SCHEDULE I [See rule 2(c)(i), 4(1)(a), 4(2), 17 and 18] Indicative Criteria and List of Chemicals PART I (a) Toxic Chemicals: Chemicals having the following values of acute toxicity and which, owing to their physical and chemical properties, are capable of producing major accidents hazards. S.No. Degree of Medium lethal dose by Medium lethal dose by the Toxicity the oral route (oral dermal route (dermal toxicity) LD50 toxicity) LD 50 (mg/kg) (mg/kg) body weight body weight of test of test animals animals Medium lethal concentration by inhalation route (four hours) LC 50 (mg/l) inhalation on test animals 1 Extremely 1 - 50 toxic 1 - 200 0.1 - 0.5 2 Highly toxic 201 - 2000 0.5 - 2.0 51 - 500 (b) Flammable chemicals: (i) Flammable gases; chemicals which in the gaseous state at normal pressure and mixed with air become flammable and the boiling point of which at normal pressure is 20°C or below; (ii) highly flammable liquids: chemicals which have a flash point lower than 23°C and the boiling point of which at normal pressure is above 20° C; (iii) flammable liquids: chemicals which have a flash point lower than 65°C- and which remain liquids under pressure, where particular processing conditions, such as high pressure and high temperature, may create major accident hazards. (c) Explosives: Chemicals which may explode under the effect of flame, heat or photo-chemical conditions or which are more sensitive to shocks or friction than dinitrobenzene. PART II LIST OF HAZARDOUS AND TOXIC CHEMICALS Sl. No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 Name of the Chemical Acetone Acetone Cynohydride Acetyle Chloride Acetylene (Ethyne) Acrolein (2-Propenal) Acrylonitrile Aldicarb Aldrin Alkyl Phthalate Allyl Alcohol Allylamine Alpha Naphthyl Thiourea (Antu) Aminodiphenyl-4 Aminophenol-2 Amiton Ammonia Ammonium Nitrate Ammonium Nitrates in fertilizers Ammonium Sulfamate Anabasine Aniline Anisidine-p Antimony and Compounds Antimony Hydride (Stibine) Arsenic Hydride (Arsine) Arsenic Pentoxide, Arsenic (v) Acid, and Salts Arsenic Trioxide, Alsenious (iii) Acids and Salts Asbestos azinophos-Ethyl Azinphos-Methyl Banum Azide Benzene Benzidine Benzidine Salts Benzoquinone 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 Benzoyl Chloride Benzoyl Peroxide Benzyl Chloride Benzyl Cynide Beryllium (Powders Compound) Biphenyl Bis ( 2-Clzloromethyl ) Ketone Bis (2, 4, 6-Trinitrophynile) Amine Bis (2, Chloroethyle sulphide) Bis (Chloromethyl) ether Bis (tert-Butyl peroxy) Butane-2, 2 Bis (tert-Butyl peroxy) Cyclohexane-11 Bis-1, 2 Tribromophenoxy Ethane Bis phenol Boron and Compounds Bromine Bromine Pentafluoride Bromoform Butoadine Butane Butanethiol Butanone-2 Butoxy Ethanol Butyl Glycidal Ether Butyl Peroxy acetate, tert BUtyL Peroxyisobutyrate, tert Butyl Peroxyisopropyl Carbonate, tert Butyl Peroxymaleate, tert Butyl Peroxypivalate, tcrt Butyl Vinyl Ether Buty-n-Mercaptan Butylamine C-9, Aromatic Hydrocarbon Fraction Cadmium and Compounds Cadmium Oxide (fumes) Calcium Cynicde Captan Captofol 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 Carbaryl (Sevin) Carbofuran Carbon Disulphide Carbon Monoxide Carbon Tetrachloride Carbophenothion Cellulose Nitrate Chlorats (used in explosives) Chlordane Chlorfenvinphos Chlorinated Benzenes Chlorine Chlorine Di Oxide Chlorine Oxide Chlorine Trifluoride Chloromequal Chloride Chloroacetalchloride Chloroacetaldehyde Chloroanilin-2 Chloroaniline4 Chlorobenzene Chlorodiphenyl Chloropoxypropane Chloroethanol Chloroethyl Chloroformate Chorolfluorocarbons Chloroform Chloroformyl-4, Merpholine Chloromethane Chloromethyl Ether Chloromethyl Methyl Ether Chloronitrobenzene Chloroprene Chlorosulphonic Acid Chlorotrinitro benzene Chloroxuron Chromium and Compounds 