DBE ESSENTIALS GRADE 10 Copyright Notice: The theory summaries in this Smart Prep Book are the original work of Science Clinic (Pty) Ltd. You may distribute this material as long as you adhere to the following conditions: • If you copy and distribute this book electronically or in paper form, you must keep this copyright notice intact. • If you use questions or syllabus summaries from this book, you must acknowledge the author. • This Smart Prep Book is meant for the benefit of the community and you may not use or distribute it for commercial purposes. • You may not broadcast, publicly perform, adapt, transform, remix, add on to this book and distribute it on your own terms. By exercising any of the rights to this Smart Prep Book, you accept and agree to the terms and conditions of the license, found on www.scienceclinic.co.za/terms-book- usage/ Content Acknowledgement Many thanks to those involved in the production, translation and moderation of this book: R Bartholomew, T Britz, S Chowles, W Cloete, L Couperwthwaite, S Dippenaar, I Govender, J Hayes, R Lodge, J MacPhee, Q Meades, J Mitchell, G Moore, A Mouton, K Munnik, C Orchison, M Potgieter, R Ramsugit, X Sithenjwa www .scienceclinic.co.za facebook.com/scienceclinicsa c Science Clinic (Pty) Ltd 2018 Grade 10 Science Essentials WHY YOU SHOULD STUDY SCIENCE SCIENCE CLINIC 2018 © Science is amazing! It is also one of the toughest subjects at school. Science-y careers are diverse and exciting, but require years of vigorous academic commitment. If it’s so hard to get somewhere with Science, why should you study it? Here’s our top reasons for getting your nerd on: 4. Diversity and flexibility: From dentistry to plasma physics, Science-y careers offer vast opportunities for professional career development and diversification. Engineers are welcomed into the financial sector, due to their problem-solving ability and analytical way of thinking. Many academic physicists teach, perform ground-breaking research and consult private clients in the same work week. Medical professionals diversify into the legal field to become patent attorneys or medical lawyers. However on the flip side, it’s rare for a professional with a ‘non-Science-y’ background to bridge into the Science-based career fields. 1. Be a modern-day hero: The single greatest reason why we should study Science, is to ensure Humanity’s sustainable survival on Earth! Ecosystems are in crisis mode, the planetary weather system is changing rapidly, and humanity is failing to coexist in harmony with other species. World food production has to double in the next thirty years, in order to sustain the growing global population. We are running out of fossil fuels which are critical to the efficiency of our industry, farming and supply chains. Fresh water is becoming increasingly scarce, with many of the World’s greatest rivers no longer running into the sea. Diseases are becoming increasingly resistant to antibiotics. The air in many Indian and Chinese cities are verging on unbreathable. The Great Pacific Garbage Patch has become an unfathomable mass of floating junk that is destroying our oceans. The use of fossil fuels is polluting our air and adding to the Greenhouse Effect. 5. Inventions: Science-y careers create an intellectual and business environment that is conducive to problem solving and invention. Look at all the exciting inventions of the last twenty years, that have completely transformed our lifestyles. The Internet, the everyday use of GPS, mobile phone technology, PC’ and touch-screen displays are but a few. This technological progress was made possible due to Science. Before you despair, there is a silver lining: every one of these problems can be improved, and even solved, through Science! If you are passionately concerned about this Planet and about a healthy future for Humanity, get stuck into your Science studies and aim for a Science-y career that will equip you to make a difference! Visit online crowdfunding platforms such as Kickstarter and Indiegogo, and appraise the exciting Science-y inventions that are being funded. The tech scene is mushrooming with skunkworks and hackathons that are creating radical innovations. It is an exciting time to be part of Science and technology, and if you want to be at the cusp of making cool things that make a big difference, study Science! 2. Be smart: The study of Science encourages problem-solving tenacity that helps you to understand the world around you. I have always explained to my students that Science illuminates one’s path, and that going through life without Science is similar to driving your car along dark roads your headlights might light your way forward, but they don’t illuminate the world around you. You travel onwards without ever understanding the context of your journey. Studying Science makes you comfortable with the unknown, and gives you the confidence to say: “I don’t know the answers, but I will find out!”. Science is gracious to naivety but does not condone the apathy of indifference: it allows you to say “I don’t know, but I want to find out”, but does not tolerate the attitude of “I don’t know and I don’t care”. 6. Be a modern-day hero (#2): South Africa has a growing deficit of expert Science teachers. If you are passionate about Science, and passionate about making a difference, teaching is a massively rewarding career path that is becoming increasingly lucrative. Remember, supply and demand dictate going rates - if there are fewer expert Science teachers around, the demand for expertise leads to increased fees. Become a Science teacher, a thought leader and a role model! 7. Wealth: More than a fifth of the planet’s wealthiest people on the Forbes 2015 list studied an engineering degree, according to a recent survey by the Approved Index platform. A quarter of the Forbes top-hundred have Science as a foundation for their work. Science is highly structured, but welcomes change - it constantly adjusts its views based on what is observed. This approach teaches you to evolve your thinking by constantly testing and investigating information, which makes you a well-rounded human being and empowers you with an ethical approach to others: it enables you to discern the difference between your opinions and facts, and to acknowledge the opinions and beliefs of others without immediately accepting or rejecting them. 8. Discovery: Science research is a field that allows you to discover the unknown. The deep oceans are unexplored, nanotechnology and photonic crystals have so many secrets, and we’re still not sure whether there is any form of life outside near-Earth space. Imagine being the person that publishes a peer-reviewed article to tell the world about a brand new discovery, or a new revelation in our understanding, or a life-altering breakthrough in technology. 3. Be adventurous: Science gets you places! I can only speak from my experience - my engineering background, which is firmly rooted in Science, has opened a door to great adventure and exploration. I have worked on four continents and have been exposed to a diversity of incredible experiences that a ‘normal’ office job would never allow. Would you like to work in jungles? Study Natural Sciences. A life of studying volcanoes or auroras, perhaps? Study geosciences. Would you like to ply you mind to solving massive problems and driving innovation? Study engineering! Would you like to work with killer whales? Study zoology! This is a call to action for young history-makers, and for a new wave of heroes to save this world and make a difference. I encourage you to become part of it! James Hayes Founder – Science Clinic Science-y careers and research allow you visit places that would not be accessible through other fields of study. Whether you want to go to Antarctica or to outer space, Science is the way to get there. 1 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za www 1 TABLE OF CONTENTS Foreword 4 6 10 Physics Physics data Pulses and Waves Sound & Electromagnetic radiation 14 15 16 19 20 27 56 29 31 33 35 36 40 42 45 47 50 54 Magnetism Electrostatics Electricity Vectors and Scalars Motion in 1D Energy Chemistry Chemistry data Classification of matter Names and formulae Kinetic molecular theory The atom The periodic table Chemical bonding Physical and chemical change Reactions in aqueous solutions Quantitative aspects of chemical change Hydrosphere Mathematics essentials www GENERAL INFORMATION Quantities, symbols and units Unit name Unit symbol kg m m -1 m·s -1 m·s -1 m·s -2 m·s Alternative symbol kilogram metre metre metre per second metre per second metre per second metre per second per second m·s s u, v u v Preferred symbol m x, y Δ x, Δ y v x, v y vi vf a metre per second per second Ek Ep Fg ν ε -2 g λ t Δt E K U W F w s s J J J J N N m -1 Hz or s s -1 m·s C V V A f T c Q, q Δ V, V E I, i R Ω second second joule joule joule joule newton newton metre hertz or per second second metre per second coulomb volt volt ampere ohm The most common quantities, symbols and SI units used in introductory Physics are listed below. A quantity should not be confused with the units in which it is measured. Quantity mass position displacement velocity initial velocity final velocity acceleration acceleration due to gravity time (instant) time interval energy kinetic energy potential energy work force weight wavelength frequency period speed of light charge potential difference emf current resistance Conventions (e.g. signs, symbols, terminology and nomenclature) The syllabus and question papers will conform to generally accepted international practices. NOTE: 1. For marking purposes, alternative symbols will also be accepted. 2. Separate compound units with a multiplication dot, not a full stop, for example m·s-1. For marking purposes, m.s-1 will also be accepted. 3. Use the equal sign only when it is mathematically correct, for example: Incorrect: 1 cm = 1 m (on a scale drawing) Correct: 1 cm = 10-2 m 1 cm represents 1 m (on a scale drawing) Information sheets – Paper 1 (Physics) me e h c g SYMBOL/SIMBOOL 9,11 x 10-31 kg -1,6 x 10-19 C 6,63 x 10-34 J·s 3,0 x 108 m·s-1 9,8 m·s-2 VALUE/WAARDE TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES NAME/NAAM Acceleration due to gravity Swaartekragversnelling Speed of light in a vacuum Spoed van lig in 'n vakuum Planck's constant Planck se konstante Charge on electron Lading op elektron Electron mass Elektronmassa TABLE 2: FORMULAE/TABEL 2: FORMULES Δx = v i Δt + 21 aΔt 2 MOTION/BEWEGING v f = v i + a Δt 2 ⎛ v + vi ⎞ Δx = ⎜ f ⎟ Δt ⎝ 2 ⎠ 2 v f = v i + 2aΔx K= 1 1 mv 2 or/of E k = mv 2 2 2 WORK, ENERGY AND POWER/ARBEID, ENERGIE EN DRYWING U = mgh or/of EP = mgh c λ T= 1 f WAVES, SOUND AND LIGHT/GOLWE, KLANK EN LIG v=fλ E = hf or/of E = h 1 1 1 = + + ... R p R1 R 2 ELECTRIC CIRCUITS/ELEKTRIESE STROOMBANE Q = I Δt V= W Q R s = R1 + R 2 + ... Transverse pulses Grade 10 Science Essentials Pulse: A single disturbance in a medium. Transverse pulse: A pulse in which the particles of the medium move at right angles to the direction of motion of the pulse. SCIENCE CLINIC 2018 © INTERFERENCE OF PULSES Interference: The overlapping of two pulses when they coincide. They meet at the same point at the same time. Superposition: The algebraic sum of the amplitudes of two pulses that occupy the same space at the same time. Constructive interference: The phenomenon where the crest of one pulse overlaps with the crest of another to produce a pulse of increased amplitude. Destructive interference: The phenomenon where the crest of one pulse overlaps with the trough of another, resulting in a pulse of reduced amplitude. When two pulses meet: CONSTRUCTIVE INTERFERENCE Before After 2a The particles in the rope move vertically up and down as the pulse moves to the right (particles are moving perpendicular to the direction of movement of the pulse). Amplitude (a) Rest posi)on During a a X Y X Y a a a a X+Y Y X X+Y Y X a a Pulse length 2a Rest position: The position from which all particles start from and return to after a pulse or wave has passed. Amplitude: The maximum displacement of particles from the rest position. Pulse length: The distance between the start and end of a pulse. A pulse moves through a medium at a certain speed (v): distance (m) speed of pulse (m ⋅ s−1) v= D Δt DESTRUCTIVE INTERFERENCE Before time (s) During a Y X a a Y X-Y After Y a X a EXAMPLE: A pulse travels a distance of 300m in 2 minutes. Determine the speed of the pulse. v= D Δt v= 300 120 X X-Y Y X b-a b v = 2,5 m ⋅ s−1 6 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za a b Transverse waves Grade 10 Science Essentials FORMATION OF TRANSVERSE WAVES Each disturbance in a medium creates a transverse pulse. Many disturbances of transverse pulses repeated at regular intervals creates a transverse wave. Hand moves up → back to rest position, and then down → back to rest position. Frequency (f) Frequency: The number of waves per second. Unit: Hz (hertz) SCIENCE CLINIC 2018 © CALCULATIONS Period (T) Period: The time taken for one complete wave. Unit: s (seconds) Wave speed (v) Wave Speed: The distance travelled by a point on a wave per unit time. speed (m ⋅ s−1) distance (m) D v= Δt Rest posi)on frequency = This motion continues at regular intervals to form a transverse wave. Transverse wave: A wave in which the particles of the medium vibrate at right angles to the direction of motion of the wave. A transverse wave is a succession of transverse pulses. number of waves total time period = Example: 5 waves pass a point in 4 s, calculate the frequency of the number of waves waves. frequency = total time 5 T = = 1,25 Hz 4 total time number of waves Example: 5 waves pass a point in 4 s, calculate the period of the waves. total time period = number of waves 4 T = = 0,8 s 5 T= Rest posi9on ONE TRANSVERSE WAVE OR f= Wave speed (v) Wave Speed: The distance travelled by a point on a wave per unit time. frequency (Hz) T- period (s) Distance (m) or Time (s) Wavelength (λ) IN phase: A–E B–F A–I D–H B F C A λ λ D I G E H Distance (m) or Time (s) λ - Trough Amplitude (a): the maximum displacement of particles from the rest position. Wavelength (λ): the distance between two consecutive points in phase. Crest: the highest point (peak) on a wave. Trough: the lowest point on a wave. wavelength (m) MULTIPLE TRANSVERSE WAVES λ Amplitude (a) v = fλ Example: Calculate the speed of a wave with a frequency of 28 Hz and a wavelength of 5 mm. v = fλ v = (28)(5 × 10−3) v = 0,14 m ⋅ s−1 f- frequency (Hz) 1 T + Crest (a) - 1 f Distance (m) Distance (m) + Example: Calculate the speed of a wave that travels 50m in 7s. D v= Δt 50 v= = 7,14 m ⋅ s−1 7 speed (m ⋅ s−1) RELATIONSHIP BETWEEN FREQUENCY AND PERIOD time (s) Points in phase: Two points in phase are separated by a whole number (1; 2; 3; …) multiple of completed wavelengths. Points in phase follow the exact same path (have identical motion). Points totally out of phase: two points following exactly the opposite path. Points partially out of phase: Points that are not separated by a whole number multiple of completed wavelengths. Two points which follow different paths. 7 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za TOTALLY OUT of phase: A–C B–D A-G D–F PARTIALY OUT of phase: A–B B–E A-F D–E Longitudinal waves ion Co C m re fa B Ra Co A IN phase: A–C C–E B–D A–E pr es s c3 o n ion pr es s Ra Longitudinal wave: a wave in which the particles of the medium vibrate parallel to the direction of motion of wave. Compression: A region of high pressure in a longitudinal wave. Rarefaction: A region of low pressure in a longitudinal wave. Rarefaction: The maximum displacement of a particle from its rest position. Co m re fa pr es s c3 o n ion When a series of forwards and backwards movements are made to a spring in consecutive intervals it creates a longitudinal wave. When particles are pushed closer together a compression is formed and when particles are drawn apart a rarefaction is formed. Wavelength is represented by the distance between consecutive compressions or consecutive rarefactions. SCIENCE CLINIC 2018 © m Grade 10 Science Essentials D TOTALLY OUT of phase: A–B B–C C–D A–D E λ λ λ CALCULATIONS Frequency (Hz) Period (T) Frequency: the number of waves that pass a point in one second. Unit: Hz (hertz) frequency = Period: the time taken for one wave to pass a point. Unit: s (seconds). number of waves total time frequency = = f = f = Wave Speed: the distance a wave travels in one second. speed (m ⋅ s−1) D v= Δt number of waves total time Example: 8 waves pass a point in 3 s, calculate the period of the waves. number of waves total time 8 3 period = f = f = 2,67 Hz total time number of waves 3 8 v = v = v = OR f- Frequency (Hz) T- period (s) 1 f= T time (s) Example: Determine the period of a wave that has a frequency of 75 Hz T = f = f = 0,013 Hz 8 f = f = f = 20m ⋅ s−1 frequency (Hz) Example: Determine the frequency of a wave that has a period of 0,3 s 1 f 1 75 D Δt 6000 300 Wave equation 0,38 s Relationship between frequency and period 1 T= f distance (m) Example: Calculate the speed of a wave that travels 60 km in 5 min. Example: 8 waves pass a point in 3 s, calculate the frequency of the waves. frequency Wave speed (v) 1 T 1 0,3 speed (m ⋅ s−1) v = fλ wavelength (m) Example: Determine the speed of a wave with a 20 mm wavelength and a frequency of 600 Hz. v = fλ v = (600)(20 × 10−3) 3,33 Hz For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za v = 12 m ⋅ s−1 Pulses and Waves- THE ESSENTIALS Grade 10 Science Essentials SCIENCE CLINIC 2018 © A pulse is a single disturbance that is propagated from a source through a medium. A wave is a repetition of pulses at regular intervals. LONGITUDINAL Transverse pulse: a pulse in which the particles of the medium move perpendicular to the direction of propagation of the pulse. Longitudinal pulse: a pulse in which the particles of the medium move parallel to the direction of movement of the pulse. Co m pr es s ion TRANSVERSE Amplitude (a) Rest posi)on Pulse length A transverse wave is a succession of transverse pulses, eg water waves. Crest ion n m pr es s c3 o Co C re fa pr es s m Co B Ra n c3 o re fa m Co Ra Rest posi9on pr es s Amplitude (a) ion A longitudinal wave is a succession of longitudinal pulses. e.g. sound waves ion Distance (m) + Distance (m) or Time (s) Wavelength (λ) A D λ (a) λ λ Trough - Frequency(f): the number of waves per second. f = 1 T Superposition: The algebraic sum of the amplitudes of two pulses that occupy the same space at the same time. Constructive interference: The phenomenon where the crest of one pulse overlaps with the crest of another to produce a pulse of increased amplitude. Destructive interference: The phenomenon where the crest of one pulse overlaps with the trough of another, resulting in a pulse of reduced amplitude Wavelength(λ): the distance between two consecutive points in phase. Amplitude: the maximum displacement of a particle from the rest position. Period(T): the time taken for one complete wave. Unit: s (seconds). T = 1 f Wave speed (v): The speed of a wave through the medium. v = fλ 9 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za E Sound Grade 10 Science Essentials SCIENCE CLINIC 2018 © WAVE PROPERTIES & SOUND SOUND WAVES Sound is created by vibrations in a medium in the direction of propagation (longitudinal wave). The vibrations cause regular variation in pressure in the medium. Sound waves are 3D longitudinal waves that