Year 12 Chemistry Activity 9.2.A.1 – Comparing free radical and catalytic addition polymerisation Module 9.2 – Production of Materials Topic 9.2.A – Synthetic Polymers Name Question 1 - Free Radical Polymerisation Label the diagram by identifying the things or processes inside the red boxes. Date Question 2 – Catalytic Polymerisation Put numbers in the boxes on the right to put each of the steps into the correct order. Step Order An ethene monomer adds to one of the alkyl groups in the aluminium trimethyl (Al(CH3)) complex Chain growth is terminated with an alkyl group Titanium tetrachloride (TiCl4) is mixed with aluminium trimethyl (Al(CH3)) Chain growth continues through the successive addition of ethene monomers without branching Titanium tetrachloride (TiCl4) and aluminium trimethyl (Al(CH3)) form an insoluble complex known as a Ziegler-Natta catalyst Page 2