International Geology Review, Vol. 49, 2007, p. 873–906. Copyright © 2007 by V. H. Winston & Son, Inc. All rights reserved. 40Ar/39Ar Ages from Coherent, High-Pressure Metamorphic Rocks of the Franciscan Complex, California: Revisiting the Timing of Metamorphism of the World’s Type Subduction Complex JOHN WAKABAYASHI1 Department of Earth and Environmental Sciences, California State University, 2576 E. San Ramon Ave., Fresno, California 93740 AND TREVOR A. DUMITRU Department of Geological and Environmental Sciences, Stanford University, Stanford, California 94305 Abstract In the Franciscan subduction complex of California, high-pressure metamorphic rocks have generally been divided into two groups, “high-grade blocks” and “coherent metamorphic rocks.” High-grade blocks, typically discrete blocks centimeters to tens of meters in diameter, exhibit coarse metamorphic minerals and relatively high metamorphic grade, including blueschist, eclogite, and amphibolite assemblages, and are typically found encased within mélange matrix of distinctly lower grade. Coherent metamorphic rocks are generally of epidote blueschist and lower grade and consist of large, more or less intact thrust sheets of metasedimentary and metavolcanic rocks. Considerable age dating work has been completed on the high-grade blocks, but dating the metamorphism of the coherent units has proven very difficult because of the very fine grain size of their metamorphic minerals, which has precluded the preparation of pure mineral separates for isotopic analysis. In this paper, we report new white mica and amphibole 40Ar/39Ar step heating ages from mineral separates from several coherent units. These new ages include: (1) white mica ages of 120.5 Ma from the South Fork Mountain Schist; (2) white mica ages of approximately 132 Ma from the Skaggs Springs schist; (3) a white mica age of approximately 154 Ma from the coherent schists of Ward Creek; and (4) white mica ages of 146.5 Ma (eclogite) and 134 Ma (epidote blueschist) from the Willow Spring slab, a newly recognized 2.1 by 1.2 km (map view) coherent metabasite slab in the Panoche Pass area comprising rocks ranging from lawsonite blueschist to eclogite. We also obtained hornblende ages of about 156 and 159 Ma, respectively, from high-grade amphibolite blocks from McLaren Park and the Hunters Point Shear Zone in San Francisco. A review of the new and previous ages indicates that the ages of the high-grade blocks and the coherent metamorphic rocks partially overlap, strongly suggesting they formed in the same subduction zone. Moreover, our field mapping near Panoche Pass has identified several fault-bounded sheets of coarse-grained, coherent metamorphic rocks similar to the Willow Spring slab that display mineralogy identical to that of many highgrade blocks. Unlike many of the world’s subduction-related metamorphic terranes, the Franciscan exhibits evidence for high-pressure metamorphism that spanned at least 80 m.y. in time, the product of subduction, accretion, and metamorphism of different packets of rock at different times. Although the Franciscan may be an exception among subduction complexes, attempts to define a single age of metamorphism in other high-pressure or ultrahigh-pressure terranes may need reconsideration. Introduction SINCE THE ADVENT of plate tectonic theory, many have regarded the Franciscan Complex of coastal 1Corresponding author; email: jwakabayashi@csufresno.edu 0020-6814/07/956/873-34 $25.00 California as the type subduction complex and as a benchmark locality for high-pressure/low-temperature (HP) metamorphic rocks, the metamorphic signature of the subduction process (e.g., Hamilton, 1969; Ernst, 1970). Although many geochronologic studies have been conducted on Franciscan rocks, 873 874 WAKABAYASHI AND DUMITRU significant questions remain regarding the timing of metamorphism of much of the Franciscan. These questions leave uncertain the relationship between tectonic events in the Franciscan and other parts of the arc-trench system, and affect the accuracy of forearc evolution and HP rock exhumation models derived from this well-known region. Within the Franciscan, only blueschist and higher-grade rocks contain newly formed metamorphic minerals that can potentially be used to date metamorphic recrystallization (e.g., Blake et al., 1988). Rocks of such grade make up more than onefourth of the exposed Franciscan (e.g., Blake et al. 1988; Terabayashi and Maruyama, 1998), but in almost all cases the metamorphic minerals are so fine grained that it is impossible to separate and prepare pure mineral concentrates for isotopic analysis. However, a very tiny fraction of Franciscan rocks do indeed have sufficiently coarse metamorphic minerals for analyses to be attempted (Fig. 1). The highest-grade metamorphic rocks are coarsegrained blueschists, eclogites, and amphibolites that occur almost entirely as exotic tectonic blocks encased within lower-grade shale- or serpentinitematrix mélanges, and are commonly referred to as “high-grade blocks.” Collectively, such high-grade blocks comprise <<1% of Franciscan metamorphic rocks (Coleman and Lanphere, 1971). The remainder of Franciscan metamorphic rocks consist of intact thrust sheets and mélange matrix, primarily of blueschist grade. Such rocks exhibit fine-grained metamorphic minerals and, excluding mélange matrix, are commonly referred to as “coherent” metamorphic rocks, to distinguish them from the high-grade blocks. Overall, various isotopic dating techniques (KAr, Rb/Sr, 40Ar/39Ar, U-Pb, Sm-Nd, and Lu-Hf) have yielded a range of model ages of metamorphic recrystallization from about 90 to about 170 Ma, with most of the older ages coming from the highgrade blocks. Unlike many HP and ultrahighpressure (UHP) terranes, where metamorphism is interpreted to have been of limited duration (e.g., Maruyama et al., 1996), metamorphic and detrital age data from the Franciscan indicate an extended duration of Franciscan HP metamorphism (e.g., Wakabayashi, 1992, 1999a). The geochronologic methods used on high-grade blocks have included K-Ar on actinolite, hornblende, and white mica (phengite) (Coleman and Lanphere, 1971; Suppe and Armstrong, 1972); UPb isochron (Mattinson, 1986); 40Ar/39Ar step heat- ing of hornblende, glaucophane, and white mica (Ross and Sharp, 1986, 1988); 40Ar/39Ar laser step heating of white mica (Wakabayashi and Deino, 1989); 40 Ar/ 39 Ar laser spot ages of white mica (Catlos and Sorenson, 2003); and U-Pb, Sm-Nd, and Lu-Hf isochron analysis of garnet-bearing assemblages (Mattinson, 1986; Anczkiewicz et al., 2004). With few exceptions, exceedingly fine metamorphic grain size has thus far precluded application of these methods to coherent metamorphic rocks. Nearly all ages obtained from coherent metamorphic rocks have been K/Ar or total fusion 40Ar/39Ar ages of whole-rock samples, where most of the K resides within very fine grained white mica (Suppe and Armstrong, 1972; Lanphere et al., 1978; McDowell et al., 1984). The few exceptions include two K-Ar ages and one laser step-heating 40Ar/39Ar age from white mica separated from the coherent blueschists of Ward Creek (Lee et al., 1964; Wakabayashi and Deino, 1989), and a U-Pb isochron dating blueschist metamorphism of a mafic intrusion into graywacke in the Diablo Range (Mattinson and Echeverria, 1980). We also consider several ages from earlier studies to be from coherent rocks, rather than high-grade blocks as originally interpreted, based on new field evidence and/or interpretations presented in this paper. The whole-rock ages from the coherent units have generated two divergent interpretations that reflect fundamentally different views of Franciscan geochronology. One view regards the temporal clustering of isotopic ages to best represent the metamorphic crystallization age of a unit (e.g., Lanphere et al., 1978). In this interpretation, the younger tail of the age distribution reflects partial loss of radiogenic daughter products, whereas the older tail may result from uptake of unsupported daughter products (excess argon) or radiogenic argon (premetamorphic) from detrital minerals. The second view regards all ages as products of post-metamorphic cooling, with the densest cluster of ages representing the time when most of the unit cooled through the effective closure temperature (Suppe and Armstrong, 1972; McDowell et al., 1984). Because the second interpretation regards measured ages as post-metamorphic cooling ages, it implies a much older timing of coherent metamorphism than the first view. These two interpretations have spawned significantly different opinions concerning the relationship between high-grade block and coherent metamorphism in the Franciscan: (1) Metamorphism FRANCISCAN COMPLEX, CALIFORNIA 875 FIG. 1. Distribution of Franciscan and other basement rocks of central and northern California, showing Franciscan rocks of different metamorphic grades and sample localities discussed in this paper. Map modified from Wakabayashi (1999). recorded in the high-grade blocks occurred roughly 20 million years or more before the oldest coherent blueschist metamorphism and was unrelated to Franciscan subduction (e.g., Coleman and Lanphere, 1971; Blake et al., 1988). (2) The timing of metamorphism in the high-grade and coherent metamorphic terranes overlap, suggesting that both formed during the