Birla Public School, Doha- Qatar Science- Chemistry. Class IX: Ch- 2- Is Matter around us pure- Notes Introduction Matter Anything which has mass and occupies space is called matter. It may be solid, liquid or gas. Substance: - It is a kind of matter that cannot be separated into other kinds of matter by any physical methods. Eg: Salt, Sugar, Water soil, alloy etc. The properties of substance can be divided as physical property and chemical property. The properties that can be observed and specified are physical properties. Eg: colour, hardness, rigidity, density, melting point, boiling point, etc. The chemical property is a characteristic of a substance that may be observed when it participates in a chemical reaction. The substance can undergo a physical change and a chemical change. Difference between Physical and Chemical changes: https://youtu.be/evcnb7KDUak, https://youtu.be/LZH8DzQTsQY S. No. Physical Change chemical change (Chemical reaction) 1. Here only the physical properties like state, shape or size of a substance change. It brings about a change in the chemical properties of a substance. 2. There is no change in chemical composition of a substance. There is always a change in chemical composition of a substance. 3. No new substance is formed. A new substance is always formed. 4. It is temporary and hence reversible. It is permanent and hence irreversible. 5. Eg. Melting of ice, dissolving sugar in water Eg. Burning of paper, rusting of iron. Types of substance: It is of two types: 1. Pure Substance 2. Impure substance 1. Pure Substance: It may be defined as a material which contains only one kind of particles. Pure substances are again of two types: (a) Elements (b) Compounds (a) Elements: * Robert Boyle used the term element for the first time. * Lavoisier gave definition of element as follows:An element is a basic form of matter that cannot be broken down into simpler substances by chemical reactions. Pure substances which are made up of only one kind of particles are known as elements. They cannot be split up into two or more simpler substances by any of the usual chemical methods. For example: Iron, gold, silver, carbon, oxygen, nitrogen and sodium etc. Elements are further grouped into the following three categories: (i) Metals:- The elements that are generally solid, lustrous, sonorous, malleable, ductile, strong and hard, denser, conductors of heat and electricity etc are called metals. (The definition is based on physical properties). Example: Iron, copper, gold, sodium, silver, mercury, etc. (ii) Non – metals:- The elements that are generally opposite to metals in the physical properties are called non- metals. Example: Carbon, oxygen, sulphur, nitrogen, oxygen, hydrogen, etc. (iii) Metalloids:- The elements that have intermediate properties between those of metals and non- metals are called metalloids. Eg: Boron, silicon, germanium, Arsenic, Tellurium etc. Physical Properties of Metals: These are lustrous (shine). They conduct heat and electricity. All metals are malleable and ductile. They are sonorous. All metals are hard except sodium and potassium. All metals are solids at room temperature except mercury which is a liquid. Physical Properties of Non-metals: These are dull in appearance. They are poor conductors of heat and electricity except diamond which is a good conductor of heat and graphite which is a good conductor of electricity. They are neither malleable nor ductile. They are generally soft except diamond which is the hardest natural substance known. They may be solids, liquids or gases at room temperature. Metalloids: The elements that have properties intermediate between those of metals and non-metals, are called metalloids. (b) Compounds: It is a form of matter formed by combining two or more elements in a definite ratio by mass and they are formed by chemical combination. It can be decomposed into its constituent elements by suitable chemical methods For example: Water (H2O), oxygen (O2), Nitrogen dioxide (NO2), etc. Illustrate that water and carbon dioxide are compounds. Water: Water is a compound formed by combining Hydrogen and Oxygen chemically and it has a chemical formula, H2O. In a water particle, 2 atoms of Hydrogen and 1 atom of Oxygen are present. When we consider the mass ratio of Hydrogen and Oxygen in one particle of water, it comes as follows: Mass ratio of Hydrogen and Oxygen in water = 2 X mass of 1 atom of H : 1 X mass of 1 atom of O = (2 X 1u) : (1 X 16u) = 2 : 16 = 1: 8 Whatever be the source of water this mass ratio remains a constant. So, Water is a compound. Carbon dioxide: Carbon dioxide is a compound formed by combining Carbon and Oxygen chemically and it has a chemical formula, CO2. In a carbon dioxide particle, 1atom of Carbon and 2 atoms of Oxygen are present. When we consider the mass ratio of Carbon and Oxygen in one particle of carbon dioxide, it comes as follows: Mass ratio of Carbon and Oxygen in carbon dioxide = 1 X mass of 1 atom of C : 2 X mass of 1 atom of O = (1 X 12u) : (2 X 16u) = 12 : 32 = 3 : 8 Whatever be the source of carbon dioxide this mass ratio remains a constant. So, Carbon dioxide is a compound. 