Nature of Science Bell Ringer: How do you know something exists if you have never seen it before? Important Vocabulary Inference Indirect evidence The Black Box Lab Purpose Materials Procedure Results Table (20 pts) Post Lab Questions (30 pts) Results (20 pts) Box # Inferences a) Example b) c) a) 1 b) c) Model Post Lab Questions (30pts) 1. How did you construct your model of what was in the boxes? 2. How do you know if something exists if you have never seen it before? 3. How does this lab relate to the scientific method? 4. To create a more accurate model, what would you want to do next without looking inside the boxes? 5. How do you think scientists use or have used empirical evidence to create models? (hint: think about topics in this class) Contents of Each Box • Box 1- Wooden block • Box 2 - 3 Pennies • Box 3 - 2 Straws • Box 4 - 10 Stickers • Box 5 - Pill Canister • Box 6 – 2 Rubber bands • Box 7 - 1 Dice • Box 8- 10 Beads • Box 9 - 10 Lima Beans • Box 10 - 2 Cotton Balls What does an atom actually look like? Closure: watch video “have you ever seen an atom?” Exit Pass – how does today’s lab relate to the discovery of the atom? Historical Scientists Jigsaw Activity It is now your turn to do some research… You will be assigned a scientist to become an expert on This scientist had an impact on the historical development of the atom YOUR JOB: give a creative, informative poster on your scientist and how they influenced the historical development of the atom You are then going to share your poster with others to inform them about your scientist. Textbook Info Dalton – pg 77-78 Thomson – pg 79 Rutherford – pg 81 Bohr – pg 91 DeBroglie – pg 91 Atoms New section in table of contents Aristotle & Democritus First philosophers to start thinking about the atom and its component Smallest divisible component vs. indivisible particle Dalton Billiard Ball Model Provided evidence for how we know atoms exist EQ 1: How do we know atoms exist? KC 1: Law of definite proportions – a chemical compound always contains the same elements in exactly the same proportions by weight or mass KC 2: Law of conservation of mass KC 3: Law of multiple proportions – when 2 elements combine to form 2 or more compounds, the mass of one element that combines with a given mass of the other is in the ratio of small whole numbers EQ 2: What are the five postulates of Dalton’s atomic theory The ancient Greeks tried to explain matter, but the scientific study of the atom began with John Dalton in the early 1800's. EQ 2: What are the five postulates of Dalton’s atomic theory KC 1: All matter is composed of extremely small particles called atoms, which cannot be subdivided, created, or destroyed Many ancient scholars believed matter was composed of such things as earth, water, air, and fire. Many believed matter could be endlessly divided into smaller and smaller pieces EQ 2: What are the five postulates of Dalton’s atomic theory KC 2: Atoms of a given element are identical in their physical and chemical properties KC 3: Atoms of different elements differ in their physical and chemical properties EQ 2: What are the five postulates of Dalton’s atomic theory KC 4: Atoms of different elements combine in simple, whole-number ratios to form compounds KC 5: In chemical reactions, atoms are combined, separated, or rearranged but never created, destroyed, or changed Thomson Plum pudding model Introduced the idea that electrons are located outside the nucleus Rutherford Discovered the nucleus Used the gold foil experiment EQ 3: What model of the atom will we use? KC 1: Bohr suggested that electrons move in circular orbitals around the nucleus Bohr’s model of the atom gives us a good starting point for understanding more about the atom EQ 3: What model of the atom will we use? KC 2: How to draw a Bohr model of an atom 1) Find your element on the periodic table. 2) Determine the number of electrons – it is the same as the atomic number. 3) Determine the number of circular orbits the atom has. 4) Add electrons = atomic number - 1st shell can hold two - 2nd and 3rd can hold eight Bohr model of the atom Elements in the 1st period have one energy level. Elements in the 2nd period have two energy levels, and so on. Bohr model of the atom C Draw a nucleus with the element symbol inside. Carbon is in the 2nd period, so it has two energy levels, or shells. Draw the shells around the nucleus. Bohr model of the atom Element name Atomic number = number of protons = number of electrons (for now…) Element symbol Average atomic mass Bohr model of the atom C Add the electrons. Carbon has 6 electrons. The first shell can only hold 2 electrons. Bohr model of the atom C Since you have 2 electrons already drawn, you need to add 4 more. These go in the 2nd shell. Add one at a time starting on the right side and going counter clock-wise. Bohr model of the atom C Check your work. You should have 6 total electrons for Carbon. Only two electrons can fit in the 1st shell. The 2nd shell can hold up to 8 electrons. The 3rd shell can hold 18, but the elements in the first few periods only use 8 electrons. Bohr model of the atom KC 3: The lowest allowable energy state of an atom is called its ground state. KC 4: When an atom gains energy, it is in an excited state. Wavelike properties of electron help relate atomic emission spectra, energy states of atoms, and atomic orbitals Bohr model of the atom A photon is a particle of electromagnetic radiation having zero mass and carrying a quantum of energy. When a photon strikes an atom it gives the atoms more energy. If enough photons strike an atom it may cause electrons to jump levels. Bohr model of the atom KC 5: The excited state occurs when an atom has a higher potential energy than it has