Published as: Healy, M.G., Rodgers, M., Mulqueen, J. 2007. Performance of a stratified sand filter in removal of chemical oxygen demand, total suspended solids and ammonia nitrogen from high-strength wastewaters. Journal of Environmental Management 83: 409415. PERFORMANCE OF A STRATIFIED SAND FILTER IN REMOVAL OF CHEMICAL OXYGEN DEMAND, TOTAL SUSPENDED SOLIDS AND AMMONIA NITROGEN FROM HIGH STRENGTH WASTEWATERS M. G. Healy *, M. Rodgers, and J. Mulqueen Department of Civil Engineering, National University of Ireland, Galway. Ireland. *Corresponding author. Tel: +353 91 495364; Fax: +353 91 750507 E-mail: mark.healy@nuigalway.ie ABSTRACT A stratified sand filter column, operated in recirculation mode and treating synthetic effluent resembling high strength dairy wastewaters was studied over a 342 day duration. The aim of this paper was to examine the organic, total suspended solids (TSS) and nutrient removal rates of the sand filter, operated in recirculation mode, under incrementally increasing hydraulic and organic loading rates and to propose a field filter sizing criterion. Best performance was obtained at a system hydraulic loading rate of 10 L m-2 d1 ; a higher system hydraulic loading rate (of 13.4 L m-2 d-1) caused surface ponding. The system hydraulic loading rate of 10 L m-2 d-1 gave a filter chemical oxygen demand (COD), TSS, and TKN loading rate of 14, 3.7, and 2.1 g m-2 d-1, respectively, and produced consistent COD and TSS removals of greater than 99%, and an effluent NO3-N concentration of 42 mg L-1 (accounting for an 86% reduction in total nitrogen (Tot-N)). As the proportional surface area requirement for the sand filter described in this study is less than the recommended surface area requirement of a free-water surface (FWS) wetland treating an effluent of similar quality, it could provide an economic and sustainable alternative to conventional wetland treatment. 1 Keywords: Recirculating sand filters, dairy parlor wastewaters, forward flow, organic loading rate. 1. INTRODUCTION The disposal of dairy parlor washings is laborious and time-consuming and can lead to environmental problems such as eutrophication. Recently, natural treatment methodologies such as constructed wetlands have been used to treat farmyard effluent (Geary and Moore, 1999; Sun et al., 1999; Nguyen, 2000); however, their use is limited by the large amount of area required for treatment, as an organic loading rate of between 0.6 and 6 g biochemical oxygen demand (BOD) m-2 d-1 is recommended for free-water surface (FWS) wetlands treating dairy parlor wastewaters (Tanner and Kloosterman, 1997). Considering a farm with 100 dairy cows, with each cow producing approximately 50 L d -1 (Department of Environment and Department of Agriculture, Food, and Forestry, 1996) at 3000 mg BOD L-1, this would mean that an area of up to about 15,000 m2 would be required for adequate treatment. Intermittently loaded sand filters are proposed as an efficient and economic alternative to this treatment process and, when operated in recirculation mode, can produce an effluent which is low in organic and nutrient concentration. To date, research has mainly focused on the use of intermittent sand filters for the treatment of domesticstrength wastewater (Schudel and Boller, 1990; Gross and Mitchell, 1990; Gold et al., 1992; Nichols et al., 1997). Generally, these filters are designed and operated in accordance with the US EPA (1980) guidelines and have provided good organic carbon, total suspended solids (TSS) and nutrient removal rates. Research on the use of intermittent sand filters in the treatment of high-strength wastewaters is more limited. Liu et al. (1998, 2000, 2003) used sand filter columns to treat high-strength, synthetic wastewater containing detergent and milk fat. Liu et al. (2003) examined the performance of 3 laboratory sand filters, comprising either a 30.5 cm-deep fine sand (Column 1), a 30.5 