travel through solids, liquids and gases but not through a vacuum → a medium is necessary for the propagation of sound. The denser the medium, the greater the speed of sound through that medium. FREQUENCY- What the human ear perceives as pitch. Measured in hertz (Hz) Pitch is directly proportional to frequency • A high pitch = high frequency. (i.e. brakes of a car squealing) • A low pitch = low frequency. (i.e. a bass guitar) A loudspeaker has a paper cone which is able to move back and forth, producing a series of compressions and rarefactions through the air. The small changes in pressure are detected by the ear and we perceive this as sound. The waves move away from the speaker in 3 dimensions getting weaker the further they travel. The amplitude diminishes and the loudness decreases. AMPLITUDE- what the human ear perceives as volume (loudness). Measured in decibels (dB). Loudness is directly proportional to amplitude • A high volume = large amplitude. • A low volume = small amplitude. ULTRASOUND ECHOES • Humans can hear sounds between 20 Hz and 20 kHz. • Ultrasound Refers to sound waves of a higher frequency than we can hear. (20 kHz to 100 kHz) Sound waves are reflected by large hard flat surfaces such as buildings walls and cliffs. EXAMPLE: The time taken for an echo to be heard by a listener on a ship is measured and is found to be 0,8 s. The speed of sound in water is 1480 m·s−1 . Determine the depth of the water at this point. Uses •Treatment of sports injuries: waves are fed through the skin to increase blood flow to the injured area. •Imaging in pregnancy: When an ultrasound wave encounters a boundary in a medium, part of the wave is reflected, part absorbed and part is transmitted through the boundary. The reflected waves are detected in the same way as echoes and can be used to form an image (sonar imaging). The reflection of the sound wave is known as an echo. An echo can be used to calculate unknown distances. REMEMBER: When a wave reflects/echoes, the wave had to travel to the object and back. It has therefore travelled double the distance between the source and the reflection surface. SOURCE Source Using sonar can produce a safe method of early diagnosis of fetal conditions and early treatment can be implemented. Echo LISTENER d Boats: use sonar to locate fish and measure the depth of the ocean. Echo Sound 1480 = D D = = depth = depth = depth = v = v = v = = = 2 × 250 500 m D Δt 500 1,5 333,33 m ⋅ s−1 ∴ speed of sound = 333,33 m ⋅ s−1 10 D Δt D 0,8 (1480)(0,8) 1184 m D 2 1184 2 592 m EXAMPLE: A man stands 250 m from a wall and hears the echo of his gunshot after 1,5 s. Calculate the velocity of sound under the circumstances. distance traveled by sound •Bats: use ultrasound to locate insects and to navigate in the dark. = The sound has to travel to the bottom and then reflect back to the ship at the surface. sound http://en.wikipedia.org/wiki/Ultrasound#/media/File:CRL_Crown_ rump_lengh_12_weeks_ecografia_Dr._Wolfgang_Moroder.jpg v For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Electromagnetic radiation Grade 10 Science Essentials SCIENCE CLINIC 2018 © Electromagnetic radiation behaves like a WAVE when it travels PARTICLE when it interacts with other materials WAVE NATURE OF ELECTROMAGNETIC RADIATION PARTICLE NATURE OF ELECTROMAGNETIC RADIATION • Accelerating charges are the source of all Electromagnetic Radiation. • The accelerating charges create a constantly changing electric field which travels away from the source in 3 dimensions. The continuously changing electric field then induces a changing magnetic field that is perpendicular to the electric field.The changing magnetic field in turn produces an electric field. Electromagnetic waves are created by oscillating magnetic and electric fields which move at right angles to each other and to the direction of the propagation of the wave. Accelerating charges produce a… Continuously changing electric field which then induces a… Continuously changing magnetic field at 90⁰ • • • • Electromagnetic radiation transfers energy to other matter in “packets” called photons. Photons have a set amount of energy → called a quantum. The amount of energy is directly proportional to the penetrating ability of the specific EM-radiation. A Photon is a quantum of EM radiation (which carries a set amount of energy) Energy of a photon can be calculated using the formula: energy (J) Electromagnetic wave is created E = hf Electric field Magne/c field frequency (Hz) Planck's constant (6,63 × 10−34 ) Direc/on of propaga/on Planck's constant (6,63 × 10−34 ) hc E= λ energy (J) speed of light (3 × 108 m ⋅ s−1) wavelength (λ) WAVE EQUATION (EM) The wave is propagated at a speed of 3×108 m·s−1. This is called c (speed of light). All electromagnetic waves travel at the speed of light. wave speed (m ⋅ s−1) wavelength (m) c = fλ frequency (Hz) EXAMPLE: Calculate the energy of a microwave with a frequency of 4,5 × 1010 Hz. EXAMPLE: Determine the wavelength of ultraviolet waves with a frequency of 1,6 × 1016 Hz c 3 × 108 = = fλ (1,6 × 1016 )λ λ = 1,88 × 10−8 m EXAMPLE: Determine the frequency of a radio wave with a wavelength of 300 m c 3 × 108 = = f = E E = = E = EXAMPLE: Determine the energy of gamma ray with a wavelength of 4 × 10−14 m. hf (6,63 × 10−34 )(4,5 × 10−10 ) 2,98 × 10−43 J E = E = E = hc λ (6,63 × 10−34 )(3 × 108 ) (4,5 × 10−14 ) 4,42 × 10−12 J PENETRATING ABILITY The penetrating ability of a wave refers to its ability to move through matter. fλ f(300) 1 × 106 m The higher the energy, the greater the penetrating ability. 11 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za penetrating ability α Energy penetrating ability α Frequency Grade 10 Science Essentials Electromagnetic radiation- Spectrum SCIENCE CLINIC 2018 © INCREASING FREQUENCY INCREASING WAVE ENERGY INCREASING WAVELENGTH Ultraviolet light (UV) X-rays Gamma rays 4 x 1014 to 7 x 1014 1 x 1016 1 x 1019 1 x 1022 1 x 10-4 7 x 10-9 to 4 x 10-9 1 x 10-8 1 x 10-10 1 x 10-14 Remote controls; op4cal fibers Objects reflect, refract or transmit light that we are able to see; photosynthesis Light bulbs; steriliza4on x-rays; CT scans; security scans Radia4on of cancer Damage to eyes and skin Damage to skin and underlying 4ssue Damage to 4ssue; nuclear radia4on Radio waves Frequency (Hz): 1 x 106 1 x 1010 1 x 1012 Wavelength (m): 1 x 102 1 x 10-2 Radio and TV broadcasts; radio telescopes Telephone and cell phone connec4ons; communica4on satellites; microwave ovens; radar systems Advantages: Microwaves Visible light Infrared radiation (IR) EM Radiation: R O Y G Disadvantages: 12 B I V For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Sound and EM Waves-THE ESSENTIALS Grade 10 Science Essentials Sound EM Radiation •Sound waves are created by vibrations in a medium. • • • • • • •The speed of sound in air = 340 m·s-1 •Sound is a longitudinal wave that travels through solids, liquids and gases but not through a vacuum. Frequency: Accelerating charges are the source of all Electromagnetic Radiation. Propagates as electric and magnetic fields which are perpendicular to each other. The wave is propagated at a speed of 3x108 m.s-1 in a vacuum. This is called c (speed of light) Does not need a medium to propagate through; can travel through a vacuum. Electromagnetic radiation behaves like a transverse wave when it propagates. Electromagnetic radiation behaves like a particle when it interacts with other materials Amplitude: What the human ear perceives as pitch. What the human ear perceives as volume. Measured in decibels (dB). •A high pitch = high frequency. (I.e. brakes of a car squealing) •A low pitch = low frequency. (I.e. a bass guitar) WAVE NATURE wave speed •A high volume = large amplitude. •A low volume = small amplitude. (m ⋅ s−1) PARTICLE NATURE wavelength (m) c = fλ • Energy of a photon can be calculated using: energy (J) Sound waves are reflected by large hard flat surfaces such as buildings walls and cliffs. The reflection of the sound wave is known as an echo. An echo can be used to calculate unknown distances. Source • Electromagnetic radiation transfers energy in “packets” called photons Photon: quanta (energy packets) that transfer energy to particles of matter frequency (Hz) ECHOES SOURCE SCIENCE CLINIC 2018 © As the frequency increases, the wavelength decreases. E = hf In any given medium, the speed remains constant. Planck′s constant (6,63 × 10−34 ) sound Planck′s constant (6,63 × 10−34 ) Electromagnetic Spectrum f Radiowaves Echo LISTENER Waves λ frequency (Hz) E= hc λ speed of light (3 × 108 m ⋅ s−1) wavelength (λ) Microwaves Infrared d Visible light In the picture: distance to wall and back 2D = = energy (J) Ultraviolet v ×t v ×t X-Rays Gamma Rays where v is the speed of sound in air; v = 340 m ⋅ s−1 13 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za The greater the energy of a photon, the higher its frequency and its penetrating ability (and the smaller/ shorter the wavelength) Magnetism Grade 10 Science Essentials Magnetic field: region in space where another magnet or ferromagnetic material will experience a non-contact force Non-contact force: A force exerted on an object without touching the object. Magnet: an object with a pair of opposite poles, called north and south Magnets can be made from ferromagnetic materials; materials which are strongly attracted by magnets and are easily magnetised. Common ferromagnetic materials include iron, cobalt, nickel and their alloys. When two magnets are brought close to each other: ~ Like poles → REPEL each other ~ Unlike poles → ATTRACT each other Even if a magnet is cut into little pieces it will form smaller magnets, each with their own north and south poles N NS N S S N S • Magnetic field lines are imaginary lines around a magnet indicating the direction and the strength of the magnetic field surrounding the magnet (iron filings on paper can be used to indicate the field lines) The field lines occur inside the magnet and 3 dimensionally outside it. They come out of the magnet near the north pole and enter near the south pole again forming a loop. SCIENCE CLINIC 2018 © Earth’s Magnetic Field The Earth behaves as if it has a giant bar magnet running through it, with its magnetic field looping around the earth The arrow of the compass is the North pole of the compass, and points towards magnetic North Pole of the Earth. In reality, the North pole of the Earth is actually the South pole of the imaginary magnet through the Earth. The point in the Northern Hemisphere where the Earth’s axis meets the surface of the Earth is the geographical or true North Pole. A compass will not point to this, but rather to the magnetic North Pole – which is actually the South pole of the imaginary magnet through Earth. The angle between the true North Pole and the magnetic North Pole is called the angle of declination. Geographical north pole: Point in the northern hemisphere where the rotation axis of the earth meets the surface. Magnetic north pole: The Point where the magnetic field lines of the earth enters the earth.It is the direction in which Magne)c North Pole Bar magnet N S Geographical North Pole Other “fields” in physics Properties of magnetic field lines • Imaginary lines • Continuous • 3 dimensional • Never cross or touch • Arrows indicate the direction of the field (N to S) • Are more concentrated at the poles where field is stronger Magnetic field Area in which a magnetic material experiences a magnetic force Electric field Area in which an electric charge experiences an electric force Gravitational field Area in which a mass experiences a gravitational force Magne&c North Pole S Geographical South Pole Geographical North Pole Angle of declina&on S N N Magne)c South Pole Attraction between unlike poles Repulsion between like poles Magnetic Phenomena The sun releases particles (mainly electrons and protons) which travel outwards in all directions at speeds of up to 900 m.s⁻¹. N S N S N S S N More particles are released during a solar storm called a coronal mass ejection. When these particles come close to the Earth, the Magnetosphere protects the Earth by deflecting most of the particles, however some penetrate the Magnetosphere and are pulled towards our North and South Poles. They enter the upper atmosphere at high speed and collide with nitrogen and oxygen molecules causing them to glow with different colours. These are known as the Aurora Borealis (Northern lights) and Aurora Australis (Southern lights). 14 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Electrostatics Grade 10 Science Essentials • All materials contain positive charges (protons) and negative charges (electrons) • A neutral object has an equal number of protons and electrons and has no net charge. • A positively charged object has lost electrons (electron deficient) • A negatively charged object has gained electrons (excess of electrons) • A charged object can also be attracted to a neutral conductor because of the movement of charges in the conductor • A charged object can also be attracted to an insulator because of the movement of polarised molecules present in the insulator • Charged objects exert forces on each other when brought close together • Like charges exert REPULSIVE forces on each other • Opposite charges exert ATTRACTIVE forces on each other QUANTISATION OF CHARGE The charge on a single electron is Methods by which a neutral object can become charged Friction • Also known as tribo-electric charging • Rub two objects together such as a glass rod and a woolen cloth. Electrons are transferred from one object to the other (this depends on which materials are used) • The one object loses electrons and the other gains them Glass rod and woolen cloth 3e¯ 3p⁺ charge of e− ( − 1,6 × 10−19 ) Q = nqe charge (C) number of electrons Examples: Calculate the number of electrons gained or lost by (a) +4,5 nC and (b)-9 µC Q = +4,5 × 10−9 = n = ∴ = neutral Q 4e¯ 4p⁺ −9 × 10−6 = n = electrons gained 0C neutral +1,4C +1,4C Neutral 7e¯ 4p⁺ 2e¯ 5p⁺ + Transfers nega5ve charge -2,3C 0C neutral neutral Nega-vely charged (e¯ excess) neutral -2,3C -2,3C Temporary charge (polarised) + ---- - - Neutral + + + + + + + + + + e⁻ are attracted to the positive rod. Positively charged leaves repel each other Nega%ve rod -+ -+ -+ + + - -+ + - -- Semi-permanent charge -- + + + ++ + + + + + + e¯ A negative rod is brought close to a neutral electroscope. The e-s are repelled. touch Posi-vely charged (e¯ deficient) + -+ -+ -+ + + - -+ + - + + A positive rod is brought close to a neutral electroscope Negative conductor touches a neutral conductor → negative charges are transferred from negative to neutral charge -4,6C Electroscope is earthed allowing extra e-s to come towards the rod. A semi-permanent charge is created. PRINCIPLE OF CONSERVATION OF CHARGE Principle of conservation of charge: the net charge of an isolated system remains constant during any physical process. Eg. When identical objects with different charges touch, charges will be transferred between conductors. The two conductors will then have equal charge. EXAMPLE: Two identical charges on insulated stands, +5 mC and -9 mC respectively, touch and move apart again. Determine (a) the new charge on each, (b) the amount of charge transferred and (c) the amount of electrons transferred. Amount of charge transferred: a) New charge on each: = 5,63 × 1013 Nega-vely charged (e¯ excess) Fric-on e¯ Q new n(−1,6 × 10−19 ) Posi-vely charged (e¯ deficient) 5e¯ 5p⁺ −2,81 × 1010 nq e + Transfers nega5ve charge +2,8C PVC rod and woolen cloth: = = Posi%ve rod -1,4C neutral Q new 2,81 × 1010 electrons lost Induction A method of charging whereby the objects do not touch one another. Neutral electroscope is charged by induction. touch nq e n(−1,6 × 10−19 ) Positive conductor touches a neutral conductor → negative charges are transferred from neutral to positive charge 7e¯ 5p⁺ 1e¯ 3p⁺ 5e¯ 5p⁺ Contact When a charged conductor touches an identic a l n e u t ra l c o n d u c t o r, e l e c t r o n s a r e transferred to make the charge on the conductors equal. Fric-on e¯ q e = − 1,6 × 10−19 C Principle of charge quantisation: all charges in the universe consist of an integer multiple of the charge of an electron: SCIENCE CLINIC 2018 © Q new = Q1 + Q 2 2 (+5 × 10−3) + (−9 × 10−3) 2 −2 × 10−3 C each ΔQ = Qf − Qi Charge transferred (C) new charge on each original charge before contact (you can use either of the original charges in this step) 15 c) Number of electrons transferred: ΔQ = Q f − Q i Q = 7 × 10−3 = ΔQ = − 7 × 10−3 C OR ΔQ = Q f − Q i n = 4,38 × 1016 ∴n = n(−1,6 × 10−19 ) ΔQ = (−2 × 10−3) − (+5 × 10−3) ΔQ = (−2 × 10−3) − (−9 × 10−3) ΔQ = − 7 × 10−3 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za C Q −7 × 10−3 n nq e n(−1,6 × 10−19 ) = 4,38 × 1016 OR = nq e = 4,38 × 1016 e− e− Electricity Grade 10 Science Essentials Electricity is the process of giving energy to a charge and then using that energy to do work. The most basic circuit is made of a POWER SOURCE, a LOAD and the conducting wires carrying the charge around the circuit. The POWER SOURCE gives electrical energy to the charge. The POWER SOURCE gives electrical energy to the charge. Some examples are generators, batteries, photovoltaic cells. The LOAD is a device that uses the energy of a charge. The LOAD is a device which dissipates/uses the energy. Some examples are resistors, light bulbs, motors, speakers, chargers. A battery goes “flat” when all of the stored chemical energy in the battery has been converted to electrical energy. The electrical energy is converted into other forms: heat, light, kinetic, chemical CURRENT is the rate of flow of charge. I= Q t Current Lightning 10 000 A Starter motor in car 200 A Fan heater 10 A Toaster 3A Light bulb 0,4 A Pocket calculator 0,005 A Nerve fibre in the body 0,000 001 A DEFINITION: The coulomb(C) is that quantity of charge which passes a fixed point in a conductor in one second when the conductor carries a current of one ampere. EXAMPLE: An electric current of 7.5 A flows through an electric circuit for 3 minutes. Calculate the amount of charge flowing through the circuit. Q Q Q = = = It (7,5)(3 × 60) 1350 C A torch is an example of a simple circuit. The arrows indicate the flow of conventional current. Conductor takes energized charge to load Cell (Chemical Energy into Electrical Energy) Light Bulb (Electrical Energy into Light Energy) Conductor returns charge to power source to get more energy POTENTIAL DIFFERENCE (p.d.) across the ends of a conductor is the energy transferred per unit electric charge that flows through it. V= I is the current strength, Q is the charge in coulombs and t is the time in seconds. The SI unit of current is the ampere (A). Typical values for electric current: Situation SCIENCE CLINIC 2018 © W Q V is Potential difference in V (volts), W is Work done or energy transferred in J (joules) and Q is Charge in C (coulombs). Note that 1V = means 1 joule per coulomb of charge. RESISTANCE & OHM’S LAW: Opposition to the flow of electric current. The greater the potential difference across the ends of a particular conductor, the greater the current in it. In a metal conductor, the charge carriers are electrons. The valence electrons of the metal atoms swarm around randomly in between the positive metal ions. When a voltage is applied across two points of the metal, the electrons migrate towards the positive point and collide with the particles of the metal. The kinetic energy of the electrons is transferred to the positive metal ions causing them to vibrate faster and get hot. Chemical energy → In cell Note: 1. Emf is the voltage measured across the terminals of a battery when no current is flowing through the battery (the switch is open). The emf is the work done per unit charge by the source 2. V term or potential difference (pd) is the voltage measured across the terminals of a battery when current is flowing through the battery. This is also known as the operating voltage. EXAMPLE: A battery transfers 60 kJ of energy to 5 kC of electric charge. Calculate the voltage of the battery. V = V = V = → Heat energy metal particles DEFINITION: Ohm's Law states that the current in a conductor is directly proportional to the potential difference across it provided its temperature remains constant. V = IR R is referred to as the electrical resistance of the conducting material, resisting the flow of charge through it. Resistance (R) is the ratio of the potential difference (V) across a resistor and the current (I) in it. The unit of resistance is called the ohm (Ω). EXAMPLE: A battery has a voltage of 12 V. The current that flows through the resistor in the circuit is 6 A. Calculate the resistance of the resistor. W Q 60000 5000 12 V 16 Electrical energy charge carriers For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za R = R = R = V I 12 6 2Ω Electricity- Series and Parallel Grade 10 Science Essentials SCIENCE CLINIC 2018 © Series Circuits: A 1,5 V cell is connected to 3 identical bulbs in series. This creates 3 times more resistance than one bulb, so the current is 3 times less Parallel circuits: A 1,5 V cell is connected to 3 identical bulbs in parallel. The cell has to supply 1,5 V to each bulb at the same time, so the current is 3 times more 1. 