Chapter 6: Mechanical Properties (of Metals) ISSUES TO ADDRESS... • Stress and strain • Elastic behavior • Plastic behavior • Toughness and ductility Chapter 6 - 1 Chapter 6: Mechanical Properties (of Metals) Callister study guide. • 6.1 – 6.9: Study all parts • 6.10: Understand terms and concepts – conversion between different hardness scales is not required. • 6.11 – 6.12: Study all parts Chapter 6 - 2 The most important properties of structural materials, including metals and alloys, ceramics, polymers, and composites, are their mechanical properties. Most researches (research publications) related to the development of new structural materials include mechanical property testing. Example: Hardness test Tensile test M. N. Hasan, et al., International Journal of Plasticity 123 (2019) 178–195 Chapter 6 - 3 A Simple Question Why do we care about mechanical properties of a material? https://www.youtube.com/watch?v=KeTizNY0zDA Mechanical properties reflect how materials respond to applied load. How do we know the mechanical properties of materials? Apply load and check how materials respond. Chapter 6 - 4 Elastic Deformation 1. Initial Elastic means reversible! 3. Unload bonds stretch Atomic bonds are stretched during an elastic deformation process and will return to their initial state once external load is released. Elastic deformation is reversible but is not necessarily linear! (e.g., a rubber band) 2. Small load return to initial d F (load) F Linearelastic Non-Linearelastic d (displacement) Chapter 6 - 5 Plastic Deformation (Metals) Plastic means permanent! 1. Initial Plastic deformation is not reversible and does not present a linear force– displacement relationship. Plastic deformation in metals can occur via plane shearing 2. Large load bonds stretch & planes shear delastic + plastic F 3. Unload planes still sheared dplastic F linear elastic linear elastic dplastic d Elastic deformation may continue after plastic deformation has initiated. This will be further discussed later. Chapter 6 - 6 Various kinds of applied forces Tensile Compressive Tension test is one of the most common mechanical tests Compression test is conducted when the inservice force is compressive or when materials are brittle in tension. Shear Torsional Torsion is a variation of pure shear Chapter 6 - 7 Engineering Stress • Tensile stress, s: It is always easier to break a thin chopstick than a thick one made from a same material. We introduce the concept of stress and strain to exclude the specimen size effect on mechanical properties. • Shear stress, t: Ft Ft Area, A Area, A Tensile stress (shear stress ) applied to a plane equals to the external load component perpendicular to (parallel with) the plane divided by the area of the plane. F Ft F s = t = lb2f or N2 m A o in original area before loading Pa or pascal Fs Fs F t= s Ao F Ft \ Stress has units: N/m2 or lbf/in2 Chapter 6 - 8 Pay Special Attention to Units in Calculations The unit of Pascal is too small. We usually use MPa and GPa MPa = 106 Pa GPa = 109 Pa Example: Tensile force of 1 KN is applied to a rod sample with a cross sectional diameter of 10 mm. What is the engineering tensile stress applied to the sample? #! #! != = # $" %& 1×10$* & 45 = ≅ 12.7×10 3.14×(5×10%$)# = 12.7 645 Chapter 6 - 9 For a sample under tensile stress, is there any shear stress component applied to the sample? Plastic deformation occurs via shearing of atomic planes. Later we will know that shearing is possible only along some specific atomic planes. This makes it important for us to calculate shear stress on these specific atomic planes. Chapter 6 - 10 Common States of Stress • Simple tension: cable F F Ao = cross sectional area (when unloaded) F s s= Ao s • Torsion (a form of shear): drive shaft M Ac M 2R Fs Ao Ski lift (photo courtesy P.M. Anderson) Fs t = Ao Note: t = M/AcR here. Chapter 6 - 11 OTHER COMMON STRESS STATES (1) • Simple compression: Ao Canyon Bridge, Los Alamos, NM Balanced Rock, Arches National Park s= F Ao Note: compressive structure member (s < 0 here). Chapter 6 - 12 OTHER COMMON STRESS STATES (2) • Bi-axial tension: Pressurized tank sq > 0 sz > 0 • Hydrostatic compression: Fish in water sh< 0 Chapter 6 - 13 Geometric Consideration of Stress State Tensile and shear stresses applied to the yellow plane s’ = s cos2q t’ = s sinq cosq s= F Ao Fs t = Ao !' <' #( # 789: = = = ! 