cm-deep coarse sand overlying a 30.5 cm-deep fine sand (Column 2) or a 3-layer sand filter comprising pea gravel (30.5 cm) overlying 30.5 cm deep coarse sand over a 30.5 cm-deep fine sand (Column 3). With an average influent organic concentration of 2382 2 mg COD L-1, the build-up of organic matter and suspended solids caused the filters to fail after 253 days of operation under an organic loading rate of 106 g COD m-2 d-1. The organic, TSS, and nitrogen loading rates have a significant effect on the clogging and performance of a filter. A number of studies have investigated the filter performance under varying loading rates in an attempt to quantify the maximum organic, TSS, and nitrogen loading rates which can safely be applied to a filter (Darby et al., 1996). In a study of 12 shallow single-pass sand filters (0.38 m deep) treating domestic effluent, with four sets having the same effective grain size (d10) and uniformity coefficient (Cu), Darby et al. (1996) found that an organic loading rate in excess of 47 g COD m -2 d-1 (based on filter surface area) caused ponding on a sand filter with d10 of 0.29 mm. Although US EPA guidelines (US EPA, 1980) recommend an organic loading rate of approximately 34 g COD m-2 d-1 on the plan filter surface area for domestic wastewater treatment by recirculating sand filters, Loudon et al. (1985) and Christopherson et al. (2001) found that recirculating single layer sand filters receiving a filter COD loading rate of approximately 4 to 7 g COD m-2 d-1 appeared to be unable to adequately treat domestic effluents to acceptable standards (Table 1). Recirculating sand filters usually can operate with a recirculation ratio of up to 5:1, with no reduction in performance (Lamb et al., 1990; Crites et al., 1997). However, the C:N ratio in the recirculation tank appears to be the main factor in the system performance (Henze et al., 1997). Lamb et al. (1990) showed that, although a sand filter received a low organic loading rate (approximately 3 g COD m -2 d-1), only a 25% reduction in Tot-N occurred when the system was operated in recirculation mode. This was due to a low C:N ratio in the recirculation tank. Similar results were obtained by Gold et al. (1992). This paper examines the performance of a 0.9 m deep intermittent recirculating sand filter column treating influent synthetic wastewater resembling dairy parlor washings from a dairy farm in County Cork, Ireland (Table 2). The impact of cleaning agents and sanitizers, contained in dairy parlor wastewater, was not considered in this study. The hydraulic loading rate was increased by an initial factor of 1.5 and later 2.0 the original system loading rate, i.e., 6.67, 10.0 and 13.4 L m-2 d-1. The aim of this paper was to examine 3 the organic, total suspended solids (TSS) and nutrient removal rates of the sand filter, operated in recirculation mode, under incrementally increasing hydraulic and organic loading rates and to propose a field filter sizing criterion. The average water retention time within the columns for each of the modes of operation (excluding the loading rate at which surface ponding occurred) was also measured. Using a series of ceramic suction cups located at various depths throughout the column, NO3-N and NH4-N concentration profiles were measured during normal system operation and immediately prior to system failure. 