BATCH PROCESSED THERMOELECTRIC ENERGY HARVESTER CHARATERIZATION AND MODELING Jiale Su1, Ziyang Wang1, Vladimir Leonov2 and Ruud J.M.Vullers1 1 imec /Holst Centre, Eindhoven, the Netherlands 2 imec, Leuven, Belgium *Presenting Author: jiale.su@imec-nl.nl Abstract: A micromachined thermoelectric energy harvester for human body applications has been developed. This paper reports the device characterization and a corresponding model to validate the performance of the device. The open circuit voltage is measured in ambient and vacuum. The model, which is an equivalent circuit, is built up by transferring the measurement setup from thermal domain to electrical domain. We find a good agreement between the model and the measurement in vacuum. However, the model of ambient does not reflect the experimental data. We believe the reason to be air convection. Keywords: Thermoelectric energy harvester, MEMS, Stepper lithography, thermopile, TEG INTRODUCTION Temperature differences in/on artificial objects (machinery, buildings, transport, pipelines) and on the skin of animals and men can be used to power autonomous devices. For example, as the first wearable wireless sensors and medical devices (Electroencephalograph (EEG) system, an Electrocardiography System in a Shirt) fully powered by thermoelectric generators (TEG) on man have been demonstrated [1]-[3]. These thermal energy harvesters have been made by using off-the-shelf thermopiles. Hence they have ‘high’ fabrication cost because of the fabrication method for thermopiles. The fabrication cost of energy harvesters is a key factor for their acceptance by industry and for moving them into mass production. Reduction of the cost can be achieved by using micromachining technologies and fabricating thousands of devices, like IC chips, in one run. In [4], the development of micromachined thermoelectric harvesters was presented. A matched load is connected to these devices for characterization. We were able to obtain the voltage and power output on the matched load in air, delivering 1.2V and 0.35µW at a temperature difference of 30K. In this paper we report additional measurements, both in vacuum and in air, using a LabviewTM program: both voltage and temperature of the hot and cold plates are measured every 0.1sec automatically. We have also developed a model, in order to analyze the results. CHARATERIZATION Measurement setup Figure 1 shows a dedicated setup designed for reliable temperature measurement. A device is placed between two aluminum blocks, which are separated by plastic spacers. To have a much larger heat capacity than the device, the aluminum blocks are 3cm×3cm×2cm, which is around 1800 times larger than the devices. One of the blocks is heated by a hotplate, while the other block has large cooling fins and acts as a cooling plate. The device is glued to both plates with thermal paste, Thermal Joint Compound 120[5], which has a thermal conductivity of 0.735Wm-1K-1. The total thickness of the paste is about 100 µm. The device is electrically connected by wire bonding to a small plastic board with large soldered connecters which can be easily connected to a voltmeter for the open circuit voltage measurement or a load for further characterization. (a) (b) Figure 1 (a) Schematic of measurement setup and (b) Photo of measurement setup A program is made to read the open circuit voltage output and the voltage values of thermocouple I (T1) and thermocouple II (T2) by three multimeters. The program converts the thermocouple voltages to the temperature difference between T1 and T2. The open circuit voltage of two different devices as a function of temperature difference is measured in both ambient and vacuum (pressure of 1mbar) environment, as shown in Figure 2. All plots are linear. We find the voltage output per unit temperature difference is 256mVK-1in ambient and 374mVK-1 in vacuum. Ambient vs. Vacuum Voltage(V) 7 6 Ambient 5 Vacuum RAL,B T2 Repoxy,B Rsi,B A y = 0.3736x + 0.0093 RAIR,d-d’ ∆T Rspacer RTP RAIR,b-b’ 4 y = 0.2563x + 0.0884 3 T1 2 A’ Repoxy,T RAL,T 1 Rsi,T (a) 0 0 5 10 15 20 25 Repoxy,B RAL,B T2 Rsi,B A ∆T (K) Figure 2 open circuit voltage measurement in ambient and vacuum The thermopile behaves differently in ambient and vacuum. In order to analyze the effect, a model is built to simulate the open circuit voltage behavior. This is discussed in the next section. Modeling A model is made which describes the whole measurement setup in analogy to an electric circuit. The elements between T1 and T2 are transferred from the thermal domain to the electrical domain, where temperature difference, heat flow and thermal resistance correspond to voltage, current and electrical resistance, respectively. This is done for both ambient and vacuum. Starting from thermocouple II (T2), in ambient (see Figure 3(a)), the heat flow passes through part of the aluminum block, RAL,B. Then the heat flow divides into three flows, one through spacer, Rspacer, one through air between two Al blocks, RAIR,b-b’, and one through epoxy between bottom Al block and bottom chip, Repoxy,B, bottom Si chip, Rsi,B, device, RAA’, from A to A’, top Si chip, Rsi,T, and epoxy between top chip and top Al block, Repoxy,T. All the heat flows come together, pass part of top Al block and reach thermocouple I (T1). But in calculation, RAIR,b-b’ and Rspacer can be neglected. Because both thermal resistors, RAIR,b-b’ and Rspacer, are in parallel with a series of thermal resistors, which are Repoxy,B, Rsi,B, RAA’, Rsi,T and Repoxy,T, the temperature differences fall across RAIR,b-b’, Rspacer and the series of thermal resistors are the same. The model of the device is a combination of the thermopile and air, so a thermal resistance of the air between top and bottom die of device, RAIR,d-d’, and a thermal resistance of thermopile, RTP in parallel represents the device in thermal domain, shown between A and A’ in Figure 3(a). Moreover, in ambient, thermal resistance of air includes air conduction, air convection and radiation. In vacuum the effects of air conduction and air convection can be neglected. Rradiation,d-d’ ∆T Rspacer RTP Rradiation,b-b’ T1 A’ Repoxy,T RAL,T Rsi,T (b) Figure 3 Equivalent circuits of elements between T1 and T2 in (a) ambient and (b) vacuum Thus only the thermal resistance of radiation is taken account in the model (shown in Figure 3(b)). The thermal resistance of each element (except the thermopile) shown in Figure 3, is listed in Table 1. In thermal domain, all thermocouples are connected in parallel. Therefore the thermal resistance of the thermopile, RTP, can be calculated by dividing the thermal resistance of one thermocouple by the total number of the thermocouples. The thermal resistance of one thermocouple is simulated by using Finite Element Model (FEM) software, ‘MSC Marc’. A 10µm wide thermocouple with a 1.5µm wide air gap on the left and right side performs as a basic element of thermopile, shown in Figure 4(b). Table 1 Thermal resistance of each element fromT1 to T2 (except thermopile) Thermal Conductivity (Wm-1K-1) Length (m) Width (m) Area (m2) Thickness (m) Thermal Resistance (KW-1) RAL,B REpoxy,B RSi,B RSi,T REpoxy,T RAL,T 237 0.7 149 149 0.7 237 0.03 0.0025 0.002 0.005 0.005 0.03 0.03 0.003 0.003 0.003 0.003 0.03 9.0× 10-4 3.0× 10-3 7.5 ×10-6 5.0 ×10-5 7.5 ×10-6 7.5 ×10-4 1.5 ×10-5 6.8 ×10-4 1.5 ×10-5 5.0 ×10-5 9.0 ×10-4 3.0 ×10-3 0.01 9.52 0.67 0.30 4.76 0.01 22.15 22.14 22.12 22.11 22.09 22.08 22.06 22.05 22.03 22.01 (a) 22.00 (b) Figure 5 Temperature difference over one thermocouple by simulation (a) in ambient and (b)in vacuum DISCUSSION (b) Figure 4 Finite element model of thermocouple (a) cross view (b) side view A relative large difference between theory and measured data is observed in Figure 6(a), while in Figure 6(b), a good agreement is found between theory and measured data. Because the setup is unchanged, the presence of air is the only difference between the ambient and vacuum condition. We believe that the air convection plays a role here, an effect which needs further