TOPIC 1 MATTER AND THE THEORY OF STATE MATTER INTRODUCTION TO THE MATTER Matter is anything that occupies space and has mass. Matter can classified into physical and chemical state. There are 4 physical states of matter : 1) Gas or Vapor No fixed volume or shape - it conforms to the container. Can be compressed or expanded Move randomly at great speeds Can vibrate, rotate, translate & have highest energy content 2) Liquid Has a fixed volume - shape depends on its container. Cannot compressed. Particle can vibrate, rotate & translate. 3) Solid • Has a fixed shape and volume; it is rigid • Cannot compressed. • Particles can vibrate & rotate at fixed positions 4) Plasma is a substance similar to gas in which electrically neutral medium of positive and negative particles they generate electrical currents by charges. THEORY OF STATE MATTER Matter is made up of tiny and discrete particles. There are spaces between these particles. The particles may be atoms, molecules or ions. An atom is the smallest particle of an element that can participate in a chemical reaction. A molecules is a group of two or more atoms which are chemically bonded together. An ion is a positively-charged or negatively-charged particle. Particles of Matter are constantly moving & contain kinetic energy. Particles of Matter are held together by very strong electric forces Matter can be classified by its chemical constituent whch are elements and compounds. a) An elements is a substance that consists of only one type of atom. b) A compound is a substance that contains two or more elements that are chemically bonded together. 5. Each substance has unique particles that are different from the particles of other substances 6. Temperature affects the speed of the particles. The higher the temperature, the faster the speed of the particles. MATTER ELEMENT COMPOUND ATOM MOLECULES MOLECULE S e.g: Gold, Au e.g: Oxygen gas, O2 e.g: Water, H2O Argon gas, Ar Sulphur, S8 Carbon Dioxide gas, CO2 ION e.g: Sodium chloride, NaCl Matter Anything with mass and volume Substance Matter with constant composition Mixture Matter with variable composition Element Substance made up of only one type of atom Compound Two or more elements that are chemically combined Heterogeneous Mixture Mixtures that are made up of more than one phase Homogeneous Mixtures Also called solutions. Mixtures that are made up of only one phase Examples - gold, silver, carbon, oxygen and hydrogen Examples - water, carbon dioxide, sodium bicarbonate, carbon monoxide Examples - sand, soil, chicken soup, pizza, chocolate chip cookies. Examples - salt water, pure air, metal alloys, seltzer water. Solid Liquid Gas Attractive force among particles Strong Fairly strong Very weak Compressibility Incompressible Incompressible Easy to compress Volume Fixed Particle movement Can only vibrate Free to move slowly Free to move quickly Shape Definite No definite shape (Fill bottom of the container) No definite shape (Fill the whole container) Kinetic energy Low Medium High Particles arrangement Fixed and similar to No fixed volume solid (occupies the whole container) Sublimation Boiling/ Melting evaporation Freezing Condensation LIQUID SOLID GAS Sublimation Heat energy absorbed Heat energy released Melting point – Temperature at which During Heating… When a solid is heated, the particles absorb heat energy. The particles vibrate faster and kinetic energy increase. The movement of particles is increase The force of attraction become weak Freezing point – Temperature at which During Cooling… When a gas is cooled, the particles release the energy. The kinetic energy will decrease The movement of particles is decrease The force of attraction become strong PHYSICAL AND CHEMICAL CHANGES PHYSICAL CHANGES CHEMICAL CHANGES A change that alters the a change in matter that APPEARANCE of a material but does not make the material into another substance Physical changes are REVERSIBLE Examples: tearing paper, chopping wood, molding clay, melting ice PRODUCES A NEW SUBSTANCE Signs that a chemical change has taken place: bubbles appear precipitate forms color change light is emitted temperature change change in smell or taste S involved during BOTH physical and c Subatomic particles of an atom Atoms are made up of three types of smaller particles, namely protons, neutrons and electrons. These particles are known as subatomic particles. The relative masses and charges of these three subatomic particles in table below. SUBATOMIC PARTICLE SYMBOL RELATIVE MASS RELATIVE ELECTRIC CHARGE PROTON P 1 +1 NEUTRON n 1 0 ELECTRON e 0 (almost) -1 Subatomic particles of an atom Protons and neutrons are found in the nucleus of an atom while electrons surround the nucleus. SYMBOLS OF ELEMENTS Each element is given a name and a symbol. Some examples of elements and their symbols are shown below. ELEMENT SYMBOL ELEMENT SYMBOL Hydrogen H Sodium Na Helium He Magnesium Mg Lithium Li Aluminium Al Beryllium Be Silicon Si Boron B Phosphorus P Carbon C Sulphur S Nitrogen N Chlorine Cl Notice that: (a) Each symbols consists of one or two letters. (b) For most elements, the letters used in their symbols take either the first letter or first and another letter of their names. Eg. Hydrogen, H; neon, Ne and Magnesium, Mg. (c) For some elements, the symbols come from Latin names such as natrium (Na) for sodium and kalium (K) for potassium. 