same subduction event (Suppe and Armstrong, 1972; Platt, 1975; Cloos, 1985, 1986). It is clear that Franciscan geochronology has been hindered by the paucity of isotopic ages from mineral separates from coherent metamorphic rocks, as well as the difficulties inherent in compar- 876 WAKABAYASHI AND DUMITRU ing isotopic ages produced using a variety of different methods with different underlying assumptions, closure temperatures, and accuracies. This paper presents new resistance furnace 40Ar/39Ar incremental heating data from 11 samples of coherent metamorphic rocks, plus 5 other Franciscan samples. Following the presentation and discussion of the data, we will discuss how the new results suggest a partial overlap in metamorphic age between the high-grade blocks and the coherent terranes, and thus favor metamorphism of both in the same evolving subduction zone. We will conclude by discussing Franciscan metamorphic geochronology in terms of general HP and UHP metamorphic processes and geochronology. Sample Descriptions Almost all Franciscan HP coherent rocks are too fine grained to allow preparation of mineral separates of requisite purity for isotopic dating. White mica of phengitic composition, the key K-bearing metamorphic phase, is common in the coherent units, but nearly in all cases as grains smaller than 0.03 mm. At such sizes, separating white mica from the chlorite present in essentially all white micabearing rocks is virtually impossible owing to similar magnetic properties and densities of the two mineral species and the extreme difficulty of hand picking such small grains. Based on review of previous studies and our own field experience, several Franciscan coherent blueschist-facies units are probably totally devoid of rocks of sufficient metamorphic grain size to permit the preparation of mineral separates. These units include the Yolla Bolly, Eylar Mountain, and Burnt Hills terranes. However, we were able to identify and collect analyzable samples from several of the most strongly recrystallized and structurally highest coherent Franciscan units. These units included the South Fork Mountain Schist of the Pickett Peak terrane, the Skaggs Springs schist, the Ward Creek coherent schist, and the Willow Spring slab near Panoche Pass (Fig. 1). The coherent rocks at Willow Spring are particularly interesting, inasmuch as they are mineralogically equivalent to many high-grade blocks and even include eclogite assemblages. In addition to sampling coherent rocks, we have also obtained data from a garnet amphibolite highgrade block from the Hunters Point shear zone, a gabbro from the Hunters Point shear zone, an epidote amphibolite slab of ambiguous field rela- tions from McLaren Park in San Francisco, a garnet blueschist from Glaucophane Ridge near Panoche Pass, and the Pilarcitos gabbro in San Mateo County. The petrography of the samples and their field relations are briefly described below. Because the Willow Spring and McLaren Park localities have not been previously described, we provide additional explanation of their field relations. Grain sizes given below refer to the maximum dimension of the largest metamorphic mineral grains observed. South Fork Mountain Schist The South Fork Mountain Schist samples were collected along the road to Tomhead Mountain from the structurally highest of the thrust sheets of the unit, according to the detailed mapping of Worrall (1981) (Figs. 1 and 2). The metamorphic grade of this unit is epidote blueschist (Brown and Ghent, 1983; Blake et al., 1988). We selected our samples from extremely rare mm-scale lenses or selvages where mica or amphibole grain size is atypically large. Presumably, local compositional and/or fluid anomalies at these sites allowed growth of somewhat larger grains. Samples SFM-4c and SFM-13 consist of white mica (to 0.1 mm and 0.2 mm, respectively) separated from very quartz-rich schists that also contain chlorite and hematite (Fig. 3). These rocks correspond to the “cgs” map unit of Worrall (1981), as shown on Figure 2, and are almost certainly metacherts. Sample SFM-3 consists of sodic amphibole (to 0.5 mm) separated from a manganiferous metachert that consists primarily of quartz, with sodic amphibole, stilpnomelane, hematite, and minor white mica (to 0.05 mm) (Fig. 3). This rock corresponds to the “bgs” map unit of Worrall (1981). Sample SFM-1x consists of white mica (to 0.15 mm) from a mica-rich selvage in a metavolcanic rock whose other metamorphic minerals include actinolite, sodic amphibole, epidote, albite, acmitic clinopyroxene, and chlorite (Fig. 3). Skaggs Springs schist The Skaggs Springs schist consists of completely recrystallized metagraywacke. The schist crops out in the Diablo Range and northwestern Coast Ranges and occupies a structurally high position within the Franciscan (Fig. 4) (Wakabayashi, 1992, 1999b). This unit generally features coarser metamorphic minerals than equivalent lithologies in the South Fork Mountain Schist, although the occurrence FRANCISCAN COMPLEX, CALIFORNIA 877 FIG. 2. Geologic map of the South Fork Mountain Schist and adjacent units in the Tomhead Mountain area, simplified from Worrall (1981). Sample localities indicated by stars. Abbreviations: Non-Franciscan: Jcro = Coast Range ophiolite; Jkgv = Great Valley Group; Q = Quaternary deposits, undifferentiated. Franciscan: sfs = South Fork Mountain schist (SFM) metaclastic rocks; mv = SFM metavolcanics, structurally highest; mvl = as above, except structurally lower; cgs = SFM chlorite-bearing metachert; bgs = SFM blue amphibole-bearing metachert; vs = Valentine Springs Formation. Geology simplified from Worrall (1981). of white mica of separable grain size is rare. The largest exposure of the Skaggs Springs schist is a 70 km long belt in the western Coast Ranges (Figs. 1 and 4). Two mineralogically similar samples (FR-1 and NS-10) were collected from this belt (Fig. 4). NS-10 has some of the coarsest metamorphic minerals of the Skaggs Springs schist, but the white mica grain size is comparable to that found in the South Fork Mountain Schist (to 0.2 mm). Its mineralogy includes sodic amphibole (to 2 mm), lawsonite (to 0. 5 mm), quartz (to 1 mm), albite (to 1 mm), and white mica (Fig. 5). Sample FR-1 is similar but with somewhat finer metamorphic grain sizes, except for the white mica (to 0.2 mm). Jadeitic clinopyroxene is found in a number of localities within the Skaggs Springs schist, but not these specific samples. Ward Creek The Ward Creek locality comprises a well-known coherent schist exposed in Ward Creek near Cazadero (e.g., Coleman and Lee, 1963; Maruyama and Liou, 1988). This coherent unit appears to be structurally high and is faulted against or imbricated with Skaggs Springs schist and other units. The field relations in the Ward Creek area are more complex than the simplified structure shown in Figure 4, and may include metabasite slabs that structurally overlie and underlie the Skaggs Spring schist (Erickson, 1991). Our sample WC-1 is a metachert containing abundant quartz, sodic amphibole (to 1 mm), white mica (to 0.7 mm; many grains in the 0.5 mm range), and spessartine garnet (Fig. 5). 878 WAKABAYASHI AND DUMITRU FIG. 3. Photomicrographs of South Fork Mountain Schist samples from the Tomhead Mountain area. Plane-polarized light. Abbreviations: am = sodic amphibole; q = quartz; wm = white mica. Willow Spring slab near Panoche Pass Four samples were collected from different structural levels of a fault-bounded sheet of coherent schist in the vicinity of Willow Spring in the Panoche Pass area (Figs. 1 and 6). To distinguish this unit from other localities in the Panoche Pass area, we will refer to it as the “Willow Spring slab.” The mineralogy and grain size of the rocks of this slab are similar to those found in many high-grade blocks. Numerous artificial exposures afforded by dirt roads and their roadcuts, as well as good natural exposures on steep slopes, enable one to ascertain that the outcrops observed comprise part of a coherent sheet rather than blocks-in-mélange. The Willow Spring slab was originally mapped as the largest of several coherent metabasite units in the Panoche Pass region by Ernst (1965), although that mapping, conducted over a much larger area and without the aid of the numerous recent artificial exposures, did not reveal the highest-grade assem- blages of the slab. The fact that formal recognition of the mélange concept in the Franciscan (e.g., Hsü, 1968) followed three years after the publication of Ernst’s paper may have led some to believe that the field relations depicted by Ernst (1965) were mélange rather than coherent. The metabasite sheet has a map dimension of 2.1 km by 1.2 km and an estimated structural thickness of 200 to 300 m (Fig. 6). Metabasites comprise the bulk of the sheet, but minor metacherts and meta-ultramafic rocks also occur. The sheet has an apparent internal inverted metamorphic gradient, with lawsonite blueschist structurally low, passing upward through epidote blueschist, garnet blueschist with local fine-grained eclogite (grain size tenths of mm), to coarse eclogite (grain size several mm) at the structurally highest level (Fig. 6). It is likely that this internal metamorphic gradient is a consequence of internal faulting separating thin sheets of different metamorphic FRANCISCAN COMPLEX, CALIFORNIA 879 FIG. 