Matter and Change I. Phases or States of Matter Depends upon how much energy the matter has: A. SOLID PHASE 1. 2. 3. 4. B. Has definite shape and definite volume Regular geometric pattern Least amount of energy Molecules just “shiver” LIQUID PHASE 1. Has definite volume but no definite shape 2. Takes the shape of its container 3. Contains more energy than a solid but less energy than a gas 4. Molecules move faster than those in the solid phase but slower than those in the gaseous phase C. GAS PHASE 1. Has no definite shape and no definite volume 2. Takes the shape of its container 3. Most amount of energy 4. Molecules move the fastest II. Properties of Matter A. There are two types of properties of matter: Physical Properties and Chemical Properties B. Physical Properties: observed without changing the composition of the matter 1. Extensive physical property: depends upon how much matter is present (mass, volume, length, energy) 2. Intensive physical property: independent of or does NOT depend on how much matter is present (density, temperature, phase, luster, color, BP, MP, solubility, conductivity) Definitions and Examples of Physical Properties: • Malleability: The property displayed by certain metals that enable them to be hammered, rolled out into sheets, shaped, etc. • Ex. Lead • Ductility: The property displayed by certain metals that enable them to be drawn into wire without breaking • Ex. Copper • Hardness: The property of an object that resists being crushed or deformed • Ex. Diamonds • Brittleness: The property of an object that can be easily broken or crushed into smaller parts under low pressure • Ex. Talc • Conductivity: The ability of a metal to allow an electric current to pass through it • Ex. Silver • Solubility: The property of a substance that allows it to dissolve • Ex. Salt dissolving in water • Melting Point – Temperature at which a solid changes to a liquid • Boiling Point – Temperature at which a liquid changes to a gas C. Chemical Properties: describes how one form of matter interacts or reacts with another (combust, corrodes (oxidize, rot, rust, decompose) react, flammable, explode) Definitions and Examples of Chemical Properties: • Combustibility/Flammability: The measure of how easily a substance burns • Ex. Wood is flammable, Kevlar is fireresistant • Reactivity with other substances: The ability to react or to not react with other chemical substances • Ex. Baking Soda + Vinegar react to create Carbon Dioxide and Water • Corrosion: The chemical reaction between a material and its environment that produces a deterioration of the material and its properties. • Ex. Iron reacts with air and water to form rust Try this?!? Determine if the properties shown below are Chemical or Physical? If Physical indicate intensive or extensive • Combustibility • Malleability • State of Matter • Density • 20mL of Vinegar • A piece of burning paper • An Iron tractor covered in Rust • Sulfuric Acid reacts with Sugar to get charcoal III. Changes in Matter A. There are two types of changes of matter: Physical Changes and Chemical Changes B. Physical Change: A change in a chemicals appearance but NOT composition 1. 2. 3. 4. Used to separate mixtures Do not alter the composition (makeup or identity) of the matter Substances in mixture are still the exact same substances they were before the physical change occurred Separation techniques include 1. filtration – particle size 2. evaporation and distillation – uses boiling pt. 3. centrifuge – density 4. magnetism – metallic property 5. decanting – solubility and density 6. chromatography – uses solubility or attraction or particle size Examples of Physical Changes: • Tearing, grinding, dissolving, phase changes C. Chemical change: A change that DOES change the identity of the substance A. B. C. DO alter the identity of the matter Requires a minimum of two different forms of matter in order to occur Reactants (beginning ingredients) and products (end form of the matter) are different from one another reactant + reactant → product(s) D. To recognize a chemical change, look for: a. formation of gas (bubbles) b. color change c. precipitate (dense solid in solution) d. sound or light energy (E) produced e. quick change in temperature (T) Thinking Questions?!? 