MENG 201: Materials Science Course Objective... Introduce fundamental concepts in Materials Science and Engineering You will learn about: • material structure • how structure dictates properties • how processing can change structure This course will help you to: • use materials properly • realize new design opportunities with materials 1 Historical perspective • Civilization strongly linked with materials • Stone age, ceramics age, bronze age, iron age, nuclear age, information age • The earliest humans had access to only a very limited number of materials e.g: wood, clay, skin, stone • Then man learned that material’s properties can be altered by heat treatment and by addition of other substances (alloying) 2 Why we study material science 1) Important to understand capabilities and limitations of materials. The following are just a few examples of catastrophic failure caused by a lack of fundamental understanding of materials, their properties, and failure modes: • Tacoma Narrows Bridge Collapse (1940) “poor design” Liberty ships (WWII) BCC Fe (metal) 3 Challenger (1986) failure of an O-ring seal (polymer) Hyatt Regency (KC) walkway collapse (1981) 4 Why we study material science (2) An understanding of Materials Science helps us to design better components, parts, devices, etc. 1) how do you make something stronger or lighter? 2) how do elements come together to form alloys? 3) why do some materials have vastly different properties than others? (3) It is interesting and helps to make you a more informed person 5 Chapter 1: Introduction • Materials Science consists of four components: • By manipulating these components, materials can be designed for human need 6 Structure Performance Properties Processing 7 Materials Science and Engineering • Material Science: involves investigating the relationship between the structure and properties of the material. • Material Engineering: Is designing or engineering the structure of a material to produce a predetermined set of properties (based on the structure-property relationship) • Structure: is the arrangement of the material’s internal components, which can be divided several levels 8 Structure and Properties • STRUCTURE: Many levels (or dimensions) of structure exists in engineering materials Sub-atomic: Electrons within an individual atom and interaction with the nuclei Atomic: Organization of atoms or molecules relative to one another (Cubic, hexagonal …etc) Phase level (microscopic): Certain arrangement (or crystal structure) of atoms prevail throughout certain area of the material which makes it homogenous in that structure arrangement and properties, it is called phase. Macroscopic: (observed by naked eye) 9 Structure and Properties 10 Level of Structures Materials are... engineered structures...not blackboxes! Structure...has many dimensions... Structural feature atomic bonding missing/extra atoms crystals (ordered atoms) second phase particles crystal texturing Dimension (m) < 10 -10 10-10 10 -8 -10-1 10 -8 -10-4 > 10 -6 11 • PROPERTIES: – Properties determine response of material to external stimuli which is able to provoke different responses – Properties are independent of Materials shape and size PROPERTY STIMULUS or INPUT EXAMPLES/TYPES Mechanical Load or Force Elastic Modulus Strength Electrical Electric Field Electrical Conductivity Dielectric Constant Thermal Heat Heat Capacity Thermal Conductivity Magnetic Magnetic Field Magnetization Optical Electromagnetic or Light Radiation Index of Reflection Deteriorative Chemical/Electrochemical Reactions Index of Refraction Corrosion Rate 12 13 14 15 Structure, Processing, & Properties • Properties depend on structure ex: hardness vs structure of steel Hardness (BHN) (d) 600 500 400 (c) (a) (b) 4m 300 200 30m 30m 100 0.01 0.1 30m 1 10 100 1000 Cooling Rate (C/s) • Processing can change structure ex: structure vs cooling rate of steel 16 ELECTRICAL • Electrical Resistivity of Copper: Adapted from Fig. 18.8, Callister 6e. (Fig. 18.8 adapted from: J.O. Linde, Ann Physik 5, 219 (1932); and C.A. Wert and R.M. Thomson, Physics of Solids, 2nd edition, McGraw-Hill Company, New York, 1970.) • Adding “impurity” atoms to Cu increases resistivity. • Deforming Cu increases resistivity. 17 THERMAL • Space Shuttle Tiles: --Silica fiber insulation offers low heat conduction. • Thermal Conductivity of Copper: Fig. 19.0, Callister 6e. (Courtesy of Lockheed Missiles and Space Company, Inc.) --It decreases when you add zinc! Adapted from Fig. 19.4W, Callister 6e. (Courtesy of Lockheed Aerospace Ceramics Systems, Sunnyvale, CA) (Note: "W" denotes fig. is on CD-ROM.) Adapted from Fig. 19.4, Callister 6e. (Fig. 19.4 is adapted from Metals Handbook: Properties and Selection: Nonferrous alloys and Pure Metals, Vol. 2, 9th ed., H. Baker, (Managing Editor), American Society for Metals, 1979, p. 315.) 18 MAGNETIC • Magnetization vs. Composition: --Adding 3 atomic % Si makes Fe a better recording medium! Adapted from C.R. Barrett, W.D. Nix, and A.S. Tetelman, The Principles of Engineering Materials, Fig. 1-7(a), p. 9, 1973. Electronically reproduced by permission of Pearson Education, Inc., Upper Saddle River, New Jersey. 19 OPTICAL • Transmittance: --Aluminum oxide may be transparent, translucent, or opaque depending on the material structure. single crystal polycrystal: low porosity polycrystal: high porosity Adapted from Fig. 1.2, Callister 6e. (Specimen preparation, P.A. Lessing; photo by J. Telford.) 20 DETERIORATIVE • Stress & Saltwater... --causes cracks! Adapted from Fig. 17.0, Callister 6e. (Fig. 17.0 is from Marine Corrosion, Causes, and Prevention, John Wiley and Sons, Inc., 1975.) • Heat treatment: slows crack speed in salt water! Adapted from Fig. 11.20(b), R.W. Hertzberg, "Deformation and Fracture Mechanics of Engineering Materials" (4th ed.), p. 505, John Wiley and Sons, 1996. (Original source: Markus O. Speidel, Brown Boveri Co.) --material: 4m 7150-T651 Al "alloy" (Zn,Cu,Mg,Zr) Adapted from Fig. 11.24, Callister 6e. (Fig. 11.24 provided courtesy of G.H. Narayanan and A.G. Miller, Boeing Commercial Airplane Company.) 21 The Materials Selection Process 1. Pick Application Determine required Properties Properties: mechanical, electrical, thermal, magnetic, optical, deteriorative. 2. Properties Identify candidate Material(s) Material: structure, composition. 3. Material Identify required Processing Processing: changes structure and overall shape ex: casting, sintering, forming, joining, annealing. 22 Next chapter Classification of Materials • There are FOUR basic classes of materials; based on (a) Chemical make-up and (b) Atomic Structure; these are: 1. 2. 3. 4. Metals and Alloys Ceramics and Glasses Polymers Composites 23