Environmental Health and Safety Engineering Environmental Components SAN JOSE STATE UNIVERSITY COLLEGE OF ENGINEERING CHEMICAL & MATERIALS ENGINEERING DEPARTMENT Copyright Michael B. Jennings, 2002 ENVIRONMENTAL ENGINEERING IS CONCERNED WITH POLLUTION • MINIMIZING GENERATION OF POLLUTION – Innovative technologies – Increasing process efficiency • MANAGING HAZARDOUS MATERIALS – Prevention of Releases – Recycling and Reuse – Safe disposition • REMEDIATION AND RECLAMATION OF CONTAMINATED SITES What is pollution? • Pollution is a component or a condition that is detrimental to the environment – Examples of components are chemicals or trash from a process HC HCCO CO NO NOx x Example of Pollution Condition • Noise from a process Hey Heyman, man,can’t can’tyou youuse use something quiet like something quiet likeaa Leaf LeafBlower? Blower? What is the Source of Pollution? • Pollution can be the result of • • natural or man-made (Anthropogenic) processes Natural processes, such as volcanic eruptions, add components that can be absorbed into the environment over time The Global Warming discussion is based on the balance between naturally occurring and anthropogenic sources of Greenhouse gases: (CO2), Methane, N2O, Ozone, and CFC’s. H2S, H2S,COS, COS,SO2, SO2, PARTICULATE, PARTICULATE, IT’S THE CHEESE! ANTHROPOGENIC POLLUTION • Man-made pollutants – may accumulate above natural background levels in the environment – and also may react with other components in unexpected ways • Examples include contamination of water supplies with MTBE or pesticides. CLASS PROJECT #1 (5 Min.) • List at least 4 potential pollutants sources related to • • using automobiles for transportation. (1 Minute) Categorize these according to their severity (1 Minute 1 is most severe). List ways to eliminate or minimize each of the pollutants (3 Minutes) No. Pollutant Source Severity Eliminate or Minimize POSSIBLE ANSWERS TO PROJECT #1 No. Pollutant Source Severity Eliminate or Minimize 1 Air Pollution (NOx, HC’s) from combustion 1 Eliminate gas engine or operate only at optimum conditions 2 Stream pollution from oil, grease, tire rubber, and brake linings 3 Leak inspections, biodegradable lubricants, change tire formulation, nonasbestos brakes 3 Noise pollution from engines 4 Better muffler design 4 Hazardous waste from improper battery and oil disposal 2 Collection systems to easily recycle oil and batteries. Deposits? 5 Solid waste from used tires 5 Tire recycle to recover raw materials. OTHER POSSIBLE ANSWERS TO PROJECT #1 No. Pollutant Source Severity Eliminate or Minimize 1 Pollution from oil refining to produce gasoline 1 Eliminate gas engine and reduce plant pollution sources 2 Pollution from steel manufacturing processes 2 Reduce energy required for steel production or use other materials 3 Pollution from manufacturing of tires and other components 3 Use other materials or reduce pollution from processes 4 Pollution from road construction and maintenance 4 Usable public transit, better planning, better road materials 5 Pollution from auto assembly operations 5 Alternate materials and assembly methods IMPOSSIBLE ANSWERS TO PROJECT #1 No. Pollutant Source Severity Eliminate or Minimize 1 Noise pollution from cars playing ______ music. 1 Disconnect or steal their battery! 2 Noise pollution from any music played through a sub-bass woofer. 1 Disconnect or steal their battery! 3 Noise pollution from horns! 1 Use hand signals! 4 Visual pollution from cars that are newer, larger, faster, etc., than mine 1 Drive in the fog, so you don’t have to see them! 5 Visual pollution from bumper stickers. 