4. Geologic map of the Skaggs Springs schist and Ward Creek areas, with sample localities (stars). Abbreviations: Franciscan: fcb = Coastal Belt; fg = metabasalt, blueschist facies, non-schistose; fml = mélange; fr = Rio Nido terrane. Other: ogv = Great Valley Group and Coast Range ophiolite. Modified from Wakabayashi (1992). grade, but the exposures are not sufficient to identify discrete faults separating internal subunits. The mafic slab appears to rest on a stack of faultbounded sheets of metagraywacke (Fig. 6). The structurally highest metagraywacke unit is completely recrystallized and mineralogically and texturally identical to the Skaggs Spring schist described above. It overlies a foliated metagraywacke that retains clastic texture (commonly called textural zone TZ2; e.g., Blake et al., 1988) and whose metamorphic minerals include jadeitic clinopyroxene, lawsonite, and sodic amphibole. This metagraywacke overlies a graywacke that lacks a penetrative fabric and jadeitic clinopyroxene but has lawsonite. This structurally lowest and lowest grade unit appears be the most areally extensive unit in the area surrounding the metabasite slab. We extracted white mica from sample Diab-107, a coarse eclogite from the structurally highest part of the metabasite slab (Fig. 6). This coarse-grained (to 3 mm in metamorphic grain size) sample consists of omphacite, garnet, barroisite, epidote, white mica (to 2 mm), and rutile with some overprinting growth of sodic amphibole and titanite rimming rutile (Fig. 7). Near the Diab-107 eclogite outcrop, a coarsegrained actinolite–chlorite–white mica rock crops out, from which we separated actinolite. This rock appears to be identical in mineralogy to metasomatic reaction rinds found around many high-grade blocks, and it may have formed during metasomatic reactions between the metabasite and intercalated selvages of ultramafic rock. Alternatively, the structurally highest part of the metabasite slab, including the coarsest eclogites, may be a serpentinite matrix mélange. We believe, however, that the progressive increase in metamorphic grade with structural level within the metabasite slab (Fig. 6), and the occurrence of similar actinolite-bearing schists 880 WAKABAYASHI AND DUMITRU FIG. 5. Photomicrographs of Skaggs Springs schist sample NS10 and Ward Creek sample WC-1. Plane-polarized light. Abbreviations: am = sodic amphibole; gt = garnet; law = lawsonite; q = quartz; wm = white mica. associated with mappable, but volumetrically minor, sheets of meta-ultramafic rocks at structurally lower levels in the metabasite slab, supports the former scenario. Sample Diab-33 is actinolite separated from a rock composed of actinolite (to 2 mm), chlorite, and white mica that may be part of a reaction zone between metabasite and a narrow (probably a few meters thick) zone of meta-ultramafic rocks that crops out at structurally lower level than the metasomatic rock sample Diab-107, described above. The metabasites in this part of the slab are mainly garnet blueschist, with some rocks composed primarily of fine (up to 0.5 mm) omphacite, epidote, chlorite, and rare garnet (fine-grained eclogites) (Fig. 6). Sample Diab-41fn is white mica (to 0.5 mm in size) from an epidote blueschist, which includes sodic amphibole, lawsonite, epidote, and chlorite. As is typical of the epidote blueschists of the Willow Spring slab, lawsonite occurs as texturally late poikiloblasts overgrowing earlier-formed minerals, including epidote. Similar poikiloblastic lawsonite is common in high-grade blocks throughout the Franciscan. Glaucophane Ridge Glaucophane Ridge is east of Panoche Pass, some 14 km ENE of the Willow Spring area. Glaucophane Ridge includes one of several rock bodies in the southern Diablo Range that the Jennings (1977) state geologic map depicts as coherent schists. In this region, we investigated several of the schist bodies indicated on the state map; these coarse blueschists appeared to be coherent slabs rather than blocks-in-mélange. The Willow Spring slab described above is one such unit. Unlike the FRANCISCAN COMPLEX, CALIFORNIA 881 FIG. 6. Geologic map of the Willow Spring slab, Panoche Pass area, with sample localities. Mapping based on this study except where noted. 882 WAKABAYASHI AND DUMITRU FIG. 7. Photomicrograph of eclogite sample Diab-107 from the Willow Spring slab. Plane-polarized light. Abbreviations: bar = barroisite; chl = chlorite; ep = epidote; gl = glaucophane; gt = garnet; om = omphacite; rt = rutile; wm = white mica. demonstrably coherent relations of the Willow Spring slab, our limited reconnaissance of Glaucophane Ridge indicates that our garnet blueschist sample Diab-4 may come from either a mélange block or a coherent slab. If the latter, the slab is less than 500 m in long dimension, with the alternative interpretation being much smaller blocks set in shale matrix. The blueschists on the ridge occur along the contact between Franciscan rocks on the west and Great Valley Group rocks on the east, and exposures of shale matrix mélange occur within a hundred meters of where we collected Diab-4. We separated white mica (to 0.5 mm) from sample Diab-4. Suppe and Armstrong (1972) dated two samples from Glaucophane Ridge, but insufficient location information is provided in their paper to determine whether they sampled the same outcrop as Diab-4. Epidote amphibolite of McLaren Park A sheet of epidote amphibolite crops out in the McLaren Park area of San Francisco (Wakabayashi, 1990, 1992) (Fig. 8). This sheet appears to be at least 1 km long by 0.3 km wide in map view. It is bordered by a shear/mélange zone on its southern side, whereas the northern contacts are not exposed. The southern mélange zone is comparatively small (up to 100 m wide in map view) compared to the size of the slab. Graywacke, shale, chert, and basalt of the coherent, prehnite-pumpellyite facies Marin Headlands terrane crop out beyond the immediate borders of the slab. The nearest regional-scale mélange zone is the City College fault zone, a shalematrix mélange with a map width that exceeds a kilometer locally. The northern border of the City College fault zone passes as close as 250 m to the southern limit of the mélange that bounds the southern edge of the epidote amphibolite slab (Fig. 8). Thus, the general field relations of the epidote amphibolite do not appear to be that of a typical block in mélange. It is possible the slab may represent a tectonic sliver or large block emplaced along the northern margin of the City College fault zone, a window into the City College fault zone, or a klippe of the structurally lowest part of the Hunters Point shear zone. The largest dimension of high-grade blocks found in either of the two regional shear zones above are less than a tenth of the size of the epidote amphibolite. The epidote amphibolite body consists mainly of strongly foliated metabasite (epidote amphibolite) with some layers of metachert and rare meta-ultramafic rocks. The epidote amphibolite mineralogy includes hornblende (to 1 mm), epidote, chlorite, albite, quartz, iron oxides, and apatite. The metachert consists of quartz, hornblende, stilpnomelange, hematite, and apatite (Fig. 9). Rare riebeckitic amphibole rims hornblende in one of 10 thin sections examined of the metachert. No petrographic evidence of a blueschist-facies overprint FRANCISCAN COMPLEX, CALIFORNIA 883 FIG. 8. Geologic map of part of San Francisco, with sample localities (stars). Geology from Schlocker (1974), Bonilla (1971), Wakabayashi (2004), and this study. was observed in any other thin section of either metabasite or metachert (collectively about 20 thin sections). Some lawsonite-bearing graywacke blocks are associated with the shear zone bounding the southern edge of the epidote-amphibolite body, along with a few blocks of fine-grained lawsonite blueschist. The hornblende separate MP-1 was taken from an epidote-amphibolite sample. 884 WAKABAYASHI AND DUMITRU FIG. 9. Photomicrographs of amphibolite samples MP-1 and HPSZ (meta). Plane-polarized light. Abbreviations: ab = albite; am = hornblende; ep = epidote; gt = garnet. High-grade block from Hunters Point shear zone The Hunters Point shear zone consists of a shale matrix mélange structurally overlain by a comparatively coherent sheet of serpentinite (Wakabayashi, 1990, 2004) (Fig. 8). Garnet-amphibolite highgrade blocks with blueschist facies overprinting occur within shale matrix mélange, or along the border between the shale matrix mélange and serpentinite at Baker Beach (Fig. 8). Sample HPSZmeta consists of tschermakitic hornblende separated from a garnet amphibolite whose metamorphic minerals include calcic amphibole (to 3 mm), garnet, inferred plagioclase (replaced by albite, lawsonite, and other fine-grained minerals), and titanite (Fig. 9). The overprinting minerals include barroisitic hornblende, sodic amphibole, lawsonite, and chlorite. Similar to the McLaren Park metabasite body, the presence of metachert interlayers suggests a basalt (rather than mafic plutonic rock) protolith for the garnet amphibolite. Hunters Point shear zone gabbro and Pilarcitos gabbro These two samples differ from any of those above, in that neither exhibits HP subductionrelated metamorphism, and because of their gabbroic protoliths. The Hunters Point shear zone gabbro sample is taken from a gabbro lens (about 30 m