789 #: $)( $"⁄789: #* # 9=>: = = = ! 9=>: 789: $)( $"⁄789: Chapter 6 - 14 Angles for Max. Stresses s’ = s cos2q t’ = s sinq cosq The maximum normal stress at q = 0°. The maximum shear stress at q = 45°. Chapter 6 - 15 Engineering Strain • Tensile strain: • Lateral strain: d/2 e = d Lo • Shear strain: wo -dL eL = wo Lo dL /2 q g = Dx/y = tan q Dx 90º - q y 90º When a tensile load is applied to two chopsticks made from the same material with different lengths but the same diameter, the longer one deforms more. To exclude this dimensional effect, the concept of strain is introduced. Strain is always dimensionless. Chapter 6 - 16 Stress–Strain Testing • Typical tensile test machine extensometer • Typical tensile specimen specimen We have introduced stress and strain, will the dimensions of specimens still affect the measured mechanical properties? Yes, ductility will be affected! = (elongation at tensile failure) gauge length Chapter 6 - 17 Effect of Specimen Dimension on Measured Ductility We will learn ductility later. ΔA ?= A" This example shows that fractured areas of superplastically deformed samples are very fine tips. Imaging the impact of (1) sample thickness on ∆l and (2) A" on the value of ∆,D,! J. Mater. Res. 32, 4541–4553 (2017) Chapter 6 - 18 Linear Elastic Properties • Modulus of Elasticity, E (GPa or psi): (also known as Young's modulus) F s • Hooke's Law: s=Ee E is the slope of the linear part of stress–strain curves. It shows material’s resistance to elastic deformation (stiffness). Is it a good idea to write Hooke’s Law as: # = E∆A where F is the applied load, K is a constant, ∆A is the change in length E Linearelastic e F simple tension test For the same material, E is a constant, but K is affected by sample dimensions Chapter 6 - 19 Non-Linear Elastic Properties (grey cast ion, concrete, and many polymers) Tangent modulus: The slope of the stress–strain curve at a specific stress value Secant modulus: The slope of a secant from the origin to a specific point of the stress–strain curve Chapter 6 - 20 Bonding Forces There is a repulsive force (caused by the overlapping of electron clouds of two atoms) and an attractive force (depending on type of bonding) between neighbouring atoms. The net force is the sum of the repulsive and attractive forces. The place where the net force is 0 is the equilibrium interatomic spacing Chapter 6 - 21 Mechanical Properties • Slope of stress strain plot (which is proportional to the elastic modulus) depends on the bond strength of materials Eµ E is a measure of the resistance to change the interatomic distance Chapter 6 - 22 Young’s Moduli: Comparison General trend on E for different materials (caused by atomic bonding): Metals Alloys 1200 1000 800 600 400 E(GPa) Metals/alloys Polymer-based composites polymers Increasing E Ceramics 200 100 80 60 40 109 Pa Graphite Composites Ceramics Polymers /fibers Semicond Diamond Tungsten Molybdenum Steel, Ni Tantalum Platinum Cu alloys Zinc, Ti Silver, Gold Aluminum Magnesium, Tin Si carbide Al oxide Si nitride Carbon fibers only CFRE(|| fibers)* <111> Si crystal Aramid fibers only <100> AFRE(|| fibers)* Glass -soda Glass fibers only GFRE(|| fibers)* Concrete GFRE* 20 10 8 6 4 2 1 0.8 0.6 0.4 0.2 CFRE* GFRE( fibers)* Graphite Polyester PET PS PC CFRE( fibers) * AFRE( fibers) * Composite data based on reinforced epoxy with 60 vol% of aligned carbon (CFRE), aramid (AFRE), or glass (GFRE) fibers. Epoxy only PP HDPE PTFE LDPE Wood( grain) Chapter 6 - 23 Stress–strain sample question (1) A copper specimen having a rectangular cross section