AP Chemistry Notes – Chapter 2 Chemistry Notes – Chapters 5 & 7 Atoms and Elements What is sciences view on the cosmic origin of the elements that we take for granted in our environment and lives? “Big Bang” Theory: (grapefruit sized sphere of matter exploded 15 billion years ago creating a cloud with a temperature of 1030 K, filled with protons, neutrons, and electrons. The cloud then cooled and the protons, neutrons and electrons began to form helium and hydrogen) The Sun: After thousands of years it is believed that the hydrogen and helium condensed into stars like our sun. Each second in the sun 700 million tons of hydrogen is converted into 695 million tons of helium and 3.9 x 1026 joules of energy. The mass that appeared lost was converted to pure energy (E = mc2). H + H He + Energy Fusion Supernovas: Exploding stars observed by us are called supernovas. Supernovas can be thought of as factories for heavier elements (elements larger than hydrogen and helium). It is thought the heavy elements produced from these supernovas move out through space and gradually condense into planets like Earth 2.1 Protons, Electrons, and Neutrons: Atomic Theory A. Many of the experiments that have led to our current MODEL of the atoms involved: 1. Electricity (1700’s) – Benjamin Franklin o o o Identified the existence positive (+) and (-) charges Opposite charges neutralize each other Like charges repel each other while unlike charges attract one another 2. Radioactivity (1899) – Henri Becquerel and Madame Curie o Uranium emitted rays that were named radioactivity, substances that emitted these rays are said to be radioactive. o Madame Curie isolated polonium and radium that emitted radioactivity Positively Charged Plate + Radioactive Source Detector Plate (Film) Negatively Charged Plate Alpha Radiation (α) - Large massed particles, charged with a +2 charge Beta Radiation (β) - Small massed particles, with a –1 charge Gamma Radiation (γ) - No charge or mass 1 B. The Nuclear Model of the Atom All matter is made up of tiny particles called atoms An atom is more than 1 000 000X smaller than the thickness of a single hair on your head. Atoms have the same basic parts Atom Most of the Mass Most of the space Nucleus Neutrons Uncharged Particles (nucleons) Electron Cloud Protons = Electrons Positively Charged Particles Negatively Charged Particles Electrically Neutral C. Experiments Leading to “NUCLEAR MODEL” of the Atom Scientist Description Name of Experiment John Dalton (1780’s) Dalton’s Atomic Theory (model) Dalton’s Atomic Theory *1) All elements are composed of tiny indivisible particles called atoms *2) Atoms of the same element are identical. Atoms of any one element are different from any other element. 3) Atoms of different elements can physically MIX together OR can CHEMICALLY COMBINE with one another in whole-number ratios to make compounds. Outcome 4) Chemical reactions occur when atoms separated, joined or rearranged. Atoms of one element are never changed into atoms of another element as a result of a chemical reaction *Later proved wrong by other observations and experiments 2 JJ Thompson (1876) A beam of electrons (cathode rays) passes through an electric and magnetic field and were deflected away from the negative plate Cathode Ray Experiment *electrons discovered *charge to mass ratio electrons *protons discovered Thompson’s Cathode Ray Experiment Eugene Goldstein (1876) A beam of protons (canal rays) passes through an electric and magnetic field and were deflected away from the positive plate Canal Ray Experiment Robert Millikan (1912) Oil drops that had electrons adhered to them fell between two charged plates, by adjusting charge an the plates and by using Thompson’s charge to mass ratio he determined the mass and charge of an electron Oil Drop Experiment * Mass of an electron 9.11 x 10-28g *Charge of an electron -1.60 x 10-19 C Millikan’s Oil Drop Experiment 3 Ernest Rutherford A beam of positive alpha (α) was directed at a piece of thin gold foil. A screen was was used to detect particles passing through. Most alpha particles passed through but some were deflected from their path (even backwards) by the dense, positively charged nucleus of some of the gold atoms. Gold Foil Experiment *nucleus discovered Rutherford’s Gold Foil Experiment Where did all these experiments on the atom leave us??????? NUCLEAR