2. 3. 4. 1. The current splits into three equal parts for each of the branches. 2. If one branch breaks, the other two will still conduct current. 3. Each bulb receives the full 1,5 V provided by the cell across it There is only one path for the current to follow. The current is the same everywhere. If the circuit is broken at any point, the current will stop flowing. The 1,5V supplied by the cell is divided up into 3 equal parts (0,5 V) across each bulb. RESISTORS IN SERIES R1 • Current is split up through resistors. • The current is inversely proportional to the resistance. The smaller resistance, the more current going through it. • Voltage is the same across each resistor in the parallel combination. • “Current divider” • Cars, houses • Current is the same through each resistor • Voltage is split up across resistors. •The voltage is directly proportional to the resistance in the series combination. Most voltage will be across the largest resistance. •“Voltage divider” •Dimmer switches, Christmas lights RTOTAL = R1 + R2 . . . R2 RESISTORS IN PARALLEL COMBINATION CIRCUITS. TO SOVLE: Identify the separate series and parallel combinations in the circuit. Apply Ohms Law to each resistor, or each combination of resistors or the whole circuit consistently. STEP 1: Find the total resistance 1 RP 1 RP = = 1 RP = ∴ RP = RTOT RTOT RTOT = = = 1 R2 1 8 + + 1 R3 1 8 2 8 4Ω RP + R1 + R 4 5+4+6 15 Ω EXAMPLE: Calculate the current through each resistor and the voltage across each resistor in the combination circuit. STEP 2: STEP 3: STEP 4: Find the total current Apply known variables Apply Ohm’s law to unknown resistors to circuit components V I = I = I = R 60 15 R1 and R2 are in series ∴ ITOT = IR = IR = 4 A 1 4A 4 IR + IR = 4A 2 3 and IR = IR 2 3 ∴ IR = IR = 2 A 2 3 VR1 = IR VR1 = (4)(5) VR1 = 20 V VR = VR = IR = VR = (2)(8) = VR = 16 V VR VR 17 2 2 2 3 3 3 VR 4 = IR = (4)(6) VR 4 = 24 V VR 4 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za R1 R2 1 RTOTAL = 1 1 + R1 R2 . . . Electricity - THE ESSENTIALS Grade 10 Science Essentials Quantity Current (I) SCIENCE CLINIC 2018 © Potential Difference (V) Resistance (R) Definition The rate of flow of charge. The energy transferred per unit electric charge. The ratio of potential difference across a resistor to the current through it. Unit A (amperes) V (volts) Ω (ohms) Equation I = Q /t V=W/Q R = V /I Meaning How much charge passes every second How much energy each coulomb of charge transfers between 2 points How many volts are required to sustain a current of 1 ampere. The coulomb (C) is that quantity of charge which passes a fixed point in a conductor in one second when the conductor carries a current of one ampere Emf is the voltage measured across the terminals of a battery when no current is flowing through the battery V term or potential difference (pd) is the voltage measured across the terminals of a battery when current is flowing through the battery. Ohm's Law states that the current in a conductor is directly proportional to the potential difference across it provided its temperature remains constant. Resistance of a material is dependent on the type of material, as well as the length, thickness and temperature of the conductor RESISTORS IN SERIES RESISTORS IN PARALLEL R1 R2 RTOTAL = R1 + R2 . . . R1 •Current is the same through each resistor •Voltage is split up across resistors. The voltage is directly proportional to the resistance in the series combination. •‘Voltage divider’ •Eg. Dimmer switches R2 1 RTOTAL COMBINATION CIRCUITS. = 1 1 + R1 R2 . . . •Current is split up through resistors. The current is inversely proportional to the resistance. The smaller resistance, the more current going through it. •Voltage is the same across each resistor in the parallel combination. •‘Current divider’ • Eg Cars, houses. Current is measured with an ammeter, which is connected in series. Potential difference is measured in parallel using a voltmeter. 18 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za • Identify the separate series and parallel combinations in the circuit. • Apply Ohms Law consistently to: o each resistor, o or each combination of resistors o or the whole circuit. Vectors and Scalars Grade 10 Science Essentials NET OR RESULTANT VECTOR Scalar Vector A physical quantity with magnitude only A physical quantity with both magnitude and direction E.g. mass (kg); distance (m); speed (m.s⁻¹); time (s); energy (J); temperature (K) E.g. Force (N); weight (N); displacement (m); velocity (m.s⁻¹); acceleration (m.s⁻²) Graphical representation of a vector Vector is represented by an arrow. Length of arrow = magnitude of vector. Direction of arrow = direction of vector. ud nit ag e M Tail = Origin + and – is used to indicate direction of a vector. +5 N left is – • Net or resultant vector: the single vector that has the same effect as two or more vectors together. • Net vector is greatest when vectors are in the same direction. • Net vector is smallest when vectors are in the opposite direction. Vectors in same direction Vectors in opposite directions Determine the net force when a 5 N force acts to the right and a 10 N force also acts to the right. Determine the net force when a 12 N force acts to the right and a 7 N force acts to the left. Let to the right be positive: Let to the right be positive: Multiple vectors in different directions Determine the net force when a 8 N force acts to the right, a 10 N force acts to the right, a 25 N force acts to the left and a 12 N acts to the left. Head = Direc3on θ e.g. right is + SCIENCE CLINIC 2018 © Fnet = = = F1 + F2 5 + 10 15 N right Fnet = = = F1 + F2 12 + (−7) 5 N right Let to the right be positive: Fnet = = = = F1 + F2 + F3 + F4 8 + 10 + (−25) + (−12) −19 N 19 N left –3N 3 METHODS TO DESCRIBE THE DIRECTION OF A VECTOR (the same vectors are used and described in each example) On a graph Bearing Use North as 0⁰ and always measure clockwise Compass (Cardinal Points or directions) FA: 10 N at 30⁰ above the positive x-axis FA: 10 N on a bearing of 60⁰ FA: 10 N at 30⁰ North of East FB: 8 N at 12⁰ left of the negative y-axis FB: 8 N on a bearing of 192⁰ FB: 8 N at 12⁰ West of South FC: 5 N at 65⁰ above the negative x-axis FC: 5 N on a bearing of 335⁰ FC: 5 N at 65⁰ North of West 19 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za NOTE: South-West, North-West, North-East and South east can only be used if the angle is 45° Motion in 1 dimension Grade 10 Science Essentials FRAME OF REFERENCE AND POSITION SCIENCE CLINIC 2018 © DISTANCE AND DISPLACEMENT • Position (x): the place where an object is relative to a specific reference point. Position is a vector. Unit is meter(m) • Reference point: a point from which the position of the object is measured (zero point). • One dimensional motion: motion that occurs either vertically or horizontally along a straight line. EXAMPLE: Let to the right be positive: Distance Displacement Total path length travelled Difference in position in space. Displacement is measured from start to final position Scalar Vector Symbol: D Symbol: ∆x (or ∆y) Unit: meter (m) Unit: meter (m) EXAMPLE: A boy runs from position A to E in a clockwise motion as shown in the diagram. Describe his distance and displacement at position B,C and E using A as the starting (reference) point. (a) Describe the position of objects A and C by using object B as a reference point as in the diagram. Object A is -3 m from B (3m to the left) Object C is +5 m from B (5m to the right) B: distance is 100 m, displacement is 80 m at 25⁰ East of South C: distance is 200 m, displacement is 120 m South E: distance is 400 m, displacement is 0 m (b) Describe the position of objects B and C by using object A as a reference point as in the diagram. Object B is 3 m right of A Object C is 8 m right of A SPEED • Speed ( v ): rate of change of distance with time. Scalar, unit is m.s⁻¹ In other words → how much distance is travelled every second. • Constant speed: covers equals distances in equal time intervals. • Average speed: total distance covered over the total time taken. speed (m ⋅ s−1) distance (m) v= D t VELOCITY ACCELERATION • Acceleration ( a ⃗ ): rate of change of velocity. Vector, unit is m.s⁻2 In other words → how much the velocity changes every second. • Constant acceleration: a constant increase or decrease in velocity • Constant velocity: covers equals displacement in equal time in equal time intervals. intervals. change in velocity (m ⋅ s−1) acceleration (m ⋅ s−2 ) • Average velocity: total displacement covered over the total time taken. vf − vi Δv ⃗ a = = −1 displacement (m) velocity (m ⋅ s ) Δt Δt time (s) • Velocity ( v ⃗ ): rate of change of position. Vector, unit is m.s⁻¹ In other words → how much the position changes every second. v⃗= Δx Δt Remember + and – refers to direction of the vectors Let us say right is + and left is – in this case: 1. Positive acceleration: Increasing velocity in + direction (speeding up right) OR decreasing velocity in the – direction (slowing down left) 2. Negative acceleration: time (s) time (s) Decreasing velocity in + direction (slowing down right) OR increasing • Instantaneous velocity: the velocity of an object at a specific velocity in the – direction (speeding up left) [if change in velocity and acceleration is in the same direction it is • Instantaneous speed: the speed of an object at a specific moment in time moment in time. e.g. 1. Let the specific time be 2 seconds – then the instantaneous speeding up and if in opposite directions it is slowing down] 3. Deceleration: e.g. 1. Let the specific time be 2 seconds – then the instantaneous velocity will be annotated by V2. Non-scientific term that means an object is slowing down. In science speed will be annotated by V2. e.g.2. the initial instantaneous velocity will be Vi. we rather refer to acceleration → direction and context describe e.g.2. the initial instantaneous speed will be Vi. whether it is speeding up or slowing down. 20 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Motion in 1D- Equations of motion Grade 10 Science Essentials VARIABLES u vi Initial velocity v vf Final velocity a a acceleration s ∆x Displacement t ∆t Time taken CALCULATIONS: A racing car starting from rest on the grid, travels straight along the track and reaches the 400 m mark after 8,6 s. a) What was its average acceleration? Let forward be positive. Equations for constant acceleration in one dimension: Old symbols v = u + at New symbols vf = vi + aΔt Leaves out s or Δx s = 12 (u + v)t Δx = 12 (vi + vf )Δt a s = ut + 12 at 2 v 2 = u 2 + 2as Δx = 12 aΔt 2 vf2 = vi2 + 2aΔx SCIENCE CLINIC 2018 © u 0 v / a ? s 400 m t 8,6 s Δx = 400 = a = viΔt + at 2 1 a8,62 2 −2 10,82 m ⋅ s forward b) What was its velocity at the 400 m mark? v or vf t or Δt vf vf = = vi + aΔt 0 + (10,82)(8,6) vf = 93,05 m ⋅ s−1 forward c) At the 400 m mark, the brakes are applied and the car slowed down at 2 m.s-2 to come to rest. Calculate the time it took for the car to stop. Steps to using the equations: a) Identify each stage of the motion, where the acceleration has changed. b) Choose a positive direction and stick to your convention. c) Record the information given and value required by writing next to each variable. Check the unit and direction. d) Select correct equation and solve for unknown. e) Include units and direction in your answer. NB! New stage of motion. Find the new value of each variable. Let forward be positive. Remember: ‘starting from rest’ means: u or vi = 0 ‘comes to a stop’ means: v or vf = 0 ‘Slowing down’ means: acceleration is negative (a < 0), while still moving in a positive direction. Constant velocity means: a =0, u = v or vi = vf Use a new set a variables for each stage of the motion. Conversion of units: 1 m.s-1 = 3,6 km.h-1. 21 u 93.05 m.s-1 v 0 a -2 m.s-2 s / t ? For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za vf 0 t = = = vi + aΔt 93,05 − 2t 46,53 s Grade 10 Science Essentials Motion in 1D- Graphs of Motion 1. 2. 3. 4. 5. 6. SCIENCE CLINIC 2018 © Tips on reading graphs: Check which variable is on the vertical axis Check which direction is positive. The velocity at any specific time, can be calculated from gradient of the x-t graph at that time. The acceleration at any specific time, can be calculated from gradient of the v-t graph at that time. The displacement up to a specific time can be calculated from the area under the v-t graph up to that time. The change in velocity up to a specific time can be calculated from the area under the a-t graph up to that time. gr a d i e n t = = area of triangle = Δy Δx y2 − y1 1 l ×b 2 area of rectangle = l × b x 2 − x1 Identify the separate stages of the motion (Forward direction positive): 1. Positive acceleration (accelerating forward) from rest. 2. Constant positive velocity (forward). 3. Negative acceleration (decelerating forward) to rest. 4. At rest 5. Negative acceleration (accelerating backwards) from rest. 6. Constant negative velocity (backwards). 7. Positive acceleration (decelerating backwards) to rest. ( i.e. Accelerating forwards) EXAMPLE: The graph shows two cars A and B are traveling at 40 m.s⁻¹ when the brakes are applied and they decelerate to rest. a) What is the initial speed of the cars in kmh-1? 40 × 3,6 = 144 km ⋅ h−1 b) Which car had the greatest deceleration? Car A, because the gradient is more steep. c) How far did car B travel after the brakes were applied? Area under triangle B = = = 22 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za 1 b×h 2 1 (6)(40) 2 120 m Grade 10 Science Essentials Examples of graphs of motion Consider the racing car we used to illustrate the equations of motion: A racing car starting from rest on the grid, travels straight along the track and reaches the 400m mark after 8,6 s. At the 400 m mark, the brakes are applied and the car slowed down at 2 m.s-2 to come to rest. The two stages of the motion can be represented by x –t, v – t and a – t graphs: x-t: The displacement is always increasing, the car always moves forward. a. Describe the motion of the object from 0 to 8 seconds. 0-3 s: Negative acceleration from 12 to 3 m.s-1 in forward direction 3-8 s: Constant velocity of 3 m.s-1 forward. Gradient of s-t at point = velocity at that point. b. What does the gradient of the line AB represent? The acceleration from A to B. The car starts from rest and ends at rest where gradient = 0. c. Calculate this value. a = gradient The max gradient is at 8,6 s. a = a = a = v-t: The velocity is always positive, the car always moves forward. The gradient from 0 to 8,6 s is positive, the car is accelerating forward. The gradient from 8,6 to 55,1 s is negative, the car is decelerating while traveling forward. vf − vi t 3 − 12 3 −3 m ⋅ s−2 ∴ a = 3 m ⋅ s−2 in the opposite direction to motion d.What is the acceleration between B and C? a(BC) = 0 m.s-2 because gradient = 0 e. Calculate the total displacement of the object in 8 seconds. 1 Δx = area = bh + lb + lb = = = 2 1 (3)(9) + (3)(3) + (5)(3) 2 13,5 + 9 + 15 37,5 m f. Draw the corresponding a – t graph for the motion: a-t: Constant positive acceleration of +10,82 m.s-2 from 0 to 8,6 s. Constant negative acceleration of -2 m.s-2 from 8,6 s to 55,1 s. 23 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za SCIENCE CLINIC 2018 © Grade 10 Science Essentials Measuring Instantaneous Velocity Ticker timers A ticker timer produces a series of dots on a tape which can be analyzed to determine the displacement between two points and the time taken between the two points. SCIENCE CLINIC 2018 © Measuring Acceleration If we know the instantaneous velocity at two times, we can calculate the acceleration between the points using Δx vaverage = t a= ∆x is measured in meters with a ruler. 1 t can be calculated from the period of the timer. T = and is measured in seconds. f vf − vi Δt Here is a section of tape from a ticker timer which vibrates at 50 Hz. When t is small we are calculating the instantaneous velocity over the time taken. When t is large we are calculating the average velocity over the time taken. To calculate the instantaneous velocity at a certain point (Z) on a tape: 1. Mark off one or more spaces before the point Z. 2. Mark off the same number of spaces after the point Z. 3. Z will occur at half the time of the interval. 4. Measure the length of the interval in meters. This is the displacement s. 5. Count the spaces in the time interval to calculate t. NOTE: t = number of spaces x T. 6. Velocity at Z is called VZ. The time interval between the dots is Divide the tape into two intervals, C to E and A to C, to find vf and vi respectively. vCE Δx VZ = t REMEMBER: The footnotes used are simply a descriptor of the time point to which the velocity refers to. 1 = 0,02 s 50 = 0,042 0,04 = 1,05 m ⋅ s−1 vAC = 0,018 0,04 = 0,45 m ⋅ s−1 At which dot was the instantaneous velocity = 1,05 m.s-1 ? D At which dot was the instantaneous velocity = 0,45 m.s-1? B a vi means velocity at the initial time point v4 means velocity at the 4th time point (4th second) vb means velocity at time point B = vD − vB t B to D a = 1,05 − 0,45 0,04 a = 15 m ⋅ s−2 Use the pattern of the dots to describe the motion of each object: REMEMBER: The average velocity across the a time section (from A to C) is equal to the instantaneous velocity in the middle of that time interval (at B) a) acceleration from rest The instantaneous velocity at B = average velocity from A to C The instantaneous velocity at C = average velocity from B to D OR from A to E The instantaneous velocity at D = average velocity from C to E b) constant speed, and then suddenly accelerates This only applies to constant acceleration or zero acceleration. Because acceleration is rarely constant in real life, this could lead to inaccuracy. In real life, the variability in acceleration is overcome by making the time across which the average velocity is calculated shorter. c) accelerating, then moving at constant velocity and then decelerating Shorter average velocity time = more accurate instantaneous velocity d) slowly decelerating 24 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Motion in 1D - THE ESSENTIALS Grade 10 Science Essentials Quan&ty Defini&on Posi&on (x) SCIENCE CLINIC 2018 © Vector/scalar Unit The place where an object is rela4ve to a specific reference point. Vector m Distance(D) Length of path taken by a moving object Scalar m Displacement (∆x) Change in posi4on with respect to a start point Vector m Speed (v) Rate of change of distance. Scalar m.s⁻¹ Velocity (v) Rate of change of posi4on. Vector m.s⁻¹ Accelera&on (a) Rate of change of velocity. Vector m.s⁻2 Average speed !!"