at its ground state. When an excited atom falls back to its ground state the substance will give off a unique color of light. Bohr model of the atom KC 6: The behavior of electrons is still not fully understood, but it is known that they do not move around the nucleus in circular orbits We use Bohr’s model because it is easy to picture and gives us a basic understanding of the atom Whiteboard Practice Draw the Bohr model for the following elements: Boron Calcium Chlorine Nitrogen EQ 4: What is an atom made of? Know Want to know Learned EQ 4: What is an atom made of? KC 1: An atom is made of a nucleus containing protons and neutrons. Electrons move around the nucleus. EQ 4: What is an atom made of? KC 2: The number of protons and the mass number define the identity of the atom Each element contains a unique positive charge in their nucleus What is an atom made of? KC 3: The number of protons in the nucleus of an atom identifies the element and is known as the element’s atomic number Atoms and Isotopes All atoms of a particular element have the same number of protons and electrons but the number of neutrons in the nucleus can differ KC 4: Atoms with the same number of protons but different numbers of neutrons are called isotopes Atomic Mass and Isotopes The relative abundance of each isotopes is usually constant Isotopes containing more neutrons have a greater mass Isotopes have the same chemical behavior KC 5: The atomic mass is the sum of the protons and neutrons in the nucleus Atomic Mass and Isotopes Isotopes There are 2 ways you will see isotopes written: Aluminum-27 27 13 Al Atomic Mass One atomic mass unit (amu) is defined as 1/12th the mass of a carbon-12 atom One amu is nearly, but not exactly, equal to one proton and one neutron. Calculating Averages If you are shopping, and something is $24.99 and 15% off, how much would you pay? Average Atomic Mass KC 6: The average atomic mass of an element is the weighted average mass of the isotopes of that element Average Atomic Mass Average atomic mass = (mass1 x abundance1) + (mass2 x abundance2) + … Istotope Mass Abundance Total Mg - 24 23.985 0.7870 18.876 Mg - 25 24.986 0.1013 2.531 Mg - 26 25.983 0.1117 2.902 Average atomic mass = 24.309 amu Practice Problems 1. The four isotopes of lead and its abundances are: Pb-204, 1.37%; Pb-206, 26.26%; Pb-207, 20.82%; and Pb-208, 51.55%. Calculate lead’s approximate atomic mass. Istotope Mass Abundance Pb-204 Pb-206 Pb-207 Pb-208 Average atomic mass = Total Practice Problems 2. Calculate the average atomic mass of neon if neon exists naturally as 90.92% neon-20, 0.257% neon-21, and 8.82% neon-22. Istotope Mass Abundance Average atomic mass = Total Practice Problems 3. Titanium has 5 common isotopes: 46Ti (8.0%), 47Ti (7.8%), 48Ti (73.4%), 49Ti (5.5%), 50Ti (5.3%). What is the average atomic mass of titanium? EQ 5: How do you determine the number of protons, neutrons, and electrons in an atom? Atom Basics – building blocks of chemistry These are must knows!! You must be able to answer the following questions… 1. What is my name? 2. What is my atomic number? 3. What is my average atomic mass? 4. (Pick one of my isotopes on the left side of the card). What would the atomic mass of that particular atom? 5. How many protons do I have? 6. How many neutrons do I have? 7. How many electrons do I have if I am neutral? 8. (Pick an ion of the right side of the card). How many protons and electrons do I have? 9. (Consider that I am the previous chosen isotope above and a neutral atom) What happens to me if I gain a p+_________ no_________ e- ________ 10. What happens to me if I lose a p+_________ no_________ e- _________ 1. What is my name? 2. What is my atomic number? KC 1: An atom’s atomic number is equal to the number of protons, which is found on the periodic table 3. What is my average atomic mass? KC 2: Average atomic mass is the averages of all of the isotopes of an element. This number is calculated and based on abundance, but also found on the periodic table. 4. What is the atomic mass of a particular isotope? 5. How many protons do I have? KC 3: The number of protons is equal to the atomic number, which is found on the periodic table 6. How many neutrons do I have? KC 4: The atomic mass = protons + neutrons Atomic number = number of protons KC 5: neutrons = atomic mass – atomic number 7. How many electrons do I have if I am neutral? KC 6: The number of electrons is equal to the number of protons in a neutral atom 8. How many protons and neutrons do I have if I am neutral? If the atom is neutral, the protons and neutrons are found from the atomic mass and atomic number of that particular isotope Protons = atomic number Neutrons = atomic mass – atomic number 9. & 10. What happens if I gain/lose a p+, n0, and e-? KC 7: When the number of protons changes, the identity of the element changes KC 8: When the number of neutrons changes, the atomic mass changes KC 9: When the number of electrons changes, the atom is no longer neutral and has a charge What happens if I gain/lose a p+, n0, and e-? Example: Calcium – 40 p+________________ no________________ e- _________________ 1. What is my name? 2. What is my atomic number? 3. What is my average atomic mass? 4. (Pick one of my isotopes on the left side of the card). What would the atomic mass of that particular atom? 5. How many protons do I have? 6. How many neutrons do I have? 7. How many electrons do I have if I am neutral? 8. (Pick an ion of the right side of the card). How many protons and electrons do I have? 9. (Consider that I am the previous chosen isotope above and a neutral atom) What happens to me if I gain a p+_________ no_________ e- ________ 10. What happens to me if I lose a p+_________ no_________ e- _________