2. Impure Substance: It may be defined as a material which contains more than one kind of pure substances. It is also named as mixture. Mixtures: A mixture is a material which contains two or more different kinds of particles (atoms or molecules) which do not react chemically but are physically mixed together in any proportion. https://youtu.be/t0iHbY9sjDc https://youtu.be/XEAiLm2zuvc Activity 2.10- text book page number 25 (Refer Text book) - Activity to distinguish mixture and compound. https://youtu.be/C2RqAE0wbqk Activity:- Group I- Mix and Iron and Sulphur Powders manually Group II- Mixture of Iron and Sulphur Powder is taken in a china dish and heated strongly till red hot and cool it. Both the groups conducted the following tests on the substances with them. Activity Observation done by Observation done by group-I group-II Appearance- colour and Non- uniform, yellow Uniform, only black colour texture colour of Sulphur and is observed. greyish colour of Iron are observed Test with magnet Iron powder got attracted Nothing got attracted to magnet Dissolution in carbon Sulphur dissolved, but not Nothing dissolved disulphide iron Heating with dilute A colourless, odourless A colourless gas with hydrochloric acid or gas is evolved. On testing rotten egg’s smell is sulphuric acid the gas with a burning evolved. On passing the match stick, the stick gas through blue coloured extinguished with a ‘pop’ copper sulphate solution, sound and the gas is the colour of the solution combustible. So, it is turned into black. So, the hydrogen gas. gas is hydrogen sulphide. Conclusion: The differences in the observations of the same activities showed that group I obtained a mixture and group II obtained a compound. The compound they obtained is iron sulphide. Difference between mixtures and compounds: S. No. Mixtures Compounds 1. Various elements just mix together to form a mixture and no new compound is formed. Elements react to form new compounds. 2. A mixture has a variable composition. The compound has a fixed composition. 3. A mixture shows the properties of its constituents. Properties of a compound are totally different from those of its constituents. 4. They do not have a fixed melting point, boiling point, etc. They have a fixed melting point, boiling point, etc. 5. The constituents can be separated easily by physical methods The constituents can be separated only by chemical processes. Types of mixture It is of two types: (a) Homogeneous mixture S. No. (b) Heterogeneous mixture Homogeneous mixture Heterogeneous mixture 1. All the components of the mixture are uniformly mixed. All the components of the mixture are not thoroughly mixed. 2. No separation boundaries are visible. Separation boundaries are visible. 3. It consists of a single phase. It consists of two or more phases. 4. Example: Sugar dissolved in water, Salt solution, Vinegar, Air. Example: sand and common salt mixture, Soil 5. It is also called solution It can be suspension and colloid. Try the following questions: Q1. Is air around us a compound or a mixture? Q2. Water is a compound. Justify. Q3. Differentiate between homogeneous and heterogeneous mixtures. Q4. Give reasons for the following: (a) Copper is used for making electric wires. electrode in a dry cell. (b) Graphite is used for making Q5. List any four characteristics by which compounds can be differentiated from mixtures. Homogeneous mixture- Solution A solution is a homogeneous mixture of two or more substances. For example: Lemon water, sugar solution, soda water, etc. Components of Solution: (1) Solvent: The component of the solution that dissolves the other component in it and is usually present in larger amount, such component of solution is called the solvent. For example: Water, alcohol etc. (2) Solute: The component of the solution that is dissolved in the solvent and is usually present in lesser quantity, such component is called the solute. For example: Salt, sugar, iodine etc. Properties of solutions: (i) It is a homogeneous mixture. (ii) Particle size in a solution is less than 1 nm in diameter. (iii) Particles of a solution cannot be seen even with a microscope. (iv) A true solution does not scatter the light; ie, it does not show Tyndall effect. The scattering of light by the particles of a medium is called Tyndall effect. (v) Solution is stable. (vi) The solute particles cannot be separated from the mixture by the process of filtration. Types of solutions: a) Based on physical state of components (solute & solvent) Various types of solutions are: (i) Solid in a solid solution: Alloys. (ii) Solid in a liquid solution: Sugar solution, salt solution. (iii) Liquid sin a liquid solution: Lemon water, vinegar (acetic acid in water) (iv) Gas in a gas solution: Air. (v) Gas in a liquid solution: Soda water. Alloys: They are a homogeneous mixture of two or metals or a metal and a non- metal which cannot be separated into their components by physical methods. But still, an alloy is considered to be a mixture because it shows the properties of its components and can have variable composition. Eg: Brass is an alloy of 30% Zinc and 70% Copper. Bronze is an alloy of 88% copper and 12% tin. b) Based on the type of solvent:- i) Aqueous solution:- When water is used as the solvent in a solution, it is called aqueous solution. Because of its easy availability, physical state of liquid at room temperature, ease of handling and ability to dissolve many substances, water is regarded as ‘Universal Solvent’. ii) Non- Aqueous solution:- When solvents other than water are used as solvent to prepare a solution, it is called non- aqueous solution. Eg for non-aqueous solvents: Carbon tetra chloride, alcohol, carbon disulphide, chloroform etc. c) Based on amount of component- solute The term concentration is used to refer the amount of solute present in a solution. If the solution has less amount of solute it is said to be of low concentration or dilute solution. If a solution has more amount of solute, it is said to be of high concentration or concentrated solution. Concentration of a solution: It is defined as the amount of solute present in a given quantity of a solution. OR It is defined as the mass of the solute in grams present in 100 grams of the solution. Concentration of a solution can be calculated by percentage method which expresses the concentration or percentage of solute in the solution. The percentage of solute can be mass by mass percentage, mass by volume percentage or volume by volume percentage. If a solution is of a solid in liquid type, we take mass by mass or mass by volume percentage. If the solution is of liquid in liquid, we consider volume by volume percentage for concentration. We can use the following formula for this; 𝑪𝒐𝒏𝒄𝒆𝒏𝒕𝒓𝒂𝒕𝒊𝒐𝒏 𝒐𝒇 𝒔𝒐𝒍𝒖𝒕𝒊𝒐𝒏 = 𝑨𝒎𝒐𝒖𝒏𝒕 𝒐𝒇 𝒔𝒐𝒍𝒖𝒕𝒆 𝑨𝒎𝒐𝒖𝒏𝒕 𝒐𝒇 𝒔𝒐𝒍𝒖𝒕𝒊𝒐𝒏 In percentage method: Mathematical expression for concentration of solution: i) 𝑴𝒂𝒔𝒔 𝒃𝒚 𝒎𝒂𝒔𝒔 % 𝒐𝒇 𝒂 𝒔𝒐𝒍𝒖𝒕𝒊𝒐𝒏 = 𝑴𝒂𝒔𝒔 𝒐𝒇 𝒔𝒐𝒍𝒖𝒕𝒆 𝑴𝒂𝒔𝒔 𝒐𝒇 𝒔𝒐𝒍𝒖𝒕𝒊𝒐𝒏 ii) 𝑴𝒂𝒔𝒔 𝒃𝒚 𝒗𝒐𝒍𝒖𝒎𝒆 % 𝒐𝒇 𝒂 𝒔𝒐𝒍𝒖𝒕𝒊𝒐𝒏 = × 𝟏𝟎𝟎 𝑴𝒂𝒔𝒔 𝒐𝒇 𝒔𝒐𝒍𝒖𝒕𝒆 𝑽𝒐𝒍𝒖𝒎𝒆 𝒐𝒇 𝒔𝒐𝒍𝒖𝒕𝒊𝒐𝒏 × 𝟏𝟎𝟎 In case of liquid solute in liquid solvent concentration can be expressed as: iii) 𝑽𝒐𝒍𝒖𝒎𝒆 𝒃𝒚 𝒗𝒐𝒍𝒖𝒎𝒆 % 𝒐𝒇 𝒂 𝒔𝒐𝒍𝒖𝒕𝒊𝒐𝒏 = 𝑽𝒐𝒍𝒖𝒎𝒆 𝒐𝒇 𝒔𝒐𝒍𝒖𝒕𝒆 𝑽𝒐𝒍𝒖𝒎𝒆 𝒐𝒇 𝒔𝒐𝒍𝒖𝒕𝒊𝒐𝒏 × 𝟏𝟎𝟎 Mass of solution = Mass of solute + mass of solvent (Numerical from text book and extra questions) d) Based on solubility of solute Solubility: The maximum amount of the solute which can be dissolved in 100 grams of a solvent at a particular temperature is known as its solubility in that particular solvent. Or The amount of the solute present in the saturated solution at a given temperature. Different solutes have different solubility in a solvent. Eg: The solubility of Potassium nitrate in 100 grams of water at 200C is 32 g whereas the solubility of Sodium chloride in 100 g of water at 200C is 36g. Conditions or factors affecting solubility: (i) Temperature: Solubility of solids in liquids increases with the increase in temperature, whereas solubility of gases in liquids decreases on increasing the temperature. (ii) Pressure: Solubility of gases in liquids increases on increasing the pressure, whereas the solubility of solids in liquids remains unaffected by the change in pressure. Based on solubility of solute, Solution can be divided as Saturated Solution: A solution in which no more quantity of solute can be dissolved at a particular temperature, is called saturated solution. Unsaturated Solution: A solution in which more quantity of solute can be dissolved without raising