in the long dimension) within the serpentinite sheet of the shear zone (Schlocker, 1974). This is the largest of several such gabbro lenses that occur within the serpentinite sheet in the Potrero Hill area of San Francisco. None of the gabbros exhibit blueschist-facies or other HP metamorphic assemblages. The gabbros have a hornblende + plagioclase assemblage defining a weak metamorphic(?) foliation, with variable retrogression of the plagioclase, FRANCISCAN COMPLEX, CALIFORNIA and local texturally late growth of fine pumpellyite needles. Sample HPSZ-gabbro is greenish-brown hornblende (to 1.5 mm) separated from a rock that consists mostly of hornblende and plagioclase, with some relict clinopyroxene, as well as variably retrogressed plagioclase, and fine-grained pumpellyite. The Pilarcitos gabbro was collected from directly east of Pilarcitos Dam in northern San Mateo County, along the tectonic contact between the Franciscan and the Salinian block (Wakabayashi, 1999b). Directly west of the gabbro are low-temperature mylonites derived from Paleocene sedimentary rocks of the Salinian block, whereas east of the gabbro are prehnite-pumpellyite–grade metabasalts, clastic sedimentary rocks, and limestone of the Franciscan Permanente terrane. The gabbro has a “bleached” appearance in outcrop, probably owing to the severe alteration of plagioclase, and the fact that the mafic minerals (predominantly actinolite) are comparatively pale. Petrographically, the rock consists primarily of severely altered plagioclase and pale green actinolite (to 1 mm), with some relict clinopyroxene. The rock lacks a penetrative fabric. All alternative exposures of this gabbro we examined show various degrees of alteration. The sample we dated consists of actinolite separated from the gabbro. 40Ar/39Ar Age Determinations 40Ar/39Ar Below, we describe resistance furnace step-heating results from hornblende, actinolite, sodic amphibole, and white mica from the abovedescribed localities in the Franciscan Complex. Table 1 summarizes the preferred model ages for each sample. McDougall and Harrison (1999) provide an overview of the 40Ar/39Ar dating method. Because of the high bulk closure temperature of hornblende (525 ± 50°C; Harrison, 1981), hornblende ages from subduction environments are generally expected to closely approximate the time of metamorphic recrystallization. However, difficulties related to excess 40Ar and intergrown K-bearing phases often arise in hornblende analyses. Such problems may be amplified when K-poor amphiboles such as sodic amphibole and actinolite are analyzed. Sodic amphiboles in particular commonly yield problematic 40Ar/39Ar results (e.g., Ross and Sharp, 1986; Baldwin and Harrison, 1989, 1992). Consequently, careful examination of the data systematics (age spectrum, K/Ca spectrum, inverse isochron, etc.) is necessary to detect problematic 885 behavior and assess which model age (plateau, total fusion, isochron, etc.) is geologically most meaningful. We assume that all of our white mica samples are phengites, based on compositional data from previous studies of equivalent Franciscan HP rocks (e.g., Maruyama and Liou, 1988; Wakabayashi, 1990), although we did not obtain compositional data from our samples. The bulk Ar closure temperature of phengite is not well known, but has been estimated as ≈350–450°C (e.g., McDougall and Harrison, 1999). It may be lower in relatively fine grained Franciscan rocks. Typically, phengite 40 Ar/39 Ar ages are interpreted as recording cooling through the phengite bulk closure temperature. However, in the Franciscan Complex, peak metamorphic temperatures of some units may have been similar to or cooler than closure temperatures, and the phengites may instead date metamorphic crystallization. As with amphiboles, phengite analyses may be complicated by excess 40Ar, as well as by multiple generations of mica or by 40Ar retained in incompletely recrystallized detrital micas. Hence, close examination of data systematics, petrography (especially textural relationships), and ideally petrology (especially estimates of the metamorphic temperature), is necessary to assess which model age is geologically most meaningful. Laboratory techniques For this study, analyses were completed in the laboratory of M. O. McWilliams at Stanford University. The minerals of interest were concentrated using standard mechanical and magnetic methods. For most samples of white mica and sodic amphibole, the concentrates were prepared from small rock specimens selected because they contained thin layers or selvages, generally a few millimeters thick, where the target mineral grains were substantially larger than was typical for the target rock unit. Grains chosen for neutron irradiation were individually inspected and hand selected under the binocular microscope. Total masses of analyzed material were about 0.6–5 mg for white mica, 10–75 mg for sodic amphibole, 7–25 mg for actinolite, and 8–15 mg for hornblende. Step heat Ar isotopic analyses were completed using a Staudacher-type resistance furnace and a MAP 216 mass spectrometer, following procedures similar to those of Hacker and Wang (1995). The J irradiation parameter was monitored using sanidine from the Taylor Creek Rhyolite (nominal age of 27.92 Ma; Duffield and Dalrymple, 1990) 886 WAKABAYASHI AND DUMITRU TABLE 1. Summary of New Franciscan 40Ar/39Ar Ages Metamorphic temperature Mineral Preferred model age (Ma, ±1s) Model type Confidence in age Sample Rock type SFM-13 metachert WM 120.53 ± 0.63 Plateau High SFM-1x metavolcanic WM 122.5 ± 1.8 Isochron High South Fork Mtn Schist—Tomhead Mtn (coherent blueshist) SFM-4c Summary age metachert (epidote-BS facies) WM 121.8 ± 3.7 Isochron High WM 120.53 ± 0.63 Plateau Very high Na-Amph Not interpretable None – Plateau Moderate 330–345°C SFM-3 metachert WC-1 Metachert NS-10 Metagraywacke WM ~132 High-T steps Moderate FR-10 Metagraywacke WM ~132 High-T steps Moderate WM ~132 High-T steps Moderate Ward Creek—Sonoma County (coherent blueschist) 290-400°C WM 154.0 ± 1.6 Skaggs Springs Schist--Sonoma County (coherent blueschist) Summary age >330°C? Willow Spring Slab—Panoche Pass (coherent blueschist and ecologite) 95Diab-107 Act Metasomatic rind Act (154.9 ± 5.1) Isochron Low 95Diab-107 Mica Coarse eclogite WM 146.51 ± 0.36 Plateau High 95Diab-33 95Diab-41 fn Reaction zone Act (142 ± 16) Isochron Very low Epidote blueschist WM 134.2 ± 0.4 Total fusion Moderate Glaucophane Ridge—Panoche Valley (may be coherent blueschist or high-grade block) 95Diab-4 Garnet blueschist WM 132.1 ± 0.2 Total fusion Moderate Maclaren Park—San Francisco (probably high-grade block) MP-1 Epidote amphibolite High T Hbl 156.2 ± 3.4 Isochron Moderate HPSZ Meta Garnet amphibolite high T Hbl 158.91 ± 0.57 Isochron Moderate HPSZ Gabbro Gabbro (not HP) – Hbl (146.5 ± 8.6) Isochron Low Pilarcitos Gabbro Gabbro (not HP) Isochron Very low Hunters Point Shear Zone—San Francisco (blocks in melange) Pilarcitos Dam—San Mateo County (low-pressure gabbro) – and the IUGS recommended decay constants (Steiger and Jager, 1977). Data were plotted and evaluated statistically with the Isoplot 3.0 software package (Ludwig, 2003). The default criteria in Isoplot were used to assess the statistical validity of potential age plateaus. Data are presented and interpreted in the form of standard step-heat age spectrum plots, step-heat K/Ca ratio spectrum plots, and inverse isochron plots (e.g., McDougall and Harri- Act (166 ± 38) son, 1999; Ludwig, 2003). Unless otherwise indicated, uncertainties are quoted and plotted at the one-sigma level and include propagated uncertainties in peak heights, blank values, rates of reactorproduced Ar isotopes, duration of irradiation, time delay between irradiation and analysis, J, monitor age, and decay rates of 37Ar, 39Ar, and 40K. Copies of tabular data are available from the authors on request. FRANCISCAN COMPLEX, CALIFORNIA South Fork Mountain Schist White micas from three samples of South Fork Mountain Schist were analyzed. Metachert sample SFM-13 yielded an age spectrum with a welldefined age plateau that included 87% of the total 39Ar yield (Fig. 10A). The plateau age is 120.53 ± 0.63 Ma, which is statistically indistinguishable from the total fusion age of 120.2 ± 0.9 Ma (both uncertainties are ±1s and include uncertainty in J). A K/Ca spectrum shows a fairly consistent K/Ca ratio averaging about 90 for this sample (Fig. 10B), a reasonable pattern for white mica. An inverse isochron plot (Fig. 10C) indicates that the sample yielded negligible atmospheric Ar (as indicated by negligible 36Ar). Because there is negligible atmospheric argon, the isochron plot cannot be used directly to assess whether excess radiogenic 40Ar is present and has perturbed the ages. However, the fact that negligible dissolved atmospheric Ar has been incorporated into white mica from fluids within this presumably fluid-rich metachert system suggests that incorporation of fluid-transported excess 40 Ar was similarly negligible (see below). We consider the plateau age of 120.53 ± 0.63 Ma to be the most appropriate model age for this sample. The essentially identical total fusion age might be used instead, but may have been slightly perturbed by the erratic ages and low K/Ca ratios at the extreme highand low-temperature ends of the release spectra. White mica from metavolcanic sample SFM-1x yielded an age spectrum characterized by initially older ages that decrease slightly with increasing 39Ar release toward a plateau at 125 Ma (Fig. 10D). In a mica, such a descending pattern could have several causes, including excess 40Ar. Excess 40Ar has been observed in white mica from many HP and UHP terranes, although virtually all of those studies have been directly at rocks considerably higher in grade than the South Fork Mountain Schist (e.g., de Jong et al., 2001; Sherlock and Kelley, 2002). An inverse isochron plot shows a clear linear trend, with an initial 36Ar/40Ar ratio somewhat less than atmospheric, evidence that the sample is moderately contaminated with excess 40Ar (Fig. 10F). Statistical tests indicate that the fit of the isochron is good. The isochron age is 122.5 ± 1.8 Ma and we consider this the most appropriate model age for this sample. The K/Ca spectrum shows lower K/Ca ratios than sample SFM-13, with considerable fluctuation (Fig. 10E). This suggests this separate is not pure white mica and may contain Ca-bearing intergrowths, inclusions, or alteration products. 