The Soil Solid Fraction Solids Pores 5% 25% Air Water Mineral 45% 25% Organic From where do mineral particles originate? Rocks and Minerals Rock Limestone Sandstone Shale Granite Basalt Dominant Mineral Calcite Quartz Clays Quartz/Feldspars Quartz/Feldspars Weathering Physical: changing the size and shape of Rocks or mineral particles without altering their chemical composition Chemical: altering a mineral particle’s chemical composition. Weathering Physical: Destruction and Synthesis freezing and thawing plants and biota wind, rain, abrasion Chemical: hydration hydrolysis oxidation/reduction acids dissolution } Reduce Size } Chemical Alteration Granite Minerals: quartz, feldspars, biotite Rocks breakdown (weather) by physical means Primary Minerals Primary minerals (e.g. quartz, feldspars) are dominated by Si, Al, O Primary minerals breakdown (weather) principally by chemical means Secondary Minerals Silicate clays Iron oxides Aluminum oxides Silicate clay minerals are dominated by Si, Al, O Primary Minerals Quartz Feldspar Biotite Albite Muscovite SiO2 KAlSi3O8 KMg3AlSi3O10(OH)2 NaAlSi3O8 KAl3Si3O10(OH)2 Aluminum and Silicon Chemical Alteration and Reorganization Primary Minerals Quartz SiO2 Feldspar KAlSi3O8 Biotite KMg3AlSi3O10(OH)2 Albite NaAlSi3O8 Muscovite KAl3Si3O10(OH)2 Chemical weathering Secondary Minerals Crystalline Aluminosilcate Clays Dominated by Aluminum, Silicon, Oxygen Silicate Clays Silicate Clays Colloidal 1.Small (< 1 micron) 2.Large surface area 3.Highly reactive Constituents of Silicate Clays Aluminosilicates Si4+ Al3+ O2- OH- These 4 ions are arranged together to form crystals with a number of important properties related to soil reactivity. Ions: what are they? Silicate Clay minerals are crystalline and formed by specific arrangement of ionic forms of Si, Al, and O Ions are stable forms of elements that possess an electrical charge. Cations are elements that have lost electrons to become (+) charged Anions are elements that have gained electrons to become (-) charged. Elements Electrons (-) Protons (+) Elements in the periodic table have equal numbers of protons and electrons. They are electrically neutral Ions Ions are stable forms of elements that acquire an electrical charge by gaining or losing electrons Elemental Sodium (Na) 11 protons (+), 11 electrons (-) Sodium ion (Na+) 11 protons (+), 10 electrons (-) By losing an electron, sodium has more protons than electrons and becomes positively charged. Na - 1e- = Na+ Sodium Na (11 electrons) e- + e- e- e- e- Na e- 11 protons e- e- e- ee- Na+ 2Na + 2H20 2Na+ + 2 OH- + H2 Ions Ions are stable forms of elements that acquire an electrical charge by gaining or losing electrons Elemental Chlorine (Cl) 17 protons (+), 17 electrons (-) Chloride ion (Cl-) 17 protons (+), 18 electrons (-) By gaining an electron, chlorine has more electrons than protons and becomes negatively charged. Cl + 1e- = Cl- Chlorine e- _ e- e- e- e- ee- e- Cl e- 17 protons e- e- e- e- e- e- e- e- e- Cl- Elements that lose electrons and become positively charged are called cations. Na+, K+, Ca2+, Mg2+, Cu2+, Fe3+ Elements that gain electrons and become negatively charged are called anions. Cl-, Br-, F-, I- CO32-, SO42-, PO4-3 oxoanions Electrostatic Attraction + + + + + + + + + Na+ Cl- - Salts Salts are formed by combining cations and anions to form solids that have no charge. Cations: K+, Na+, Mg2+, Ca2+ Anions: Cl-, CO3-2, SO4-2 K+ + Cl- = KCl Na+ + Cl- = NaCl KCl, NaCl, MgCl2, CaCO3, CaSO4 Conversely, if solid salts are mixed with water they dissolve and the ions go into solution solution solid KCl NaCl Water Water K+ + Cl- Na+ + Cl- CaCO3 Ca+2 and CO3-2 CaSO4 Ca+2 and SO4-2 Dissolution ClCl Cl Na Cl Cl NaCl Na+ Building a Crystal with Cations and Anions Crystalline Mineral Colloids Aluminosilicates Cations and Anions Si4+ Al3+ O2- OH- Building Blocks for Silicate Clays Silicon Tetrahedron oxygen silicon (Si4+) Aluminum octahedron hydroxide (OH-) Aluminum (Al3+) Fundamental Building Blocks Silicon Tetrahedron Aluminum Octahedron Crystalline Minerals Graphite Oxygen (O2-) silicon (Si4+) Diamond Hydroxide (OH-) Aluminum (Al3+) Tetrahedra and Octahedra Sharing the Oxygens Linkage of thousands of silica tetrahedra and aluminum octahedra O { octahedra { Tetrahedra Si O, OH Al OH 1:1 Mineral 2:1 mineral { octahedra { Tetrahedra { Tetrahedra 1:1 minerals 2:1 minerals Layers and Interlayers Layer interlayers Electrical Properties of Soil Minerals Charge Balance Si4+ O2- Al3+ OH- Positive charge Al3+ Si4+ = Negative charge OH- O2- Uncharged silicate clay minerals Positive Charge Talc Al3+ Si4+ Pyrophillite Negative Charge O2- OH- AlSi2O5OH. +3 2 x (+4) = +8 5 x (-2) = -10 Total = zero -1 Isomorphous Substitution Substitution of lower-charge cations for higher charge cations during mineral formation. Al3+ for Si4+ in tetrahedra Mg2+ for Al3+ in octahedra The result is a deficit of positive charge or a surplus of negative charge in the mineral structure. Tetrahedral Substitution Al3+ for Si4+ Positive Charge = Negative Charge Octahedral Substitution Mg2+ for Al3+ Positive Charge = Negative Charge Tetrahedral Substitution Al3+ for Si4+ Octahedral Substitution Mg2+ for Al3+ Charge Na+ Na+ Na+ Na+ Na+ Na+ Na+ Cation Exchange K+ K+ Na+ Na+ K+ Na+ Na+ Na+ Na+ Na+ K+ K+ Implications of Negative Charge sites. Important Cations: H+, Ca2+, Mg2+, Zn2+, Mn2+, K+, NH4+, Cu2+ reserve Paraquat, Diquat, Triazines Pyridine, quinoline, arcidine