1 Tailgate while you are reading them! How does the EH&S Engineer fit into the pollution equation? • Prevention and Reduction of Pollutants – Identify the actual and potential sources – DESIGN the system to minimize quantities Recycling and Reuse • DESIGN systems to reuse materials in the original process or in some other process – Recycling unused raw materials increases yields while reducing pollution – Recycling products as raw materials reduces the energy required to produce the raw material. Treatment • DESIGN systems to treat materials and recover reactants that have not been consumed and/or valuable byproducts A RECYCLE C&D SEP’N & TREATMENT 1 C PRODUCT A SEP’N & TREATMENT 3 A, B, C & D B SEP’N REACTOR B, C & D B RECYCLE D PRODUCT DISPOSAL • The last-resort option is to DESIGN a safe means for disposal – Long term disposal systems are very expensive – There are few locations to accept waste materials REMEDIATION • Many non-hazardous wastes sites, if properly designed, can be recycled into productive operations. – Must avoid Groundwater contamination. – Include Soil layers to seal and provide biota to break down wastes Photos from http://www.zerowasteamerica.org /Pictures.htm EH&S Engineers Design for the Environment (DFE) • DESIGN for ENVIRONMENT considers the environmental impact of a material from cradle to grave. Raw Materials Production Manufacturing Product Distribution Final Disposition or Recycle Product Use What are the basic concepts involved in Design for Environment? • Compare and improve the performance and • • human health and environmental risks and costs of existing and alternative products, processes, and practices, OVER THE LIFE CYCLE OF THE PRODUCT. Projects for integrating cleaner, cheaper, and smarter solutions into everyday business practices MAKE GOOD ECONOMIC SENSE. If you don’t make a mess in the first place, you won’t have to clean it up! LIFE CYCLE EXAMPLE – PAPER OR PLASTIC BAGS? – AN EH&S ENGINEERING ANALYSIS • Considering the SOURCES OF RAW MATERIALS: – Oil – Not renewable, easy to extract – Trees – Renewable, costly to harvest – Recycle – both are recycled, but not at the same fraction of original material Life Cycle Example - Manufacturing and Distribution • Both products are manufactured by automated processing • Both materials are distributed in bulk Life Cycle Example USE AND RECYCLE • Both materials are used and recycled in a similar • manner The fraction of each material that is recycled may vary Life Cycle Example – EVENTUAL DISPOSITION • Both materials can be used as fuels and reduce energy costs • Both materials can end up in land-fills – Organic landfill materials can produce natural gas – Paper decomposes more rapidly than plastic Life Cycle Analysis EMISSIONS FROM PROCESSING • Total particulate, hydrocarbon, and greenhouse gases are greater for the paper sacks than the plastic sacks. Life Cycle Analysis – SUMMARY • The energy • • requirements are less for plastics The emissions are less with plastics Plastics use a nonrenewable resource for a raw material Results of DFE • This is a money-making process for most companies. • DFE has been formalized using ISO 14000 to promulgate environmental management standards EH&S ENGINEERS and REMEDIATION & RECLAMATION PROCESSES • Recover contaminated sites for productive purposes • Most sites result from improper disposal of materials PHOTOS FROM http://www.dep.state.pa.us/dep/deputate/minres/bamr/bark_camp/barkhomepage.htm TYPES OF POLLUTION FROM LANDFILLS & DUMP SITES – Ground Water Pollution. – Air Pollution. – Noise Pollution – Odor Pollution – Blowing Trash – and Visual Pollution. Photo from http://www.zerowasteamerica.org/Pictures.htm GROUNDWATER REMEDIATION • Project for Steam Injection in Visalia PHOTOS FROM: http://www.llnl.go v/str/Newmark.ht ml CLASS PROJECT #2 DESIGN FOR RECYCLING OPERATIONS (20 Min) • Over the last few centuries, we have produced some interesting deposits of materials that are referred to as: • MUNICIPAL SOLID WASTE (MSW) HOW WAS THIS MATERIAL GENERATED? • On any weekend you can see it is being • bought and sold. Signs show: Sometimes folks just forget the B. SATURDAY & SUNDAY 8:00 UNTIL 5:00 BIG GARBAGE GARAGE SALE PROJECT DESCRIPTION • We assume some process has been developed to collect MSW (Municipal Solid Waste) – The process does not separate the