MODEL of the Atom: 4 Review The following scientists and the research that they carried out was pivotal in creating the Nuclear Model (Theory) of the atom. Please match the experiment and finding on the left with scientist on the right : ______ a) Oil Drop Experiment; Using charge/mass ratio from cathode ray studies the mass and charge of an electron was determined ______ b) Gold Foil Experiment; Alpha particles directed at a piece of gold foil were deflected supporting the existence of a dense positively charged nucleus. ______ c) Canal Ray Experiment; Bema of proton rays (canal rays) were passed through an electric field and were deflected away from the positive plate supporting the existence of protons ______ d) Cathode Ray Experiment; A beam of electrons were passed through an electric field and were deflected away from the negative plate supporting the existence of electrons a) Eugene Goldstein b) Robert Millikan c) JJ Thompson d) Ernest Rutherford 2.2 Atomic Number and Atomic Mass A. Atomic Number (Z) The number of protons in the nucleus of an atom of an element is its atomic number, given the symbol Z. All atoms of the same element have the same number of protons in the nucleus. The number of protons in an atom of any element can be found on the periodic table: Atoms of an element have the same number of protons as electrons making them ___________________. Chemical properties (how atoms react) of an element depends on the number of electrons in its atoms. The identity of an atom can be determined from the number of the protons in the nucleus. Hydrogen is the simplest element, its atoms only have one proton in their nucleus Atomic Number (Z) 29 Cu 63.546 Practice: a) How many protons in an atom of uranium?_________ b) Atoms are neutral (have no net charge), knowing this how many electrons do you think a uranium atom would have?___________ c) What type of element has atoms that contain 20 protons? __________________ d) What type of element has atoms who electron clouds contain 7 electrons? __________________ B. Relative Atomic Mass and the Atomic Mass Unit What is the mass of an atom of an element? Masses of atoms are always determined RELATIVE to the carbon atom that is made up of 6 protons, 6 neutrons, and 6 electrons. This carbon atom has been assigned a mass of EXACTLY 12.000 atomic mass units (amu). One atomic mass unit, 1 amu, is 1/12th the mass of carbon atom that is made up of 6 protons, 6 neutrons, and 6 electrons. The “amu” can be related to the gram by the following conversion factor: 1 amu = 1.661 x 10-24 g 5 For example: An oxygen atom has been found to be 1.33X the mass of a carbon atom with 6 protons, 6 neutrons and 6 electrons (12.00 amu). What is its mass in amu’s? grams? C. Mass Number (A) Mass Particl e Electron *Proton *Neutron Grams 9.109 x 10-28 1.673 x 10-24 1.675 x 10-24 Relative Mass (amu) 0.00549 1.01 1.01 Charge -1 +1 0 Symbol e1p1+ n0 *Protons and neutrons have masses very close to 1 amu The sum of the number of protons and neutrons for an atom is called its mass number and is given the symbol A. Determine the mass of ONE Atom in amu and g’s 6 Examples: 1) A sodium atom has 11 protons and 12 neutrons in its nucleus what is its: mass number (A) ?_____ atomic number (Z)?______ How many electrons would it have?________ 2) An atom is made up of 16 protons, 16 neutrons, and 16 electrons. Using your periodic table what is the identity of the element (Symbol)?_________ Mass number (A)?_______ Atomic number (Z)?_______ 3) a) Identify the following atoms… 17 e- ______________ ________________ b) Why is the electron cloud of the atom with 17 e1- larger than the atom with 10 e1-? 3) Complete the table assuming all species are atoms: Name Symbol Atomic Composition of Nucleus (nucleons) Number Protons Neutrons (Z) Iron ________ _________ ________ _______ 80 ___________ ___________ ___________ 120 Mass Number (A) Number of Electrons 56 _________ _______ _________ _________ ________ _______ 47 ___________ _______ 47 _________ _______ ___________ ___________ 207 _________ _______ ___________ 31 59 _________ Pb _________ ________ C. Symbolizing Atoms of Various Elements Atoms of various elements can be symbolized using X NOTATION Mass Number Symbol Atomic number X NOTATION or HYPHEN NOTATION: HYPHEN NOTATION A X Z Element Name – Mass# Example : The most common atom of uranium has 92 protons, 146 neutrons and _______electrons. Symbolize this atom using both techniques described above: 7 Practice: a) What is the mass number of a calcium atom with 24 neutrons? Symbolize using both methods? b) Identify the element who’s atoms are identified… i.) with the following symbol 31 ?? 