its temperature, is called unsaturated solution. Super saturated solution:- A solution which contains solute more than the saturation level is called super saturated solution. Try the following questions: Q1. What would it mean by saying a 15% of alcohol solution? Q2. Calculate the concentration of a solution containing 2.5g of salt dissolved in 50g of water. Q3. Name the different types of solutions along with an example for each. Q4. Define (a) Solute (b) Solvent. Heterogeneous mixture- a) Colloid A heterogeneous mixture which appears to be uniform (homogeneous) due to the relative smaller size of the particles and it can scatter a beam of light is called a colloid. OR Solutions in which the size of particles lies in between those of true solutions and suspensions are called colloidal solutions or simply colloids. For example: Milk, smoke and starch solution etc. Properties: (i) It is a heterogeneous mixture. (ii) Particle size in a colloid is between 1 nm- 100nm in diameter. (iii) Particles of a colloid cannot be seen even with naked eye. (iv) A colloid can scatter the light; ie, it shows Tyndall effect. (v) Colloid is stable. (vi) The particles cannot be separated from the mixture by the process of filtration. Components of a colloid: i) Dispersed phase- The solute like component or the dispersed particles in a colloid is called dispersed phase. ii) Dispersing medium- the solvent like component or the component in which the dispersed phase is suspended is called dispersing medium Tyndall Effect: The scattering of light by the colloidal particles is known as Tyndall effect. It can be observed when: A fine beam of light enters a room through a small hole. Sunlight passes through the canopy of a dense forest. Note: The colloidal particles are not the true solutions as their particles are big enough to show the Tyndall effect, whereas the particles of a true solution do no show Tyndall effect. https://youtu.be/W4KAbbVNMxc Types of colloid- Based on the physical state of the components of a colloid. Dispersed Dispersing Type of colloid Example phase medium Liquid Gas Aerosol Fog, cloud, mist Solid Gas Aerosol Smoke, automobile exhaust Gas Liquid Foam Shaving cream Liquid Liquid Emulsion Milk, face cream Solid Liquid Sol Milk of magnesia, mud Gas Solid Foam Foam, rubber, sponge, pumice Liquid Solid Gel Jelly, cheese, butter Solid Solid Solid Sol Coloured gemstone, milky glass Heterogeneous mixture- b) Suspension A heterogeneous mixture in which the solute particles do not dissolve but remain suspended throughout the bulk of the medium and are visible to naked eye is called a suspension. Eg: muddy water, chalk powder in water, flour in water, etc. OR The heterogeneous mixture in which solids are dispersed in a liquid are called suspensions. Properties of a Suspension: (i) It is a heterogeneous mixture. (ii) The particles of a suspension can be seen by naked eyes. (iii) The particles of a suspension scatter a beam of light passing through it and make its path visible. (iv) A suspension is unstable. (v) Constituents of a suspension can be separated by the process of filtration. Differences between solution, colloid and suspension Property Solution Colloid Suspension Homogeneity (uniformity) Homogeneous Appears to be homogeneous, but Heterogeneous Heterogeneous Particle size Lesser than 1 nm 1 nm- 100 nm Greater than 100 nm Stability (settlement of particles) Stable since particles do not settle down Stable Unstable since particles can settle down Filterability Cannot filter Cannot filter Can be filter Tyndall effect Do not show Shows Shows before the settlement of particles. Transparency Transparent Translucent Opaque Try the following questions: Q1. How will you distinguish a colloid from a solution? Q2. What is effect of temperature on the solubility of solids in liquids? Q3. Sea water can be classified both as a homogeneous as well as a heterogeneous mixture. Comment? Q4. Distinguish between the following as physical changes and chemical changes? (a) Burning of a magnesium wire (b) Rusting of iron (c) Condensation of steam (d) Glowing of an electric bulb The separation of components of a Mixture: Need of separation of components of a mixture: To remove the unwanted substances To obtain the useful substances To get the pure substances To get individual components and study and use them. Some of the important methods used to separate different mixtures are explained below: (1) Filtration: - The process of separating an insoluble solid from a liquid by using a filter or filter paper is