887 White mica from metachert sample SFM-4c yielded an age spectrum generally similar to SFM1x, although without a well-defined plateau (Fig. 10G). Again, the inverse isochron plot shows a clear linear trend with initial 36Ar/40Ar less than atmospheric, indicating excess 40Ar, and statistical tests indicate the fit of the isochron is good (Fig. 10I). The isochron age is 121.8 ± 3.7 Ma, and we consider this the most appropriate model age for this sample. The K/Ca spectrum shows features similar to SFM-1x (Fig. 10H). The preferred model ages from the three white mica samples are statistically identical, even though the samples incorporated varying amounts of excess 40Ar. This increases confidence that the ages are reliable and geologically meaningful. Because sample SFM-13 exhibits a well-defined age plateau, essentially identical plateau and total fusion ages, low uncertainties on ages, and very low 36Ar/40Ar, we infer that its plateau age, 120.53 ± 0.63 Ma (±1s), best represents the 40Ar/39Ar white mica age of the South Fork Mountain Schist at this locality (Table 1). For purposes of discussion, we will refer to this age later as 120.5 Ma. In many HP metamorphic terranes, white micas (phengites) have yielded consistent and apparently reliable 40Ar/39Ar ages, but, in other HP areas, excess 40Ar has clearly perturbed the system. Judgments as to the reliability of the ages are generally based on the detailed Ar systematics of individual samples and the consistency of ages between samples. Given this, potential complications with the South Fork Mountain Schist samples should be considered. First, SFM-13 yielded an excellent age plateau (Fig. 10A), which might be interpreted as indicating rapid cooling through the bulk argon closure temperature. However, the degassing mechanism for a mica in a high-temperature laboratory furnace is physically different from that in nature, so such a plateau could alternatively be an experimental artifact caused by Ar homogenization during laboratory step heating (e.g., Sletten and Onstott, 1998; McDougall and Harrison, 1999). The age spectra for samples SFM-1x and SFM-4c exhibit moderate curvature (Fig. 10D and 10G), which we have attributed to relatively minor excess Ar. Alternatively, curved age spectra in white micas are sometimes attributed to mixing of argon from two generations of micas of different ages and compositions (e.g., phengite overgrowth by muscovite or phengite altered to illite), such as in terranes where HP rocks have been overprinted by greenschist- 888 WAKABAYASHI AND DUMITRU FIG. 10. 40Ar/39Ar data from four samples from the South Fork Mountain Schist. Upper plots are age spectra, middle plots are spectra of K/Ca ratios, and lower plots are inverse isochrons (e.g., McDougall and Harrison, 1999; Ludwig, 2003). Nominal furnace degassing temperatures (°C) are indicated on the age spectra and inverse isochron plots. In plots of 40Ar/39Ar data, all uncertainties are quoted and plotted at the one-sigma level unless otherwise indicated. facies conditions (e.g., Wijbrans and McDougall, 1986; de Jong et al., 2001). However, the Franciscan Complex is notable among subduction com- plexes for its lack of any greenschist-facies overprint (Ernst, 1988). Although we do not have compositional data from our white micas, multiple FRANCISCAN COMPLEX, CALIFORNIA 889 FIG. 10. Continued. generations of phengites have not previously been reported in the Franciscan coherent rocks we have examined (e.g., Maruyama and Liou, 1988) and we infer that these samples contain only a single generation of white mica of phengitic composition. A tendency may exist for major excess 40Ar contamination in phengites to be more prevalent in closed, fluid-absent systems, where fluid-mediated transport of dissolved argon is very slow (Sherlock and Kelley, 2002), such as in exhumed UHP 890 WAKABAYASHI AND DUMITRU predominately a porous marine mudstone metamorphosed to relatively low grade. Metasedimentary rocks within the South Fork Mountain Schist exhibit major syndeformational quartz veining (Worrall, 1981), evidence of substantial fluid flow during metamorphism. Another potential complication in low-grade metamorphic terranes is the retention of radiogenic 40 Ar within incompletely recrystallized coarsegrained detrital muscovite grains in metagraywackes (e.g., McDowell et al., 1984). The genesis of our South Fork Mountain Schist samples as metacherts and metavolcanics presumably lacking in detrital muscovite makes this complication unlikely. In addition, these samples were collected from the highest-grade, most thoroughly recrystallized rocks in the Franciscan Eastern Belt, those least likely to retain any incompletely recrystallized detrital muscovite. In sum, the three white mica samples from this area have yielded well-behaved data that indicate a consistent age from sample to sample. We therefore conclude that 120.5 Ma represents a reliable and geologically meaningful 40Ar/39Ar age for the South Fork Mountain Schist at this locality. Ward Creek FIG. 11. 40Ar/39Ar data from white mica sample WC-1 from Ward Creek. terranes where dry conditions are a key requirement for preservation UHP assemblages (Hacker and Peacock, 1995). In contrast, our white mica samples are likely from open, wet systems, given that the protolith of the South Fork Mountain Schist was White mica from Ward Creek metachert sample WC-1 yielded a monotonically ascending “staircase” age spectrum, with its oldest step at 160.4 Ma (Fig. 11). The center of the spectrum exhibits a weakly sloping plateau at 154.0 Ma, similar to the total fusion age of 152.6 Ma. The K/Ca spectrum shows fluctuating ratios between about 10 and 38, somewhat low for a simple, pure white mica. The inverse isochron plot indicates negligible atmospheric Ar and is not useful for assessing excess 40Ar. The overall staircase shape of the age spectrum conforms remarkably well to theoretical spectra expected with partial loss of Ar by simple diffusion processes (e.g., McDougall and Harrison, 1999), and similar spectra from white micas have commonly been interpreted in such a manner (e.g., Wijbrans and McDougall, 1986; Baldwin and Harrison, 1989, 1992; Grove and Bebout, 1995). However, because release of Ar in a high-temperature laboratory furnace occurs under conditions that are well outside of the thermal stability field of hydrous white mica, it is unclear how such a natural partial loss situation would generate a staircase spectrum (e.g., Sletten and Onstott, 1998; McDougall and FRANCISCAN COMPLEX, CALIFORNIA Harrison, 1999). If a partial loss interpretation of the spectrum is accepted, it would suggest crystallization of the mica at about 160 Ma or earlier, followed by cooling through the mica closure temperature at about 154 Ma, followed by additional later cooling accompanied by additional partial loss of Ar. Another possible explanation of staircase patterns is that multiple generations of white mica with different ages and different compositions are degassing at different temperatures (e.g., Wijbrans and McDougall, 1986). We discount this explanation, because neither a greenschist-facies overprint nor multiple generations of white mica growth have been reported from this well-studied Franciscan locality (Maruyama and Liou, 1988). A third possible explanation is that minor, micron-scale alteration of the white mica has generated less retentive zones within the grains that are responsible for the younger ages measured during the lower temperature steps (e.g., Sletten and Onstott, 1998). Recognizing the ambiguities with this sample, we accept the plateau age of 153.99 ± 1.62 Ma as the preferred model age for this sample, mainly because the plateau age partially filters out the young steps at low release temperatures, which are difficult to explain geologically. In addition, the plateau and total fusion ages are essentially identical. Our sample was taken from the epidote blueschist part of the Ward Creek coherent sequence, estimated to have undergone metamorphism at 290–400°C (Maruyama and Liou, 1988; Oh and Liou, 1990). Accordingly, our model age may represent either the time of metamorphism or of cooling through the bulk phengite closure temperature. Skaggs Springs schist White mica from