15 ii) as having 13 electrons and a mass number of 27 iii) as having (Z) = 19 and (A) = 39. _________________________ _________________________ _________________________ c) What is the identity of an element whos atoms have 90 protons and 142 electrons? Symbolize using both methods? d) Complete the table: X-NOTATION 80 35 ?? Protons HYPHEN NOTATION ___________________ _______ ________ Sulfur-32 _______ Neutrons Electrons Atomic # Mass # (Z) (A) ________ ________ ______ _______ ________ ________ ______ _______ 2.3 Isotopes ?? Only in VERY few instances (for example, aluminum, fluorine, and phosphorous) do all atoms of the same element have the same mass. Most elements consist of atoms having different mass numbers. Atoms with the same atomic number (number of protons) but different mass numbers (different number of neutrons) are called isotopes. Sample of Neon Atoms ?? ?? Symbol Notation _____________ _______________ ______________ 8 Identifying and Quantifying Isotopes of an Element – The Mass Spectrometer The mass number of an isotope is an approximation of the exact atomic mass of the isotope. The masses of isotopes of an element and their percent abundance experimentally determined using a MASS SPECTROMETER. The mass spectrometer is an analytical instrument used to measure atomic masses (mass of atoms) and molecular masses (masses of molecules) directly. A. Isotope Abundance o o Isotope Mass (amu) Relative Percent Abundance Abundance ______ 19.9924 ________ ________ ______ 20.9940 ________ ________ ______ 21.9914 ________ ________ Important points regarding exact atomic masses: The exact mass of any isotope of an element is not an integral (whole) number (except for carbon-12, which is EXACTLY 12.000 by definition). The exact mass of any atom is slightly less than the sum of the masses of protons, neutrons, and electrons in the atom. This difference is sometimes called the mass defect, and is related to the mass that was converted to energy (E = mc2) to bind the particles found in the nucleus (protons and neutrons) together. 9 B. Using Mass Spectrometer Data to Calculate the Atomic Weight of an Element The atomic weight an atom of an element must be somewhere between the exact atomic masses of each isotope. The atomic weight of an element is a weighted average of the exact masses of each isotope of an element. This is why atomic weights are NEVER whole numbers. Atomic =(relative abundance Isotope 1)(Exact Mass Isotope 1) + (relative abundance Isotope 2)(Exact Mass Isotope 2). . . Weight Practice: 1. If you could count out 10,000 boron atoms from a natural sample 1991 of them would be boron-10 and 8009 of them would be boron-11 atoms. The percent of a certain isotope in a sample of a naturally occurring element is termed percent abundance. RELATIVE ABUNDANCE Percent Abundance = number of atoms of a given isotope total number of atoms sampled X 100% = PERCENT ABUNDANCE X 100% = a. Calculate the abundance of each isotope of Boron: Isotope Relative Mass Boron Sample 8009 10 000 Boron atoms 1991 Relative Abundance Percent Abundance 11 B 5 or Boron-11 11.0093 amu ___________ ____________ 10 B 5 or Boron-10 10.0129 amu ___________ ____________ Total ___________ ____________ b. Calculate the weighted average atomic mass of Boron: 10 2. a) Argon has three isotopes with 18, 20, and 22 neutrons, respectively. What are the mass numbers and symbols of these three isotopes? b) Gallium has two isotopes: Gallium-69 and Gallium-71. i) How many protons and neutrons are in the nuclei of each isotope? Protons Neutrons Gallium-69 _______ _______ Gallium-71 _______ _______ ii) If the abundance of Gallium-69 is 60.1%, what is the abundance of Gallium-71?