2. MATERIALS AND METHODS The column used in this study was 0.9 m deep and 0.3 m in diameter and contained layers of stratified sand media, after Gross and Mitchell (1985), who obtained good removal efficiency with this design. Prior to operation, the column was seeded with 1 L of mixed liquor from the return flow of an activated sludge plant used for BOD removal and nitrification. The mixed liquor was applied in a single dose to the top of the filter column. In the column, a 100 mm layer of distribution gravel (10-20 mm in size) overlaid a 250 mm layer of coarse sand media (d10=0.45 mm) and two 150 mm layers of fine sand (d10=0.11 mm) which were separated from each other by 75 mm layers of pea gravel (10-20 mm in size). The bottom layer of sand was underlain by a 100 mm layer of pea gravel (10-20 mm in size). The column design and layout is illustrated in Figure 1. [Figure 1 here] In previous laboratory studies, due to the small diameter of the columns tested, replication was carried out (Gross and Mitchell, 1985, Pell and Nyberg, 1989a, b). However, due to the relatively large area of the sand filter used in this study (diameter = 0.3 m) replication was not employed; this is consistent with other studies using filters of similar dimensions (diameter=0.185 m; Castillo et al., 2001). The synthetic dairy wastewater was prepared daily with a composition as shown in Table 3 (Odegaard and Rusten, 1980). The synthetic wastewater was made up daily and was pumped in 4 doses each day to a 4 recirculation tank. The wastewater temperature ranged from 10oC – 12oC. 75% of the sand filter effluent, collected in a sump, was pumped back to the recirculation tank, and the mixed effluent was then applied to the sand filter via a spiral distribution manifold. This gave a recirculation ratio of 3:1. The peristaltic pump was operational for a period of 5 minutes per dose. Almost daily testing of the water quality parameters was carried out throughout the period of operation. Analysis was carried out on samples from the feed and recirculation tanks, and on the effluent water from the column. The water quality parameters measured were: COD (closed reflux, titrimetric method), Tot-N (persulfate method), ammonium-N (NH4-N) (ammonia-selective electrode method; NH 500/2, WTW, Weilheim, Germany), NO 3-N (nitrate electrode method; WTW, Weilheim, Germany), and TSS (total suspended solids dried at 103-105oC). All water quality parameters were tested in accordance with the Standard Methods (APHA-AWWA-WEF, 1995). The average water retention time within the column was determined using sodium bromide (NaBr) as a tracer (Levenspiel, 1999). The tracer was made up to 10 g L-1 concentration and applied as a pulse in one hydraulic loading interval to the sand filter using the peristaltic pump. A fraction collector (REDIFRAC, Amersham Pharmacia Biotech, Bucks, UK), positioned under the column, collected samples in timed increments. Fully saturated suction cups, positioned along the side of the filter column, were emptied of all de-aired water, and a suction of approximately 200 cm was applied to each cup using a syringe to allow the pore water to drain into the cups. This allowed NO3-N and NH4-N concentrations and the extent of nitrification along the depth of the filter column to be determined in each sand layer during a 6-hour period between wastewater applications under normal loading conditions and immediately prior to surface ponding. 3. RESULTS AND DISCUSSION Analysis of steady-state data was performed during system hydraulic loading rates of 6.67 (Rec. 1), 10 (Rec. 2) and 13.4 L m-2 d-1 (Rec. 3). During the final loading period (13.4 L m-2 d-1) surface ponding developed within 42 days of start-up and the analysis was terminated. 5 3.1 Nitrogen conversion and removal. Throughout the entire period of operation in recirculation mode, the average Tot-N concentration in the feed tank was 332 mg L-1 (Table 4). This was greater than the measured Tot-N concentration (Table 2) as it was difficult to approximate all water quality parameters fully. Using flow-averaged concentrations, the combined average Tot-N entering the recirculation tank (during recirculation modes 1,2, and 3) was 117 mg L-1 (representing a 63% reduction in Tot-N from the feed tank), of which inorganic-N composed 54 % of the influent Tot-N entering into the recirculation tank. NO 3-N comprised between 42 and 58% of the influent inorganic N into the recirculation tank during the three recirculation