#$!%# = Average velocity !!"#$!%# = Instantaneous velocity Posi&ve accelera&on ∆! ∆! the velocity of an object at a specific moment in 4me. Eg. Vi is ini4al velocity. Vf is final velocity. Accelera&on Nega&ve accelera&on ! ∆! != !! − !! ∆! Decreasing velocity in + direc4on OR increasing velocity in the – direc4on Increasing velocity in + direc4on OR decreasing velocity in the – direc4on FORMULAE Old symbols v = u + at New symbols vf = vi + aΔt Leaves out s or Δx s = 12 (u + v)t Δx = 12 (vi + vf )Δt a s = ut + 12 at 2 v 2 = u 2 + 2as Δx = 12 aΔt 2 vf2 = vi2 + 2aΔx 25 v or vf t or Δt For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Grade 10 Science Essentials Graphs of motion- THE ESSENTIALS SCIENCE CLINIC 2018 © Displacement-Time • 1 is positive acceleration • 2 is constant velocity • 3 is negative acceleration • 4 is at rest GRADIENT: Velocity AREA: n/a Velocity-Time • 1 is positive acceleration • 2 is constant velocity • 3 is negative acceleration • 4 is at rest GRADIENT: Acceleration AREA: Displacement Acceleration-Time • 1 is positive acceleration • 2 is constant velocity (a = 0) GRADIENT: n/a • 3 is negative acceleration • 4 is at rest, but negative acceleration still applies 26 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za AREA: Velocity Energy Grade 10 Science Essentials PRINCIPLE OF CONSERVATION OF MECHANICAL ENERGY ENERGY The ability to do work Unit: joules (J) Scalar quantity Gravitational Potential Energy (EP) The energy an object possesses due to its position in the gravitational field relative to a reference point. Amount of energy transferred when an object changes position relative to the earth’s surface. Kinetic Energy (EK) The energy an object possesses as a result of its motion Amount of energy transferred to an object as it changes speed. EP = mgh EK = -2 1 2 mv 2 g = 9,8m.s , m is mass in kg, h is height in m m is mass in kg, v is velocity in m.s-1 Example: Determine the gravitational potential energy of a 500 g ball when it is placed on a table with a height of 3 m. Example: Determine the kinetic energy of a 500 g ball when it travels with a velocity of 3 m.s -1. EP = = = mgh (0,5)(9,8)(3) 14,7 J EK = = = 1 mv 2 2 1 (0,5)(32 ) 2 2,25 J Mechanical Energy (EM) The sum of gravitational potential and kinetic energy at a point EM = EP + EK EM = mgh + 12 mv 2 EM = = EM = EM = EP + E K 1 2 mgh + mv (0,5)(9,8)(2,5) + 2 1 (0,5)(1,82 ) 2 13,06 J Principle of conservation of mechanical energy: The total mechanical energy in an isolated system remains constant. The law of conservation of mechanical energy applies when there is no friction or air resistance acting on the object. In the absence of air resistance, or other forces, the mechanical energy of an object moving in the earth’s gravitational field in free fall, is conserved. EMECHA (EP + EK )A 1 (m gh + 2 m v 2 )A = EMECHB = (EP + EK )B = (m gh + 2 m v 2 )B 1 Law of conservation of energy: The total energy of an isolated system remains constant. In the following instances the gravitational potential energy of an object is converted to kinetic energy (and vice versa), while the mechanical energy remains constant EXAMPLE 1: Object moving vertically A 2 kg ball is dropped from rest at A, determine the maximum velocity of the ball at B just before impact. (EP + EK )A = (EP + EK )B (m gh + m v )A = (2)(9,8)(4) + 12 (2)(0 2 ) (m gh + 12 m v 2 )B = 78,4 + 0 = v = v = 1 2 2 (2)(9,8)(0) + 12 (2)v 2 0 + 1v 2 78,4 8,85 m ⋅ s−1 downwards EXAMPLE 2: Object moving on an inclined plane A 2 kg ball rolls at 3 m·s−1 on the ground at A, determine the maximum height the ball will reach at B. (EP + EK )A = (EP + EK )B (m gh + m v )A = (2)(9,8)(0) + 12 (2)(32 ) (m gh + 2 m v 2 )B = 9 19,6 = h = 0,46 m 1 2 2 0+9 h EXAMPLE: A ball, mass 500 g, is thrown horizontally through the air. The ball travels at a velocity of 1,8 m·s−1 and is 2,5 m from the ground. Determine the mechanical energy of the ball. EM SCIENCE CLINIC 2018 © 1 (2)(9,8)(h) + 12 (2)(0 2 ) = 19,6h + 0 EXAMPLE 3: Rollercoaster The 2 kg ball rolls on a toy rollercoaster from A, at 20 m above the ground, to B where its height is 8 m and velocity is 14 m·s−1. Calculate its starting velocity at A. (EP + EK )A = (EP + EK )B = 1 (m gh + 2 m v 2 )B = 392 + v 2 (2)(9,8)(16) + 2 (2)(142 ) = 313,6 + 196 v = v = 1 2 2 (m gh + m v )A (2)(9,8)(20) + 2 (2)(v 2 ) 27 1 1 313,6 + 196 − 392 10,84 m ⋅ s−1 to the right For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za www Information sheets – Paper 2 (Chemistry) NA e Tθ Vm pθ SYMBOL/SIMBOOL 6,02 x 1023 mol-1 -1,6 x 10-19 C 273 K 22,4 dm3·mol-1 1,013 x 105 Pa VALUE/WAARDE TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES NAME/NAAM Standard pressure Standaarddruk Molar gas volume at STP Molêre gasvolume by STD Standard temperature Standaardtemperatuur Charge on electron Lading op elektron Avogadro's constant Avogadro-konstante OR c = m MV n= n= V Vm N NA TABLE 2: FORMULAE/TABEL 2: FORMULES m n= M n V c= TABLE 3: THE PERIODIC TABLE OF ELEMENTS/TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE 6 28 29 K Ca Sc Ti V Cr Mn Fe Co Ni Cu 8 9 B C N O F Ne 19 17 20 18 11 13 12 14 Aℓ Si 14 15 16 16 Cℓ Ar 30 27 31 28 32 31 33 32 34 S 35,5 35 40 36 Zn Ga Ge As Se Br Kr 3,0 P 4,0 7 3,5 6 2,8 27 1,9 26 1,8 25 1,8 24 1,8 23 1,5 22 1,6 21 1,6 24 20 5 2,5 63,5 18 (VIII) 4 10 3,0 Symbol Simbool Cu Approximate relative atomic mass Benaderde relatiewe atoommassa 1,5 17 (VII) He 2,5 29 Electronegativity Elektronegatiwiteit 1,3 16 (VI) 2 23 19 1,0 15 (V) 2,4 Mg 14 (IV) 2,1 Na 13 (III) 2,0 9 12 1,2 7 11 12 1,8 Be 11 1,5 Li 10 Atomic number Atoomgetal 1,9 4 1,5 1 3 9 1,8 H 8 7 KEY/SLEUTEL 79 52 80 53 84 54 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 91 72 92 73 Ra Ac 0,9 Fr 226 103 77 106 78 108 79 112 80 115 81 119 82 Tℓ Pb 122 83 128 84 127 85 131 86 Bi Po At Rn Hf Ta W Re Os Ir Pt Au Hg 179 181 184 186 190 192 195 197 201 204 207 209 58 59 60 61 62 63 64 65 66 67 68 69 70 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 140 141 144 150 152 157 159 163 165 167 169 173 175 90 91 92 93 94 95 96 97 98 99 100 101 102 103 Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr 232 238 2,5 139 89 101 76 2,0 La 137 88 75 1,9 Ba 96 74 1,8 Cs 133 87 89 57 1,8 88 56 1,6 86 55 2,5 75 51 2,1 73 50 1,9 70 49 1,8 65 48 1,7 63,5 47 1,7 59 46 1,9 59 45 2,2 56 44 2,2 55 43 2,2 52 42 1,9 51 41 1,8 48 40 1,4 45 39 1,2 40 38 1,0 39 37 0,9 0,7 0,8 0,8 0,9 1,0 2,1 1 0,7 5 4 2,0 3 1,6 2 (II) 1,6 1 (I) 71 Classification of Matter Grade 10 Science Essentials SCIENCE CLINIC 2018 © CLASSIFICATION All matter is made up of particles whose properties determine the observable characteristics and reactivity. Elements of the periodic table can be classified into 3 different categories: Ions Atoms Non-metals, Metals and Metalloids Molecules Par:cles Non-metals All ma9er Pure substances Mixtures Elements Metals Compounds Metalloids Nonmetals Eg. Silicon Poor electrical conductors (except graphite) Good electrical conductors Poor electrical conductors but conductivity increases with an increase in temperature Poor thermal conductors (Except diamond) Good thermal conductors Varied thermal conductivity Dull appearance Lustre (shiny) Lustre (shiny) Brittle Malleable and ductile Brittle Low melting and boiling points High melting and boiling points Melting and boiling points differ vastly Can be solids, liquids or gases at room temperature All solids except mercury (Hg) at room temperature Solids at room temperature ELECTRICAL CHARACTERISTICS Pure substances Compound Metalloids Eg. Copper MIXTURES AND PURE SUBSTANCES Mixture Metals Eg. Sulphur Element Consists of different particles, not chemically joined. Consists of two or more elements chemically bonded Consists of only one type of atom Components can be separated into simpler substances by physical means Components can only be separated into simpler substances by chemical means Cannot be separated into simpler substances Smallest sample will reflect the composition of mixture Smallest particles are molecules or ions or formula units Smallest particles are atoms or molecules No fixed ratio between the different particles. Fixed ratio between the smallest particles Eg. Sand in water Eg. H2O, MgSO4 Insulator Electrical conductor Semi-conductor A material that prevents the flow of charge A material that allows the flow of charge A substance that can conduct electricity under certain conditions Non-metals Metals Metalloids Eg. Plastic and rubber Eg. Electrical cables Eg. Diodes and LEDs (light emitting diodes) and integrated circuits. MAGNETIC PROPERTIES Ferromagnetic materials Materials can be influenced by a magnet Non-magnetic materials Materials which are not influenced by a magnet Soft magnetic materials Hard magnetic materials Are easily magnetised but lose magnetism easily Not easily magnetised but retain magnetism for a long time Cannot become magnetised Eg. Iron (Fe) Uses: Temporary magnets such as electromagnets in metal scrap yards and loud speakers Eg. Cobalt (Co), Nickel (Ni), Steel Uses: Permanent magnets and compasses Eg. Other elements including metals such as aluminium (Al), zinc (Zn),Copper(Cu) Eg. Cu, H2 31 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Classification of Matter-THE ESSENTIALS Grade 10 Science Essentials Physical Properties of materials Ions Strength: the ability of a material to resist stress and strain Atoms SCIENCE CLINIC 2018 © Molecules Thermal conductivity: the ability of material to conduct heat Par:cles Electrical conductivity: the ability of a material to conduct electricity Brittle: hard but likely to break Malleable: Ability to be hammered or pressed into shape without breaking or cracking All ma9er Ductile: the ability to be stretched into a wire Pure substances Magnetic: a material which can be attracted or repelled by a magnet (its domains are aligned) Non-magnetic: a material which is not attracted or repelled by a magnet (its domains are misaligned) Elements Density: the mass per unit volume of a substance Mixtures Compounds Melting point: The temperature at which a solid becomes a liquid. Boiling point: the temperature of a liquid at which its vapour pressure equals the external (atmospheric) pressure Metals Metalloids Pure Substance A substance that cannot be separated into simpler components by physical methods Pure copper, O2 Element Pure substance consisting of only one type of atom Argon, mercury, silicon, gold Compound Pure substance consisting of two or more elements chemically bonded in a fixed ratio Water, carbon dioxide, sodium chloride Mixture Consists of different particles mixed together, but not chemically joined. Milk, air, salt water Homogenous mixture A mixture of uniform composition and in which all components are in the same phase Eg: air, brine, steel Heterogeneous mixture A mixture of non-uniform composition and of which the components can be easily identified Sand and rock mixture, Pizza toppings 32 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Nonmetals Names and formulae Grade 10 Science Essentials BASIC CONCEPTS • Atoms combine in very specific ratios to form certain compounds. E.g. carbon dioxide consists of 1 carbon and 2 oxygen atoms. •These ratios remain fixed for that compound. The ratio is given by the formula. e.g. CO2 SCIENCE CLINIC 2018 © TABLE OF COMMON ELEMENTS CARBON OXYGEN OXYGEN •Simple ions are single atoms which carry a charge. They are also called monatomic ions. Polyatomic ions are groups of atoms bonded together which collectively carry a charge. H Hydrogen Ne Neon K Potassium Zn Zinc He Helium Na Sodium Ca Calcium Br Bromine Li Lithium Mg Magnesium V Vanadium Sn Tin Be Beryllium Al Aluminium Cr Chromium Pt Platinum B Boron Si Silicon Mn Manganese Ag Silver C Carbon P Phosphorus Fe Iron Au Gold N Nitrogen S Sulphur Co Cobalt Hg Mercury O Oxygen Cl Chlorine Ni Nickel Pb Lead F Fluorine Ar Argon Cu Copper Xe Xenon TABLE OF COMMON CATIONS AND ANIONS TABLE OF COMMON COMPOUNDS Formula Chemical name Common name H2O Hydrogen oxide Water ANIONS (NEGATIVE IONS) CO2 Carbon dioxide Carbon dioxide All Group 7 NH3 Hydrogen nitride Ammonia OH¯ Hydroxide ion SO4²¯ Sulphate ion HCℓ Hydrogen chloride Hydrochloric acid NO3¯ Nitrate ion SO3²¯ Sulfite ion H2SO4 Hydrogen sulphate Sulphuric acid NO2¯ Nitrite ion CO3²¯ Carbonate ion HNO3 Hydrogen nitrate Nitric acid MnO4¯ Permanganate ion CrO4²¯ Chromate ion H2CO3 Hydrogen carbonate Carbonic acid CℓO3¯ Chlorate ion Cr2O4²¯ Dichromate ion H3PO4 Hydrogen phosphate Phosphoric acid CℓO¯ Hypochlorite ion O2²¯ Peroxide ion CH3COOH Ethanoic acid Vinegar HCO3¯ Hydrogen carbonate ion NaCℓ Sodium chloride Table salt HSO3¯ Hydrogen sulphate ion NaOH Sodium hydroxide Caustic soda HSO4¯ Hydrogen sulfite ion NaHCO3 Sodium hydrogen carbonate Baking soda (bicarbonate of soda) H2PO4¯ Dihydrogen phosphate ion Na2CO3 Sodium carbonate Washing soda CH3COO¯ Acetate ion NaNO3 Sodium nitrate Chile saltpetre CATIONS (POSITIVE IONS) KOH Potassium hydroxide Caustic potash All Group 1 KNO3 Potassium nitrate Saltpetre NH4+ CaCO3 Calcium carbonate Marble/ chalk/ lime stone CaSO4 Calcium sulphate Gypsum MgSO4 Magnesium sulphate Epsom salts CuSO4 Copper sulphate Blue vitriol CH4 Methane Natural gas SINGLE CHARGE DOUBLE CHARGE All Group 6 All Group 2 Ammonium ion + H3O Hydronium ion 33 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za TRIPLE CHARGE All Group 5 PO4³¯ Phosphate ion All Group 3 Names and formulae Grade 10 Science Essentials WRITING CHEMICAL FORMULAE SCIENCE CLINIC 2018 © BALANCING CHEMICAL EQUATIONS Follow these basic steps to write chemical formulae for ionic substances: A chemical equation represents the chemical changes that occur when a reaction takes place. 1. Write symbol for the positive ion first, then for the negative ion. The ions could be monatomic ions or polyatomic ions. The Law of conservation of matter means that matter cannot be created or destroyed, merely transferred from one substance to another. •A chemical equation must be balanced in order to conform to the above law. •Compounds have fixed ratios, thus only the number of compounds on either side of the arrow can be changed . •Numbers are placed in front of compounds on either side of the arrow to balance the equation. •The total number of each atom should be the same on either side of the equation. 2. Write ionic charges at top right of symbols • Monatomic ion → the ion of one single element only, so you can use periodic table to determine the charge. • Polyatomic ion → you must memorise the charges. 3. “Cross multiply” the numbers so that the total charge of the compound is 0. 4. Write final compound: • ends in –ide → monatomic ion Eg. Hydrogen Sulphide = H2S • the name ends in –ate or –ite if it includes oxygen Steps for balancing reaction equations: 1.Identify all reactants and products of the reaction. 2.Start from the word equation where possible. 3.Write the correct formula for the compounds of the reactant and products and separate them with an arrow. 4.Indicate the phases of each compound. 5.Count the number of atoms of each element on either side of the arrow, and add numbers in front of compounds in order to get it to balance. 6.Check the total number of atoms of a certain element in reactants must equal the total number atoms of the same element in the product. • Roman numerals (II) → ionic charge of the metal Eg. Copper(II)sulphate → Cu2 SO4 EXAMPLE: In the Synthesis of water, Hydrogen reacts with oxygen to form water. EXAMPLE: Aluminium Aℓ3+ Aℓ 2 O Step 1. Hydrogen + oxygen → water. oxide O23 Step 2. H2 + O2→ H2 O (“cross-multiply” numbers ) Step 3. H2 (g) + O2(g) → H2 O(g) Step 4a. Add a 2 in front of H2O to balance the oxygen atoms. H2 (g) + O2(g) → 2H2 O(g) (the total charge must be zero) Step 4b. Add a 2 in front of H2 to balance the hydrogen atoms. 2H2 (g) + O2(g) → 2H2 O(g) Step 5. Reactants have 4 H atoms and 2 oxygen atoms. Products have 4 H atoms and 2 oxygen atoms. Equation is balanced. PHASES OF A COMPOUND NOTE: These steps are a systematic approach to balancing chemical equations. You don’t have to show all the steps in your working out. Usually only the final balanced equation is required. Phases are represented as subscripts after the formulae as follow: (s) solid state (ℓ) liquid state (aq) aqueous solution (g) gaseous state 34 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Kinetic Theory of Matter STATES OF MATTER CHANGES OF STATE HEATING AND COOLING CURVES FOR WATER Mel/ng •Matter occurs in one of three states, solid, liquid or gas, depending on the temperature. •The state of matter depends on its melting point (MP) and boiling point (BP). If the temperature is below the MP, it is a solid. If the temperature is above the MP, but below the BP, it is a liquid. If the temperature is above the BP, it is a gas. Solid Temperature (oC) Sublima/on •All matter has mass and takes up space (volume). Boiling/ evapora/on Liquid Freezing Gas boiling mel+ng Condensa/on water molecules equilibrium Properties of states of matter freezing Time (min) Cooling Curve The Kinetic Theory of Matter states that: EVIDENCE FOR THE KINETIC THEORY OF MATTER dye molecules condensing Time (min) Hea+ng Curve Deposi/on Diffusion is the movement of atoms or molecules from an area of high concentration to an area of lower concentration. The higher the temperature, the faster diffusion takes place. SCIENCE CLINIC 2018 © Temperature (oC) Grade 10 Science Essentials Brownian motion is the random movement of microscopic particles suspended in a gas or liquid. When we use a microscope to study smoke particles in air or pollen particles in water, these particles jiggle about in a completely random way. The tiny particles of air or water, which are too small to be seen with the microscope, are in constant motion. They collide with the bigger particles of smoke and pollen, causing the bigger particles to change direction and speed. •All matter is made of tiny particles with spaces in between them. •The tiny particles are constantly moving, but the particles lose no kinetic energy when they collide with other particles or with the walls of their container. •The kinetic energy of the particles depends on how fast they are moving. At any given time, some particles are moving slowly while others are moving fast. The temperature is a measure of the average kinetic energy of the particles. •The potential energy of the particles depends on how far they are apart and depends on their state (solid, liquid or gas). •There are attractive forces between the particles which become stronger as the particle move closer. Volume Shape Spaces between particles Forces between particles Arrangement of particles Movement of particles Solid Fixed volume Fixed shape Touching each other Strong Close together. Fixed positions in a set pattern. Vibrate about fixed positions Liquid Definite volume Takes the shape of the container Touching each other Medium Random – no fixed pattern Slide past each other switching places. Far apart Very weak Gas Particle diagram No definite shape or volume. Expands to fill container 35 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za On their own Fast and free The atom- Atomic models Grade 10 Science Essentials J.J Thomson (1897) 1.Thomson used a cathoderay tube to show that there are small negative particles inside atoms. He called them “electrons”. 