SCH4U 2015 Date: Unit 2 Energy Changes and Rates of Reaction Review Study smarter! Not necessarily longer! Remember reviewing/studying for the test does NOT mean doing the homework/questions for the first time. Pick and choose questions that YOU need more practice/review with. All the questions in the review sections are labeled with the corresponding section. Use the multiple choice to test your understanding, build up your confidence, and spend more time practice questions you are having difficult with. Homework: Multiple Choice Practice Pg. 404 #1-16, Pg. 406 #1-12 Full Solutions Pg. 408 # 46, 50, 53, 55, 79, 80, 87, 88 You must know how to use and rearrange the following equations: Calorimetry: q = mcDT and qreaction = -qcalorimeter Heat of formation: DH = å nDH0f Products -å nDH0fReactants Molar enthalpy change DH = nDHr Bond dissociation: DH = å nDReactants -å nDProducts m n Rate law equation: rate = k éëAùû éëBùû m n Rate law expression: rateµéëAùû éëBùû Chapter 5 Thermochemistry Review Homework: Multiple Choice Practice Pg. 337 #1-8, Pg. 338 #1-8 Full Solutions Pg. 338 # 34, 36, 37, 41, 46, 52, 53, 56, 59 2.1 Energy Changes Physical / Chemical / Nuclear change Thermochemistry Energy Potential / Kinetic energy Thermal energy Heat Temperature Chemical system / Surroundings Open / closed / isolated systems Exothermic / Endothermic Fusion / Fission Law of conservation of energy 2.4 Hess’ Law Path / State function Heat of summation 2.2 Calorimetry and Enthalpy Specific heat capacity Calorimetry Calorimeter Enthalpy Enthalpy change (H) Molar enthalpy change (Hr) Potential energy diagrams 2.5 Standard Enthalpy of Formation Standard enthalpy of formation (H0f) Standard state Combustion 2.3 Bond Energies Bond dissociation energy (D) Average bond energies Multiple bonds Bond type Bond number 2.6 Present and Future Energy Sources Coal slurry Syngas efficiency Chapter 6 Chemical Kinetics Review Homework: Multiple Choice/True and False Practice Pg. 395 #1-10, Pg. 396 #1-9 Full Solutions Pg. 50, 52, 62, 63, 68, 71 2.7 Reaction Rates Chemical kinetics Reaction rate Average reaction rate Instantaneous reaction rate Nature of the reactants Catalyst Heterogeneous catalyst Homogeneous catalyst Surface area 2.8 Collision Theory Collision theory Kinetic molecular theory Orientation (geometry) Activation energy (EA) Activated complex Maxwell-Boltzmann distribution Ineffective / effective collision Average kinetic energy 2.9 Rate Law Rate law expression Rate law equation Order of reaction Total order of reaction Initial rate Rate constant (k) 2.10 Reaction Mechanisms Elementary step Reaction mechanisms Overall EA Rate-determining step (RDS) Reaction intermediate Molecularity Uni / Bi / Ter - molecularity Concentration