rates and influent NH 4-N averaged 30±8 mg L-1 and increased by 33% in the recirculation tank. This was consistent with a study by Piluk and Hao (1989). Due to the processes of cell synthesis, biological conversion and denitrification, Tot-N was reduced by between 48 and 52% in the recirculation tank, with N going to cell synthesis and denitrification. This may have resulted from the increased growth of microbial biomass in the recirculation tank. In the recirculation tank, mixed liquor total suspended solids averaged 1415±536 mg L-1 during Rec. 1, increasing to 2548±574 and 3675±433 mg L-1, respectively, for Rec. 2 and Rec. 3. Organic-N conversion within the recirculation tank was more pronounced at the higher loading rates than at the lower loading rates: a 65% organic-N conversion was measured during Rec. 1, versus a conversion of 82% for the higher hydraulic loading rates. Little variation was noted in the effluent inorganic N from the recirculation tank. An average effluent concentration of 45±6 mg L-1 was observed over the duration of the recirculation phase of the study and it was mainly composed of NH4-N. During Rec. 3, NO3-N was reduced from a combined average influent concentration of 23±2 mg L-1 entering the recirculation tank to 1 mg L-1 exiting the recirculation tank, with a co-existent dissolved oxygen (DO) reduction from a combined average of 8±1 mg L-1 to 0 mg L-1. 6 Nitrogen concentration profile measurements (Figure 2) taken in the sand filter column during Rec. 3 (25 days before surface ponding) indicated that nitrification was almost complete by the bottom of the coarse sand layer (350 mm from the surface of the column). Eight days before surface ponding, the development of anoxic conditions within the column meant that nitrification rates were attenuated, and full nitrification took longer to be completed (Figure 2). [Figure 2 here] 3.2 Chemical oxygen demand removal Over the duration of operation in recirculation mode, average total COD (CODT) in the feed tank was 3261±322 mg L-1 (2445±206 mg filtered COD (CODF) L-1). Using flow averaged concentrations, total and filtered COD entering the recirculation tank remained constant at 835±58 mg CODT L-1 and 641±54 mg CODF L-1 throughout the entire operation in recirculation. During the 3 hydraulic loading rates, wastewater effluent COD from the recirculation tank was 242±62 mg COD T L-1 (72% removal) during Rec. 1, 358±106 mg CODT L-1 (54% removal) during Rec. 2, and 339±59 mg CODT L-1 (58% removal) during Rec. 3. The filter achieved a CODT reduction in excess of 90% under all loading rates, producing an average total and filtered COD effluent concentration of 28±15 mg CODT L-1 and 21±12 mg CODF L-1, respectively. The decreasing average water retention time in the column from 6.7 days during Rec. 1 to 4.4 days during Rec. 2 did not appear to have a major effect on the performance of the column. 3.3 System performance and sizing. The best performance of the sand filter system used in this study occurred under system hydraulic and organic loading rates of 10 L m-2 d-1 and 30.4 g CODT m-2 d-1, respectively, with a recirculation ratio of 3 times the influent hydraulic loading rate (Table 5). This gave filter COD, TSS, and TKN loading rates of 7 14, 3.7, and 2.1 g m-2 d-1, respectively, for this wastewater and produced an 86% reduction in effluent TotN. Considering a farm with 100 cows, with each cow producing 50 L day -1 at, say, an organic concentration of 3000 mg COD L-1, this means that a sand filter with a surface area of 493 m2 would be required for the adequate treatment of dairy parlor washings. 