called filtration. The principle of this method is solubility. Application: It is applied in supply of drinking water in cities, towns etc. The main steps in this are:- a) sedimentation, b) Loading (The process of adding certain substances like alum to settle the minute suspended solid particles in water), c) Filtration, d) Chlorination (adding chlorine to destroy germs), e) Supply. Refer Fig. 2.13 in txt bk pg# 24. (2) Evaporation: Evaporation is a process which is used to separate a solid substance dissolved in liquid. It is based on the fact that liquids vaporize easily whereas solids do not. So we can separate a volatile (vapourising solvent) component from its non- volatile (solute) component by evaporation. The principle of this method is volatility. Activity 2.4- Refer Txt Bk Pg # 19 (How can we get coloured component (dye) from ink?) Ink is a mixture of a dye in water. Applications of Evaporation: Obtaining salt from sea water, Separating dye from ink (3) Centrifugation: It is a method of separating the suspended particles of a substance from a liquid in which the mixture is rotated at high speed in a centrifuge. The principle of this method is density. It is a better method for separating colloidal mixtures. This method is useful in case the suspended particles in a liquid are too small to be retained by filter paper. When the mixture is rotated at high speed, the suspended particles get collected, becoming heavy and settling down and the lighter particles stay at the top. Applications of Centrifugation: Used in dairies to separate cream from milk. Used in washing machines to squeeze out water from wet clothes. (3) Separating funnel Description of Separating Funnel:- It is a special type of funnel which has a stop cock or tap on its stem to control the flow of liquid from the funnel. It has a lid at the top. It is used to separate two immiscible liquids using the principle of density. It is used to separate a mixture of two immiscible liquids, like oil and water. Refer Activity 2.6- Txt bk Pg# 20 https://www.youtube.com/watch?v=7oqLUIHpqOc Principle of separating funnel: When a mixture of two immiscible liquids is kept in a separating funnel, the liquids separate out in layers depending on their densities. Applications of Separating funnel: To separate mixture of oil and water. In the extraction of iron from its ore where the lighter slag (molten waste material) is removed from the top by to leave the molten iron at the bottom of the blast furnace. (4) Sublimation: This method is used to separate those components from a mixture which can sublime on heating. So, It is a method of separating a sublimable component from a nonsublimable component from their mixture. For example: Ammonium chloride, camphor, naphthalene etc, can be separated from their mixture by sublimation. Principle of the method is sublimation. https://www.youtube.com/watch?v=XqRx3tydnxc Applications of Sublimation: Iron can be separated from a mixture of iron fillings and camphor (volatile). Common salt can be separated from a mixture of salt and ammonium chloride (volatile). (5) Chromatography This method is used to separate two or more dissolved solids which are present in a solution in very small quantities. https://www.youtube.com/watch?v=1LdYvgy94fg https://www.youtube.com/watch?v=PvHvx7k7UPU Activity 2.7- Refer Txt Bk Pg # 21 Principle of Chromatography: This method of separation is based on the fact that though two substances are dissolved in the same solvent but their solubilities can be different. The component which is more soluble in, rises faster and gets separated from the mixture. Applications of Chromatography: To separate colours in a dye by paper chromatography. To separate pigments from natural colours To separate drugs from blood, also in forensic science to detect and identify the amount of substance like poison in the body. (6) Distillation: This method is used to separate a mixture solid in a liquid. It is the process of heating the liquid to form vapour, and then cooling the vapour to get back liquid. It is used for the separation of components of a mixture containing two miscible liquids that boil without decomposition and have sufficient difference in their boiling points- more than 25K. Activity 2.8- Refer Txt Bk Pg # 21 Description of the apparatus:- The apparatus used for distillation consists of a distillation flask and a condenser. Distillation flask is a round bottomed flask having a side tube. The condenser is a long narrow glass tube surrounded by a wider glass tube called