of 15.2 mm x 19.1 mm is pulled in tension with 44,500 N force, producing only elastic deformation. Calculate the resulting strain. If the original specimen length is 100 mm, calculate the elongation. E = 110 GPa. Chapter 6 - 24 Stress–strain sample question (1) A copper specimen having a rectangular cross section of 15.2 mm x 19.1 mm is pulled in tension with 44,500 N force, producing only elastic deformation. Calculate the resulting strain. If the original specimen length is 100 mm, calculate the elongation. E = 110 GPa. ! = F? à ? = !DF ! = #D$ -----(2) " -----(1) Combining (1) and (2): # 44500 %$ ?= = = 1.39×10 $"F (15.2×10%$)×(19.1×10%$)×(110×10∆A ?= A" à ∆A = ?A" = 1.39×10%$×100 HH = 0.139 HH Chapter 6 - 25 What We Have Learnt So Far Tensile Stress Pa (Pascal) = N/m2 or MPa (M = 106) Shear Stress Young’s Modulus GPa (G = 109) Tensile Strain Shear Strain L Dimensionless Lateral Strain Hooke's Law: s=Ee # = E∆A K is determined by both materials and dimensions E is a function of materials Chapter 6 - 26 E vs Temperature Young’s modulus decreases monotonically, but not linearly, with increasing temperature. Chapter 6 - 27 Anelasticity • Time dependent elastic behaviour What are the primary differences among elastic, anelastic, and plastic deformation behaviours? DOI: 10.1021/nl401175t Elastic deformation is reversible. It occurs by interatomic bond stretching. Anelastic deformation is a special kind of elastic deformation. It takes time for a material to return to its original shape. Plastic deformation is permanent deformation. It occurs via atomic plane shearing. Applications in damping systems to reduce/eliminate noise for a broad range of industrial, electronic, and structural applications Chapter 6 - 28 Poisson's ratio, n • Poisson's ratio, n: eL eL n=- e e -n metals: n ~ 0.33 ceramics: n ~ 0.25 polymers: n ~ 0.40 Units: E: [GPa] or [psi] n: dimensionless Volumetric change ∆V ≈ (1 − 2M)? J When tensile (compressive) load is applied to a sample, the sample is stretched (compressed) that changes the dimension along the loading direction. At the same time, the lateral dimension of the sample also changes. The ratio of (lateral strain)/(strain along loading direction) is called Poisson’s ratio. –n > 0.50 density increases –n < 0.50 density decreases (voids form) Chapter 6 - 29 Stress–strain sample question (2) A cylindrical copper specimen having a diameter of 10 mm is pulled in tension. If diameter reduction is 0.0025 mm and the deformation is entirely elastic. Determine the applied load. E = 110 GPa. # != $" à # = !$" ----(1) ! = F? ----(2) ∆O −?. ?. = ----(4) N= ----(3) L O eL eL = " ? n%∆2 = ⁄-2!e %/o" w # = !$" = F? $" = F( 0 )$" = F( 0 )$" s=Ee metals: n ~ 0.33 ceramics: n ~ 0.25 polymers: n ~ 0.40 F %$)×3.14×(5×10%$)# −F∆O$" (110×10-)×(0.0025×10 s= = = %$ )×0.33 O"N (10×10A o = 6.53×10$* Anything wrong here? Number of significant figures Chapter 6 - 30 Relationship among moduli and Poisson ratio • Elastic Shear modulus, G: t=Gg t G g Same properties along all directions • Special relations for isotropic materials: E G= 2(1 + n) E K= 3(1 - 2n) Poisson ratio Chapter 6 - 31 Plastic (Permanent) Deformation Unloading line // elastic loading line • Simple tension test: Elastic+Plastic at larger stress engineering stress, s Elastic initially ep plastic strain The recovered part is larger than the initial elastic deform. Further elastic def. occurs during plastic def. permanent (plastic) after load is removed engineering strain, e Elastic strain Note: shearing occurs only on some specific planes. The shear planes are closely related to crystal structure. Chapter 6 - 32 Yield Strength, sy • Stress at which noticeable plastic deformation has occurred. when ep = 0.002 tensile stress, s sy Yield strength Draw a straight line starting from 0.2% strain point and parallel to the elastic stress–strain (SS) sy = yield strength line. The straight line intercepts with the SS curve. The stress value at Note: for 2 inch