4. CONCLUSIONS Analyses of a stratified sand filter column, operated in recirculation mode, over a period of 342 days show that it is capable of removing over 99% of COD, and 100% of TSS. By increasing the hydraulic loading on the column in gradual increments, the best performance occurred at a forward flow of 10 L m-2 d-1 with a 3:1 recirculation. This gave a Tot-N reduction of 86%. On the basis of measurements taken during Rec. 3, nitrification was complete by a depth of 350 mm from the filter surface. During this period of operation, the filter COD, SS, and TKN loading rates were 14, 3.7, and 2.1 g m-2 d-1 and, although the average water retention time in the filter reduced from a maximum of 6.7 days (Rec. 1, Table 5) to 4.4 days ( Rec. 2, Table 5), no adverse effect on removal performance was noted. A further increase in the forward flow hydraulic loading rate to 13.4 L m-2 d-1 produced surface ponding. A study using an intermediate hydraulic loading rate between 10 and 13.4 L m-2 d-1 to better individuate the optimum loading conditions is recommended. ACKNOWLEDGEMENTS The authors are grateful to Teagasc for the award of a Walsh fellowship to the first author and for financial support for the work. The authors acknowledge the technical help of M. Reidy (Teagasc, Moorepark), M. Rathaille, M. O’Brien and G. Hynes (NUI, Galway). 8 REFERENCES 1. APHA-AWWA-WEF, Standard Methods for the Examination of Water and Wastewater, (19th ed.) American Public Health Association. Washington. 2. Castillo, G., Mena, M.P., Dibarrart, F., Honeyman, G., Water quality improvement of treated wastewater by intermittent soil percolation. Wat. Sci. and Tech. 43 (2001) 187-190. 3. S.H. Christopherson, J.L. Anderson, D.M. Gustafson, Evaluation of recirculating sand filters in Minnesota., in: Karen Mancl (ed), On-Site Wastewater Treatment: Proceedings of the Ninth National Symposium on Individual and Small Community Sewage Systems, March 11-14, 2001 Ft. Worth, Texas. American Society of Agricultural Engineers, St. Joseph, Michigan USA, 2001, pp. 207-214. 4. R. 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Tuovinen, Effect of inoculation on the biodegradation of butterfat-detergent mixtures in fixed-film sand columns, Biores. Tech. 64 (1998) 27-32. 15. Q. Liu, K. Mancl, O.H. Tuovinen, High fat wastewater remediation using layered sand filter biofilm systems, in: Proceedings of the international symposium on animal, agricultural and food processing wastes, ASAE, St. Joseph, Michigan, 2000, pp. 242-248. 16. Q. Liu, K. Mancl, O.H. Tuovinen, Biomass accumulation and carbon utilization in layered sand filter biofilm systems receiving milk fat and detergent mixtures, Biores. Tech. 89 (2003) 275-279. 10 17. T.L. Loudon, D.B. Thompson, L. Fay, L.E. Reese, Cold climate performance of recirculating sand filters, Proceedings of the fourth national symposium on individual and small community sewage systems, New Orleans, LA. December 10-11, 1984. ASAE Publication 07-85, 1985, pp. 333-342. 18. L.M. Nguyen, Organic matter composition, microbial biomass and microbial activity in gravel-bed constructed wetlands treating farm dairy wastewaters, Ecol. Eng. 16 (2000) 199-221. 19. D.J. Nichols, D.C. Wolf, M.A. Gross, E.M. Rutledge, Renovation of septic effluent in a stratified sand filter, in M.S. Bedinger, J.S. Fleming, A.I. Johnson (eds), Site characterisation and design of on-site septic systems, ASTM STP 1324. American Society for Testing and Materials, 1997, pp. 235-247. 20. H. Odegaard, B. Rusten, Nitrogen removal in rotating biological contactors without the use of external carbon source, Proceedings of the first international symposium/workshop on rotating biological contactor technology, Champion, PA, 1980, pp. 1301-1317. 21. Pell, M., Nyberg, F., Infiltration of wastewater in a newly started pilot sand–filter system: I. Reduction of organic matter and phosphorus, J. Environ. Qual 18 (1989a) 451-457. 22. Pell, M., Nyberg, F., Infiltration of wastewater in a newly started pilot sand-filter system: III. Transformation of nitrogen, J. Environ. Qual. 18 (1989b) 463-467. 23. R.J. Piluk, O.J. Hao, Evaluation of on-site waste disposal system for nitrogen reduction, J. Env. Eng. Div. ASCE 115 (1989) 725-740. 