oxide PbO cadmium(I) oxide BaI2 nickel(II) nitrate CsI tin(II) oxide TiO2 tin(IV) chloride Cu3P2 cupric oxide AlCl3 ferrous sulfide HgO ferric sulfide Hg2O chromium(III) oxide FeCl2 lead(IV) oxide FeCl3 barium chloride Co2O3 cupric fluoride MoS2 calcium nitride TlBr strontium selenide NaAt chromiium(II) iodide CaO manganese(II) sulfide CuO silver acetate Cs2O cobalt(II) sulfide Fe2O3 Fe3O4 NOMENCLATURE D FORMULA COMPOUND NAME FORMULA NaBr COMPOUND NAME sulfur hexabromide Li2O SF2 mercury(II) nitrate Cu(OH)2 strontium nitrite Cr(NO3)3 magnesium oxide MnP cobalt(II) sulfate tin(IV) oxide PbO2 NH4OH dinitrogen trioxide sulfuric acid Ag2 SO4 lead(II) acetate AlF3 SO2 Ca(CN)2 calcium hydroxide iron(III) cyanide phosphoric acid Na2SO3 hydrogen AgCH3COO potassium acetate RbNO2 Cl2O BH3 Fe(NO2)2 lithium sulfite carbon tetrachloride manganese(II) phosphate ammonium hydroxide Ba(C2H3O2)2 Li2SO3 Sn(OH)4 phosphorus pentachloride (NH4)2SO4 fluorine Hg2O sulfur trioxide MnCO3 chromium(III) phosphate oxygen silver carbonate K3PO4 NaHCO3 Co(NO3)2 NiI3 radium hydroxide cesium sulfate KCLO3 potassium chlorate potassium chlorite NOMENCLATURE E (as in "EXTRA") 1. Name the following componds: A. LiOH B. Zn(CN)2 C. H2S D.Al(NO3)3 E. CoCO3 F. CuO G. MnO2 H. Cu2SO3 I. PF3 J. P2O5 K. TlHCO3 L. SiO2 A. NiO B. Mn(NO3)2 C. Li2SO4 D. NH4Br E. CrCO3 F. CuSO3 G. Ni(CN)2 H. Pb(CO3)2 I. NH4OH J. P4O6 K. Mg(NO3)2 L. Na2S M. NH4Cl N. FeSO3 O. Bi(OH)3 P. Cr(CH3COO)3 Q. CH3COOH R. Cr2(SO4)3 S. HCl T. MnS2 U. H2CO3 V. HBr NOMENCLATURE F Write the correct formulas for the following compounds: A. potassium chloride B. lithium nitrite C. iron(III) phosphide D. cobalt(III) nitride E. copper(I) phosphate F.phosphorous triiodide G. Tin(II) sulfite H. copper(II) carbonate I. bismuth(III) sulfide 3. Write the correct formulas for the following compounds: A. potassium nitrate D. iron(II) oxide B. lithium carbonate E. triantimony pentanitride C. ruthenium(III) oxide F. copper(I) phosphate G. Tin(IV) sulfate H. cobalt(III) nitrite I. silicon (mono)carbide J. iron(II) acetate K. disulfur dichloride L. ammonium carbonate M. chromium(III) oxide N. Tin(IV) sulfide O. hydrobromic acid P. gold(III) selenide Q. lead(II) acetate R.manganese(II) carbonate S. iron(II) hydrogen sulfate T. sulfuric acid V. diphoshorous tetrahydride W. diphosphorous pentasulfide X. Titanium(II) hydride Y. phosphoric acid U. uranium(VI) fluoride Z. bismuth(III) sulfate CHEMISTRY -- COMPOUND STORY Each blank should be filled with the correct formula of the compound indicated directly after the blank. Two of the examples have already been completed. Make sure to include the correct subscripts! A long time Ag2O [silver oxide], on a cold winter _______ [nickel(II) telluride], I went for a walk. I bundled _____ [uranium(III) phosphide] in a ______ [cobalt(II) astatide] and ______ [hydrogen astatide], because it looked like ______ [tin(II) oxide]. As I ______ [tungsten(III) arsenide] walking along I saw a cat [ruthenium(II) nitride] under a porch. Behind it was a dog. [radium nitride] up to me. street. Ru3N2 When the dog saw me he _____ The dog followed me as I continued down the After I had walked several blocks I noticed that the dog was still following me. I liked him, so I decided to take him home. Just then I let out a big sneeze -- ____________ [gold(I) acetate]. When I got home I turned on a _______ [lithium telluride] and fired up the _______ [gallium arsenide] stove. The dog had curled up for a ______ [sodium phosphide], so I made myself a cup of hot _______ [cobalt(II) carbonate]. As I drank my cocoa I began making plans for the next day -- to buy a _______ [calcium germanide] and some ______ [aluminum phosphate], as well as a ______ [ruthenium(III) bromide] pork chop for the dog to play with. I also came up with a name for my new friend. My last thought as I nodded off to sleep that ______ [nickel(II) telluride] was to hope _____ [aluminum fluoride] didn't commit the big _______ [nobelium(I) nitrate] and ______ [plutonium(III) phosphate] on the carpet...