sample the intercept is the yield strength. e = 0.002 = Dz/z Proportional limit \ Dz = 0.004 in Behavior of some steels engineering strain, e ep = 0.002 0.2% Adapted from Fig. 6.10 (a), Callister 7e. Question: Does plastic deformation occur before the stress reaches the yield strength? Chapter 6 - 33 Yield Strength : Comparison Metals/ Alloys 2000 Graphite/ Ceramics/ Semicond Polymers Composites/ fibers !3 can be easily manipulated by changing the microstructures of materials 300 200 Al (6061) ag Steel (1020) hr Ti (pure) a Ta (pure) Cu (71500) hr 100 70 60 50 40 Al (6061) a 30 20 10 Tin (pure) ¨ dry PC Nylon 6,6 PET PVC humid PP HDPE LDPE in ceramic matrix and epoxy matrix composites, since in tension, fracture usually occurs before yield. 700 600 500 400 Ti (5Al-2.5Sn) a W (pure) Cu (71500) cw Mo (pure) Steel (4140) a Steel (1020) cd Hard to measure, 1000 Hard to measure , since in tension, fracture usually occurs before yield. Yield strength, sy (MPa) Steel (4140) qt Room temperature values Based on data in Table B.4, Callister & Rethwisch 8e. a = annealed hr = hot rolled ag = aged cd = cold drawn cw = cold worked qt = quenched & tempered Al alloy with σy > 1 GPa DOI: 10.1038/ncomms1062 Chapter 6 - 34 Tensile Strength, TS • Maximum stress on engineering stress–strain curve. TS F = fracture strength sy engineering stress A key point: “on engineering stress–strain curve” Typical response of a metal strain engineering strain Neck – acts as stress concentrator A question: how will the S–S curve be affected if we use a thicker specimen? • Metals: occurs when noticeable necking starts. • Polymers: occurs when polymer backbone chains are aligned and about to break. Chapter 6 - 35 Mechanical properties from stress-strain plot • • • • Young’s modulus Yield strength at a strain offset of 0.002 (0.2%) Tensile strength, maximum load Change in length (strain) under a specific stress Chapter 6 - 36 Tensile Strength : Comparison Metals/ Alloys Tensile strength, TS (MPa) 5000 3000 2000 1000 300 200 100 40 30 20 Graphite/ Ceramics/ Semicond Polymers Composites/ fibers C fibers Aramid fib E-glass fib Steel (4140) qt Diamond W (pure) Ti (5Al-2.5Sn)aa Steel (4140)cw Si nitride Cu (71500) Cu (71500) hr Al oxide Steel (1020) ag Al (6061) a Ti (pure) Ta (pure) Al (6061) a Si crystal <100> Glass-soda Concrete Graphite AFRE(|| fiber) GFRE(|| fiber) CFRE(|| fiber) We will learn the strengthening mechanisms later. Room Temp. values Nylon 6,6 PC PET PVC PP HDPE wood(|| fiber) GFRE( fiber) CFRE( fiber) AFRE( fiber) LDPE 10 wood ( 1 Let’s compare: a vs ag, pure vs alloying, hr vs cw fiber) a = annealed hr = hot rolled ag = aged cd = cold drawn cw = cold worked qt = quenched & tempered AFRE, GFRE, & CFRE = aramid, glass, & carbon fiber-reinforced epoxy composites, with 60 vol% fibers. Chapter 6 - 37 Ductility • Plastic tensile strain at failure: Engineering tensile stress, s Lf - Lo x 100 %EL = Lo Key points: • Plastic • Tensile smaller %EL (brittle) larger %EL (ductile) Lo Ao Af Lf X Engineering tensile strain, e • Another ductility measure: (used less frequently) Ao - Af %RA = x 100 Ao Chapter 6 - 38 Toughness • Energy to break a unit volume of material • Approximate by the area under the stress-strain curve. small toughness (ceramics) Engineering tensile large toughness (metals) stress, s very small toughness (unreinforced polymers) Engineering tensile strain, e Brittle fracture: elastic energy Ductile fracture: elastic + plastic energy Chapter 6 - 39 Resilience, Ur • Ability of a material to store energy for elastic deformation – Modulus of resilience – the strain energy per unit volume for stress up to the point of yielding Modulus of resilience = Ur = ò ey 0 sde If we assume a linear stress-strain curve, this simplifies to 1 Ur @ sy e y =(sy)2/2E 2 Chapter 6 - 40 Concept check • (a) Which will experience the greatest percent reduction in area? (largest deformation) • (b) Which is the strongest? (largest strengths) • (c) Which is the stiffest? (largest E) Chapter 6 - 41 Mechanical properties from s-e plot • • • • • • • • Young’s modulus Yield strength at a strain offset of 0.002 (0.2%) Tensile strength, maximum load Change in length under a specific stress Ductility Elastic strain Toughness Modulus of resilience Chapter 6 - 42 True Stress & Strain Note: The instantaneous dimensions of a sample change when the sample is stretched sT = s(1 + e ) • True tensile stress sT = F Ai ? eT = ln(1 + e ) ∆A5 A5 • True tensile strain ?4 = Q A = ln(A ) ? 