2. Electrons are found in all atoms. They have the same charge and mass regardless of which substance they come from. 3. He used the current bun (A.K.A Plum pudding) model to explain that the negative electrons are found inside a solid positive mass. SCIENCE CLINIC 2018 © James Chadwick (1932) Electrons - - - Uniform, posi1vely charged sphere 1. Discovered the neutron which is a particle in the nucleus. 2. Neutrons have no charge, and their mass is almost the same as a proton. Niels Bohr (1913) •Electrons travel around the nucleus in circular, definite paths called orbits- like planets orbit around the sun. •Each orbit has a ‘certain energy.’ Electrons in the same orbit have the same energy. •The further the orbit is from the nucleus, the higher the energy. •Electrons can jump from one orbit to another. •When an electron moves to higher energy level it gains energy. Schrödinger (1926) 1. It is not possible to find the exact position of an electron, but only the most probable regions where the electrons move. 2. The regions inside an atom where electrons are likely to be found are called orbitals. TIMELINE OF THE HISTORY OF THE ATOM Democritus ( +/- 440 BC) 1. Democritus proposed that if you kept cutting a substance in half repeatedly, you would eventually end up with an “uncuttable” particle. 2. He called these particles atoms. John Dalton (1803) Ernest Rutherford (1909) 1. All elements are made up of small, indestructible, solid spheres called atoms. 2. A t o m s o f t h e same element are identical: same size, shape and mass. 3. An atom is the smallest particle of an element which can take part in a chemical reaction. 4. Compounds are formed when the atoms of two or more elements combine with one another in fixed whole number ratios. Rutherford conducted an experiment in which he shot a beam of alpha particles towards a sheet of very thin gold foil . Most of the particles continued in a straight line, but some were deflected He deduced that: i.The positive charge is not evenly distributed as suggested by Thomson but is in the centre of the atom, in the nucleus. ii.Mass is concentrated in the nucleus. The nucleus has a large enough mass to deflect the alpha particles. iii.The nucleus is small compared to the atom because most of the particles passed undisturbed through the gold foil. iv.Electrons are extremely small and far from the nucleus and make up practically the whole volume of the atom. v.The volume of the atom is 10 000 greater than the volume of the nucleus. The atom is mostly empty space. flourescent screen metal foil α-par&cle source undeflected α-par&cles solid nucleus Shortcomings: 1. Atoms are not solid spheres. 2. All atoms of an element are not identical. There are different isotopes of elements. 3. Atoms consist of sub-particles. deflected α-par&cles 36 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za gold atom The atom Grade 10 Science Essentials WHAT IS AN ATOM? •Atoms are the very small particles of which all elements are made- they are the basic building block of all matter – including your own body, your hair, your organs, the earth, the sun are all made of different combinations of atoms. •E.g. Your body is made of 65% Oxygen, 19% Carbon and 10% Hydrogen by mass. SCIENCE CLINIC 2018 © Consider the atom shown here: Atomic Number (Z) and Atomic Mass (A) An atom is identified by the contents of its nucleus. An atom is represented by the notation: A Z •All known elements are arranged on the periodic table in order of increasing atomic number. E E Symbol of the element A Atomic Mass (A) is the number of nucleons Z Atomic Number (Z) is the number of protons •Elements in the periodic table are arranged in order of increasing atomic number (Z). •The number of protons (Z) gives each element its unique properties. •Z also indicates how many electrons are present in the atom as the atom is electrically neutral. •A indicates the mass of the atom how many nucleons are present in the atom. •Number of neutrons = Atomic mass number - Number of protons (N = A - Z) •Periodic refers to ‘repeating patterns.’ Elements are arranged into groups (vertical columns) and periods (horizontal rows). •Elements in within a group have similar physical and chemical properties. •Atomic theory is the basis for understanding the interactions and changes in matter. ATOMS AND SUB-ATOMIC PARTICLES •There are three subatomic particles that are found inside the atoms, i.e. protons, neutrons and electrons. •The nucleus is in the centre of the atom and contributes most of the mass. The nucleus is made of the protons and neutrons which are called nucleons. •Because subatomic particles have extremely small masses, the atomic mass unit amu is used. 1 amu = 1,677 × 10−27 kg. •The mass of an atom is measured relative to the mass of carbon-12 atom. Carbon-12 is exactly 12 amu, therefore 1 amu is one-twelfth the mass of carbon-12 atom. proton p+ neutron n0 electron e- 1,677 × 10−27 (1 amu) 1,677 × 10−27 ( 1 amu) 9,11 × 10−31 Units of charge +1 0 Isotopes have different: number of neutrons different masses 1 1 -1 + + n n + n - - - H Hydrogen 2 1 3 1 H Deuterium The diameter of an atom varies for each type of atom. The diameter is about 1 x 10 -10 m. + + - Carbon Atom 7 3 Li EXAMPLE 1: Lithium (Z) Atomic number is 3: 3 protons, therefore 3 electrons (A) Atomic Mass is 7: 3 protons and (7 - 3) = 4 neutrons 32 16 S EXAMPLE 2: Sulphur 13 6 C EXAMPLE 3: Carbon-13 (Z) Atomic number is 6: 6 protons, therefore 6 electrons (A) Atomic Mass is 13 : 6 protons and (13 - 6) = 7 neutrons EXAMPLE Hydrogen exists as isotopes. 99,65% of H atoms are 1 1 H 0,30% of H atoms are 1 2 H 0,05% of H atoms are 1 3 H RAM(H) H Tri2um 37 + - Relative Atomic Mass (RAM) Isotopes of elements number of protons number of electrons chemical properties. It has 6 electrons so it has a total charge of 6 + (-6) = 0. It is neutral. - RAM indicates how many times the average mass of an atom of a certain element is heavier than 1/12 the mass of a carbon atom. Isotopes in an element are responsible for the RAM of elements NOT being whole numbers. Consider these three atoms of hydrogen. They each have one proton, but they have different numbers of neutrons. They are called isotopes. Isotopes have the same: - It has 6 neutrons. This means it has 12 nucleons and a mass of 12 amu. (Z) Atomic number is 16: 16 protons, therefore 16 electrons (A) Atomic Mass is 32 : 16 protons and (32 - 16) = 16 neutrons Table showing the mass and charge of subatomic particles Mass (kg) 6 Protons 6 Neutrons It has 6 protons. This means it is a Carbon atom. For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za = = 99,65 × 1 100 + 0,30 × 2 100 1,004 + 0,05 × 3 100 Grade 10 Science Essentials ELECTRON ARRANGEMENT IN THE ATOM The atom SCIENCE CLINIC 2018 © IONS 1. In neutral atoms, the number of electrons in the cloud around the nucleus equals the number of protons in the nucleus. 2. The electrons closer to the nucleus have less energy than the electrons further away from the nucleus. 3. The electrons occur in energy levels (n). 4. Different energy levels are able to accommodate different numbers of electrons (Total electrons = n2). 5. The electrons are found in certain regions within an energy level, referred to as orbitals. Each orbital can accommodate 2 electrons. CATIONS Cations are positive ions which are formed when the electrons from the outermost energy level are separated from the atom. ANIONS Anions are negative ions which are formed when electrons attach to an atom to fill the outermost energy level of the atom. The atoms become charged atoms known as ions. These charges need to be considered when completing Aufbau diagrams or electron configurations. The atoms become charged atoms known as ions. These charges need to be considered when completing Aufbau diagrams or electron configurations. Electrons are always found in positions of lowest possible energy (as close to the nucleus as possible) A neutral atom of aluminium contains 13 protons and 13 electrons. This aluminium ion has a charge of +3, indicating it has 3 protons more than electrons. The number of protons does not change for a given element, thus it has lost 3 electrons and has 10 electrons. • • • energy level 1: 1 s orbital energy level 2: 1 s and 3 p orbitals energy level 3: 1 s, 3 p and 5 d orbitals Shapes of the orbitals 1s orbital Energy level 1 Spherical in shape 2px, 2py , 2pz orbitals Energy level 2 Dumbbell shapes along x,y and z axes +3 13Al Orbital box (Aufbau) diagrams Aufbau diagrams is most detailed description of the way the orbitals are filled with electrons. The orbitals are filled from the lowest energy at the bottom in the following way: 4s 3p Energy 2 s orbital Energy level 1 Spherical in shape Electrons spend more time further from nucleus EXAMPLE: Valence electrons are in the outer most energy level and take part in bonding. •the size of their s and p orbitals also increases. •The number of orbitals increases. •We encounter d and f orbitals which are more complicated shapes. Spectroscopic Electron Configuration (spd) notation: This is a concise way to indicate the electron arrangement in an atom. This is similar to the Aufbau diagram, but represents it in a simpler way. EXAMPLE: 2 2 5 9F = 1s 2s 2p 2 2 6 2 1 13Al = 1s 2s 2p 3s 3p 2 2 6 2 6 2 20Ca = 1s 2s 2p 3s 3p 4s Negative ions have gained electrons Positive ions have lost electrons 2p Core electrons are in full energy levels and are not involved in bonding. 1s Flourine As the energy level(n) increases A neutral atom of fluorine contains 9 protons and 9 electrons. This fluorine ion has a charge of -1, indicating it has 1 electron more than protons. The number of protons does not change for a given element, thus it has gained electron and has 10 electrons. We can also concisely represent the Electron Configuration of ions in this way: 3s 2s EXAMPLE: 9F- Pauli’s exclusion principle: Maximum of two electrons per orbital provided that they spin in opposite directions. (arrows in opposite directions) Hund’s rule: No pairing in p orbitals before at least one electron in each of them. 38 EXAMPLE: 2 2 6 9F = 1s 2s 2p +3 = 1s2 2s2 2p6 13Al +2 = 1s2 2s2 2p6 3s2 3p6 20Ca We can also write the electron configuration according to noble gas notation. Noble gas notation makes use of the first preceding noble gas, which has a completely filled outer energy level. EXAMPLE: 5 9F = [He] 2p 2 1 13Al = [Ne]3s 3p 2 20Ca = [Ar]4s For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Lewis dot diagrams Lewis dot diagrams are used to show the position of the valence electrons around an element. The valence electrons are related to the group of the element. In all of the examples below, X represents any element in the group. Group 1 Group 2 X X Group 3 Group 4 X X Group 5 Group 6 X X Group 7 Group 8 X X The atom-THE ESSENTIALS Grade 10 Science Essentials Atomic models John Dalton (1803) J.J Thomson (1897) Ernest Rutherford (1909) Niels Bohr (1913) James Chadwick (1932) Mass and charge of subatomic particles 1. All elements are made up of small, indestructible, solid spheres called atoms like billiard balls. 2. Atoms of the same element are identical. Mass (kg) Electrons are negative particles, found inside a solid positive mass, like raisins in a current bun. 1. The positive charge is in the centre of the atom, in the nucleus. 2. Mass is concentrated in the nucleus. 3. The nucleus is small compared to the atom. 4. Electrons are extremely small and travel far from the nucleus. 5. Most of the atom is empty space. Electrons travel around the nucleus in circular, definite paths called orbits. Each orbit has a ‘certain energy’. SCIENCE CLINIC 2018 © proton p+ neutron n0 electron e- 1,677 × 10−27 (1 amu) 1,677 × 10−27 ( 1 amu) 9,11 × 10−31 Units of charge +1 0 Isotopes have the same number of protons (Z) but different number of neutrons (A) Relative Atomic Mass (RAM) RAM indicates how many times the average mass of an atom of a certain element is heavier than 1/12 the mass of a carbon atom. Electron arrangement (neutral atom) 1. Number of electrons = Z 2. The electrons occur in energy levels (n). 3. The closer to the nucleus, the less the energy. 4. Total electrons in a level = n2 5. The electrons are found in orbitals. Each orbital can accommodate 2 electrons. -1 Representing atoms A Z E E Symbol of the element A Atomic Mass (A) is the number of nucleons Z Atomic Number (Z) is the number of protons Orbitals • level 1: 1 s orbital • level 2: 1 s and 3 p orbitals • level 3: 1 s, 3 p and 5 d orbitals Valence electrons are found in the outer energy level. Notations for Electron Configuration Aufbau: orbitals are shown as boxes. Electrons are shown as arrows in the boxes. spd: 1s2 2s2 2p6 3s2 3p6 4s2 In a neutral atom: Number of protons = Z Number of electrons = Z Number of neutrons = A - Z The neutron is a particle in the nucleus with no charge, and almost the same mass as a proton. 4s Valence electrons are in the outer most energy level and take part in bonding. Energy 3p IONS CATIONS ANIONS Cations are positive ions which are formed when the electrons from the outermost energy level are separated from the atom. Anions are negative ions which are formed when electrons attach to an atom to fill the outermost energy level of an atom. The atoms become charged atoms known as ions. These charges need to be considered when completing Aufbau diagrams or electron configurations. The atoms become charged atoms known as ions. These charges need to be considered when completing Aufbau diagrams or electron configurations. 3s 2p 2s 1s Flourine 39 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Core electrons are in full energy levels and are not involved in bonding. The periodic table Grade 10 Science Essentials s-block GROUPS (COLUMNS) •Groups are the vertical columns in the periodic table. •Elements in a group have similar outer electron configurations. •This means they have similar chemical properties. •The group number corresponds to the number of valence electrons. •Eg All of Group 2 elements have two valence electrons. p-block 1s 2s 3s 4s 5s 6s 7s IMPORTANT GROUPS TO REMEMBER: 1: Alkali metals 2: Alkali Earth metals 17: Halogens 18: Noble gases Group 1: Alkali metals SCIENCE CLINIC 2018 © PERIOD (ROWS) 1s 2p 3p 4p 5p 6p d-block 3d 4d 5d 6d •Eg Period 3: outermost electrons in the 3rd energy level. EXAMPLE: Locating an element. Group 18: Group 17: Noble gases Halogens Group 2: Alkali Earth metals •Periods are the horizontal rows in the periodic table. •There is a gradual change in the physical and chemical properties as we move across a period. •The Period number tells us the energy level where the outermost electrons are found. 1. Silicon is in group 4 and period 3. 2. Calcium is in group 2 and period 4. TRENDS OF THE PERIODIC TABLE IONISATION ENERGY (IE) Energy needed per mole to remove an electron from an atom in the gaseous phase. First ionization energy is the energy required to remove the first electron (outermost electron in the highest energy sublevel) Na Loses outer electron Sodium atom ATOMIC RADIUS The distance from the nucleus to the border of the outer orbital. •Atomic radii decrease across a period because as electrons are being added to the same energy level, protons are being added to the nucleus, which pulls the electrons with a stronger force. •Atomic radii increase down a group because a)electrons enter a whole new energy level in the next period b)the core electrons shield the outer electron from the pull of the nucleus. Na+ 1A The smaller the atom, the more the force of attraction by the nucleus on the outer electron, hence the higher the ionization energy. •IE increases across a period •IE decreases down a group ELECTRONEGATIVITY (EN) The tendency of an atom in a molecule to attract bonding electrons. Electronegativity range from 0,7 (Cs) to 4,0 (F). F Atomic radii (pm) 2A 3A 4A 5A 6A 7A 8A Li Be B C N O 37 F 152 112 85 77 75 73 72 71 Na Mg Al Si P S Cl Ar 186 160 143 118 110 100 98 Sodium ion ELECTRON AFFINITY (EA) The energy released when an electron is is attached to an atom or molecule to form a negative ion. 31 Ne Gains outer electron Fluorine atom F− Fluorine ion The electron affinity is also a description of how likely an atom is to accept an electron The smaller the atom, the greater the ability of an atom to receive an electron due to proximity to the nucleus. • EA increase across a period • EA decreases down a group Interesting trend: 103 • EN increases across a period • EN decreases down a group 40 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Melting point, Boiling point and Density increase from group 1 to 4, then drop in Group 5 and start increasing again from Group 5 to 8. Periodic table-THE ESSENTIALS Grade 10 Science Essentials SCIENCE CLINIC 2018 © TABLE 3: THE PERIODIC TABLE OF ELEMENTS 6 Y 2 26 27 28 Cr Mn Fe Co Ni 56 44 Mo Tc Ru METALS 96 101 Zn Ga Rh Pd Ag Cd 28 32 Ge In Sn Sb 181 184 186 190 Ra Ac 58 59 60 61 Ce Pr Nd Pm 140 141 144 90 91 92 93 94 95 96 97 98 99 100 Th Pa U Np Pu Am Cm Bk Cf Es Fm 0,9 Se 4,0 79 52 Te I Xe 122 83 128 84 127 85 131 86 Bi Po At Rn Ir Pt Au Hg 192 195 197 201 204 207 209 62 63 64 65 66 67 68 69 70 Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 150 152 157 159 163 165 167 169 173 175 101 102 103 Md No Lr 1,9 112 80 1,8 108 79 238 AR DECREASES IE INCREASES The energy released when an electron is added to a neutral atom to form a negative ion. 41 Atomic radius (AR) The distance between the nucleus and the outermost orbital. For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za IE INCREASES IE DECREASES AR INCREASES IE DECREASES EN DECREASES Electron affinity (EA) 40 36 106 78 1,8 1,6 1,9 179 1,8 139 89 1,7 137 88 1,7 Os 1,9 Re 2,2 W 2,2 Ta 2,2 Hf 1,9 76 La 1,8 75 Ba 1,4 74 Cs 1,2 92 73 1,0 Nb 3,0 84 54 91 72 226 3,5 Kr Zr Fr 20 18 80 53 89 57 Pb Ne Br 75 51 Tℓ F 19 17 As 73 50 119 82 O 16 16 Ar 70 49 115 81 4 10 NONS Cℓ 31 32 35,5 33 METALS 34 35 88 56 103 77 9 8 2,5 3,0 P 2,1 Si Cu 65 48 2,5 Aℓ 1,8 14 15 30 63,5 47 N 12 14 29 59 46 C 11 13 27 31 59 45 7 2,8 25 B 6 2,4 24 55 43 2,0 1,5 1,9 Approximate relative atomic mass Benaderde relatiewe atoommassa 52 42 5 86 55 EN INCREASES The tendency of an atom to attract a bonding pair of electrons. Electronegativity range from 0,7 (Cs) to 4,0 (F). 63,5 18 (VIII) He 2,5 Sr 51 41 17 (VII) 2,5 Rb V 48 40 16 (VI) 2,1 Ti 45 39 15 (V) 2,0 Sc 40 38 14 (IV) 2,0 Ca 13 (III) 1,8 K 39 37 23 12 1,6 22 1,5 21 1,3 24 20 1,0 23 19 11 1,6 Mg 10 Symbol Simbool Cu 1,8 Na Electronegativity Elektronegatiwiteit 1,8 9 12 1,2 7 11 9 Atomic number Atoomgetal 1,5 Be 1,6 Li 8 29 1,6 4 1,5 1 3 232 Electronegativity (EN) 7 KEY/SLEUTEL 133 87 0,7 5 1,9 4 1,8 3 H 0,9 2,1 1,0 0,8 0,7 IMPORTANT GROUPS TO REMEMBER: 1: Alkali metals 2: Alkali Earth metals 17: Halogens 18: Noble gases 2 (II) 1 0,8 PERIOD (ROWS) •There is a gradual change in the physical and chemical properties as we move across a period. •The Period number tells us the energy level where the outermost electrons are found. 