11 5 Nucleon number A Z Proton number x Symbol of element B Proton number = 5 Nucleon number = 11 Neutron number = 11 – 5 =6 PROTON NUMBER & NUCLEON NUMBER Proton number : an elements is the number of protons in its atom. Since atoms are neutral, the proton number is also the number of electrons in the atom. Each elements has its own proton number. E.g: sodium has a proton number of 11. Hence all atoms of sodium have 11 protons. Oxygen has a proton number of 8, so all oxygen atoms have 8 protons. The nucleon number is also known as the mass number. The relative mass of an atom is almost the same as its nucleon number. The nucleon number is sometimes used as the approximate relative mass in calculations. Protons and neutrons are collectively called nucleons because protons and neutrons occupy the nucleus. Nucleon number: total number of protons and total number of neutrons in its atom. From definition, Nucleon number = number of proton + number of neutrons or Number of neutrons = nucleon number – number of proton Remember the charge on each subatomic particle like this: Protons are positive, Neutrons are neutral, so electrons must be negative. In a neutral atom, number of electrons = number of protons ISOTOPES Isotopes are atoms of the same element with the same number of protons but different numbers of neutrons. Isotopes of an element have the same: (a) number of protons in an atom. (b) number of electrons in an atom. (c) electron arrangement. (d) chemical properties because they have the same electron arrangement. Isotopes of an element have different: (a) nucleon number. (b) number of neutrons in an atom. (c) physical properties (such as density, melting point and boiling point), though these different are very small. USES OF ISOTOPES There are 2 types of isotopes, namely the radioactive and the non-radioactive isotopes. Radioactive isotopes or radioisotopes produce harmful radiation. However, radioisotopes can have important uses if they are handled properly. They are used in medicine, industry, agriculture and general research. 1) Medical use Gamma-rays emitted from cobalt-60 are used in radiotherapy for the treatment of cancer. Superficial cancers such as skin cancer can be treated by less penetrating radiation from phosphorus-32 or strontium-90. A heart pacemaker which contains plutonium-238 is used to regulate the heartbeats of patients with heart problems. Iodine-131 is used in the treatment of thyroid diseases. 2) Agricultural uses The uptake of phosphate and the metabolism of phosphorus by plants can be studied using a phosphate fertiliser containing phosphorus-32. Radioactive tracer studies using carbon-14 have helped in the understanding of photosynthesis and protein synthesis. 3) Industry uses Sodium-24 can be used to trace leaks in gas or oil pipes and ventilating systems. The gamma rays of cobalt-60 are passed through food to destroy bacteria which cause the food to spoil without changing the quality, flavour, or texture of the food. The radiation from krypton-85 can be used to control the thickness of plastic sheets in the industry. 4) Power sources Uranium-235 is the most common fuel used in nuclear power stations. 5) Archaeological uses • Carbon-14 can be used to estimate the age bone, wood or fossils by measuring the fraction of carbon-14 it contains. ELECTRONIC STRUCTURE OF AN ATOM Electrons are arranged around the nucleus in the shells of an atom. The shell of an atom are numbered 1, 2, 3 and so on, starting from the one closest to the nucleus. Each shell can occupy a certain number of electron. ELECTRONIC STRUCTURE OF AN ATOM First shell : 2 electrons Second shell: 8 electrons Third shell: 8 electrons + 1 2 3 Fourth shell: 18 electrons nucleus FINDING THE ELECTRON ARRANGEMENT To write the electron arrangement of an atom, follow these steps: STEPS 1 – Find out the proton number of the atom. (can refer to the Periodic Table) STEPS 2 – Find out the number of electrons of the atom. For a neutral atom, the number of electrons is the same as the number of protons. FINDING THE ELECTRON ARRANGEMENT STEPS 3 – Arrange the electrons in shells. Electrons occupy the shell closest to the nucleus first. The electrons only start occupying a new shell when the previous one has been occupied. VALENCE ELECTRONS Valence electrons are found in the outermost occupied shell of an atom. They determine the chemical properties of the element VALENCE ELECTRONS For e.g: the electron arrangement of a chlorine atom is 2.8.7. There are 7 electrons in the outermost occupied shell of the chlorine atom. Therefore, the number of valence electrons in a chlorine atom is 7. 1) How many states of matter are there? A) 1 B)2 C) 3 D)4 ANS: There are 4 states of matter. You will find solids, liquids, gases and plasmas. 2) Atoms in a liquid are farther apart than the atoms in a gas. A) true B) false ANS: Atoms in a gas are actually farther apart than the atoms in a liquid. Solids are the densest state of matter (of solids liquids, and gases). Gases are the least dense and have atoms that are the most spread out. 3) Which has the least energetic molecules? a) Solids b) Liquids c) Gases d) Plasmas Ans : Solids have the least energetic molecules. Plasmas and gases have the most energetic atoms. 4) What force pulls liquids towards the ground? a) Pressure b) Temperature c) Gravity d) centrifugal Ans: Gravity is the one force that pulls every object towards the surface of the Earth. 5) When a substance goes from being a solid to a liquid, it is a... a) chemical change b) Physical change Ans: When a substance moves from one state to another, it is a physical change. Physical changes usually happen because you add or take away energy. If one substance combines with another to make a new compound... That is a chemical change.