Ecomix - Ecosoft.ua

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Contents

1. Business

2. Technology

3. Applications

ECOMIX. BUSINESS

ECOMIX

® is a multipurpose filtration material to treat 5 major problems of well water:

• Hardness

• Iron

• Manganese

• Tannins (Natural Organic

Matter)

• Ammonia

International

Trust

500 000 liters = 20 000 systems

Ecomix Sales 2013. 500 m 3 = 20 000 bags

How we arrived at the point?

5 typical problems of Ukraine ’s well water:

• Iron

• Manganese

• Hardness

• Ammonia

• Tannins, Natural

Organic Matter

(by COD)

Insides of a dishwasher that has run on raw well water

If we use conventional technology…

Raw water

1. Fe, Mn 2. Ca 3. Tannins 4. NH

4

1. Catalytic media (Birm, MTM, Greensand) for Iron removal

2. Cation exchange resin for softening

3. Activated carbon for tannins removal

4. Zeolite for ammonia treatment

• Detailed water analysis is required

• Deep knowledge of water chemistry and experience are necessary

• Limited effectiveness

• High cost

• Tricky in operation

EFFECTIVE

If we use ECOMIX…

• Market’s best solution for

Manganese and Iron

SIMPLE

CHEAP

• One filter for 5 impurities.

No detailed water analysis required. Retrofit of traditional softener.

UNIVERSAL

• Proved effectiveness for the majority of waters worldwide

• Lower cost and higher gain

3 2

5

Today Ecomix is not just another iron removal media, but a powerful business development tool in iron contaminated water areas.

Water treatment dealers and shops

Non-water companies

Only one parameter required – Total Iron

Internet sales

No water analysis required

Commercial advantages

ECOMIX. TECHNOLOGY

ECOMIX

® is a composition of FIVE materials of different origin and properties

Includes two patented adsorption components invented by Ecosoft.

patented patented

Inert resin removes oxidized iron and ensures even flow distribution in backwash

Modified sorbent FerroSorb binds

Fe(II), provides formation of firm Fe(III) oxides layer and autocatalytic adsorption of iron and manganese compounds

Modified sorbent HumiSorb retains

NOM through electrostatic interaction with charged groups and hydrophobic binding with aromatic fragments.

Cation exchange resin exchanges Ca and Mg and residuals of

Fe (II).

Quartz sand support bed

Ecomix includes a tailor-made iron and manganese sorbent FerroSorb

Outer active layer of the FerroSorb allows to efficiently remove IRON and MANGANESE from water

Cross-section of

FerroSorb

Adsorption-oxidation (AOX) mechanism of Iron sorption by FerroSorb

2

2.1

2.2

Active centers for Mn 2+ sorption

FerroSorb in Ecomix works to efficiently remove iron and manganese

Common cation exchange resins take iron too, but due to poor regeneration become exhausted very fast

• FerroSorb is regenerated by Surface

Scouring Mechanism (SSM) in fluidized bed

• Other resins are exhausted irreversibly

Well-known oxidation-filtration is not applicable to

FerroSorb , because FerroSorb provides totally different mechanism of action:

Adsorption → Oxidation → Layer Formation →

Multicycle Autocatalytic Sorption

Ecomix includes a tailor-made HumiSorb that reduces level of Tannins and color of water fresh HumiSorb

HumiSorb after

Tannins adsorption

Electrostatic-hydrophobic mechanism of Tannin adsorption

Electrostatic interaction

Hydrophobic binding

• HumiSorb is not just an anion exchange resin o Very efficient for aquatic tannins o Regeneration with Cl -

• Due to irreversible binding of tannins common anion exchange resins become exhausted very fast

Ecomix production technology is a knowhow of Ecosoft:

• Provides activation of the surface modifiers in FerriSorb

& HumiSorb

• Homogenity

• Consistent quality and composition

• Ecomix production is

ISO 9001:2009 certified

ECOMIX

®

is manufactured in:

Ukraine

(for ex-USSR countries)

Germany

(for EU countries and the United States)

Supplied in 25 L (0.9 ft 3 ) and 12 L (0.4 ft 3 ) bags

50% reduction of Tannins (COD)

80% reduction of Tannins (COD)

Maximum concentration level

Tannins

(by COD) ppm O

2

Hardness*

*limit installed due to sodium effluent meq/L gpg ppm

CaCO

3

Fe Mn ppm ppm

20 15 45 750 15 3

Removal efficiency,

%

50%

80%

97%

NH

4 ppm

4

98% 98% 90%

Regeneration

NaCl 100 g/liter

5,5 lbs/bag

Competitors

1. Generic mixtures of ion exchange resins

2. Synthetic zeolite

What is the difference?