1 (I) 0,9 GROUPS (COLUMNS) •Elements in a group have similar outer electron configurations and similar chemical properties. •The group number corresponds to the number of valence electrons. Ionization Energy (IE) The energy required to remove an electron from an atom in the gaseous phase. 71 Chemical bonding Grade 10 Science Essentials CHEMICAL BONDS are INTRAMOLECULAR BONDS which occur between atoms within molecules. Atoms tend to gain, lose, or share electrons until they are surrounded by a full electron shell. A full shell makes the atom more stable like a noble gas. This is known as The Octet Rule: Each atom requires 8 electrons in the outer shell, except for H and He. A) Covalent Bonding 1. Sharing of at least one pair of electrons by two non-metal atoms. 2. Results in simple molecules with only a few atoms connected to each other. Eg. H2, H2O, CO2, Cl2 , CH4. Single Covalent E.g. H−H Each H atom needs one more electron to fill the outer shell with 2 electrons. As the hydrogen atoms come closer so their orbitals overlap. The sharing of electrons results in a lower energy for both electrons. A single bond is formed. SCIENCE CLINIC 2018 © • If two non-metal atoms approach, they tend to share their valence electrons and form a covalent bond. • If a metal and a non-metal atom approach, the metal transfers its valence electrons to the non-metal. They form an ionic bond. • If two metal atoms approach, they release their valence electrons to surround them and form a metallic bond. B) Ionic Bonding 1. Involves a complete transfer of electron(s). 2. Metal atom gives e- to non-metal. 3. Metal forms a positive cation. 4. Non-metal forms a negative anion. 5. Electrostatic attraction of ions leads to formation of giant crystal lattice. Ionic Bonding takes place in two steps. 1. Donation of e-(s) to form ions 2. Electrostatic attraction C) Metallic Bonding 1. Occurs between a metal and a metal atom. 2. The metal atoms release their valence electrons to surround them. There is a strong but flexible bond between the positive metal kernels and a sea of delocalised electrons. Metal atoms are very closely packed, so that the outermost energy levels overlap. The valence electrons are able to move from their respective atoms. They are called delocalised electrons or free electrons. The bond is between the positive metal kernels and the sea of electrons. Double Covalent E.g. O=O Each O atom needs two more electrons to fill the outer shell with 8 electrons. The diagram shows two oxygen atoms coming closer so their orbitals overlap. They each share 2 outer electrons. A double bond is formed. Na+ Cl- Triple Covalent E.g. N≡N Each N atom needs three more electrons to fill the outer shell with 8 electrons. The diagram shows two nitrogen atoms coming closer so their orbitals overlap. They each share 3 outer electrons. A triple bond is formed. Diagrams show the crystal lattice made of alternate ions. IONIC BONDING maintains the la2ce structure between ions Delocalised electrons 42 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Chemical bonding- Properties of substances Giant Covalent Network Structures: Properties of simple covalent (molecular) substances • Low Melting and Boiling Points because molecules are not bonded to each other, but only loosely held together. They are easily separated. E.g. nitrogen has a BP of -1830C. • Highly volatile. (High tendency of a substance to vaporize.) • Insulators – there are no free charge carriers. Properties of ionic substances • Hard, crystalline solids because the Ions held together by strong ionic bonds. • flat sides and regular shapes because the ions are arranged in straight rows in a pattern. • Melting points & Boiling points are very high because there are strong ionic bonds between cations and anions. A large amount of energy is required to separate the ions e.g. NaCl melts at 808ºC and boils at 1465ºC. • Low volatility because there are strong ionic bonds between the ions. • Solid ionic compounds don’t conduct electricity, because the ions cannot move, there are no free charge carriers. • Molten or dissolved ionic compounds conduct electricity because in these situations the ions can move and carry charge, which allows current to flow. Properties of metallic substances The sea of delocalised electrons and tightly packed metal kernels are responsible for the properties of metals: • High density • Good conductors of electricity • The delocalised electrons are free to move randomly throughout the metal, but if a cell is connected across the terminals, the electrons will drift towards the positive end. • Good conductors of heat • Delocalised electrons can also transfer heat energy from a region of high temperature to a region of low temperature, because they move so freely. • Metals have high melting and boiling points because of the strength of the metallic bond. • Metals are malleable and ductile- they can be easily flattened, shaped or drawn into threads without breaking. This is because the metals kernels are not attracted to one specific electron. This makes them different from an ionic compound which is brittle. • Metallic lustre: The sea of electrons would reflect all frequencies of light to give a shiny surface. SCIENCE CLINIC 2018 © These occur when a non-metal atom forms covalent bonds with more than one other non-metal atom. This allows a giant covalent lattices to form. EXAMPLE 1: Diamond. Each C is bonded to four other carbon atoms. Properties: 1. Hard: Many strong covalent bonds holding the structure together-making it a very strong crystal. 2. Very high melting point: Many strong covalent bonds hold the structure together. It requires massive amounts of energy to pull it apart- about 35000C 3. Insulator: All of the valence electrons are used in bonding. None of the electrons are free to move. EXAMPLE 2: Graphite. Each C is bonded to three other atoms to form a layer. Properties: 1. The bonds between the layers are weak and thus the layers can slide over each other- making graphite slippery and can be used as a lubricant. 2. Because only three electrons out four valence electrons are used for bonding, the fourth electron is free to move around. This is why graphite, unlike other non-metals, can conduct electricity. EXAMPLE 3: Silicon Dioxide. Silicon dioxide (SiO2), also called silica. Many precious gems contain silica. There are no discrete SiO2 units. Every Si is bonded to two O atoms. 43 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Diamonds and Graphite are both allotropes of carbon. Allotropes are different forms of the same element but has different physical and chemical properties due to the difference in particle arrangement. Grade 10 Science Essentials Grade 10 Science Essentials Chemical bonding-THE ESSENTIALS SCIENCE CLINIC 2018 © Inter-atomic bonding/ Intramolecular bonding COVALENT BONDING IONIC BONDING METALLIC BONDING Between 2 or more non-metals Between 2 or more metal and non-metal atoms Between 2 or more metal atoms Molecules of an element Covalent network structures Example: Diatomic gases P4 S8 Example: diamond graphite SiO2 C60 (buckyballs) Ionic network structures Metallic network structures Crystals made from a network of cations and anions. Positive kernels and a sea of electrons Example: NaCl KMnO4 Molecules of compounds Example: water (H2O) Ammonia (NH3) 44 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Physical and Chemical change Grade 10 Science Essentials PHYSICAL CHANGE SCIENCE CLINIC 2018 © CHEMICAL CHANGE 1. Usually easy to reverse. 2. No new substances formed. 3. Small energy changes involved. 4. Eg. Melting, evaporation, separation of mixtures. 1. Usually hard to reverse. 2. New substances formed. 3. Large energy changes involved. 4. Eg. Decomposition, synthesis, burning, rotting, rusting. The particles stay the same, but their arrangement changes. The particles change, because the bonding between their atoms changes. Example of Physical change: Water EXAMPLE: Decomposition of Hydrogen peroxide Consider liquid water evaporating to form water vapour. Each water molecule consists of one oxygen atom bonded to two hydrogen atoms. O H Reactants H Products Word Equation Hydrogen peroxide forms water and oxygen Balanced chemical equation 2 H2 O2 → 2 H2 O + O2 Particle diagram Evapora'on 2H2O2 Hydrogen Peroxide Water Spaces between water molecules 2H2O + Water O2 Oxygen water vapor EXAMPLE: Synthesis of water Touching each other Far apart Reactants Forces between water molecules Medium forces No forces, except when they come close to each other there are weak forces Movement of water molecules Slide past each other switching places slowly. Flying freely at high speeds Hydrogen + oxygen forms Water Balanced chemical equation 2 H2 + O2 → 2 H2 O Particle diagram Chemical Reac+on During evaporation, the actual water molecules do not change. The mass of water and the number of molecules does not change. Energy is absorbed to overcome the forces between the molecules. This changes their arrangement and movement. This change could be represented as follows: Reactants Products Word Equation Products Word Equation water forms water vapor Balanced chemical equation H2O (l) → H2O (g) These two reactions are chemical changes because new substances are formed. Huge energy changes are involved. The bonds between the atoms of the reactants are broken and new bonds are formed to create the molecules of the products. Every atom in the reactants becomes an atom in the products. The mass is conserved, but the atoms have been rearranged. 45 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Chemical change- Chemical reactions Grade 10 Science Essentials SCIENCE CLINIC 2018 © Law of constant composition Law of conservation of matter In any particular chemical compound, all samples of that compound will be made up of the same elements in the same proportion or ratio as per its chemical formula. In a chemical reaction, the sum of the mass of the reactants equals the sum of the mass of the products. This is also know as the Law of conservation of matter, which indicates that matter particles can not be created or destroyed, but can be rearranged in chemical reactions. For example, any water molecule is always made up of two hydrogen atoms and one oxygen atom in a ratio according to the formula H2O. + 2 Parts Hydrogen + OR 1 Part Oxygen 1 Part Water 4 Parts Hydrogen 2 Parts Oxygen 2 Parts Water Consider the following reaction to form ammonia: any ammonia molecule is always made up of three hydrogen atoms and one nitrogen atom in a ratio according to the formula NH3. The different parts of the reaction are summarised in the table below: Reactants before Word equation Chemical equation Hydrogen + nitrogen 3 H2 + N2 Products after React to form ammonia → 2 NH3 Atoms 6H 2N → 6H 2N Total mass of all atoms 3 x ( 1+1) + 1 x (14+14)= 34 → 2 x (14 + 1+1+1) = 34 Energy Energy used to break: 3 x H-H bonds And 1 N-N bond → Energy released when forming 6 x N-H bonds 46 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Reactions in aqueous solutions Grade 10 Science Essentials Ionic network structure Because cations and anions are oppositely charged, they attract each other. In solid form, giant ionic crystals are created, such as sodium chloride and magnesium nitrate. Ions in aqueous solution Ions are atoms or groups of atoms which carry charge. Cations are positively charged, and anions are negatively charged. The table below has examples of common ions: Ion Formula Charge Nitrate NO3 -1 -1 Chloride -1 Cl -1 Ammonium NH4+1 +1 Sodium Na+1 +1 Magnesium Mg+2 +2 +3 +3 Aluminium Al Polar nature of water SCIENCE CLINIC 2018 © Reactions in aqueous solutions Reactions in aqueous solutions are reactions of chemicals that have been dissolved. A solution is formed when a solute dissolves in a solvent. Many reactions in chemistry and in living systems are carried out in aqueous solution. This means that water is the solvent. In order for a reaction to occur the particles of the reactant need to collide with each other. For the collision to be successful, there needs to be a transfer of either : A. ions – these are known as ion exchange reactions B. electrons – these are known as redox reactions. Hydration of ions The ions of the solute become totally surrounded by water molecules. This is called hydration. When the water molecules surround the ions, they keep the ions apart. Water is the solvent in all aqueous solutions. The charge in a water molecule is not evenly distributed. The oxygen atom is slightly negative (δ-), and the hydrogen atoms are slightly positive δ+). We say that water is polar. The negative dipole of one water molecule is attracted to the positive dipole of another water molecule. Dissolving of ionic substances Water molecules are attracted to each other, but also to ionic compounds with the oxygen (δ-) closest to the cation(+) and the hydrogen (δ+) closest to the anions(-). If the ions are pulled free from the crystal, the crystal dissolves. Electrolytes Electrolytes are aqueous solutions which contain ions, such as NaCl (aq) or KNO3 (aq). Because the ions are free to move, electrolytes conduct electricAmmeter ity. A simple circuit can be used to test the conductivity of the electrolyte, by measuring the current through the solution with an ammeter. The more ions in solution the better the electrolyte conducts the current. Dissolving is a physical process because no new substances are formed. When all the ions are separated, the ionic crystal has dissolved. EXAMPLE: Certain substances, like sugar, are also soluble in water, but do not form ions in solution, and do not affect conductivity. NaCl (s) → Na+(aq) + Cl-(aq) 47 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Ba0ery Crocodile clip A Test substance Circuit diagram for testing the conductivity of a solution. Reactions in aqueous solutions- Reaction types Grade 10 Science Essentials SCIENCE CLINIC 2018 © A. Ion exchange reactions An ion exchange reaction is where the cations exchange their respective anions. There are 3 types of ion-exchange reaction, classified according to the reactants and products involved. 1. Precipitation reactions In precipitation reactions, anions and cations bond with new partners to form insoluble salts. Certain cations and anions attract each other so well that they will not be pulled from the ionic crystal. These salts are insoluble and form a precipitate. EXAMPLE: NaI (aq) is added to AgNO3 (aq). There are Na+, l-, Ag+ and NO3- ions present in solution. When the I- and Ag+ ions attract, they from an insoluble salt AgI(s) which a yellow cloudy precipitate. NaI (aq) + Ag NO3 (aq) → AgI(s) + NaNO3 (aq) Test Positive result Chloride 1. Add a few drops of AgNO3 2. Acidify with Dilute HNO3 White precipitate forms after step 1, and remains after step 2. AgCl(s) Bromide Add a few drops of AgNO3 Cream precipitate AgBr(s) Iodide Add a few drops of AgNO3 Yellow precipitate AgI(s) Sulphate 1. Add a few drops of BaNO3 2. Acidify in Dilute HNO3 White precipitate forms after step 1, and remains after step 2. BaSO4 1. Add a few drops of BaNO3 2. Acidify in Dilute HNO3 White precipitate forms after step 1, and dissolves after step 2. BaCO3 Carbonate There are 4 types of acid-base reactions: 1. Acid + metal → salt + hydrogen 2. Acid + metal oxide → salt + water 3. Acid + metal hydroxide → salt + water 4. Acid + metal carbonate → salt + water + carbon dioxide EXAMPLE: Acid+ Metal carbonate → salt + water + carbon dioxide Na2CO3 (s) + 2HCl(aq)→ 2NaCl(aq) + H2O(ℓ) + CO2 (g) The sodium ions from the sodium hydroxide swap places with the hydrogen in the hydrogen chloride forming sodium chloride. At the same time the hydroxide and the hydrogen combine to form water. Precipitate 3. Gas forming reactions In gas forming reactions, anions and cations have bonded with new partners and through the exchange of ions a gas is formed. EXAMPLE: Metal hydroxide + acid → salt + water NaOH(aq) + HCl(aq)→NaCl(aq) + H2O(ℓ) Precipitation reactions can be used to test for the presence of certain anions. An environmental scientist analyses water for pollutants. The following table shows how to test for some of these anions. Anion 2. Acid-base reactions Acid-base reactions take place between acids and bases. Through the exchange of ions, the products formed will be water and an ionic salt. EXAMPLE: Metal oxide + acid → salt + water CuO(aq) + 2HCl(aq) → CuCl2(aq) + H2O(l) The copper ions from the copper oxide swap places with the hydrogen in the hydrogen chloride forming copper(II) chloride. At the same time the oxide ion(-) and the hydrogen combine to form water. EXAMPLE: acid + metal → salt + hydrogen H2SO4+Mg → MgSO4 + H2 Gas Test Result Hydrogen (H2) Plunge a lighted wooden splint into a test tube of hydrogen. makes a popping sound Oxygen (O2) Plunge a glowing wooden splint into a test tube of oxygen. splint relights Carbon dioxide (CO2) Bubble the test gas through limewater calcium hydroxide solution. Carbon dioxide turns the limewater cloudy white B. Redox reactions Redox reactions occur when one reactant gains electron(s) called reduction, and another reactant loses electron(s) called oxidation. The atom or group of atoms which loses electron(s) becomes more positive, while the atom or group of atoms which gains electron(s) becomes more negative. EXAMPLE: Hydrochloric acid reacts with zinc to form zinc chloride and hydrogen gas. 2HCl(aq) + Zn(s) → ZnCl2 + H2 We show the transfer of electrons as follow: Zn(s) → Zn 2+ + 2e- (Oxidation) 2 H+ + 2 e- → H2 (g) ( Reduction) O I L R I G OIL RIG oxidation is a loss of electrons reduction is a gain of electrons 48 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za EXAMPLE: Copper Sulphate reacts with zinc to form zinc sulphate and Copper. CuSO4(aq) + Zn(s) → ZnSO4(aq) + Cu(s) We show the transfer of electrons as follows: Zn(s) → Zn 2+ + 2e- (Oxidation) Cu2+ + 2 e- → Cu(s) ( Reduction) Reactions in aqueous solutions-THE ESSENTIALS Grade 10 Science Essentials AQUEOUS SOLUTIONS SCIENCE CLINIC 2018 © REACTIONS Water Water is the solvent in all aqueous solutions. Water is polar. Polar molecules are molecules that have oppositely charged poles and are known as dipoles. A. Ion exchange reactions 1.Precipitation reactions In precipitation reactions, anions and cations bond with new partners to form insoluble salts. NaI (aq) + Ag NO3 (aq) → AgI(s) + NaNO3 (aq) Water dissolves ionic substances which are made up of Cations (positively charged), and anions (negatively charged) Precipitation reactions can be used to test for the presence of certain anions 2. Acid-base reactions There are 4 types of acid-base reactions: 1. Acid + metal → salt + hydrogen 2. Acid + metal oxide → salt + water 3. Acid + metal hydroxide → salt + water 4. Acid + metal carbonate → salt + water + carbon dioxide Water molecules pull the ions free from the ionic crystal. This is called dissolution. 