Writing Electron Configurations Noble gas method Write an electron configuration for uranium (92 electrons). Write an electron configuration for uranium (92 electrons). • 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f4 Write an electron configuration for uranium (92 electrons). • 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f4 • This can take a long time for large atoms, especially when the valence electrons are the only ones we care about. Noble gas method • This method represents a much quicker and easier way to identify valence electrons. Noble gas method • This method represents a much quicker and easier way to identify valence electrons. • The s-sublevel is always the first sublevel to be filled within a particular energy level. Noble gas method • This method represents a much quicker and easier way to identify valence electrons. • The s-sublevel is always the first sublevel to be filled within a particular energy level. • The outermost energy level is the most important, so why not start there? Noble gas method • This method represents a much quicker and easier way to identify valence electrons. • The s-sublevel is always the first sublevel to be filled within a particular energy level. • The outermost energy level is the most important, so why not start there? • 7s25f4 (start with the 7th energy level) Noble gas method • This method represents a much quicker and easier way to identify valence electrons. • The s-sublevel is always the first sublevel to be filled within a particular energy level. • The outermost energy level is the most important, so why not start there? • 7s25f4 (start with the 7th energy level) • [Rn] is used to represent the first 86 electrons. • [Rn] means the same thing as 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p6 • [Rn] means the same thing as 1s22s22p63s23p64s23d104p65s24d105p66s24f145d10 • Therefore, [Rn]7s25f4 means the same thing as 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f4 Write an electron configuration for selenium using the noble gas method. Write an electron configuration for selenium using the noble gas method. • Start with the s-sublevel for the period selenium is in (4s) Write an electron configuration for selenium using the noble gas method. • Start with the s-sublevel for the period selenium is in (4s) • Select the noble gas from the previous period and place it in brackets ([Ar]4s) Write an electron configuration for selenium using the noble gas method. • Start with the s-sublevel for the period selenium is in (4s) • Select the noble gas from the previous period and place it in brackets ([Ar]4s) • The argon accounts for 18 of the 34 electrons needed. Continue until you reach 34. Write an electron configuration for selenium using the noble gas method. • Start with the s-sublevel for the period selenium is in (4s) • Select the noble gas from the previous period and place it in brackets ([Ar]4s) • The argon accounts for 18 of the 34 electrons needed. Continue until you reach 34. • [Ar]4s23d104p4 Electron configuration exceptions Electron configuration exceptions • Electrons are arranged in a way that maximizes stability. Electron configuration exceptions • Electrons are arranged in a way that maximizes stability. • Sublevels that are filled are the most stable. Half-filled sublevels are stable. Anything else is unstable. Chromium • The noble gas configuration for chromium is expected to be [Ar]4s23d4 Chromium • The noble gas configuration for chromium is expected to be [Ar]4s23d4 Chromium • The noble gas configuration for chromium is expected to be [Ar]4s23d4 The 3d sublevel is unstable due to the single empty orbital. Chromium • The noble gas configuration for chromium is expected to be [Ar]4s23d4 Promoting one of the 4s electrons increases stability.