Competitors

Generic mixture1

Genuine

Ecomix

• Visual differences

• Generics do not contain FerroSorb and HumiSorb

• Not homogeneous → no guaranty for stable product composition

• Become exhausted after iron sorption

Generic mixture 2

Mixtures of ion exchange resins that are sold at several times the price of their ingredients

Caution!

Generics are dangerous because of Mn!

1. Lower retention capacity for iron and hardness

2. Adsorption capacity deteriorates after each service cycle, generics do not regenerate completely

3. There is a risk of releasing retained manganese!

Generic

Ecomix

ECOMIX vs. Synthetic zeolite

Exchange capacity, eq/L (grains/cft)

Ecomix

Ecomix A – 0,75 (15 200)

Ecomix C – 0,65 (13 100)

Synthetic zeolite

0,6 (12 092)

Consumption of salt per regeneration, g/L

100

(6.2 lbs/ft 3 )

130

(8.1 lbs/ft 3 )

Iron reduction

Tannins reduction

Dissolved inorganic, organic iron

Ecomix A – 50%

Ecomix C – 80%

Do not retain organic iron

Tight limit

H

2

S

Does not exhaust, reduction – 50%

Exhaust ,

Soda regeneration required

ECOMIX vs. Synthetic zeolite

Concentration limits

Acceptable limits pH

Tannins by COD, ppm O

2

Iron, ppm

Manganese, ppm

Grains Hardness, (CaCO

3

)

Ecomix

5-9

<20

<15

<3

<45

(due to sodium effluent)

Synthetic zeolite

>6 or >7

<6

Fe+Mn <15

<38 or <76 min 3 min TDS: 80 ppm

ECOMIX. APPLICATION

10% of sales

18% of sales

55% of sales

Exchange capacity and regeneration

Ecomix service cycle is neatly calculated from its ion exchange capacity:

• ECOMIX A 0,75 eq/l = 15 200 grains/cft*

• ECOMIX C 0,65 eq/l = 13 100 grains/cft*

(* at 100 g NaCl/liter or 6,2 lbs/ft 3 )

Water treatment for household

FPC 1054

FPC 1252

FPC 1465

FPC 1665

UV disinfection

Cartridge fine filter

FK 1054

FK 1252

FK 1465

FK 1665

Hydrogen sulfide removal

Drinking water purification

Reverse osmosis water pre-treatment

Reverse osmosis system

UV disinfection

Cartridge fine filter

Holding tank and pump

Water for boilers and heaters

Cartridge fine filter

Deep softening of water

Chemical conditioning

Purified water

Calculate the capacity based on water hardness используйте только значения жесткости.

Run a regeneration procedure after having installed the system

Attention! Drain line should not exceed length of 2 m

Sediment filter is an essential unit.

Iron < 7-10 ppm – cartridge filter

Iron > 10 ppm – media filter

Raw water

Recommended inlet pressure is 3-4 bar (45-60 PSI)

Properly use Ecomix:

Adhere to guidelines

• Ensure the media and the system are operated according to manufacturer’s requirements

Pre-filter water

• Cartridge or rinsable fine filter

Properly regenerate

• Ensure sufficient quantity and saturation of brine is provided

• Ensure obstruction and impediment free water flow

Early recognition of any issues and their causes helps secure long service life of Ecomix media

1

Most frequent problems and their causes

Leak

Hardness and iron in treated water

2

Poor regeneration

Iron in treated water

For successful operation ensure adequate regeneration

Consequences and causes of poor regeneration

Accumulation and aggregation of trapped fines

Excessive volume of media

Insufficient or excessive backwash flow rate

Too short backwash time

Loss of ion exchange capacity

Insufficient brine volume and/or concentration

Insufficient brine contact time

Poor/restricted brine percolation due to buildup of fines or channel forming in the bed

Restoring the media after improper use

Thorough rinsing to release trapped fines

Extensive brining

Cleaning with acids

Cleaning with oxidants

Cleaning with sulfite type chemicals

Restoring the media after improper use

1. Interval backwashing with 20-30 second periods of rest

2. Air scouring the bed (5-10 minutes)

5 - 10 times

3. Making brine in the filter tank (1,3-1,5 kg of salt per 10 L of the media)

4. Air scouring the bed while resting it in brine (15-20 minutes)

5. Interval backwashing with 20-30 second periods of rest until the brine is completely flushed away

3 - 5 times

Controlling odors

Certain types of water may promote emergence of odor

Use 250-300 mL (0.07 gal) of household bleach per 25 L (0.9 ft 3 ) of Ecomix

Pour the bleach into the brine tank, mix and start regeneration

Shut off the water supply after the brine tank has been emptied

Leave for 6-12 hours

Complete regeneration procedure

Run one more regeneration procedure

ECOMIX

1. Is not merely a ‘mix’ of resins

2. Is sure to work

3. Allows to sell more

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