6.1 Acids and Bases SNC2D Properties of Acids Acids: taste sour Properties of Acids Acids: taste sour are corrosive (react with metals to produce hydrogen gas) Properties of Acids Acids: taste sour are corrosive (react with metals to produce hydrogen gas) release hydrogen ions (H+) in solution (therefore, the physical state is always aqueous) Examples of Acids acetic acid HC2H3O2 (aq) Examples of Acids acetic acid (in vinegar) HC2H3O2 (aq) Examples of Acids acetic acid (in vinegar) HC2H3O2 (aq) citric acid (in citrus fruit) H3C6H5O7 (aq) Examples of Acids acetic acid (in vinegar) HC2H3O2 (aq) citric acid (in citrus fruit) H3C6H5O7 (aq) carbonic acid H2CO3 (aq) Examples of Acids acetic acid (in vinegar) HC2H3O2 (aq) citric acid (in citrus fruit) H3C6H5O7 (aq) carbonic acid (in soft drinks) H2CO3 (aq) Examples of Acids acetic acid (in vinegar) HC2H3O2 (aq) citric acid (in citrus fruit) H3C6H5O7 (aq) carbonic acid (in soft drinks) H2CO3 (aq) hydrochloric acid HCl (aq) Examples of Acids acetic acid (in vinegar) HC2H3O2 (aq) citric acid (in citrus fruit) H3C6H5O7 (aq) carbonic acid (in soft drinks) H2CO3 (aq) hydrochloric acid (in your digestive system) HCl (aq) Naming Acids Binary acids (hydrogen + a single element) are called hydro_______ic acids e.g. H2S(aq) is hydrosulphuric acid Naming Acids Oxyacids (hydrogen + a polyatomic ion) are called: _______ic acids if the name of the ion ends in -ate _____ous acids if the name of the ion ends in –ite e.g. HNO3(aq) is nitric acid (NO3- is nitrate) HNO2(aq) is nitrous acid (NO2- is nitrite) Writing Chemical Formulas The following steps should be followed when writing acid formulas. 1. Determine whether it is a binary acid or an oxyacid. If it is a binary acid, the name starts with hydro- . If it is a oxyacid, the name doesn’t start with hydro-. 2. Find the ion symbols and their charges using a periodic table and then cross over the charges. If the oxyacid ends with -ic, the polyatomic ion’s name must end with -ate. If the oxyacid ends with –ous, the polyatomic ion’s name must end with –ite. Writing Chemical Formulas 1. phosphoric acid a. does not start with hydro- , so it is an oxyacid b. look for the polyatomic that ends in –ate, since the acid name ends in –ic (phosphate) c. cross over the charges, H+ PO43- H3PO4 (aq) 2. hydrobromic acid a. starts with hydro- , so it is a binary acid b. look for the symbol and charges in the periodic table c. cross over the charges, H+ BrHBr (aq) Properties of Bases Bases: taste bitter Properties of Bases Bases: taste bitter feel slippery Properties of Bases Bases: taste bitter feel slippery are corrosive (break down proteins) Properties of Bases Bases: taste bitter feel slippery are corrosive (break down proteins) release hydroxide ions (OH-) in solution Examples of Bases Sodium hydroxide NaOH Calcium hydroxide Ca(OH)2 Aluminum hydroxide Al(OH)3 Examples of Bases Sodium hydroxide NaOH Calcium hydroxide Ca(OH)2 Aluminum hydroxide Al(OH)3 Sodium bicarbonate NaHCO3 Ammonia NH3 Writing Formulas for Bases The following steps should be followed when writing base formulas. 1. Use the periodic table and table of polyatomic ions to identify the symbols for the cation and anion in the base and their charges. 2. Cross over the charges. e.g. : magnesium hydroxide Mg2+ OH- Mg(OH)2 Copyright © 2010 McGraw-Hill Ryerson Ltd. Strong and Weak Some acids and bases are much stronger (have a higher concentration of ions in solution) than others. e.g. nitric acid is a strong acid; ammonia is a weak base