Skaggs Springs schist samples NS-10 and FR-1 both yielded moderately descending age spectra and fluctuating K/Ca spectra (Fig. 12). Note that the lowest temperature furnace steps were inadvertently omitted for NS-10, and this probably obscures the young ages commonly observed over the initial several percent of gas release. Total fusion ages for the samples are similar, 136.2 ± 1.3 Ma and 132.6 ± 2.4 Ma, respectively. Isochron plots indicate that minor amounts of atmospheric Ar are present, but valid isochrons cannot be fit. These data are difficult to interpret. The decreasing spectra may represent minor to moderate excess Ar. We interpreted similar spectra and isochron plots for SFM-1x and SFM-4c as reflecting excess 40Ar (Fig. 10). If excess 40Ar is present, the near-horizontal 891 portions of the spectra between about 60% and 90% cumulative 39Ar may best approach the correct age, about 132 Ma in both cases, and we tentatively propose this as the most plausible model age for these samples (Table 1). However, for SFM-1x and SFM-4c, the ages of the corresponding intervals on the age spectra were about 3 million years older than the isochron ages we ultimately preferred for those samples, so a “correct” age for the Skaggs Springs samples could be somewhat different from 132 Ma. The fine grain size of the white mica (same size as the South Fork Mountain Schist samples) suggests that these ages may reflect cooling through Ar closure rather than metamorphic crystallization. Although no estimates of metamorphic temperature have been obtained from the Skaggs Springs schist, it is more thoroughly recrystallized and exhibits coarser metamorphic minerals than the South Fork Mountain Schist. Unfortunately, the exceedingly rare occurrences of separable white mica we found in the former were no coarser than the similarly very rare separable white micas we sampled from the latter. Willow Spring slab White mica from coarse eclogite sample Diab107 (Fig. 13) yielded a well-defined age plateau at 146.51 ± 0.36 Ma (±1σ, including uncertainty in J), which we accept as its most geologically meaningful model age. The K/Ca spectrum shows somewhat low ratios between about 20 and 30, suggestive of an impure mica. The inverse isochron plot shows negligible atmospheric Ar and is therefore not useful in assessing excess 40Ar. Because this coarse eclogite likely crystallized at greater than 450°C based on thermobarometric studies of similar Franciscan rocks (e.g., Tsujimori et al., 2006), the results are best interpreted as recording cooling through the bulk closure temperature of white mica at about 147 Ma. Actinolite from a metasomatic reaction zone near eclogite Diab-107 yielded an ascending age spectrum (Fig. 14). The center of the spectrum exhibits a poorly developed plateau of 148 ± 10 Ma, whereas the high-temperature end of the spectrum rises to about 160 Ma. A K/Ca spectrum shows a nearconstant ratio of 0.01 over 96% of 39Ar release, consistent with degassing of actinolite. An isochron on the steps with near-constant K/Ca ratio yields an age of 154.9 ± 5.9 Ma and an intercept near atmospheric, revealing no evidence for excess Ar. 892 WAKABAYASHI AND DUMITRU FIG. 12. 40Ar/39Ar data from two white mica samples from the Skaggs Spring schist. Note that a non-optimal laboratory heating schedule starting at 600°C was used for sample NS-10. This probably obscured the younger ages normally expected over the initial several percent of 39Ar release. Statistically, however, the fit of the isochron is poor. Despite the poor fit, we accept the isochron age at the most geologically meaningful model age for this sample. Similar actinolite-rich reaction zones in the Franciscan are estimated to have formed at about 300–370°C (Moore, 1984), significantly cooler than the bulk closure temperature of hornblende of about 525 ± 50°C (Harrison, 1981). The data are probably FRANCISCAN COMPLEX, CALIFORNIA 893 FIG. 13. 40Ar/39Ar data from two white mica samples from the Willow Spring slab. best interpreted as indicating crystallization of actinolite at about 154.9 ± 5.9 Ma. Actinolite from sample Diab-33, probably a metasomatic zone between meta-ultramafic rocks and garnet blueschist at a structurally lower level in the slab than Diab-107, yielded an irregular ascend- ing spectrum that rises to a maximum of roughly 160 Ma (Fig. 14). A K/Ca spectrum shows a near-constant K/Ca ratio of about 0.003 over about 84% of 39Ar release, consistent with degassing of actinolite. An isochron on the steps with near-constant K/Ca yields an age of 142 ± 16 Ma and an intercept close 894 WAKABAYASHI AND DUMITRU FIG. 14. 40Ar/39Ar data from two actinolite samples from the Willow Spring slab. to atmospheric, revealing no evidence for excess Ar. However, the fit of the isochron is poor. The isochron age is probably the best model age for this sample, but given the poor isochron fit, the high uncertainty on the isochron age, and the erratic age spectrum, a useful geologic interpretation of this sample is not possible. White mica from epidote blueschist sample Diab-41fn yielded a relatively flat age spectra, with most steps between about 132 and 137 Ma (Fig. 13). FRANCISCAN COMPLEX, CALIFORNIA 895 Although this sample did not yield a plateau, the total fusion age of 134.2 ± 0.4 describes the data well, and we accept this as the best model age for this sample. The K/Ca spectrum shows low and variable K/Ca ratios between about 3 to 8, inconsistent with a pure white mica. While the inverse isochron plot does not meet statistical expectations of a simple two-component mixture, the imprecise isochron age of 132 Ma is very similar to the total fusion age. Based on metamorphic temperature estimates for similar epidote blueschists as Ward Creek, the metamorphic temperature of this sample may have been about 290–400°C (Maruyama and Liou, 1988; Oh and Liou, 1990). These data are best interpreted as recording metamorphic white mica growth or cooling through the bulk closure temperature of white mica at about 134 Ma. Glaucophane Ridge White mica from sample Diab-4 at Glaucophane Ridge yielded a complex age spectrum generally similar to Diab-41fn from Willow Spring about 14 km away, with most steps yielding ages between about 122 and 140 Ma (Fig. 15). The K/Ca spectrum shows K/Ca ratios between about 30 and 40. The inverse isochron plot shows negligible atmospheric Ar and is not useful in assessing excess 40Ar. We tentatively accept the total fusion age of 132 Ma as the most geologically meaningful model age for this sample. Based on comparison to similar mineral assemblages at Ward Creek, the metamorphic temperature for this sample may have been about 350– 400°C (Oh and Liou, 1990). Accordingly, we infer that the data are best interpreted as recording metamorphic growth of white mica or cooling through the bulk closure temperature of white mica at about 132 Ma. This interpretation is essentially identical to that for sample Diab-41fn, which yielded a 134 Ma total fusion age. Epidote amphibolite of McLaren Park Hornblende from the epidote amphibolite sample MP-1 yielded a somewhat irregular age spectrum, which is not unusual for hornblende analyses (Fig. 16). K/Ca ratios are consistent over the last ~60% of 39Ar release and are compatible with a relatively pure hornblende phase. Anomalous ages between about 58 and 66% cumulative 39Ar are not unexpected and reflect incongruent melting of hornblende in the laboratory furnace (e.g., Wartho et al., 1991). The most reliable age for such samples is generally considered to be obtained from the higher FIG. 15. 40Ar/39Ar data from white mica sample Diab-4 from Glaucophane Ridge. temperature steps after the melting anomalies. An isochron on the five highest-T steps yields an age of 156.2 ± 3.4 Ma. The initial 36Ar/40Ar ratio is near atmospheric and gives no indication of excess 40Ar. The quality of the isochron fit is fair. The isochron 896 WAKABAYASHI AND DUMITRU FIG. 16. 40Ar/39Ar data from two hornblende samples from the city of San Francisco. age is statistically indistinguishable from the total fusion age of 153.9 ± 0.6 Ma. We therefore accept the isochron age as the most geologically meaningful model age for this sample. The poorly constrained peak temperature of this unit has been estimated as about 400–600°C (Wakabayashi, 1990) so metamor- phic crystallization temperatures may have exceeded the bulk closure temperature of hornblende. Accordingly, the model age for the epidote amphibolite of McLaren Park may reflect cooling through the bulk closure temperature of hornblende or metamorphic crystallization. Cooling of high- FRANCISCAN COMPLEX, CALIFORNIA grade rocks of the Franciscan has been interpreted to be rapid from the peak temperature of metamorphism to the bulk hornblende closure temperature, based on evaluation of earlier geochronologic studies, regional tectonic models, and thermal modeling (Wakabayashi, 1990). The positive correlation between Lu-Hf of garnet-bearing high-grade Franciscan rocks and corresponding metamorphic temperatures suggests slow cooling (Anczkiewicz et al., 2004), however, so the assumption that hornblende 40Ar/39Ar ages in Franciscan high-grade rocks closely approximate metamorphic crystallization because of rapid cooling may be incorrect. High-grade block from the Hunters Point shear zone Hornblende from garnet amphibolite block HPSZ-meta