Introduction to Materials Science & Engineering Course Objective... Introduce fundamental concepts in Materials Science & Engineering You will learn about: • material structures • how structure dictates properties • how processing can change structure This course will help you to: • use materials properly • realize new design opportunities with materials Chapter 1 - 1 OFFICE HOUR Professor: Doo-Man Chun Professor’s room: Building 2, Room 421 Office hour: for 1 hour after every class** **Contact professor for special arrangements Activities: • Discuss homework, quizzes, exams • Discuss lectures, book • Pick up missed handouts Chapter 1 - 2 1 COURSE MATERIALS (with text) Required text: • Fundamentals of Materials Science and Engineering, W.D. Callister, Jr. and D.G. Rethwisch, 5th edition, John Wiley and Sons, Inc. (2016). Optional Material: • Materials Science and Engineering (9th edition), William D. Callister, Jr., John Wiley & Sons, Inc., 2014 • Engineering Materials 1 : An Introduction to properties, applications and design (4th edition), Michael F. Ashby, Elsevier Ltd, 2012 Chapter 1 - 3 WEBSITES Course Website: http://ulms.ulsan.ac.kr • Syllabus • Lecture notes • Grades Chapter 1 - 4 2 GRADING Attendance 20% Including report and quiz Midterm 40% Material covered: Ch. 1~5, 7~9 Final 40% Material covered: Ch.10~11, 13~16 Chapter 1 - 5 TENTATIVE READING SCHEDULE Week 1 : Introduction Week 2 : atomic structure and interatomic bonding Week 3 : Structures of metals Week 4 : Imperfections in solids Week 5 : Mechanical properties and measurement methods Week 6 : Deformation and strengthening mechanisms Week 7 : Failure Week 8 : Mid-term exam Week 9 : Phase diagrams Week 10-11 : Phase transformations Week 12-13 : Synthesis, fabrication, and processing of materials Week 14 : Types and applications of materials (ferrous alloys, nonferrous alloys) Week 15 : Types and applications of materials (ceramic materials, polymers, composites), Corrosion Week 16 : Final exam Chapter 1 - 6 3 Chapter 1 - Introduction • What is materials science? • Why should we know about it? • Materials drive our society – – – – Stone Age Bronze Age Iron Age Now? • Silicon Age? • Polymer Age? Chapter 1 - 7 Material Science • Materials science is an interdisciplinary field applying the properties of matter to various areas of science and engineering. This scientific field investigates the relationship between the structure of materials at atomic or molecular scales and their macroscopic properties. It incorporates elements of applied physics and chemistry. Reference - http://en.wikipedia.org/wiki/Materials_science Chapter 1 - 8 4 Materials Science & Engineering Chapter 1 - 9 Forging (단조) Chapter 1 - 5 Structure, Processing, & Properties • Properties depend on structure ex: hardness(경도) vs structure of steel (d) Hardness (BHN) 600 500 400 (a) (b) 4 mm 300 200 30 mm (c) 30 mm 100 0.01 0.1 30 mm Data obtained from Figs. 11.31(a) and 11.33 with 4 wt% C composition, and from Fig. 14.8 and associated discussion, Callister & Rethwisch 4e. Micrographs adapted from (a) Fig. 11.19; (b) Fig. 10.34;(c) Fig. 11.34; and (d) Fig. 11.22, Callister & Rethwisch 4e. 1 10 100 1000 Cooling Rate (ºC/s) • Processing can change structure ex: structure vs cooling rate of steel Chapter 1 - 11 Importance of Materials • Material Selection - Carbonated Beverage (탄산음료) Container – Be strong and capable of surviving a drop from a height of several feet – Provide a barrier to the passage of carbon dioxide – Be nontoxic, unreactive with the beverage – Retain the optical clarity (Transparency) – Be capable of being produced in different colors – Be inexpensive Chapter 1 - 12 6 Example Metal (Al) Ceramic (Glass) Polymer (PET) Chapter 1 - History of Materials Chapter 1 Source - M. Ashby, “Materials Selection in Mechanical Design”, Oxford, Butterworth-Heinemann, 2005 7 Types of Materials • Metals: Metallic bonding – Strong, ductile – High thermal & electrical conductivity – Opaque, reflective. • Polymers/plastics: Covalent bonding à sharing of e’s – Soft, ductile, low strength, low density – Thermal & electrical insulators – Optically translucent or transparent. • Ceramics: ionic bonding (refractory) – compounds of metallic & non-metallic elements (oxides, carbides, nitrides, sulfides) – Brittle, glassy, elastic – Non-conducting (insulators) Chapter 1 - 15 Types of Materials Chapter 1 Source – W. Callister et al., “Materials Science and Engineering – An Introduction”, John Wiley & Sons, Inc., 2010 8 Physical properties Chapter 1 Source – W. Callister et al., “Materials Science and Engineering – An Introduction”, John Wiley & Sons, Inc., 2010 Mechanical properties Chapter 1 Source – W. Callister et al., “Materials Science and Engineering – An Introduction”, John Wiley & Sons, Inc., 2010 9 Mechanical properties Chapter 1 Source – W. Callister et al., “Materials Science and Engineering – An Introduction”, John Wiley & Sons, Inc., 2010 Mechanical properties Chapter 1 Source – W. Callister et al., “Materials Science and Engineering – An Introduction”, John Wiley & Sons, Inc., 2010 10 ELECTRICAL • Electrical Resistivity of Copper: 6 Adapted from Fig. 12.8, Callister & Rethwisch 4e. (Fig. 12.8 adapted from: J.O. Linde, Ann Physik 5, 219 (1932); and C.A. Wert and R.M. Thomson, Physics of Solids, 2nd edition, McGraw-Hill Company, New York, 1970.) (10-8 Ohm-m) Resistivity, r 5 4 3 2 1 0 -200 -100 0 T (°C) • Adding “impurity” atoms to Cu increases resistivity. • Deforming Cu increases resistivity. Chapter 1 - 21 THERMAL -- Silica fiber insulation offers low heat conduction. Adapted from chapteropening photograph, Chapter 17, Callister & Rethwisch 3e. (Courtesy of Lockheed Missiles and Space Company, Inc.) 100 mm • Thermal Conductivity of Copper: -- It decreases when you add zinc! Thermal Conductivity (W/m-K) • Space Shuttle Tiles: Adapted from Fig. 19.4W, Callister 6e. (Courtesy of Lockheed Aerospace Ceramics Systems, Sunnyvale, CA) (Note: "W" denotes fig. is on CD-ROM.) 400 300 200 100 0 0 10 20 30 40 Composition (wt% Zinc) Adapted from Fig. 17.4, Callister & Rethwisch 4e. (Fig. 17.4 is adapted from Metals Handbook: Properties and Selection: Nonferrous alloys and Pure Metals, Vol. 2, 9th ed., H. Baker, (Managing Editor), American Society for Metals, 1979, p. 315.) Chapter 1 - 22 11 MAGNETIC • Magnetic Storage: • Magnetic Permeability vs. Composition: -- Adding 3 atomic % Si makes Fe a better recording medium! Magnetization -- Recording medium is magnetized by recording head. Fe+3%Si Fe Magnetic Field Adapted from C.R. Barrett, W.D. Nix, and A.S. Tetelman, The Principles of Engineering Materials, Fig. 1-7(a), p. 9, 1973. Electronically reproduced by permission of Pearson Education, Inc., Upper Saddle River, New Jersey. Fig. 18.23, Callister & Rethwisch 4e. Chapter 1 - 23 OPTICAL • Transmittance: -- Aluminum oxide may be transparent, translucent, or opaque depending on the material’s structure (i.e., single crystal vs. polycrystal, and degree of porosity). single crystal polycrystal: no porosity polycrystal: some porosity Adapted from Fig. 1.2, Callister & Rethwisch 4e. (Specimen preparation, P.A. Lessing; photo by S. Tanner.) Chapter 1 - 24 12 DETERIORATIVE • Stress & Saltwater... • Heat treatment: slows -- causes cracks! crack speed in salt water! Adapted from Fig. 16.21, Callister & Rethwisch 4e. (from Marine Corrosion, Causes, and Prevention, John Wiley and Sons, Inc., 1975.) crack speed (m/s) 10 -8 “as-is” “held at 160ºC for 1 hr before testing” 10 -10 Alloy 7178 tested in saturated aqueous NaCl solution at 23ºC increasing load Adapted from Fig. 11.20(b), R.W. Hertzberg, "Deformation and Fracture Mechanics of Engineering Materials" (4th ed.), p. 505, John Wiley and Sons, 1996. (Original source: Markus O. Speidel, Brown Boveri Co.) Chapter 1 - 25 Materials Selection Process 1. Pick Application Determine required Properties Properties: mechanical, electrical, thermal, magnetic, optical, deteriorative. 2. Properties Identify candidate Material(s) Material: structure, composition. 3. Material Identify required Processing Processing: changes structure and overall shape ex: casting, sintering, vapor deposition, doping forming, joining, annealing. Chapter 1 - 26 13 Material information • Automation Creation (www.matweb.com) • Korean material DB (www.matbank.org) • National Institute for Material Science (NIMS, mits.nims.go.jp) • Granta Design (www.grantadesign.com) Chapter 1 - SUMMARY Course Goals: • Use the right material for the job. • Understand the relation between properties, structure, and processing. • Recognize new design opportunities offered by materials selection. Chapter 1 - 28 14