investigation in our devices. In vacuum, where air convection can be neglected, the model is more accurate. Simulated vs. Measured 8 22.10 22.09 Measured 6 y = 0.3272x - 0.0029 5 4 3 22.08 2 22.07 1 22.06 Simulated 7 Voltage (V) In the simulation, thermal conductivity of air is chosen for the measurement in ambient (0.026Wm1 -1 K ), while in the case of vacuum the conductivity is 2.6×10-5Wm-1K-1. Applying a heat flux of 1mWmm-2 from the bottom face, a temperature difference ∆T of 0.10K is falling over the thermocouple in ambient (see Figure 5(a)) and 0.15K in vacuum (see Figure 5(b)). The total area of one thermocouple is 5.44×10-4 mm2 ((L) 45µm × (W) 12µm). The heat flow, Q, is found to be 5.40×10-7W, by multiplying the heat flux and the area. The thermal resistance of the thermocouple is 1.85×105KW-1 in ambient and 2.78×105KW-1 in vacuum, which is calculated according to heat transfer equation, R= ∆T/Q. We thus find the thermal resistance of the thermopile to be 104KW-1 in ambient and 156KW-1 in vacuum. A MATLAB program is written to model the circuit in Figure 3, where the thermal resistance of each element (except the thermopile) is calculated in Table 1. The temperature results measured from T1 and T2 in both ambient and vacuum are imported in the MATLAB program to calculate the open circuit voltage. The data are plotted in Figure 6(a) and (b). y = 0.2563x + 0.0884 0 22.05 0 22.04 5 10 15 ∆T (K) 22.03 (a) 22.02 22.01 22.00 (a) 20 25 Furthermore, new poly-SiGe micromachined thermopiles are being fabricated. The whole fabrication process will be optimized in several aspects, such as, avoiding short circuit between adjacent thermocouples and decreasing specific contact resistance between Al and n-SiGe, which were discussed in [4]. The new devices will be characterized and compared with current devices. Simulated vs. Measured 7 measured y = 0.3863x + 4E-05 Voltage(V) 6 simulated 5 4 y = 0.3736x + 0.0093 3 2 REFERENCE: 1 0 0 5 10 15 20 ∆T(K) (b) Figure 6 Simulated data vs. measured data of the device in both (a) ambient and (b) vacuum CONCLUSION In this paper, a dedicated measurement setup is fabricated to characterize the device. A sophisticated model is derived by converting the measurement setup including the device from thermal domain to electrical domain. The device is measured using the same setup both in ambient and vacuum. The theoretical open circuit voltage is calculated according to the measured temperature differences through the model. The theoretical value agrees with the measured results in vacuum but not in ambient. We believe the reason to be the lack of proper description of air convection in our model in ambient. For future work, we will try to adjust our model in order to have a better agreement between the model and the measurements. [1] Leonov, V., Fiorini, P., Sedky, S., Torfs, T., and Van Hoof, C., “Thermoelectric MEMS Generators as a Power Supply for a Body Area Network,” Proc. 13th Int. Conf. on Solid-State Sensors, Actuators and Microsystems (Transducers’05), IEEE, 2005, pp. 291-294. [2] Van Bavel, M., Leonov, V., Yazicioglu, R. F., Torfs, T., Van Hoof, C., Posthuma, N., and Vullers, R. J. M., “Wearable Battery-Free Wireless 2-Channel EEG Systems Powered by Energy Scavengers,” Sensors& Transducers, 2008, Vol. 94, No. 7, pp. 103-115, http://www.sensorsportal.com/HTML/DIGEST/P_30 0.htm [3] Vladimir Leonov, Tom Torfs, Chris Van Hoof and Ruud J. M. Vullers, “Smart Wireless Sensors Integrated in Clothing: an Electrocardiography System in a Shirt Powered Using Human Body Heat”, Sensors & Transducers J., Vol. 107, Issue 8, August 2009, pp. 165-176, http://www. sensorsportal.com/HTML/DIGEST/P_485.htm [4] Jiale Su, M Goedbloed, Y Van Andel, M C De Nooijer, Rene Elfrink, Vladimir Leonov, Z Wang and Ruud Vullers, ‘Batch process micromachined thermoelectric energy harvester: fabrication and characterization’, Journal of Micromachining and Microengineering, Vol. 20 No. 10, 2010, doi: 10.1088/0960-1317/20/10/104005 [5] http://www.wakefield.com/PDF/accessories.pdf