from the Hunters Point Shear zone yielded data generally similar to sample MP-1 (Fig. 16). The isochron age of the six highest-T steps is 158.91 ± 0.57 Ma, with an intercept that is essentially atmospheric. The fit of the isochron is good. As with MP-1, we accept the isochron age as the most geologically meaningful model age for this sample. Wakabayashi (1990) estimated the metamorphic temperature of the HPSZ block as about 690–730°C, significantly higher than the bulk hornblende closure temperature. We therefore consider the model age for the Hunters Point shear zone garnet amphibolite block to date cooling through the bulk hornblende closure temperature. Gabbro block from the Hunters Point Shear zone Hornblende from sample HPSZ-gabbro, a gabbro lens within Hunters Point shear zone serpentinite, also yielded data generally similar to sample MP-1 (Fig. 17). The isochron age of the eight highest-T steps is 146.5 ± 8.6 Ma, with an intercept that is essentially atmospheric. However, the fit of the isochron is poor. Although the fit is poor, we tentatively accept the isochron age as the most geologically meaningful model age for this sample and consider that it dates hornblende crystallization. Note that the large uncertainty on the isochron age means that hornblende in this gabbro sample did not necessary crystallize after the hornblende in HPSZ-meta. Pilarcitos gabbro Actinolite from a sample of the Pilarcitos gabbro yielded an irregular ascending age spectrum (Fig. 17). A K/Ca spectrum shows a fairly uniform K/Ca ratio of about 0.005. Figure 17B shows an attempt to 897 fit an isochron to the four highest-T steps. This isochron yields at age of 166 ± 38 Ma and an initial 36Ar/40Ar ratio near atmospheric. However the fit of the isochron is poor. Alternative isochrons including different steps are no better (not shown). As mentioned above, this sample showed evidence of significant alteration and this may be a factor in the poor data quality. These data cannot be interpreted in detail. We can infer only that actinolite crystallization in this sample was apparently grossly coeval with hornblende crystallization in MP-1, HPSZmeta, and HPSZ-gabbro. Sodic amphibole samples We also attempted to date sodic amphiboles from five samples. As mentioned, sodic amphiboles commonly yield problematic 40Ar/39Ar results. Four of our samples yielded erratic, uninterpretable data, which are not presented here. These four samples included sodic amphiboles from samples WC-1 and NS-10 discussed above, from sample SFM-14, a metabasite collected near white mica sample SFM13, and from sample AI, a coherent metachert from Angel Island in San Francisco Bay. One sodic amphibole sample did yield tantalizing data. This sample, SFM-3, was collected from a manganiferous metachert within the South Fork Mountain Schist (Figs. 2 and 3). It exhibits a staircase spectrum, with the oldest step at 135 Ma (Fig. 10J). Sodic amphiboles lack K in their nominal compositional formulae and Sisson and Onstott (1986) suggested any K may be hosted within finegrained white mica inclusions. Alternatively, Eide et al. (1992) reported strongly zoned trace K up to 0.16% within the main sodic amphibole phase. The K/Ca spectrum from SFM-3 (Fig. 10K) appears to show a phase with a low and very uniform K/Ca ratio of 0.03 as the source of Ar over the last 56% of the 39Ar released, and we tentatively infer that this interval does indeed represent degassing of the main amphibole phase. An inverse isochron plot indicates that all steps contain significant atmospheric Ar (Fig. 10L). However, attempting to project a single isochron through the data requires an initial 36Ar/ 40Ar ratio that is greater than atmospheric, which is not reasonable physically (e.g., McDougall and Harrison, 1999), so the isochron age from the plot is not valid. Thus while the data patterns from sodic amphibole sample SFM-3 are initially intriguing, a reliable interpretation is not possible. 898 WAKABAYASHI AND DUMITRU FIG. 17. 40Ar/39Ar data from two gabbro samples not subjected to HP metamorphism. Discussion Preliminary comment on Franciscan Lu-Hf ages Anczkiewicz et al. (2004) reported five new LuHf garnet ages that are especially important in understanding the early evolution of the Franciscan Complex, because they probably directly date metamorphic recrystallization of the high-grade, garnetbearing units. However, it should be noted that important uncertainties remain in the value of the 176Lu decay constant. Anczkiewicz et al. (2004) used what is probably the best available estimate FRANCISCAN COMPLEX, CALIFORNIA (Scherer et al., 2001) and their samples appear to yield geologically reasonable ages, especially their sample from Santa Catalina Island. We therefore accept their ages in the discussions below. However, use of alternative values would reduce the Lu-Hf ages by up to about 5% or increase them by up to about 10% (Begemann et al., 2001; Norman et al., 2004), and this unfortunately generates considerably ambiguity when attempting to compare the LuHf ages with 40Ar/39Ar ages. High-grade blocks and coherent metamorphic rocks: Unrelated or part of the same subduction event? Our new 40Ar/39Ar ages (Table 1), when evaluated in the context of existing ages, show that the ages of coherent metamorphism partially overlap the ages of high-grade block metamorphism (Fig. 18). This strongly suggests that the metamorphism of both was associated with evolution of the same subduction zone (e.g., Platt, 1975; Cloos, 1985; Wakabayashi, 1990), rather than with separate subduction episodes (e.g., Blake et al., 1988). This is consistent with the observations that: (1) metamorphic assemblages show an overlap rather than a sharp discontinuity in conditions between the highest-grade coherent metamorphic rocks and the highgrade blocks; and (2) field relations at the Willow Spring slab define a coherent sheet of rocks in which mineral assemblages are identical to those in many high-grade blocks. The Willow Spring slab is clearly one of a stack of Franciscan thrust sheets and not a mélange block. Anczkiewicz et al. (2004) obtained a Lu-Hf garnet age of 146.7 ± 0.7 Ma from garnet blueschist of the slab, within the range of our 40Ar/39Ar ages. Field relations of the Willow Spring slab are similar to a smaller coherent body of blueschist-overprinted amphibolite and garnet amphibolite at Goat Mountain in the northern Coast Ranges. The Goat Mountain rocks exhibit high-grade block mineralogy, but coherent field relations (Ernst et al., 1970) and have yielded K/Ar ages that are identical to those obtained from high-grade blocks using the same methods (Suppe and Foland, 1978). During field reconnaissance in the southern Diablo Range, we examined several other slabs of coarse-grained metabasite, somewhat smaller (up to 1.5 km in the long dimension) than the Willow Spring slab, that appear to be thrust sheets overlying metagraywacke, rather than blocks-in-mélange. Several of these are denoted as “csch” near Willow 899 Spring on Figure 1 and some are also broken out as coherent schists on the state geologic map of Jennings (1977). Our field observations suggest that these slabs occupy the structurally highest levels of the Franciscan in the southern Diablo Range. The slabs crop out along or near the regional contact between the Franciscan and the structurally overlying Coast Range ophiolite and/or Great Valley Group. One of these apparently coherent sheets is a garnet amphibolite slab with variable blueschist overprint located about 2 km east of the Willow Springs slab. This slab, which is about 700 m in long dimension and structurally overlies metagraywacke, was described by Ernst (1965) and by Hermes (1973), and we refer to it informally here as the “Antelope Creek slab.” 159-163 Ma Ar-Ar hornblende ages and a 168.7 ± 0.8 Ma Lu-Hf garnet age have been obtained from this slab (Ross and Sharp, 1988; Anczkiewicz et al., 2004). These observations suggest that coherent, high-grade rocks in the Franciscan are more common than previously recognized, although they still constitute much less than 1% of Franciscan metamorphic rocks. The coherent field relations indicate that although much of the high-grade material in the Franciscan may have been exhumed as blocks-in-mélange, at least some of it has been exhumed as coherent, fault-bounded sheets in a manner generally similar to the larger, lower-grade coherent units. In addition to the rocks with demonstrably coherent field relations (Ward Creek, Willow Spring, Antelope Creek), high-grade block sample HPSZmeta and the epidote amphibolite of McLaren Park of somewhat ambiguous field relations gave hornblendes 40Ar/39Ar ages similar to those obtained from high-grade blocks in previous studies (Ross and Sharp 1986, 1988). Does the high-grade geochronology of the Franciscan reflect a slow initiation of subduction? Models for the thermal histories of subduction zones generally predict very rapid cooling over the first few million years following the initiation of subduction (e.g., Peacock, 1988; Hacker, 1991). Anczkiewicz et al. (2004) reported a correlation between the peak metamorphic temperatures and the Lu-Hf ages of their high-grade, garnet-bearing samples (n = 5), with older samples recording metamorphism at higher temperatures. Their data suggested remarkably slow and protracted cooling of the Franciscan subduction zone over about the first 20 million years following the initiation of subduc- 900 WAKABAYASHI AND DUMITRU FIG. 18. Summary of age data on Franciscan blueschist and higher grade rocks. 