Trends in the Periodic Table The Periodic Table • Dmitri Mendeleev (1834-1907) determined the properties of every known element at the time – – – – – Atomic Mass Density Colour Melting Point Boiling Point The Periodic Table: Periods • Mendeleev arranged the known elements in order of increasing atomic mass • He found that the properties of the elements repeated at definite, or PERIODIC, intervals – Na has similar properties to Li and K The Modern Periodic Table: Atomic Number • In 1915, the Periodic Table was reorganized based on the element’s atomic structure • Each element has an ATOMIC NUMBER, which is unique to each element • The atomic number begins with H (1) in the upper-left hand corner, and moves from Left to Right The Modern Periodic Table: Groups • Vertical columns in the periodic table • Chemical families • Elements in a group share very similar properties • Numbered from 1-18 • Elements in the same GROUP 12 have the same number of atomic SHELLS where VALENCE ELECTRONS (outer electrons) are held 343210 Elements are grouped based on specific properties: Nonmetals Metalloids Metals Metals Non-Metals Metalloids The Modern Periodic Table: Characteristics of Groups • The number of valence electrons in the elements is same in a group. • The atomic radii increase from top to bottom • Metallic Elements: – Metallic character and chemical reactivity increase from top to bottom • Non-Metallic Elements: – Metallic character and chemical reactivity decrease from top to bottom Elements are ordered in the periodic table according to reactivity and atomic number: Mg and Ca React with Hydrochloric Acid (Same Group) Na and K react with Water Na K F, Cl, I are gases F Mg Cl Ca I The Modern Periodic Table: Groups of Elements 1 18 2 13 3 4 5 6 7 8 9 10 11 12 14 15 16 17 Group 1: Alkali Metals • Very reactive metals that do not occur freely in nature (Cs, Fr the most reactive) • Valence Electrons: One; ready to lose that one electron to bond with other elements. • Properties: Malleable, ductile, good conductors of heat and electricity, softer than most metals • Can explode if exposed to water. Group 2: Alkaline Earth Metals • Very reactive • Valence Electrons: 2; can bond easily with other elements • Not found free in nature Groups 3-12: Transition Metals • Properties: Ductile, malleable, conduct electricity and heat • Valence Electrons: present in more than one shell • Iron, cobalt, and nickel are the only elements known to produce a magnetic field. Groups 13-15: Other Metals • Properties: Ductile and malleable, solid, high density, opaque • Valence Electrons: present in their outer shell. Metalloids • Along the stair-step line that distinguishes metals from non-metals • Al is an exception as it is classified as an “Other Metal” • Properties: Similar to metals and non-metals • Si and Ge are semi-conductors (can carry an electrical charge under special conditions; used in calculators and computers) Group 14-16: Non-Metals • Properties: Do not conduct electricity or heat very well, brittle, not malleable or ductile, no luster, do not reflect light • Exist as gases (N, O) or solids (C, S) Group 17: Halogens • “Salt-former”, compounds containing halogens are called “salts” • Valence Electrons: 7; will bond easily with Alkali Metals. • Exist as solids (I, At), liquid (Br), and gas (F, Cl) Group 18: Noble Gases • Valence Electrons: 0; prevents gases from readily forming compounds • Very stable because they have the maximum electrons in their outer shell Rare Earth Elements • Lanthanide and Actinide series (Group 3 and Period 6-7) • One element of the lanthanide series and most of the elements in the actinide series are transuranium (synthetic or man-made) Mendeleev’s Periodic Law