3. Gas forming reactions In gas forming reactions, anions and cations have bonded with new partners and through the exchange of ions a gas is formed The ions become totally surrounded by water molecules. This is called hydration. Electrolytes Electrolytes are aqueous solutions which contain ions, such as NaCl (aq) or KNO3 (aq). Because the ions are free to move electrolytes conduct electricity. The more ions in solution the better the electrolyte conducts the current. This can be tested with the use of a simple circuit as shown below. Gas Test Result Hydrogen (H2) Plunge a lighted wooden splint into a test tube of hydrogen. makes a popping sound Oxygen (O2) Plunge a glowing wooden splint into a test tube of oxygen. splint relights Carbon dioxide (CO2) Bubble the test gas through limewater - calcium hydroxide solution. Carbon dioxide turns the limewater cloudy white Ba0ery Ammeter Crocodile clip A B. Redox reactions One reactant gains electron(s) → reduction; another reactant loses electron(s) → oxidation. Iron + copper(II)sulphate → Copper + iron (II) sulphate Eg. Fe(s) + CuSO4 (aq) → Cu (s) + FeSO4 (aq) Cu 2+ ions gained 2 electrons → Cu atoms Fe atoms lost 2 electrons → Fe 2+ ions Test substance 49 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Quantitative aspects of chemical change Grade 10 Science Essentials The Mole Atoms, molecules and ions are too small to count, and there are so many particles in even the smallest sample of a substance. Percentage Composition Percentage composition is the mass of each atom present in the compound expressed as a percentage of the total mass of the compound. There are more particles of water in a teaspoon then there are teaspoons of water in all the oceans. Percentage composition of element = Rather than dealing with the particles individually, we deal with a special number of particles. The mole is a name for a special number. Many numbers have names, such as: 2 = pair 3 = hat-trick 12 = dozen Ore This many grains of sand, piled on the surface of the earth would almost reach the moon. The mole is defined as the amount of substance having the same of particles or atoms in 12,0 g of Carbon -12. Molar Mass Particles are too small to weigh individually. Molar mass (M) is defined as the mass of one mole of particles (atoms, molecules or formula units) and is measured in the unit g.mol-1. mass of substance (g) m M Example Formula Molar mass (g.mol-1) Atoms Neon Ne 20 Covalent compound Usually Molecules Carbon dioxide CO2 12+32 = 44 Ionic compound Ions (formula units) Salt NaCl 23+35,5 = 58,5 Metallic compound Positive kernels and delocalized electrons Gold Au 197 Element Particles EXAMPLE: What is the relative formula mass of Calcium sulphate (CaSO4)? MR (CaSO4) = AR (Ca) + AR (S)+ (4 x AR (O)) = 40 + 32 + (4 x 16) = 136 (no unit) Magnetite Fe2O3 Fe3O4 Relative molecular mass (2 x 56) + (3 x 16) =160 (3 x 56) + (4 x 16) =232 % iron by mass [(2 x 56) /160] x 100 = 70% [(3 x 56) / 232] x 100 = 72% ∴ magnetite contains more iron Different types of Chemical Formulae Consider the substance ethane. molar mass (g·mol−1) Ball and stick model of ethane Relative atomic mass (Ar) is the average mass of an atom compared to the mass of a Carbon 12 atom. It is measured in atomic mass units (amu). Molar mass (M) of an element is equal to the magnitude of relative atomic mass (Ar) in amu. This is found on the periodic table. See the table below for other substances: Type of substance Haematite Formula 602 000 000 000 000 000 000 000 . n= molar mass of element × 100 MR of compound Consider these iron ores: haematite and magnetite – which contains more iron by mass? A mole of particles is an amount of 6,02 x 1023 particles. 6,02 x 1023 is known as Avogadro’s number, NA. Avogadro’s number (NA) is too big to imagine. number of mole (mol) SCIENCE CLINIC 2018 © It also can be represented using a formula. There are three types of formulas we use: Molecular formula Actual number of each atom. Eg. C2H6 Empirical formula Simplest whole number ratio of the atoms. Eg.C1H3 → CH3 Shows how the atoms are joined. Structural formula EXAMPLE: What is the molar mass of Calcium sulphate (CaSO4)? 136 g.mol-1 EXAMPLE: What is the relative molecular mass of sucrose (C12H22O11)? MR (C12H22O11) = 12 x AR (C) + 22 x AR (H)+ 11 x AR (O) = (12x 12) + (22x1) + (11 x 16) = 342 (no unit) 50 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za EXAMPLE: What is the molar mass of sucrose(C12H22O11) ? 342 g.mol-1 Quantitative aspects of chemical change Grade 10 Science Essentials Concentrations of solutions Solutions are homogeneous (uniform) mixtures of two or more substances. A solution is formed when a solute dissolves in a solvent. The solvent and solute can be a gas, liquid or solid. The most common solvent is liquid water. This is called an aqueous solution. Solution Solute Solvent salt water Salt water Soda water Carbon dioxide water SCIENCE CLINIC 2018 © Molar Volumes of Gases If different gases have the same volume under the same conditions of temperature and pressure, they will have the same number of molecules. This is known as Avogadro’s Law: One mole of any gas occupies the same volume at the same temperature and pressure. Concentration The concentration of a solution is the number of mole of solute per unit volume of solution. number of moles (mol) n c= V concentration (mol ⋅ dm-3) volume (dm3) VM for all gases at STP is 22.4 dm3·mol−1. can also be calculated with m c= MV i.e. The number moles of solute per 1 dm3 of solution i.e. mol. dm-3. If a solution of potassium permanganate KMnO4 has a concentration of 2 mol.dm-3 it means that for every 1 dm3 of solution, there are 2 moles of KMnO4 dissolved in the solvent. Standard Temperature and Pressure (STP) is 273 K (0°C) and 1,01x105 Pa. Note: 1000 cm3 = 1 dm3 (= 1 litre) 1 cm3 = 0,001 dm3 1 cm3 = 1 ml EXAMPLE: EXAMPLE: A solution contains 10 g of sodium hydroxide, NaOH, in 200 cm 3 of solution. Calculate the concentration of the solution. Calculate the mass of solute in 600 cm3 of 1,5 mol·dm -3 sodium chloride solution. n(NaOH) = = = m M 10 23 + 16 + 1 0,25 mol V = 200 cm3 = 0,2 dm3 c(NaOH) = n V 0,25 0,2 = 1,25 mol ⋅ dm−3 = V = 600 cm3 = 0,6 dm3 M(NaCl) = = n m The molar volume of a gas, VM, is the volume occupied by one mole of the gas. This also means that for reactions at constant temperature and pressure, gas volumes will react in the same ratio as the molar ratio. N2 + 2O2 1 mol + 2 mol 1 dm3 + 2 dm3 V n= VM number of moles (mol) 23 + 35,5 58,5 g ⋅ mol−1 = = = cV 1,5 × 0,6 0,9 mol = = = nM 0,9 × 58,5 52,65 g → → → 2NO2 2 mol 2 dm3 volume of gaseous substance (dm3) molar gas volume at STP (22,4 dm3·mol−1) EXAMPLE: A gas jar with a volume of 224 cm3 is full of chlorine gas, at STP. How many moles of chlorine gas are there in the gas jar? n = V VM = 0,224 22,4 = 51 0,01 m ol For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Grade 10 Science Essentials Water of crystallization Quantitative aspects of chemical change Some ionic crystals trap a certain number of water molecules between the ions as they are forming. These water molecules are known as “Water of crystallization”. Eg. Hydrated copper sulphate: CuSO4 · 5 H2O has 5 water molecules per formula unit. When the hydrated salt crystals are heated, the water molecules evaporate off, leaving the anhydrous salt behind. EXAMPLE: 13,2 g of a sample of zinc sulphate, ZnSO4.xH2O, was heated in a crucible. Calculate the number of moles of water of crystallisation if 7.4 g of solid remained. 1 . m(H2 O) = 13,2 g − 7,4 g = 5,8 g = CuSO4 · 5 H2O(s) → CuSO4 (s) + 5 H2O(g) = To calculate the number of moles of water of crystallization: 1. 2. 3. 4. 5. Note: The dot in the formula ( · ) between the salt and the water means that a light bond is formed. It is NOT a multiplication dot. 1.Determine the mass of the elements. 2.Determine mol of each substance. 3.Simplify the atomic ratio. = EXAMPLE: In a combustion reaction 0,48 g of magnesium ribbon is burnt. The amount of magnesium oxide produced is 0,80 g. Calculate the empirical formula for magnesium oxide. m M 7,4 161 = 0,046 mol Steps mol water mol anhydrous salt 4 . ratio = 0,32 0,046 = = 1:7 5 . ∴ formula = Z n SO4 ⋅ 7H2O Calculating the Empirical Formula from Percentage Composition The empirical formula of a compound can also be found from its percentage composition. We assume that 100 g of the compound is analysed, then each percentage gives the mass of the element in grams in 100 g of the compound. An oxide of sulphur contains 40% sulphur and 60% oxygen by mass. Determine the empirical formula of this oxide of sulphur. Steps Sulphur Empirical formula is the chemical formula of a compound that shows the smallest whole number ratio of the atoms. To calculate the empirical formula of a compound from mass: 0,32 mol 3 . n(ZnSO4 ) = Calculate the mass of water that evaporated off. Calculate the moles of water. Calculate the moles of anhydrous salt. Determine the ratio of water to anhydrous salt. Write the formula for the hydrated salt. Calculating the Empirical Formula of a Compound from Mass m M 5,8 18 2 . n(H2 O) = SCIENCE CLINIC 2018 © Magnesium Oxygen Step 1: Mass of element 0.48 g 0.80 – 0.48 = 0.32 g Step 2: Mol (divide by mass of 1 mol) n=m/M = 0.48 / 24 = 0,02 mol n=m/M = 0.32 / 16 = 0,02 mol Step 3: Atom ratio (divide by smallest no in ratio) 1 1 Empirical formula: MgO EXAMPLE: A sample of an oxide of copper contains 8 g of copper combined with 1 g of oxygen. Find the empirical formula of the compound. Oxygen Step 1: % of element 40 60 Step 2: Mass of element (g) 40 60 Step 3: Mol n=m/M = 40 / 32 = 1,25 mol n=m/M = 60 / 16 = 3,75 mol Step 4: Smallest mol ratio 1,25 / 1,25 =1 3,75 /1,25 =3 Steps Oxygen Step 1: Mass of element 8g 1g Step 2: Mol (divide by mass of 1 mol) n=m/M = 8 / 63,5 = 0,126 mol n=m/M = 1 / 16 = 0,0625 mol Step 3: Atom ratio (divide by smallest no in ratio) 0,125/0,0625 ≈2 0,0625/0,0625 =1 Empirical formula: Cu2O Empirical formula: SO3 52 Copper For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za Quantitative aspects of chemical change -THE ESSENTIALS Grade 10 Science Essentials Calculating the Empirical Formula of a Compound from SCIENCE CLINIC 2018 © To calculate the number of moles of water of crystallization: Empirical formula is the chemical formula of a compound that shows the smallest whole number ratio of the atoms. 1. 2. 3. 4. 5. Mass Calculate the mass of water that evaporated off Calculate the moles of water Calculate the moles of anhydrous salt Determine the ratio of water to anhydrous salt. Write the formula for the hydrated salt. To calculate the empirical formula of a compound from mass: 1.Determine the mass of the elements 2.Determine mol of each substance 3.Simplify the atomic ratio Molar mass (M) is defined as the mass of one mole of particles Number of par,cles Mass of pure substance (in grams) != The concentration of a solution is the amount of solute per unit volume of solution. Solu,on ! ! ! = !" Volume of gas at STP (in dm3) ! 22,4 M v for all gases at STP is 22.4 dm3.mol-1. Standard Temperature and Pressure (STP) is 0°C and 101.3 kPa 53 # 6,02×10!" Number of moles != The molar volume of a gas, Mv, is the volume occupied by one mole of the gas. != For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za The mole is the same number of particles or atoms in 12,0 g of Carbon Hydrosphere Grade 10 Science Essentials Water Water exists in 3 forms: •Solid: snow caps at the poles, icebergs and permafrost •Liquid: surface water (oceans, lakes, dams, rivers) and ground water •Vapour: water vapour in the atmosphere Water is important for: •All living organisms depend on water → cells consist mainly of water, substances in cells are suspended or dissolved in water, substances are transported to and from cells in water •Drinking water, habitat, photosynthesis. •Cooking, cleaning, manufacturing processes, agriculture etc. SCIENCE CLINIC 2018 © SYSTEMS OF THE EARTH Systems influenced by the HYDROSPHERE ATMOSPHERE LITHOSPHERE BIOSPHERE Components of system All gaseous components of the earth Hard crust of the earth, semi-solid rocks, hot liquid rocks and molten iron core All living organisms on earth Processes influenced by water Evaporation, condensation and precipitation Surface run-off and percolation Photosynthesis, metabolism etc. Description Energy from the sun causes water to evaporate and form water vapour which condenses to form clouds and becomes too heavy and falls to the earth as precipitation. Precipitation filters through the soil. A certain portion flows across the surface as run-off and the other portion seeps deeper into underwater rivers. Water collects in lakes, dams and oceans. Water is essential for all living organisms. Plants require water for photosynthesis, animals and humans require water for metabolism and various other intracellular processes. HYDROSPHERE •The water cycle (also known as hydrosphere) describes the continuous movement of water through the ground (lithosphere), living organisms (biosphere) and the atmosphere. •Importance of water cycle -Water is recycled -Water is purified CLOUDS Condensa8on Water vapour collects and droplets form which s.ck together and form clouds Precipita8on Water droplets become too heavy and fall to the earth Water vapour Precipita.on: Rain, hail, snow Transpira8on Water is released from plants and evaporates PLANTS SOIL Surface run-off Water runs over the surface of the ground Evapora8on Liquid water is converted to a vapour OCEANS, LAKES, DAMS, RIVERS, STREAMS Surface and ground water Percola8on Water filters through the ground and collects in underground streams and dams INFLUENCE OF DAMS Environmental Influence •Flooding in surrounding areas → affects the plant and animal life •A dam has a large surface area resulting in increased evaporation which may affect the local climate in the area •Erosion and deepening of rivers due to initial emptying of rivers and periodical release of water from the dam •Silting up of dams •Altering of temperature of water in dam due to large surface area •Fish migration is prevented •Dams provide water for agricultural use •Dams produce water used in households and various industrial processes •Production of hydroelectricity Economical Influence •Cost of buying private land to build the dam on •Cost of building the dam •Cost of buying electricity (energy) to run the dam 54 For more information about Science Clinic’s seminars, classes and resources, visit www.scienceclinic.co.za www Scientific Notation N is a number between 1 and 9,99 3) N × 10n n is the integer power of 10. 1000 = 1 × 103 10 000 = 1 × 104 54 500 = 5,45 × 104 4) Very large numbers such as 352 000 000 or very small numbers such as 0,00000000000000085 are difficult to read and write. Scientific notation is used to write these very large or very small numbers. In scientific notation, a number is written with only 1 digit to the left of the comma. The number is expressed as the product of 2 numbers as follows: Positive Exponents 100 = 1 × 102 2500 = 2,5 × 103 2) 125 = 1,25 × 102 4) 1 SYSTEMMATHS | © 0,00000018 = 1,8 × 10-7 0,0000018 = 1,8 × 10-6 0,000018 = 1,8 × 10-5 0,00018 = 1,8 × 10-4 300 000 000 m.s-1 = 7,856157236 billion 7 856 157 236 = 7,856157236 × 109 1 000 000 000 = 1 × 109 [109 = a billion] 17 = 1,7 × 101 1 = 0,001 = 10-3 1000 7) 31572 = 3,1572 × 104 8 157 236 = 8,157236 × 106 1 000 000 = 1 × 106 [106 = a million] 8971 = 8,971 × 103 6) 389 = 3,89 × 102 100 000 = 1 × 105 85 = 8,5 × 101 10 = 1 × 101 Examples: 1) 5) 715 723 = 7,15723 × 105 = 8,157236 million Real Life Example: The speed of light is written in scientific notation as 3 × 108 m.s-1 Negative Exponents Numbers less than 1 (fractional numbers) have negative exponents. 1 = 0,01 = 10-2 100 0,0027 = 2,7 × 10-3 3) 1 = 0,1 = 10-1 10 0,051 = 5,1 × 10-2 0,0091 = 9,1 × 10-3 2) 0,12 = 1,2 × 10-1 0,037 = 3,7 × 10-2 Examples: 1) 0,85 = 8,5 × 10-1 Type 9 . 1 Example 2: When typing 9,1 × 10-31 1. Do not type: 9 . 1 × 1 0 Exp +/– 3 1 3. Type +/– 3 1 2. Press the Exp / ×10 x 0,000 000 000 000 000 000 000 000 000 009 1 kg Real Life Example: The mass of an electron is written in scientific notation is 9,1 × 10-31 kg. Calculator Skills: x button How to use the “ Exp ” or “ ×10 ” button on a calculator: Type 6 . 0 2 Example 1: When typing 6,02 × 1023 1. x 2. Press the Exp / ×10 3. Type 2 3 Do not type: 6 . 0 2 × 1 0 Exp 2 3 Grade 10 Maths Essentials This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. The Metric System Time – second (s) Temperature – Kelvin (K) Mass – kilogram (kg) Light intensity – candela (cd) 2 The System International d’Unites, abbreviated as SI units is the system of units used by scientists. There are seven base units and all other units are derived from these. SI Base Units Length – metre (m) Electric Current – Ampere (A) Amount of matter – mole (mol) nano μ micro × 10-3 pico n 10-6 × 10-3 p 10-9 × 103 10-12 × 103 × 10-3 × 10-3 deci k × 10-3 centi d kilo milli c unit m 103 or 1000 100 × 103 10-1 or 1 1 1000 × 103 10-2 or 1 10-3 or × 103 10 The metric system is a decimal system of units. Units increase or decrease in size by factors of 10. These factors are indicated by prefixes e.g. kilogram is 1000 grams. Metrix Prefixes Prefix abbreviation value Conversions to SI units 2) 875 × 10-9 J = 8,75 × 10-7 J 45 × 10-3 s = 4,5 × 10-2 s 45 ms = 45 ÷ 1000 s = 0,045 s or 2) or p p p p-2 p p p p p p3 × p-5 = p-2 because 3) 4) p3 × p-2 = p1 875 nJ = 875 ÷ 1 000 000 000 J = 0,000000875 J To convert to the SI unit, replace the prefix by its numerical value. All final answers below are written in Scientific Notation. 25 × 103 m = 2,5 × 104 m Examples: 25 km = 25 × 1000 m = 25 000 m or or 1) 43 μC = 43 ÷ 1 000 000 C p × p2 = p3 43 × 10-6 C = 4,3 × 10-5 C 3) = 0,000043 C Multiplying powers p × p = p2 p × p × p = p3 p3 × p2 = p5 (not p6) Rule: “When bases are the same, add the exponents.” 1) p p because p p p p [All final answers below are written in Scientific Notation.] because p3 × p2 = p × p × p × p × p = p5 Conversions between any unit To convert between any units, count the number of “jumps” left or right on the Metrix prefixes table above. kilo 2 jumps right kilo 2 jumps right × 10-6 × 10-6 5) 2) micro 2 jumps right kilo 4 jumps right × 10-6 × 10-12 2,7 × 1015 nm = 2,7 × 1015 × 10-12 km = 2,7 × 103 km nano 2071 pA = 2071 × 10-6 μA = 2,071 × 10-3 μA pico 6) 3) milli 3 jumps right micro 2 jumps right × 10-9 × 10-6 SYSTEMMATHS | © = 1,5 × 10-11 μC 1,5 × 10-5 pC = 1,5 × 10-5 × 10-6 μC pico 0,17 pJ = 0,17 × 10-9 mJ = 1,7 × 10-10 mJ pico One jump right means × 10-3. Two jumps right means 10-3 × 10-3 = 10-6. Four jumps right means 10-3 × 10-3 × 10-3 × 10-3 = 10-12 etc. (Note: this is not applicable for centi- and deci-) milli 785 mm = 785 × 10-6 km = 7,85 × 10-4 km milli Examples: 1) 4) 7,8 × 104 mm = 7,8 × 104 × 10-6 km = 7,8 × 10-2 km Grade 10 Maths Essentials This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. milli 2 jumps left milli 2 jumps left 106 × 106 5) 2) nano 1 jump left pico 3 jumps left = 8,3 × 102 ps (p-2) 3 = p-6 × 103 × 109 8,3 × 10-7 ms = 8,3 × 10-7 × 109 ps milli 12,7 μC = 12,7 × 103 nC = 1,27 × 104 nC micro (p3) 3 = p9 (p-3) 3 = p-9 1 km = 1000 m 6) 3) pico 2 jumps left nano 1 jump left = 1,8 nC × × 103 25 cm2 = 25 × (10-2)2 m2 = 25 × 10-4 m2 = 2,5 × 10-3 m2 1 km = 1000 m 3) 1,8 × 10-3 μC = 1,8 × 10-3 × 103 nC micro 0,85 μC = 0,85 × 106 pC = 8,5 × 105 nC 106 micro One jump left means × 103. Therefore two jumps left means 103 × 103 = 106. Three jumps left means 103 × 103 × 103 = 109 etc. (Note: this is not applicable for centi- and deci-) kilo 37 km = 37 × 106 mm = 3,7 × 107 mm kilo Examples: 1) 4) 4,5 × 104 km = 4,5 × 104 × 106 mm = 4,5 × 1010 mm Raising a power to a power (p2) 2 = p2 × p2 = p4 (p3) 2 = p3 × p3 = p6 (p2) 3 = p6 Rule: “When raising a power to a power, multiply the exponents.” Examples: Conversions of square units If the unit is squared, as for area, the conversion factors must also be squared. 