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 Cobalt and Compounds Copper and Compounds Coumafuryl Coumaphos Coumateralyl Cresols Cumidine Cumene Cynophos Cynothoate Cyanuric Fluoride Cyclohexane Cyclohexanol Cyclohexane Cycloheximide Cyclopentadinene Cyclopentane Cyclotetramethylenetrinitramine Cyclotriethylene Trinitramine DDT Dicarbomodiphenyl Oxide Demeton Di-Isobutyl Peroxide Di n-Propyl Peroxydicarbonate Di-sec-Butyl Peroxydicarbonate Dalifos Mazodinitrophewl Diszomethane Dibenzyl Peroxydicarbonate Diehloroaeetylene Diehlorobenzene-0 Dichlorobenzene-2 Di-chloroethane Dichlorethyl Ether Dichlorophenol-2, 4 Dichlorophenol-2, 6 Dichlorophenoxy Acetic Acid, -2,4 (2,4-D) Dichloropropane-1, 2 Diehlorosalicylic Acid, -3,5 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 Dichlorovos (DDVP) Dicrotophos Dieldrin Diepoxybutane Diethyl Peroxydicarbonate Diethyl Glycol Dinitrate Diethylene Triarnine Diehyleneglycol Butyl Ether/Diethyleteglycol Butyl Acetate Diethylenetriarnine (DETA) Diglycidyl Ether Dihydroperoxypropane, -2,2 Diisobutyryl Peroxide Dimethoate Dimethyl Phosphoramidocynidic Acid Dimelhyl Phthalate Dimethylcarbonyl Dimethylnitrosamine Dinitrophenol, Salts Dinitroluene Dinitro-o-Cresol Dioxane Dioxathion Dioxalane Diphacinone Diphosphoramide Octamethyl Dipropylene Glycolmethylether Disulfoton Endosulfan Endrin Epiehlorohydrine EPN Epoxypropane, 1, 2 Ehion Ethyl Carbarnate f Ethyl ether Ethyl Hexanol, -2 Ethyl Mercaptan Ethyl Methacrylate 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 Ethyl Nitrate Ethylamine Ethylene Ethylene Chlorohydrine Ethylene Diamine Ethylene Dibromide Ethylene Dichloride Ethylene Glycol Dinitrate Ethylene Oxide Ethyleneimine Ethylthiocynate Fensulphothion Fluenetil Fluoro, -4,2-Hydroxybutyric Acid and Salts, Esters, Amides Fluoroacetic Acid and Salts, Esters, Amides Fluorobutyric Acid, -4, and Salts, Esters, Amides Fluorocrotonic Acid, -4, and Salts, Esters, Amides Formaldehyde Glyconitrite (Hydroxyacetonitrite) Guanyl, -1, 4 Nitrosaminoguanyl-1-Tetrazenc Heptachlor Haxachloro Cyclopentadiene Hexachlorocyclohexane Hexachlorocy cloamethane Hexachlorodibenzo-p-Dioxin, -1, 2, 3, 7, 8, 9 Hexafluoropropene Hexamethylphosphoramide Hexamethyl, -3, 3, 6, 6, 9, 9, -1, 2, 4, 5-Tetroxacyclononane Hexamethylenediamine Hexane Hexanitrosstibene, -2, 2, 4, 4, 6, 6, Hexavalent Chromium Hydrazine Hyrazine Nitrate Hydrochloric Acid Hydrogen Hydrogen Bromide (Hydrobromic Acid) Hydrogen Chloride (Liquified Gas) Hydrogen Cynide 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259 260 261 262 263 Hydrogen Fluoride Hydrogen Selenide Hydrogen Sulphide Hydroquinone Iodine Isobenzan Isodrin Isophorone Diisocynate Isopropyl Ether Juglone (5-Hydroxynaphthalene-1, 4-Dione) Lead (inorganic fumes & dusts) Lead 2, 4, 6 -Trinitroresorcinoxide (Lead Styphnate) Lead Azide Leptophos Lindane Liquified Petroleum Gas (LPG) Maleic Anhydride Manganese & Compounds Mercapto Benzothiawle Mercury Alkyl Mercury Fulminate Mercury Methyl Methacrylic Anhydride Methacrylonitrite Methacryloyl Chloride Methamidophos Methanesuphonyl Fluoride Methanethiol Methoxy Ethanol (2-Methyl Cellosive) Methoxy ethyl mercuric Acetate Methyl Acrylate Melhyl Alcohol Methyl Amylketone Methyl Bromide (Bromomethane) Methyl Chloride Methyl Chloroform Methyl Cyclohexene Methyl Ethyl Ketone Peroxide 264 265 266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 300 301 Methyl Hydrazine Methyl Isobutyl Ketone Methy Isobutyl Ketone Peroxide Mthyl Isocycnate Methyl Isothiocynate Methyl Mercaptian Methyl Methacrylate Methyl Parathion Methyl Phosphonic Dichloride Methyl-N, 2, 4, 6,-Trinitroaniline Methylene Chloride Methylenebis, -4, 4, (2-Chloroaniline) Methyltrichlcrosilane Mevinphos Molybdenum & Compounds N-Methyl-N, 2, 4, 6-N-Tetranitroanilin Naptha (Coal Tar) Naphthylamine, 2 Nickel & Compounds Nickel Tetracarbonyl Noitroaniline-O Nitroaniline-P Nitrobenzene Nitrochloroberizene-P Nitrocyclohexane Nitriothage Nitrogen.Dioxide Nitrogen Oxide Nitrogen Trifluoride Nitroglycerine Nitrophenol-P Nitropropane-1 Nitropropane-2 Nitrosodirnethylarnine Nitrotolune Octabrornophenyl Oxide Oleurn Oleylarnine 302 303 304 305 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 OO-Diethyl S-EthyIsulphonyImethyl phosbhorothioate OO-Diethyl S-Ethylthiornethyl Phosphorothioate OO-Diethyl S-Ethiomethyl'Phosphorathioate OO-Diethyl S-1sopropyliniornethyl Phosphorolithioate OO-diethyl S-Propylthiornethyl Phosphorodithioate Oxyarnyl Oxydisulioton Oxygen (Liquid) Oxygen Difluoride Ozone Paraoxon (Diethyl 4-Nitrophenyl Phosphate) Paraquat Parathion Parathion Methyl Paris green (Bis Aceto Hexametaatsinito Tetracopper) Pentaborane Pentabromodiphenyl Oxide Pentabromophenol Pentachloro Naphthalene Pentachloroethane Petachlorophenol Pentacrythritol Tetranitrate Pentane Peracetic Acid Perchloroethylene Perchlorornethyl Mercaptan Pentanone, 2,4-Methyl Phenol Phenyl Glycidal Ether Phenylene p-Diarnine Phenylmercury Acetate Phorate Phosacetim Phosalone Phosfolan Phosgene (Carbonyl Chloride) Phosmet Phospamidon 340 341 342 343 344 345 346 347 348 349 350 351 352 353 354 355 356 357 358 359 360 361 362 363 364 365 366 367 368 369 370 371 372 373 374 375 Phosphine (Hydrogen Phosphide) Phosphoric Acid and Esters Phosphoric Acid, Bromethyl Bromo (2,2-dimethylpropyl) Bromoethyl Ester Phosphoric Acid, Bromoethyl Bromo (2,2-Dimethylpropyl) Chlorethyethyl Ester Phosphoric Acid, Chlorocthyl Bromo (2,2-Dimethoxylpropyl) Chloroethyl Ester Phosporous & Compounds Phostalan Pircic Acid (2,4,6-Trinitrophenol) Polybrominaled Biphenyl Potassium Arsenite Potassium Chlorate Promurit (1-(3, 4-Dichlorophenyl)-3-Triazenethiocarboxamide) Propanesultone-1, 3 Propen,-1, 2-Chloro-1,3-Diol-Diacetate Propylene Dichloride Propylene Oxide Propyleneimine Pyrazoxon Selenium Hexafluoride Semicarbazide Hydrochloride Sodium Arsenite Sodium Azide Sodium Chlorate Sodium Cynide Sodium Picramate Sodium Selenite Styrene, 1, 1, 2, 2-Tetrachloroethane Sulfotep Sulphur Dichloride Sulphur Dioxide Sulphur Trioxide Sulphuric Acid Sulphoxide, 3-Chloropropyloctyl Tellurium Tellurium Hexafluoride Tepp Terbufos 376 377 378 379 380 381 382 383 384 385 386 387 388 389 390 391 392 393 394 395 396 397 398 399 400 401 402 403 404 405 406 407 408 409 410 411 412 413 Tetrabromobisphenol-A Tetrachloro, 2, 2, 5, 6, 2, 5-Cyclohexadiene-1, 4-Dione Tetrachlorodibenzo-p Dioxin, 2, 3, 7, 8 (TCDD) Tetraethyl Lead Tetrafluoroethane Tetramethylenedisulphotetramine Tetramethyl Lead Tetramnitromethane Thalium & Compounds Thionzin Thionyl Chloride Tirpate Toluene Toluidien-2, 4 Diisocynate Toluidiene-O Toluene 2, 6-Diisocynate Trans-1, 4-Chlorobutene Tri, -1 (Cyclohexyl) Stannyl-1H, 1, 2, 4-Trazole Triamino, -1, 3, 5, 2, 4, 6-Trinitrobenzene Tribromophenol, 2, 4, 6 Trichloro Acetyl Chloride Trichloro Ethane Trichloro Naphthalene Ttichloro (chloromethyl) Silane Trichlorodichlorophenylsilane Triochloroethane, l, l, l Trichloroethyl Silane Trichloroethylene Trichloromethanesulphenyl Chloride Trichlorophenol, 2, 2, 6 Trichlorophenol, 2, 4, 5 Triethylamine Triethylenemelamine Trimethyl Chlorosilane Trimethylopropane Phosphite Trinitroaniline Trinitroanisole, 2, 2, 4, 6 Trinolrobenzene 414 415 416 417 418 419 420 421 422 423 424 425 426 427 428 429 Trinitrobenzoic Acid Trinitrocresol Trinitrophenetole, 2, 4, 6 Trinitroesorcinol, 2, 4, 6 (Styphnic Acid) Trinitrotoluene Triorthocressyl Phosphate Triphenylin Chloride Turpenline Uranium & Compounds Vanadium & Compounds Vinyl Chloride Vinyl Fluoride Warfarin Xylene Xylidine Zinc & Compounds Zirconium & Compounds