24. P. Schudel, M. Boller, Onsite wastewater treatment with intermittent buried filters, Wat. Sci. and Tech. 22 (1990) 93-100. 11 25.G. Sun, K.R. Gray, A.J. Biddlestone, D.J. Cooper, Treatment of agricultural wastewater in a combined tidal flow-downflow reed bed system, Wat. Sci. and Tech. 40 (1999) 139-146. 26. C.C. Tanner, V.C. Kloosterman, Guidelines for Constructed Wetland Treatment of Farm Dairy Wastewaters in New Zealand, NIWA Science and Technology Series No. 48. Hamilton, New Zealand. 27. U.S. Environmental Protection Agency, Design Manual: Onsite Wastewater Treatment and Disposal Systems. EPA Report no. 625/1-80-012. Cincinnati, OH. 12 LIST OF FIGURES Figure 1. Layout of recirculating sand filter system. Single-pass operation excludes anoxic tank. Figure 2. NH4-N and NO3-N concentration profiles in the 0.9 m filter column during Rec. 3. 13 Table 1. Filter design and loading rates for recirculating sand filters. _________________________________________________________________________________________________________________________________ Reference Forward flowa Recirculation ratio COD L m-2 d-1 Filter mediab Filter loading rates TSS Comments TKN ________g m-2 d-1_______ _________________________________________________________________________________________________________________________________ Christopherson, et. 41 5:1 ~4 3.6 1.2 al., 2001 Single-layer filter Domestic effluent. Effluent unable d10 = 1.5-2.5mm; UC<2 to meet BOD5/TSS/fecal coliform standard. Crites et al., 1997 Loudon et al., 1985 EPA guidelinesc 9.6 42 120-200 5:1 4:1 3:1-5:1 ~2 ~7 34 <1 <3 2 0.3 5.8 7.7 Single-layer filter Domestic effluent. Effluent d10 = 3 mm; UC<2 treated to discharge standards. Single-layer filter Domestic effluent. Nitrification d10 = 0.3; UC=4 incomplete in filter. Single-layer filter d10 = 1.0-1.5; UC<4 a The forward flow is the hydraulic loading rate on the sand filtration system. b Filters comprise media with different uniformity coefficients (UC) and effective sizes (d 10) c US EPA (1980). Calculations based on a forward flow of 160 L m-2 d-1 at a recirculation ratio of 5:1, and with COD, TSS, and TKN concentrations in the recirculation tank of 35, 6 and 8 mg L-1 (data from Leverenz et al., 2000). 14 Table 2. Characteristics of wastewater from a dairy farm in Co. Cork, Ireland (mg L -1). ______________________________________________________________________________________ na CODTb Tot-N NH4-N NO3-N PO4-P TSS ______________________________________________________________________________________ Concentration 53 ± Std. deviation 2921 175.7 84.8 8.5 23.0 352.9 1395 66.3 62.3 12.5 6.8 457.4 ______________________________________________________________________________________ a Number of samples. b CODT = Total unfiltered COD. 15 Table 3. Composition of synthetic wastewatera ______________________________________________________________________________________ Component Amount (mg) ______________________________________________________________________________________ Glucose 14400 Yeast 2160 Dried Milk 8640 Urea 1620 NH4Cl 3500 Na2PO412H2O 5400 KHCO3 3600 NaHCO3 9360 MgSO4.7H2O 3600 FeSO4.7H2O 144 MnSO4.H2O 144 CaCl2.6H2O 216 Bentonite 2880 ______________________________________________________________________________________ a Dissolved in 6 litres, respectively, to give an organic concentration of approximately 3000 mg chemical oxygen demand (COD) L-1. 