5 5 " Valid before necking & assuming same volume, i.e. A0l0 = Aili M’ < M Why? For tensile deformation, A5 > A". ∆6 ∆6 Therefore, ∑ 6 # < 6 # ! (how do we know this is tensile deformation?) Chapter 6 - 43 A578 − A5 ∆A5 ?4 = Q =Q A5 A5 5 5 (by making delta(li) infinitesimal) = 6# 26 ∫6 6 ! After necking, deformation is no longer uniform. True strain varies from one place to another. The calculated value then becomes meanless = ln(6#D6! ) Assuming constant volume and no necking # !4 = $5 $ 5 A5 = $ " A" $ " A" à $5 = A5 Valid only before necking. What if necking has occurred? # # A5 A5 − A" + A" !4 = = =! = !(? + 1) A" $ " A" A" $" A5 (1) (2) "! (3) "" !! !" Chapter 6 - 44 Work Hardening & Elastic Strain Recovery Work hardening is an increase in sy due to plastic deformation Releasing load recovers the elastic strain. The unloading curve is therefore a straight line with a slope the same that of original linear line. When reloading, yielding occurs at the last unloading stress, i.e., the yield point increases from !!! to !!" . The phenomenon is called work hardening ab < cd, implying that elastic deformation continues after yielding. a b c d Later we will learn that plastic deformation occurs via dislocation motion. Work hardening simply means dislocation motion becomes more difficult. Work hardening is a very important method to strengthen materials Chapter 6 - 45 Work Hardening • An increase in sy due to plastic deformation. s large hardening sy 1 sy small hardening 0 Work hardening capability affects significantly the ductility of materials e • Curve fit to the stress-strain response: ( ) sT = K eT “true” stress (F/A) n strain hardening exponent: n = 0.15 (some steels) to n = 0.5 (some coppers) “true” strain: ln(L/Lo) Chapter 6 - 46 Work Hardening Capability, Necking and Ductility TS engineering stress sy Typical response of a metal strain engineering strain Macroscopically uniform plastic deformation is not “uniform” at the microscale. Deformation occurs F = fracture on individual atomic planes. This strength leads to local work hardening and stops the local deformation. The Neck – acts subsequent deformation then as stress occurs elsewhere. However, if the concentrator material loses its hardening capability, the deformation will continue because of higher local stress (smaller cross-sectional area caused by necking) and fracture will finally occur. You will have better understanding of this issue later. Chapter 6 47 Concept check . A schematic tensile stress-strain curve of a metallic sample is shown below. The elastic strain at point A is: 1) 2) 3) 4) OB OC CD OD The plastic strain at point A is: 1) 2) 3) 4) OC OD BC OB Chapter 6 - 48 Problem 6.35 Prove that true strain can also be expressed as eT = ln(A0 /Ai) Original definition: eT = ln(! i ! o ) Assuming no volume change à Aili = A0l0 Therefore li/l0 = A0/Ai Put this to the original definition eT = ln(A0 /Ai) This expression is more valid during necking because Ai is taken as the area of the neck. Chapter 6 - 49 Concept check Make a schematic plot showing the tensile engineering stress–strain behavior for a typical metal alloy to the point of fracture. Now superimpose on this plot a schematic compressive engineering stress-strain curve for the same alloy. Explain any differences between the two curves. Hint: pay attention to the evolution of cross-sectional area during deformation Reasons: • The true cross-sectional area in compression is larger than the original one. • There is no necking in compression. Therefore, the engineering stress keeps increasing. • Larger strain in compression because of no necking. Chapter 6 - 50 # # !" = != $# $! Tension F Compression F $! !! !