materials for recycling – The landfill is almost full, so some way to reduce volume is necessary. PROJECT OBJECTIVES • DESIGN a process to separate and recycle components in MSW – 1. As it is collected, assuming recycling separates metals, plastics, glasses, newspapers, mixed papers and cardboard – 2. As it is collected with no recycling – 3. After it is mined from existing landfills. WHAT IS THE RAW MATERIAL? DEFINITIONS OF MSW 1 • Paper - Newsprint, high grade, magazines boxboard, mixed recyclable paper and nonrecyclable mixed paper • Plastic - Polyethylene terephthalate (PET) and high density polyethylene (HDPE • Metals – Aluminum, ferrous and nonferrous • Glass - Clear, brown, and green glass DEFINITIONS OF MSW 2 • Organic Materials - Yard waste, wood pallets, treated • • • • wood, and untreated wood. Problem Materials - Sources of trace metals such as lead, cadmium, and mercury; such as batteries, televisions, computers and electric and electronic products Household Hazardous Waste/Hazardous Waste (HHW/HW) - Latex and oil paints, automotive used oil/filters and anti-freeze. Other Waste - Textiles, carpet, rubber, and sharp and infectious wastes, construction and demolition debris excluding wood) and household bulky items (furniture and mattresses) More Details are located at: http://www.epa.gov/epaoswer/nonhw/muncpl/factbook/internet/toc.htm HOW ARE RECOVERED MSW MATERIALS UTILIZED 1? • PAPER – Recycled goes to paper mills. http://recycledproducts.plasticsresource.com/ Reused can be combusted. http://www.epa.gov/epaoswer/nonhw/muncpl/disposal.htm • PLASTIC - Recycled goes to into a wide range of products. http://www.resystems.com/paper.html Reused can be combusted or pyrolyzed into chemicals or fuels. http://www.apme.org/literature/htm/05.htm HOW ARE RECOVERED MSW MATERIALS UTILIZED 2? • METALS – Recycled goes to into a wide range of products based on remelting to base metals for reuse in new products. http://www.westinghouseplasma.com/gsteel.htm • GLASS - Recycled goes to smelters and is use to make new products. http://www.gpi.org/Handling.html Reused can be used as an aggregate in for ceramic materials and for sand blasting. http://www.crbt.org/glass.html HOW ARE RECOVERED MSW MATERIALS UTILIZED 3? • ORGANIC MATERIALS – Reused materials are • • composted for soil amendments or sometimes combusted as a fuel http://www.compostwashington.org/ PROBLEM MATERIALS – may be redirected to specialty recyclers for recovery of precious metals http://www.drms.dla.mil/pubaff/html/pmrp.html HHW/HW – Recycled materials can be processed into useable solvent or converted into fuels http://www.romic.com/ HOW ARE RECOVERED MSW MATERIALS UTILIZED 4? • Other Wastes – These are sent to specialty recyclers for processing and reuse. Some are used as combustion fuels. http://www.tranclo.com/hp31.asp http://www.happyharry.com/howwzer.htm QUESTIONS TO ADDRESS • SORTING - How can physical properties be used • to separate materials? Density, solubility (washing), screening, grinding, etc. IMPACT OF PROCESSING – What will be the results of the sorting process. – Can the material be recycled after sorting or are additional processing steps required? – Has the sorting process created any waste materials that need special processing for disposal? RECOMMENDED SEQUENCE FOR THE PROJECT • EACH TEAM MEMBER DEVELOP A DESIGN FOR ONE OR TWO CLASSES OF MATERIALS IN MSW – Examine techniques that work for each material – Determine which of these will work for more than one material – Develop the optimum sequence to process the MSW • COMBINE THE DESIGN INTO AN OVERALL PROCESS – Individual process steps – Utility requirements – Create a Flow Sheet for the Process, with a description of the operation – Write up a one page summary of the process design EH&S CONTACTS FOR MORE INFORMATION @ San Jose State University • M. B. JENNINGS – 408/924-3926 • M. A. McNEIL – 408/924-3873 • ART DIAZ – 408/924-3944 • WEB PAGE ADDRESS: • http://www.engr.sjsu.edu/ehs/