16 Table 4. Water quality parameter concentrations ( std. deviations) from the feed tank (FT), entering and exiting the recirculation tank (RT), and effluent from the sand filter (SF) for recirculation modes. ________________________________________________________________________________________________________________________________________________ Treatmenta Location System hy. loading CODTb CODFc Tot-N NH4-N NO3-N TSS DO rate L m-2 d-1 _______________________________ mg L-1 ________________________________ ________________________________________________________________________________________________________________________________________________ Rec. 1 FT 3510 (200) 2711 (181) 375 (25) 134 (15) 2 (1) 780 (154) 5 (2) 895 (50) 680 (55) 141 (12) 34 (4) 45 (5) 195 (38) 7 (1) Exiting RT 242 (62) 198 (49) 68 (5) 43 (5) 2 (1) 120 (47) 0 (0) SF 23 (13) 17 (11) 60 (12) 0 (0) 60 (6) 0 (0) 8 (2) 3045 (281) 2477 (270) 297 (20) 122 (25) 1 (1) 884 (137) 3 (3) Entering RT 785 (68) 619 (67) 106 (5) 28 (10) 32 (5) 221 (34) 8 (1) Exiting RT 358 (106) 284 (92) 54 (8) 43 (10) 1 (1) 92 (38) 0 (0) SF 34 (25) 24 (18) 42 (4) 0 (0) 42 (6) 0 (0) 9 (1) Entering RT Rec. 2 Rec. 3 6.67 d FT e Average FT 10 3228 (222) 2446 (167) 324 (15) 127 (6) 1 (0) 902 (108) 0 (0) Entering RT 13.4 826 (57) 623 (41) 104 (4) 29 (9) 23 (2) 225 (27) 8 (1) Exiting RT 339 (59) 283 (76) 53 (5) 44 (3) 1 (0) 57 (12) 0 (0) SF 27 (8) 22 (7) 30 (3) 0 (0) 30 (2) 0 (0) 9 (1) FT 3261 (322) 2545 (206) 332 (20) 127 (15) 1 (1) 855 (133) 3 (2) Entering RT 835 (58) 641 (54) 117 (7) 30 (8) 33 (4) 214 (33) 7 (1) Exiting RT 313 (76) 255 (72) 58 (7) 43 (6) 1 (1 ) 90 (33) 0 (0) SF 28 (15) 21 (12) 44 (6) 0 (0) 44 (5) 0 (0) 9 (1) ________________________________________________________________________________________________________________________________________________ a Rec. 1 = Recirculation 1; Rec. 2 = Recirculation 2; Rec. 3=Recirculation 3 b, c CODT = total unfiltered COD; CODF = filtered COD. d Flow-averaged concentrations. e Ponding occurred 42 days after loading commenced. 17 Table 5. Summary of loading conditions and treatment performance of the stratified intermittent sand filter. _____________________________________________________________________________________________________________________________ ____ Treatment Period of Organic conc. in System hy. System loading Filter loading operation feed tank. loading ratea rate rateb CODTc TSS (days) mg CODT L-1 L m-2d-1 Sizingd % Removals CODT TSS CODT Tot-N NH4-N TSS ________ g m-2 d-1 ________ m2 _____________________________________________________________________________________________________________________________ ____ Rec. 1 165 3510 6.67 23.4 5.2 6.5 3.2 99 83 100 100 641 Rec. 2 135 3045 10.0 30.4 8.8 14 3.7 99 86 100 100 493 Rec. 3e 42 3228 13.4 43 12 18 3.0 99 91 100 100 349 _____________________________________________________________________________________________________________________________ ____ a The forward flow through the system. b For operation in recirculation mode, the filter hydraulic loading rate equals 4 times the system hydraulic loading rate, based on a 3:1 recirculation ratio. c CODT = total unfiltered COD. d Sizing of pilot field-scale intermittent sand filter is based on a 100 cow farm, with each cow producing 50 L per day (Department of Environment and Department of Agriculture, Food and Forestry, 1996) at an organic concentration of 3000 mg CODT L-1. e Ponding occurred 42 days after loading commenced. 18 M. G. Healy, M. Rodgers, and J. Mulqueen (2005). Optimization of a stratified sand filter for chemical oxygen demand, total suspended solids, and nitrogen removal from high strength wastewaters. Figure 1. Q 4Q Sand filter 100 mm dist. gravel 250 mm c. sand Feed tank 75 mm p. gravel 150 mm f. sand 75 mm p. gravel 150 mm f. sand Anoxic tank (recirculating tank) 100Qmm p. gravel 3Q Effluent sump 19 M. G. Healy, M. Rodgers, and J. Mulqueen (2005). Optimization of a stratified sand filter for chemical oxygen demand, total suspended solids, and nitrogen removal from high strength wastewaters. Figure 2. NH4-N / NO3-N +/- standard deviation (mg L-1) 0 10 20 30 40 50 0 Pea gravel Depth below surface (mm) 100 200 Coarse sand layer 300 400 Pea gravel 500 Fine sand layer 600 700 800 900 25 days before ponding:NH4-N (mg L-1) 25 days before ponding:NO3-N (mg L-1) 8 days before ponding: NO3-N (mg L-1) 8 days before ponding: NH4-N (mg L-1) 20 Pea gravel Fine sand layer Pea gravel