# Chapter 6 - 51 Hardness • Resistance to permanently indenting the surface. • Large hardness means: --resistance to plastic deformation or cracking in compression. --better wear properties. e.g., 10 mm sphere apply known force D most plastics brasses Al alloys measure size of indent after removing load Smaller indents mean larger hardness. d easy to machine steels file hard cutting tools nitrided steels diamond increasing hardness Chapter 6 - 52 Hardness Hardness tests more frequently than other mechanical properties because: •Simple & inexpensive •Nondestructive – only small indentation •Can be approximately converted to other properties (e.g., tensile strength) •High spatial resolution (especially for nanoindentation), making the connection between local microstructure and mechanical properties possible. Chapter 6 - 53 Hardness: Measurement • Rockwell – Each scale runs to 130 but only useful in range 20-100. – Minor load 10 kg – Major load 60 (A), 100 (B) & 150 (C) kg • A = diamond, B = 1/16 in. ball, C = diamond Hardness specification includes: 1. hardness number 2. scale symbol ex: 80 HRB à 80 Rockwell hardness on the B scale Chapter 6 - 54 Hardness: Measurement Chapter 6 - 55 Comparison of different hardness scales •Hardness is not a well-defined property •Comprehensive conversion scheme not available •Conversion data depend on materials •Most reliable data exist for steels Artificial materials harder than natural diamond: • Nanotwinned diamond. DOI: 10.1038/nature13381 • Amorphous carbon. DOI: 10.1093/nsr/nwab140 Fig 6.18 Chapter 6 - 56 Hardness-Tensile Strength relationship HB = Brinell Hardness For most steels: TS (psia) = 500 x HB TS (MPa) = 3.45 x HB Chapter 6 - 57 Variability in Material Properties • Elastic modulus is material property • Critical properties depend largely on sample flaws (defects, etc.). Large sample to sample variability. • Statistics n – Mean – Standard Deviation S xn x= n 2ù én S(x i - x ) ú ê s= ê n -1 ú ë û 1 2 where n is the number of data points Chapter 6 - 58 Scatter •Test method •Inhomogeneity •Slight structural difference •Operator bias •… in experimental data Typical strength-ductility trade-off Curves with the same color come from specimens made from the same material Chapter 6 - 59 Design/Safety Factors Uncertainties: • Uncertain stress level for in-service applications • Variability in materials properties • Imperfections introduced during manufacture • Sustained damage during service Need to introduce a design safety factor so that the applied stress is reduced Design Stress Y; !2 = *′!9 *′ > 1 is a design factor, !9 is calculated stress level Safe stress (work stress) Y< !3 !: = * N is a factor of safety, !3 is the yield strength Chapter 6 - 60 Summary • Stress and strain: These are size-independent measures of load and displacement, respectively. • Elastic behavior: This reversible behavior often shows a linear relation between stress and strain. To minimize deformation, select a material with a large elastic modulus (E or G). • Plastic behavior: This permanent deformation behavior occurs when the tensile (or compressive) uniaxial stress reaches sy. • Toughness: The energy needed to break a unit volume of material. • Ductility: The plastic strain at failure. Chapter 6 - 61 Concepts And Equations To Be Fully Understood Engineer stress (6.1), engineering strain (6.2), shear stress (6.3), Hooke’s law (6.5), Young’s modulus, elastic and plastic deformation, anelasticity, yield strength, tensile strength, ductility (6.11 & 6.12), resilience, modulus of resilience (6.13 & 6.14), toughness, true stress (6.15), true strain (6.16), hardness, variability of materials properties (6.21 & 6.22), and design safety factors (6.23 & 6.24). Chapter 6 - 62