water jacket. The water jacket has inlet to circulate the cold water and an outlet to take out the hot water. During distillation, cold water is circulated in the water jacket of the condenser and condenses the hot vapour passing through the inner tube of the condenser. So the water becomes warm and can be collected out through the outlet. https://www.youtube.com/watch?v=V5ep0-ojPGw Principle of Distillation: The volatile liquid evaporates on heating which can be recovered by cooling its vapours by the process of condensation. Applications of Distillation: It is used to remove salt from sea water to obtain drinking water. It is used to prepare distilled water. It is used to obtain pure solvent from a solution. (7) Fractional distillation https://www.youtube.com/watch?v=vRHk4bOivAk It is the process of separating two or more miscible liquids by distillation, the distillate being collected in fractions due to boiling at different temperatures. Fractionating Column: The apparatus used in this process is similar to that for simple distillation except a fractionating column which is fitted in between the distillation flask and the condenser. A simple fractionating column is a tube packed with glass beads. The beads provide surface for the vapours to cool and condense repeatedly. Principle of Fractional Distillation: In a mixture of two or more miscible liquids, the separation of various liquids depends on their boiling points. The liquid having lower boiling point boils first and can be obtained first from the fractionating column than the liquid having higher boiling point. Applications of Fractional Distillation: It is used to separate a mixture of miscible liquids like alcohol-water mixture. It is used to separate crude oil ‘petroleum’ into useful fractions like kerosene, petrol, diesel, etc. It is used to separate different gases of the air by taking the liquid air. How can we obtain different gases from air? Refer the flow chart- Fig. 2.11- Txt bk Pg# 22, Fig. 2.12- Txt bk Pg# 23. (8) Crystallisation: Crystallisation is a process used to separates a pure solid in the form of its crystals from a solution. The process involves cooling a hot, concentrated solution of a substance to obtain crystals. How can we obtain pure copper sulphate from impure sample? Refer Activity 2.8- Refer Txt Bk Pg # 21 Advantages of Crystallisation or merits of Crystallisation over evaporation This method can be used to separate pure crystals from the impure samples, but in evaporation, these impurities may remain along with the solid. This method can be used even for the separation of solids that decompose or get charred on heating during evaporation Applications of Crystallisation: Purification of common salt obtained from sea water. To obtain crystals of alum (phitkari) from impure samples. To obtain pure copper sulphate from an impure sample. Separation of Mixture and Separation Techniques used Types of Mixture Separation Technique Principle Insoluble solid in a solvent Filtration Particle size Fine particles of solid present in the solvent Centrifugation Density of components Solution of solid in liquid to get solid Evaporation Volatility of components Solution of solid in liquid to get pure solid Crystallisation Volatility of components Solution of solid in liquid to get solid as well as pure liquid Distillation Difference in boiling point Miscible liquids having difference in boiling point more than 250C Simple distillation Difference in boiling point Miscible liquids having difference in boiling point less than 250C Fractional distillation Difference in boiling point Immiscible liquids Using a separating funnel Difference in density of the liquids Mixture of two solids in which one can sublime Sublimation Sublimation Mixture of substances in solution having different solubility Chromatography Difference in solubility Mixture of magnetic and non- magnetic substances Magnetic separation Magnetic property Try the following questions: Q1. Name the method of separation that you will apply for separation of the following mixtures? (a) Ammonium chloride from a powdered mixture of sodium chloride and Ammonium chloride. (b) Butter from cream. (c) Oil from water. Q2. Which of the following will show Tyndall effect: (a) Salt solution (b) Milk (c) Starch Q3. How will you separate a mixture of iron filings, chalk powder and common salt? Q4. Discuss the process of purification of impure copper sulphate by crystallization. Q5. Explain how nitrogen, oxygen and argon gases are separated from air? Prepared by: Sheri Symon