1. Do you encounter chemical changes in your everyday lives? Answer: Baking cookies, Leaves changing color in the fall 2. Can a change in a physical property indicate a chemical change? Answer: Yes, color is a physical property and color of the beginning substances can differ from the color of the final substance. Remember Copper Sulfate IV. Classification of Matter Based on the number of different substances it has in it A. Mixture – matter composed of different parts that are physically combined 1. homogeneous mixture (solution) a. Characteristics: • Consistency w/in sample • Uniform throughout b. Example: • Salt and water solution 2. heterogeneous mixture a. Characteristics: • No consistency w/in sample • Not uniform throughout • Often cloudy • Often settle upon standing • Can usually filter to separate b. Example: • Sand and water mixture 3. are NOT governed by the Law of Definite Proportions a. Definition: • states that a chemical compound always contains exactly the same proportion of elements by mass B. 4. CAN be separated (purified) by physical means • Filtration (only for Heterogeneous mixtures) • Evaporation • Distillation • Decanting • Crystallization • Magnetism 5. Do NOT combine chemically Pure Substance – matter composed of parts which are identical in properties and composition 1. element – one and only one kind of atom present a. Characteristics: • ALL atoms are identical • CANNOT be broken down at ALL • Simplest kind of matter b. Examples: • The ENTIRE periodic table 2. compound (cmpd) – requires a minimum of two kinds of atoms bonded together per piece of substance a. Characteristics: • TWO or MORE elements chemically combined and separated • New Properties • Examples: - Copper Sulfate - Sodium Chloride Sodium (Na) - Soft silver-colored metal - Reacts violently with water Chlorine (Cl2) - Poisonous, yellow-green gas - Sharp odor - Used during WWI When combined form Table Salt (NaCl) - Essential to life - Regulate water content in our bodies • Definite Ratio • Ex. H2O vs. H2O2 3. are governed by the Law of Definite Proportions 4. cannot be separated (purified) further by physical means MATTER Is it uniform throughout? YES ! NO! HETEROgeneous MIXTURE HOMOgeneous Can it be separated by physical means? YES ! NO! PURE SUBSTANCE HOMOgeneous MIXTURE (SOLUTION) Can it be chemically decomposed? NO! ELEMENT YES ! COMPOUND V. How to distinguish among elements, compounds and mixtures A. Given Diagrams: see worksheet B. Given Examples: 1. If it is on the periodic table, it is an element 2. If it has only 1 capital letter, it is an element a. Chemical symbols on the periodic table always contain ONE and only ONE capital letter b. Examples: • Ba, H, Ne, Au, U, etc. 3. If it has more than 1 capital letter, it is a compound a. Examples: • NaCl (salt) contains two capital letters which means that the compound is made up of two different elements • HCO3 (Baking Soda) contains three capital letters which means three different elements are present 4. If it has a complicated 2 word name, it is a compound (except for: sugar, salt, water, alcohol, ammonia) a. Examples: • Barium Hydroxide • Hydrogen Peroxide 5. If you think it is chemically combined (i.e. you can’t imagine any physical way to separate it), it is a compound. Otherwise, it is a mixture. 6. Homogeneous mixtures won’t settle and are even or uniform throughout a. Examples: • Salt-water solution • Sugar-water solution 7. If something is produced that has completely different properties, then it is a compound a. Examples: • Copper sulfate (Blue color) 8. If it can’t be broken down at all, then it is an element 9. If it can only be separated chemically, then it is a compound 10. If it can be separated physically (boiling, distillation, magnet, filtering (only heterogeneous)), then it is a mixture 11. If it is (s) or (l) it is an element or compound, if it is (aq) then it is a homogeneous mixture a. Example: • NaCl(s) vs NaCl(aq) Experimental data examples Question #1 Two samples were sent to a lab and various tests were performed • Test #1 – Filtration • Sample 1 was able to be filtered • Sample 2 was not able to be filtered • Test #2 – Heating • Sample 2 was found to contain two different Boiling Points • What could Sample 1 be? – Heterogeneous mixture able to be filtered • What could Sample 2 be? – Homogeneous mixture Two different Boiling Points Question #2 Two samples were sent to a lab and a chemical reaction was performed • Test #1 – Chemical Reaction • Sample 1 did not react and was not able to be chemically separated • Sample 2 was able to react and be chemically separated • What could Sample 1 be? – Element Not able to be chemically separated • What could Sample 2 be? – Compound Chemically separated Question #3 Two samples were sent to a lab and a chemical reaction was performed • Test #1 – Filtration • Sample 1 was able to be filtered • Sample 2 was not able to be filtered • Test #2 – Heating • After heating Sample 2, a solid was found left behind which was tested and found to be salt • What could Sample 1 be? – Heterogeneous mixture able to be filtered • What could Sample 2 be? – Homogeneous mixture solid found to be dissolved Thinking question?!? What would you classify NH4NO3 as? Explain your reasoning. – Compound – Contains multiple capital letters, aka multiple elements present VI. Law of Conservation of Mass-Energy (Matter) You cannot create nor destroy matter or energy in any physical or chemical change; What you start with is always equal to what you end with in any change; The mass of the reactants will always equal the mass of the products; What has been here since “the beginning” is still here, and will always be here until “the end;” You can’t get something from nothing!