_____ Mass Defect Problem (E = mc2) You might expect the mass of a deuterium (2H), would be the sum of the masses of one proton and one neutron Mass of proton + Mass neutron = Mass Deuterium Atom 1.007276 amu 1.008665 2.015941 However the actual mass of 2H (which is actually measured to be 2.01355 amu using a mass spectrometer) is LESS than the some of its constituents. Where did the mass disappear to? = = = Actual mass of Deuterium - Theoretical mass of Deuterium ________________amu The”missing mass” is converted to energy, the binding energy (E= mc2) 2.4 Atomic Weight (Mass) of Elements The mass shown on the periodic table is the weighted average of the exact masses of each isotope of an element 29 Cu 63.546 The mass shown on the periodic table when rounded is indicative of the most abundant isotope of an element. ISOTOPES OF THE SAME ELEMENT CHEMICALLY REACT IDENTICALLY. 11 Practice Calculating the Atomic Weight of an Element: Using the percent abundance and atomic masses of each of nitrogen’s isotopes given on page 8 of this packet of notes, calculate the average atomic mass of nitrogen. Calculating the Abundances of an Isotope The element europium exists in nature as two isotopes: europium-151 which has a mass of 150.9196 amu and europium-153 which has a mass of 152.9209. The weighted average atomic mass of europium is 151.96 amu. Calculate the relative abundance of each isotope of europium Element Symbol Atomic Weight Mass Number Isotopic Mass Abundance (weighted avg) (amu) Europium Eu 151.96 151 153 150.9196 152.9209 _______% _______% 12 Practice Calculating the Abundance of Isotopes of an Element: 1) Using the data from page 7 of this packet of notes, calculate the abundances of each of the two isotopes of chlorine. 2) Thallium has two stable isotopes, 203Tl and 205Tl. What is the weighted average atomic weight of thallium? Which isotope is more abundant? Explain 2.5 Atoms and the Mole (Counting by Weighing) In chemistry we need a method of counting atoms, no matter how small they are. We must be able to connect the macroscopic world (what we can see) with the microscopic world of atoms, molecules and ions. We do this by defining a convenient unit of matter that contains a known number of particles. The chemical counting quantity is the mole (mol). The mole is the SI base unit for measuring the amount of a substance. A mole is the amount of a substance that contains as many elementary entities (atoms, molecules, or anything else) as there are atoms in exactly 12 g of the carbon-12 isotope In 12.0 g of carbon-12 atoms there are 6.02 x 1023 atoms (this is Avogadro’s Number) 1 2.0 g carbon-12 atoms = 6.02 x 1023 carbon atoms = 1 mole Avogadro’s Number The Molar Mass The mass in grams of one mole of atoms of any element (6.02 x 1023 atoms of that element) is the molar mass of that element. The units for the molar mass of an element are grams/mole. For elements, molar mass is an amount in grams numerically equal to the atomic mass in atomic mass units. This value is most easily found on the periodic table: 13 Counting ATOMS By Weighing Molar mass of copper (Cu) = In other words… mass of exactly mol of Cu atoms = 63.546 g/mol = mass of 6.02 x 1023 Cu atoms 1 mole Cu = 6.02 x 1023 atoms of Cu 29 Cu 63.546 = 63.546 g Cu Practice: 1) a) What is the mass, in grams, of 1.5 mol of copper? b) If a copper ornament has a mass of 2.0 g, how many copper atoms are in the ornament? c) If a copper ornament has a mass of 2.0 g, how many moles of copper atoms are in the ornament? d) What is the mass of a single atom of copper? 14 Homework 2) i) A lead fishing weight has a mass of ______g, Conversion Table: 1 mole Pb atoms = ______________g Pb a a) How many moles of lead atoms are present? = 6.02 x 1023 atoms of Pb b) How many lead atoms are present? c) What is the mass of one atom of lead in grams? 3) The mass of a single piece of pencil graphite (pure carbon) is ____________g. Conversion Table: 1 mole C atoms = ______________g C a) How many moles of carbon atoms are present? = 6.02 x 1023 atoms of C b) How many carbon atoms are present? c) If you wanted 6.5 x 1013 carbon atoms, how many grams of carbon would you need to mass out? d) If you wanted 6.5 x 1013 carbon atoms, how many moles of carbon atoms would you need? 4) The mass of Mr. B’s gold ring (Au) is ____________g. Conversion Table: 1 mole Au atoms = ______________g Au a) How many moles of gold atoms are present? = 6.02 x 1023 atoms of Au b) How many moles of gold atoms are present? 15 b) a) A single atom of this element has a mass of 2.28 x 10-22 g. What is its molar mass and identify the element? (Hint: Remember the units for molar mass are g / mol) c) To what group and period does the element in part a belong? Group_________Period_________ 6) A 5.00 g sample of an unknown element is known to contain 0.2632 moles of atoms. What is the identity of the unknown element (Hint: Remember the units for molar mass are g / mol)? What state of matter is this element present in at room temperature? 