1 m = 100 cm Reasoning: 1 cm = 10 mm 1 km2 = 1 km × 1 km = 1000 m × 1000 m = 10002 m2 or = 1 000 000 m2 2) 13 dm2 = 13 × (10-1)2 m2 = 13 × 10-2 m2 = 1,3 × 10-1 m2 1 m2 = 1 m × 1 m = 100 cm × 100 cm = 1002 cm2 or = 10 000 cm2 or 5 km2 = 5 × (103)2 m2 = 5 × 106 m2 1 cm2 = 1 cm × 1 cm = 10 mm × 10 mm = 102 mm2 or = 100 mm2 Examples: 1) 5 km2 = 5 × 10002 m2 = 5 000 000 m2 Conversions of cubic units If the unit is cubed, as for volume, the conversion factors must also be cubed. 1 m = 100 cm Reasoning: 1 cm = 10 mm × 10-3 × 103 m3 ( kl ) 1 km3 = 1 km × 1 km × 1 km = 1000 m × 1000 m × 1000 m = 10003 m3 or = 1 000 000 000 m3 × 10-3 dm3 ( l ) 1 m3 = 1 m × 1 m × 1 m = 100 cm × 100 cm × 100 cm = 1003 cm3 or = 1 000 000 cm3 cm3 ( ml ) × 103 2) 13 dm3 = 13 × (10-1)3 m3 = 13 × 10-3 m3 = 1,3 × 10-2 m3 3) 25 cm3 = 25 × (10-2)3 m3 = 25 × 10-6 m3 = 2,5 × 10-5 m3 3 SYSTEMMATHS | © Note: ◦ An object with a volume of 1 cm3 will displace exactly 1 ml of water. ◦ An object with a volume of 1 dm3 will displace exactly 1 l of water. ◦ An object with a volume of 1 m3 will displace exactly 1 kl of water. 1 cm3 = 1 cm × 1 cm × 1 cm = 10 mm × 10 mm × 10 mm = 103 mm3 or = 1000 mm3 Study: Examples: 1) 7 km3 = 7 × (103)3 m3 = 7 × 109 m3 Grade 10 Maths Essentials This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. Solving an equation for an unknown variable then x–3=y–3 x+3=y+3 x=y 4 3 2 1 1 4 3x x = = 3y y 2 x+3 5 = = y+3 3 x-3 = y-3 4 An equation is like a pair of scales balancing on the equals sign. To maintain the balance means that whatever you do to the left–hand side you must also do to the right–hand side. If the same operation is carried out on both sides of the equal sign, the equality is maintained. and 3x = 3y If and 5 x 3 y 3 and Examples In all examples below the unknown variable is “p”. Each equation is solved for p by making it the subject of the formula (writing “p” on its own on one side of the equal sign.) Remember: Only if the same operation is carried out on both sides of the equal sign will equality be maintained. 4 =4 p 1 Example 2 p-2=8 p-2+2=8+2 1 p = 10 18 2 p = 12 3 2 3 p = 12 3 2 Example 6 1 Add 2 to both sides. 3 2 p 1 Multiply both sides by 3 2 1 Example 4 3 Example 3 1 p because 2 3 5 7 3 2 7 5 1 SYSTEMMATHS | © 1 5 is the reciprocal of 7 7 5 because 3 is the reciprocal of 2 2 3 Note: Example 6 and 7 When the coefficient of the variable is a fraction, multiply both sides of the equation by the fraction’s reciprocal. 1 Multiply both sides by 3. p = 12 3p = 15 15 3 7 5 p =4 3 3 4 3 1 3p 3 p=5 22, 4 5 p = 16 7 5 7 p = 16 7 5 Example 7 1 Divide both sides by 3. 7 5 p 1 Multiply both sides by 1 Please note: All the steps are written out in the examples, however the numbered steps 1 , 2 and 3 in grey are only shown for completeness. These steps can and should be done mentally or on a calculator. 1) Basic examples: Example 1 p + 8 = 15 p + 8 - 8 = 15 - 8 1 p=7 p 3 p Example 5 1 Subtract 8 from both sides. 3 p 3 = 4p 3 4p = 2 4 4 3 p= or 0,75 4 1 Multiply both sides by p. (p 0) 2 Divide both sides by 4. Grade 10 Maths Essentials This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. Example 8 p 7 = 2 9 p 2 7 2 1 2 9 14 p= or 1,56 9 1 Multiply both sides by 2. 1 LCD is 9p Example 9 2 5 = p 9 2×9×p 5×9×p = p 9 1 LCD is 8p Example 10 5 9 = 8 p 2 5×8×p 9×8×p = 8 p 72 5p 5p 18 5p 72 = 5 5 14, 4 1 Multiply both sides by 8p 2 Divide both sides by 5. p 18 5p = 2 5 5 18 or 3,6 5 p 1 Multiply both sides by 9p 2 Divide both sides by 5. 2p = 16 2p 16 = 2 2 p=8 p 3 Example 14 p 3 3 3 3 2 3 p +1=4 3 p +1-1 =4-1 1 3 p 3 p=9 1 Subtract 1 from both sides. 2 Multiply both sides by 3. ) alone on one side first. 1 Add 1 to both sides. 2 Divide both sides by 2. 2 2p - 1 + 1 = 15 + 1 1 2p - 1 = 15 Example 13 1 LCD is 10p Example 11 3 5 = 10 2p 25 2 3 × 10 × p 5 × 10 × p = 10 2p 3p 8, 3 3p 25 = 3 3 p 1 Multiply both sides by 10p 2 Divide both sides by 3. p 3 p p 7 7 p 2 3 = 7p 3 7p = 3 7 7 3 or 0,43 (2 dec. places) 7 p= 5 SYSTEMMATHS | © 1 Subtract 1 from both sides. 2 Multiply both sides by p. 3 Divide both sides by 7. 3 3 +1-1 =8-1 1 p 3 +1=8 p Example 15 Example 9, 10 and 11: When the variable is in the denominator, always multiply both sides of the equation by the Lowest Common Denominator (LCD). Example 12 2p + 7 = 15 2 2p + 7 - 7 = 15 - 7 1 2p = 8 2p 8 = 2 2 p=4 1 Subtract 7 from both sides. 2 Divide by 2 on both sides. Examples 12 - 15: Always get the variable (e.g. 2p or Grade 10 Maths Essentials This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. Example 2 -2p + 12 = 4 2 -2p + 12 - 12 = 4 - 12 1 -2p = -8 -2p -8 = -2 -2 p=4 1 Subtract 12 from both sides. 2 Divide both sides by -2. Example 6 -0,2p - 1,8 = 1,5 2 -0,2p - 1,8 + 1,8 = 1,5 + 1,8 1 -0,2p 3,3 = -0,2 -0,2 p = -16,5 1 Add 1,8 to both sides. 2 Divide both sides by -0,2. Example 3 p 3 3 -3 3 2 -3 p +4=1 3 p +4-4 =1-4 1 3 p 3 p = -9 p 0,3 0,3 0,3 -46,7 -46,7 0,3 2 p = -14, 01 1 Subtract 1,7 from both sides. 2 Multiply both sides by 0,3. p p + 1,7 - 1,7 = -45 - 1,7 1 0,3 p + 1,7 = -45 0,3 Example 7 1 Subtract 4 from both sides. 2 Multiply both sides by 3. 2) Examples including negative numbers and decimal fractions: Example 1 2p + 15 = 8 2 2p + 15 - 15 = 8 - 15 1 2p = -7 2p -7 = 2 2 p = -3,5 1 Subtract 15 from both sides. 2 Divide both sides by 2. Example 5 2,5p + 0,7 = 5,25 2 2,5p + 0,7 - 0,7 = 5,25 - 0,7 1 2,5p = 4,55 2,5p 4,55 = 2,5 2,5 p = 1,82 1 Subtract 0,7 from both sides. 2 Divide both sides by 2,5. Grade 10 Maths Essentials This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. Example 4 3 +9=3 p p p 3 p -6 p 2 -6 3 +9-9 =3-9 1 p 3 3 = -6p 3 -6p = 3 -6 -6 1 p = - or -0,5 2 1 Subtract 9 from both sides. 2 Multiply both sides by p. 3 Divide both sides by -6. Example 8 5 - 2,3 = 4,5 p p 5 p p 47,3 47,3 p 47,3p 3 2 5 - 2,3 + 2,3 = 45 + 2,3 1 p 5 5 5 47,3p = 47,3 47 ,3 6 p = 0,11 (2 dec. places) 1 Add 2,3 to both sides. 2 Multiply both sides by p. 3 Divide both sides by 47,3. SYSTEMMATHS | © = 4 2 1 1 2 2 Example 2 2 2 7 - 13 p 4 Example 2 25 = -6 p 2 p 25 = -6 25p = p 25p = - 6 25p -6 = 25 25 p = - 0,24 1 Multiply both sides by p. 2 Divide both sides by 25 1 1 Subtract 4 from both sides. 2 Find the square root of both sides. p= p = 16 2 p = 16 p + 4 - 4 = 20 - 4 1 p + 4 = 20 2 3) Examples including squares and square roots: Example 1 2 2 p =4 p 2 =3 p =3 2 2 and p= p p=9 1 Find the square root of both sides. 2 Square both sides. p+3 2 Example 1 19 = 5 19 5 p+3 = 5 5 2 19 p+3 = 5 2 19 p+3 = 2 5 2 3 4) Examples including more complex fractions: 2 7,6 = p + 3 7,6 - 3 = p + 3 - 3 p = 4,6 1 Divide both sides by 5 2 Multiply both sides by 2. 3 Subtract 3 from both sides. Grade 10 Maths Essentials Example 3 1 2 18 = 5 + p 2 1 2 18 - 5 = 5 - 5 + p 2 1 2 13 = p 2 1 2 p 2 2 3 2 1 5,1 (1 dec. place) p 2 13 2 = 2 26 = p 26 = p= Example 4 2 9 = 3 + 0,7p 2 3 2 9 - 3 = 3 - 3 + 0,7p 2 6 = 0,7p 2 0,7p 6 = 0,7 0,7 2 1 2, 93 (2 dec. place) p 6 2 =p 0,7 6 = 0 ,7 p= p = 2 4 × 5 × 10 p × 10 p 1 1 4×5 = LCD = 10p 2 p × 10 1 Subtract 3 from both sides. 2 Divide both sides by 0.7. 3 Find the square root of both sides. 2 5p = 20 5p 20 = 5 5 p=4 7 SYSTEMMATHS | © 1 Multiply both sides by 10p. 2 Divide both sides by 5. 10 1 Subtract 5 from both sides. 2 Multiply both sides by 2. 3 Find the square root of both sides. = 45,5 3 2 1 Example 4 13 p2 2 p = 45,5p 2 Example 3 13 p2 2 2 0 ,53 (2 dec. place) p 45,5p2 45,5 13 = 45,5p 13 45,5 13 2 =p 45,5 13 45,5 p= 1 Multiply both sides by p2. 2 Divide both sides by 45,5. 3 Find the square root of both sides. This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. Ratios The Basics If a certain substance consists of 3 kg of X and 5 kg of Y we say, “the ratio of the mass of X to the mass of Y is 3 to 5”. X 3kg 3 = = . NB: No units in the answer. Y 5kg 5 This can be written as X : Y = 3 : 5 or in fraction form If another substance consists of 9 kg of X and 12 kg of Y we say, “the ratio of the mass of X to the mass of Y is 9 to 12”. X 9kg 3 = = in simplest fraction form. Y 12kg 4 This can be written as X : Y = 9 : 12 = 3 : 4 in simplest form or Ratios can only be determined for quantities of the same kind i.e. the quantities must have the same units. 60c 60c 6 1 For example, the ratio of 60c to R5,40 = 60c : 540c = 6 : 54 = 1 : 9 in simplest form or R5,40 = 540c = 54 = 9 . 1 : 2 = 5 : 10 and or and or 1 5 = 2 10 sec ond sec ond = first first first first = sec ond sec ond 3 6 = 2 4 2 4 = 3 6 sec ond sec ond = first first first first = sec ond sec ond “The ratio of 2 parts to 3 parts is equal to the ratio of 4 parts to 6 parts” can be written in the following ways. 2 10 = 1 5 “The ratio of 1 part to 2 parts is equal to the ratio of 5 parts to 10 parts” can be written in the following ways. Writing ratios in different ways 1) 2) 2:3 = 4:6 Solving problems involving ratios Example 2 Example 3 0,6 0,6 3 4 Example 4 12 : b 12 = 6 : 12b = 8 : 9 6 3 Divide both sides by 2. 8 SYSTEMMATHS | © 12b 9 2 6 8 9 2b 3 8 9 b= or 0,5625 16 1 Multiply each fraction by the LCD. 2 Simplify 12 1 2 1 2 3 :b= : LCD = 12 2 3 4 2 3 12 : 12 1 3 4 of 2 to 3 . The ratio of 1 to b is equal to the ratio 2 NB: When solving a ratio for an unknown variable, always write the variable in the numerator of the fraction as it makes solving the equation much easier. Example 1 0,5 : 0,3 = 0,6 : b The ratio of 0,5 parts to 0,3 parts is equal to the ratio of 0,6 parts to b parts. 4 : 3 = b : 13 b 0,3 b = 0,5 0,6 0,3 0,6 0,5 1 The ratio of 4 parts to 3 parts is equal to the ratio of b parts to 13 parts. 4 = 4 b = 3 13 13 b 13 13 3 b = 0,36 0,36 = b b = 17,3 1 Multiply both sides by 0,6. 17,3 = b 1 Multiply both sides by 13. 1 The ratio of 2 parts to b parts is equal to the ratio of 5 parts to 3 parts. 2:b=5:3 b 3 = 2 5 b 2 3 2 1 2 5 6 b= or 1,2 5 1 Multiply both sides by 2. Grade 10 Maths Essentials This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. Add: 2 + 3 = 5 [we have 5 equal parts] Divide: 15 ÷ 5 = 3 Multiply both sides of the ratio by 3: 2×3:3×3 6 : 9 o 3 : 6 = 1 : 2 NB: Simplify the ratio first 1 × 0,5 : 2 × 0,5 0,5A : 1A Add: 1 + 2 = 3 [we have 5 equal parts] Divide: 1,5 ÷ 3 = 0,5 Multiply both sides of the ratio by 0,5: Answer is: 5 Divide a current of 33 A in a ratio of 1 : 3 . 1 3 : (LCD = 10) 2 5 1 3 10 : 10 2 5 5 : 6 5×3:6×3 15A : 18A Add: 5 + 6 = 11 Divide: 33 ÷11 = 3 Multiply both sides of the ratio by 3: 2 o o o Divide a current of 1,5 A in a ratio of 3 : 6. Answer is: o o o Divide 15 in a ratio of 2 : 3. [think “2 parts to 3 parts”] Dividing a number into a ratio: 1) 3) 5) o o o Answer is: Grade 10 Maths Essentials 2) 4) 4) Add: 1 + 2 = 3 [we have 3 equal parts] Divide: 0,75 ÷ 3 = 0,25 Multiply both sides of the ratio by 0,25: 4 4 9 SYSTEMMATHS | © Divide 0,75 in a ratio of 2 : 1. [think “2 parts to 1 part”] o o o 2 × 0,25 : 1 × 0,25 Answer is: 0,5 : 0,25 2 Divide 10m in a ratio of 1 : 3 2×2:3×2 4m : 6m Add: 2 + 3 = 5 [we have 5 equal parts] Divide: 10 ÷ 5 = 2 Multiply both sides of the ratio by 2: 1 3 : (LCD = 4) 2 4 1 3 4: 4 2 4 2 : 3 NB: Simplify the ratio first: o o o Answer is: 3 Divide 55m in a ratio of 2 : 1 8×5:3×5 40m : 15m Add: 8 + 3 = 11 Divide: 55 ÷ 11 = 5 Multiply both sides of the ratio by 5: 2 1 : (LCD = 12) 3 4 2 1 12 : 12 3 4 8 : 3 o o o Answer is: This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. Straight line graphs and the Cartesian plane 1 3 2 6 3 9 4 12 The rule is y = 3x or x:y=1:3 The table below shows a relationship between input values (x values) and output values (y values). x y (1 ; 3) 2 (2 ; 6) 3 (3 ; 9) 4 (4 ; 12) 5 X or y x 3 1 Quadrant 2 0 Quadrant 4 Quadrant 1 Y Quadrant 3 y x k 10 If the points are joined with a straight line, it means that each point on the line represents the rule y = 3x. The point (0 ; 0), the point of intersection of the X-axis and the Y-axis, is called the origin. The point (2 ; 6) is 2 units from the Y-axis and 6 units from the X-axis. The y co-ordinate of a point indicates how far the point is from the X-axis. The x co-ordinate of a point indicates how far the point is from the Y-axis. The x- and y-values are called the co-ordinates of the points. The input (x) values are represented on the horizontal axis and the output (y) values on the vertical axis. X Another way to express the relationship between the x-values and the y-values is as ordered number pairs, namely (1 ; 3) , (2 ; 6) , (3 ; 9) and (4 ; 12). The input value (x-value) is always written 1st and the output value (y-value) 2nd inside the round brackets. 1 Graphs are visual representations of relationships where the shape of the graph indicates the properties of the relationship. Graphs are drawn on the Cartesian plane. The vertical number line, called the Y-axis, and the horizontal number line, called the X-axis, divide the Cartesian plane into 4 quadrants. Y 12 10 8 6 4 2 0 or Graph is a straight line passing through the origin. y = kx In the Cartesian plane: Horizontal change to the right is in a positive direction and to the left is in a negative direction. Vertical change upwards is in a positive direction and downwards is in a negative direction. NB: DIRECTLY PROPORTIONAL RELATIONSHIPS k. Consider the equation y = 3x above. This is a directly proportional relationship. y This means that y = kx where k is a constant. This can also be written as x In the above example, the value of this constant is 3. Increasing linear function. As the x -values increase the y -values decrease. Decreasing linear function. Types of straight line graphs: Graphs are used to communicate information and relationships. To read a graph, one must understand how the quantities in the graph relate to each other e.g. look to see if the quantities make the graph go up or down or remain constant. Constant linear function As the x -values increase the y -values increase. SYSTEMMATHS | © As the x-values increase the y-values remain constant. Grade 10 Maths Essentials This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. The gradient of a straight line graph y2 x2 y1 . x1 (2;4) A 2 Y (2;2) B (3;3) 3 (2;-1) 2 y1 x1 y1 x1 ( 1) 1 1 y2 x2 2 1 1 11 ) means “change in”. 3 3 1 1 Gradient of graph B y y y2 2 1 x2 x1 x2 3 1 1 2 4 2 1 2 2 1 2 3 2 1 y1 x1 Gradient of graph C y2 x2 1 2 1 ( 1) 1 1 2 1 2 or 2 0, 6 3 1 2 or 1 X 0, 6 3 Note: (-1;1) can be used as the starting point or (2;-1) can also be used to calculate the gradient of line C. 2 2 1 SYSTEMMATHS | © 1 0 1 1 Gradient of graph D y2 y1 x2 x1 Note: Any two co-ordinates on a graph can be used to work out its gradient. 2 Gradient of graph A y2 y1 x2 x1 Note: Delta ( The vertical change divided by the horizontal change between any 2 points on a straight line indicates the steepness of its slope and whether it slopes to the left or the right. This value is known as the gradient of the straight line. y change in y The gradient is written as follow The vertical change or or most commonly x change in x The horizontal change Example 1 (1;2) (1;1) 1 X The two straight line graphs below, A and B, both slope to the right and therefore have positive gradients. The gradients can easily be worked out using the formula y y2 y1 , as shown below. x x2 x1 Graph A is visibly “steeper” than graph B and therefore has a larger gradient. Y 4 3 2 1 0 Example 2 D (0;1) 0 (1;-1) The two straight line graphs below, C and D, both slope to the left and therefore have negative gradients. The gradients can easily be worked out using the formula y y2 y1 , as shown below. x x2 x1 Graph D is visibly “steeper” than graph C and therefore has a larger gradient. C (-1;1) Grade 10 Maths Essentials This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. Example 3 12 The horizontal change The two straight line graphs below, E and F, are both constant graphs. Remember, the gradient of the graphs means The vertical change . 0 3 0 2 1 2 2 Gradient of graph E 3 2 3 4 4 1,5 5 6 6 1 or The rule is k x y 6 x xy = k. or 2 0 0 1 ( 1) 1 1 2 2 0 undefined k x SYSTEMMATHS | © Graph is a curved line and does not pass through the origin. xy = k or y xy = 6 Gradient of graph F . Therefore a vertical line’s gradient is undefined. 0 . Therefore a horizontal line’s gradient is 0. The horizontal change E Graph E is horizontal and therefore has no vertical change i.e. Y (0;2) 0 (1;2) The vertical change 0 (-1;2) (-1;1) (-1;0) (-1;-1) X Graph F is vertical and therefore has no horizontal change i.e. F Inversely proportional relationships 1 6 2 X The table below shows a relationship between input values (x values) and output values (y values). x y 1 This relationship is represented graphically as follows: Y 6 5 4 3 2 1 0 6 above. x NB: INVERSELY PROPORTIONAL RELATIONSHIPS Consider the equation y This is an inversely proportional relationship. This is written as y In the above example k = 6. Grade 10 Maths Essentials This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. B B Trigonometry Trigonometry is the branch of Mathematics which deals with the relationship between the sides and angles of a triangle. Understanding the terms “Opposite”, “Adjacent” and “Hypotenuse”. 4cm 8cm A AB LEARN: sin A = opposite Example 4: adjacent Example 2: B C AB AD 10 AD opposite hypotenuse 5 B C 5 With respect to  : 13 o BC is the opposite side o AC is the adjacent side o AB is the hypotenuse o AC is the opposite side o BC is the adjacent side o AB is the hypotenuse With respect to B̂ : A A AB adjacent AD AB cos A = adjacent hypotenuse This constant ratio is called the cosine of  or cos A. LEARN: adjacent A For any angle  , the ratio of the length of the side adjacent to  to the length of the hypotenuse is a constant. AD In the adjacent triangles, AC = 3 and AE = 6 = 3 . Therefore AC = AE . 10 hypotenuse is a constant. This constant ratio is called the sine of  or sin A. For any angle  , the ratio of the length of the side opposite  to the length of the 5 In the adjacent triangles, BC = 4 and DE = 8 = 4 . Therefore BC = DE . o BC is the opposite side o AC is the adjacent side o AB is the hypotenuse D E D E 5 Definition: The Hypotenuse is the longest side of a right-angled triangle. It is always the side opposite the right angle. With respect to B̂ : o AC is the opposite side o BC is the adjacent* side o AB is the hypotenuse C With respect to  : *adjacent means next to or adjoining A C A Consider the right-angled triangles below: Example 1: adjacent Example 3: opposite B C B C opposite Trigonometric ratios: Sine, Cosine and Tangent 1) Sine A 3cm 6cm opposite This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. SYSTEMMATHS | © opposite 2) Cosine A Grade 10 Maths Essentials adjacent opposite adjacent 3cm B C 6cm 4cm D E 8cm AC 3 AE 6 3 AC AE In the adjacent triangles, BC = 4 and DE = 8 = 4 . Therefore BC = DE . adjacent A 14 For any angle  , the ratio of the length of the side opposite  to the length of the side adjacent to  is a constant. tan A = This constant ratio is called the tangent of  or tan A. LEARN: opposite adjacent Trigonometric ratios are independent of the lengths of the sides of a triangle and depend only on the angle size. Hence trigonometric ratios are considered to be functions of the angles. 3) Tangent A NB: Grade 10 Maths Essentials This material may be copied and distributed freely according to the copyright notice. Not for commercial use. Accreditation required. For Mathematics textbooks, please visit www.systemmaths.co.za. SYSTEMMATHS | © opposite