7) a) Which has more atoms present 1 mole of Copper (Cu) or 1 mole of Carbon (C)? Explain b) Which has a greater mass 1 mole of Copper (Cu) or 1 mole of Carbon (C)? Explain c) Which contains more atoms 6.0 g of carbon or 10 g of neon? Explain 16 2.6 The Periodic Table The most useful tool in chemistry is the ___________________ ___________________. Some of the things we can get from it… State of matter at room temperature: Solid (Black), Liquid (Blue), Gaseous (RED) Diatomic Elements (there are 7): H2, N2, O2, F2, Cl2, Br2, I2 Information on Each of the elements: 29 ________________ A. Features of the Periodic Table Cu _________________ 63.546 _________________ ______________ ______________ Main Features of the Table Elements with similar chemical and physical properties lie in VERTICAL columns called _______ or ___________. The periodic table is made up of _______ groups. In the United States we see them numbered 1A-8A and 1B-8B. Typically they are numbered 1-18. Groups 1-2 and 13-18 are called main group elements while the groups 3-12 are called transition elements. There are ______ horizontal rows in the periodic table, these are called ______________ Inner transition elements (Lanthanides and Actinides) 17 Element Silver (Ag) Calcium (Ca) Iodine (I) _________________ _________________ Period _____ _____ _____ 7 2 Group (Family) ___________ ___________ ___________ 2 17 Main Group or Transition ___________________ ___________________ ___________________ ___________________ ___________________ Periodic Table Divided According to Element Properties Metals Properties: Metals are… Solid at room temperature (except for mercury), conduct electricity, ductile, malleable, form alloys (brass is a homogeneous mixture of copper and zinc atoms), high luster (shiny). Metals lie to the _____________________ of the “staircase.” **When reacting with non-metals atoms, metal atoms tend to __________electrons to become stable forming POSITIVELY charged atoms (______________). Non-Metals Properties: Non-Metals are… Solid in some cases (ie. sulfur), liquid in some cases (ie. bromine), and gaseous in other cases (oxygen), don’t conduct electricity. Nonmetals lie to the _____________________ of the “staircase.” **When reacting with metals atoms, non-metal atoms tend to __________electrons to become stable forming NEGATIVELY charged atoms (________________). Metalloids (Semimetals): Properties: Semimetals are… elements that have characteristics of metals and non-metals. Nonmetals lie on the “staircase.” B, Si, Ge, As, Sb, & Te The Development of the Periodic Table Mendeleev (Father of the Periodic Table) The first periodic table of the elements created by Dmitri Mendeleev was arranged based on atomic masses. Upon studying the chemical and physical properties of the elements known at his time (1869) he realized elements with similar properties appeared in a regular pattern (periodicity). He organized the elements into a table by lining them up in a horizontal row in order of increasing atomic mass. Every time he came to an element similar to one already in the row, he started a new row. The columns then contained elements with similar chemical and physical properties. 18 Moseley In 1913, H.G.J Moseley REORDERED the table so that elements were organized into a table by increasing atomic number. The law of chemical periodicity is now stated as “ the properties of the elements are periodic functions of their _______________________________. 2.7 An Overview of the Elements The groups of the periodic table have similar chemical and physical properties, and several of these groups have distinct names that are important to know: Group 1A (1) – The Alkali Metals All elements are metals and solids at room temperature. All metals in this group are VERY reactive this means in nature you find these elements in compounds. These elements react with water to produce alkaline (basic) solutions. Group 2A (2) – The Alkaline Earth Metals All elements are metals and solids at room temperature. All metals in this group are VERY reactive this means in nature you find these elements in compoundsThese elements (Except Beryllium) react with water to produce alkaline (basic) solutions. 19 Groups 1B-8B Transition Metals All elements in this portion of the periodic table are metals Virtually all transition metals have commercial uses. Commercial Uses of Transition Metals: Structural Material: Iron (Fe), Titanium (Ti), Paints: Chromium (Cr), Copper (Cu) Titanium (Ti), Chromium (Cr) Catalytic Converters: Platinum (Pl) Coins: Copper (Cu), Nickel (Ni), Zinc (Zn) Nuclear Power Plants : Uranium-235 (235U) Biological Roles of Transition Metals: Red Blood Cell –Iron (Fe) is found in the ___________ carrying component of our blood (hemoglobin). Group 3A (13)- Boron Group (Family) Al, Ga, In, and Tl are all metals whereas Boron (B) is a metalloid Aluminum (Al) is the most abundant metal in the earth’s crust Group 4A (14) – Carbon Group (Family) Starting in this group, groups will begin to contain more and more non-metals. Nonmetals: Carbon Metalloids: Silicon, Germanium Metals: Tin, Lead Carbon is the basis for the great variety of compounds that make-up living things. Carbon can exist in several distinct forms Graphite each with their own distinct set of Diamond chemical and physical properties Bucky Ball Carbon Buckminsterfullerene (BuckyBall Carbon) Allotropes- Distinct forms of an element with their own unique physical and chemical properties Group 5A (15) – Nitrogen Group (Family) Nitrogen (N2) is the most abundant element in the Earth’s atmosphere. Nitrogen is also a critical element found in chlorophyll, proteins, and DNA. Phosphorous is essential to life as a constituent in bones and teeth. 20 Group 6A (16) – Oxygen Family Oxygen (O2) is the second most abundant element in the Earth’s atmosphere. Most of the energy that powers life on Earth is derived from reactions in which oxygen combines with other substances. Example: Burning Gasoline (Octane): C8H18 (l) + O2 (g) CO2 (g) + H2O (g) Oxygen is the most abundant element in the Earth’s crust and in the human body Oxygen also has allotropes: ____________________ and ____________________ Group 7A (17) – Halogens All elements in this group are NON-METALS This group contains the most reactive of all NON-METAL elements All elements in this group are diatomic elements (F2, Cl2, Br2, and I2) All react VIOLENTLY with alkali metals (also with other metals just not as violently) Group 8A (18) – Noble Gases All elements in this group are NON-METALS This group contains the least reactive of all NON-METAL elements 21 Elemental Make-up: Human Body 2.1 1.9 10.0 3.1 18.1 64.8 Oxygen Carbon Hydrogen Nitrogen Calcium Other Elemental Make-up: Earth's Crust 7.6 4.8 3.4 7.9 49.8 26.5 Oxygen Silicon Other Aluminum Iron Calcium Elemental Make-up: Earth's Atmosphere 7.9 26.5 7.6 49.8 Nitrogen Oxygen Carbon Dioxide Argon and Others 22 Periodic Table Practice Problems : 1) Identify a Noble Gas with 54 protons in the nucleus ________ 2) In what period(s) do we find a solid, liquid, and a gas element (at lab conditions) ________ 3) In what group(s) do we find a solid, liquid, and a gas element (at lab conditions) ________ 4) Identify a transition element with 42 electrons ________ 5) How many elements are found in … a) Period 2 b) Period 4 c) Group 15 ________ ________ ________ 6) In what group do we find 1 non-metal, 2 metalloid, and 3 metal elements ________ 7) In what group do we find the most chemically reactive: a) Metals b) Non-metals ________ ________ 8) Which of the Noble gases has ONLY radioactive isotopes ________ 9) This group containing only non-metals is made up of only monatomic gaseous elements ________ 10) A radioactive element whose atoms contain 95 protons and 95 electrons that are commonly used in household smoke detectors. ________ 11) A inner transition (actinide series) element whose atoms contain 90 protons and 95 electrons that are commonly used treat lantern mantles to increase the amount of light given off when they burn (this element is also radioactive) ________ 12) The most reactive of all NON METAL elements ________ 13) The most reactive of all METAL elements ________ 14) What element has a molar mass that is ½ the molar mass of manganese (Mn) ________ 15) Identify the element with the following symbol 39 ?? 19 16) An alkaline earth metal element that is important to healthy bones 17) A diatomic element found in group 17 period 5 ________ ________ ________ 23