40Ar/39Ar ages from this study are in bold and larger type, with ±1σ error bars displayed unless uncertainties are smaller than the symbol size. “<<<<<“ symbols with grayed letters denote protolith ages that predate metamorphism (for fossils, the range of “<<<<<“ denotes the biostratigraphic age range). “>>>>>” symbols represent zircon fission track ages that postdate metamorphism (range of “>>>>>” represents ±2σ uncertainty range on the fission track ages). Abbreviations: Ar-Ar = 40Ar/39Ar step heating, except wrtf (whole-rock total fusion); Dzrc = maximum depositional age from detrital zircon; Fss = depositional age from fossils in clastic rocks; K/Ar: potassium-argon; Lu-Hf = lutetium-hafnium, garnet-bearing assemblages; U/Pb = uranium-lead, zircon; U/Pbi = uranium lead isochron; ZFT = zircon fission track. Mineral/rock abbreviations: act = actinolite; bi = biotite; ep-bsch = epidote-blueschist; gt-bsch = garnet-blueschist; hbl = hornblende; WM = white mica; wr = whole rock; NaAm = sodic amphibole. Sources: Lee et al. (1964), Coleman and Lanphere (1971), Suppe and Armstrong (1972), Lanphere et al. (1978), Suppe and Foland (1978), Mattinson and Echeverria (1980), McDowell et al. (1984), Blake et al. (1984, 1988), Mattinson (1986), Ross and Sharp (1986, 1988), Wakabayashi and Deino (1989), Elder and Miller (1993), Tagami and Dumitru (1996), Mertz et al. (2001), Catlos and Sorensen (2003), Joesten et al. (2004), Tripathy et al. (2005), Dumitru et al. (2006). tion, much slower than indicated by the models. They suggested that the slow cooling might be evidence for slow subduction rates over that time period. Examination of 40Ar/39Ar ages from Franciscan rocks allow additional insights into this slow cooling hypothesis in the temperature range around the bulk closure temperatures of hornblende (525 ± 50°C) and white mica (400 ± 50°C). Figure 19 is a plot of age versus closure or metamorphic temperature for the oldest Franciscan HP rocks. An overall trend of decreasing temperature with decreasing age is apparent, but the plot exhibits considerable scatter. The scatter could reflect a variety of factors, including different cooling, mineral growth, and recrystal- FRANCISCAN COMPLEX, CALIFORNIA 901 FIG. 19. Plot of age versus temperature for the oldest Franciscan metamorphic rocks. For the 40Ar/39Ar ages, closure temperatures of 525 ± 50°C (Harrison, 1981) were used for hornblende ages where metamorphic (hornblende crystallization) temperatures are estimated to have been higher. For white mica ages from the Willow Spring slab eclogite, a 400 ± 50°C bulk closure temperature for phengite (McDougall and Harrison, 1999) was assigned because the micas were coarse grained and probably crystallized at temperatures exceeding the bulk closure temperature. The phengite bulk closure was also applied for texturally early (pre-rind) white micas from Tiburon Peninsula high-grade blocks (Catlos and Sorensen, 2003), although it is possible that at least some of these phengites grew at temperatures below the bulk closure temperature. For the Ward Creek, Glaucophane Ridge (Diab-4), and Willow Spring slab epidote blueschist (Diab-41) white mica samples, where peak metamorphic temperature estimates are lower than phengite bulk closure temperature, the metamorphic temperature range estimates were used on the plot (see text). For the Skaggs Springs schist and South Fork Mountain Schist samples, we used a temperature range of 250–345°C, reflecting the reduction in bulk closure temperature of white mica owing to fine grain size, as well as maximum metamorphic temperature estimate for the South Fork Mountain Schist (see text). The lack of a plotted uncertainty in age for the Skaggs Spring schist reflects the difficulty in assigning an uncertainty to this model age (see text) rather than a high level of precision. The Mount Hamilton white mica ages of Catlos and Sorensen (2003) are plotted in grey tone because of the possibility that white mica crystallization there reflects late fluid infiltration events at poorly constrained temperatures. We have tried to make the metamorphic temperature estimates as internally consistent as possible, so that temperature estimates reflect the application of the same geothermometers. This led to a slight reduction (300–450°C to 290–400°C) in the assigned temperature of the youngest Anczkiewicz et al. (2004) sample from the Willow Spring slab to match our Willow Spring slab and Ward Creek temperature estimates for similar mineral assemblages. lization histories in different areas, as well as errors in some of the temperatures and age determinations. From hornblende analyses, Ross and Sharp (1988) reported a mean age of 161.1 ± 1.7 Ma from the Antelope Creek garnet amphibolite slab and we obtained ages of 158.9 ± 0.6 from the garnet amphibolite in the Hunters Point shear zone and 156.2 ± 3.4 Ma from the epidote amphibolite in 902 WAKABAYASHI AND DUMITRU McLaren Park (Fig. 19). The ages of these three units are statistically indistinguishable (mean 159.1 ± 1.1 Ma, MSWD 1.11, prob. 0.33). This is consistent with the results of Ross and Sharp (1986), who reported 40Ar/39Ar hornblende plateau ages of 158–162 Ma from widely distributed Franciscan amphibolite localities. From white mica analyses, our Ward Creek sample suggests that, by about 154 Ma, at least part of the Franciscan had cooled to metamorphic temperatures of 290–400°C (Maruyama and Liou, 1988; Oh and Liou, 1990) and Catlos and Sorenson (2003) reported essentially identical mean laser spot ages of 153 ± 2, 154 ± 2, 155 ± 2, and 156 ± 6 Ma from eclogite and garnet amphibolite high-grade blocks at Tiburon. Comparison of these very limited data suggest somewhat more rapid cooling from bulk hornblende closure (525 ± 50°C) to temperatures in the 350 ± 50°C range than suggested by the Lu-Hf ages. However, enough uncertainty exists in ages and temperatures that slow cooling is alternatively permitted. Accordingly, it appears the existing quite limited Franciscan 40Ar/39Ar data set can neither refute nor confirm the slow cooling hypothesis suggested by the Lu-Hf ages. When was the South Fork Mountain Schist metamorphosed? Several dozen argon samples have previously been dated from the South Fork Mountain Schist (Suppe and Armstrong, 1972; Lanphere et al., 1978; McDowell et al., 1984). Because of the extremely fine grain size of these rocks, this work was completed using whole-rock 40Ar/39Ar total fusion methods (not step heating) and whole-rock K-Ar methods. These ages tend to cluster around 120– 125 Ma, but many ages are substantially older or substantially younger (Fig. 18). Because of the limitations of the total fusion 40 Ar/ 39 Ar and K-Ar approaches, it was not possible to assess these samples for excess argon, argon partial loss, or other complications. As discussed above, we have obtained 40Ar/39Ar step heat data from three pure white mica mineral separates from the Tomhead Mountain area. The ages of these samples are statistically indistinguishable and yield a preferred age of 120.5 Ma, which we consider highly reliable. Two of these samples contain moderate excess 40Ar contamination, suggesting that excess 40Ar could explain some of the older whole-rock ages reported previously. Very recently, Dumitru et al. (2006, in prep.) obtained 135 Ma detrital zircon ages from the Tomhead area, requiring that accretion and metamorphism postdate 135 Ma. Therefore, the 120.5 Ma 40Ar/39Ar age may date metamorphic recrystallization of the South Fork Mountain Schist at about 120.5 Ma, or may date cooling following metamorphism that occurred sometime between 135 and 121 Ma. In either case, accretion and metamorphism of the coherent South Fork Mountain Schist definitely post-dates all dated Franciscan high-grade block metamorphism and also the metamorphism of the higher-grade coherent units at Willow Spring and Ward Creek. Interpretation of the Hunters Point shear zone gabbro and Pilarcitos gabbro ages Neither of these rocks exhibits high-P metamorphism, in contrast to the high-grade blocks and the coherent, blueschist-facies rocks. The early metamorphism of these blocks and formation of calcic amphibole, the lack of a strong penetrative fabric, and their gabbro protoliths are consistent with seafloor hydrothermal metamorphism (Wakabayashi, 2004) in contrast to the high-grade blocks, whose high-T metamorphism has been ascribed to inception of subduction in young oceanic crust (Platt, 1975; Wakabayashi, 1990). The late growth of pumpellyite in these gabbro blocks may be related to their subduction history. Accordingly, we interpret the ages from these gabbros as representing the ages of their hydrothermal metamorphism at or near a spreading center. The large uncertainties in the ages discourage further speculation about their tectonic significance. Franciscan metamorphism: Subduction of different units at different times and comparison with other HP terranes The Franciscan Complex is one of the many HP and UHP terranes of the world and, for the majority of such terranes, a narrow age range, or a singular age, of metamorphism is commonly interpreted or sought (e.g., Maruyama et al., 1996). Discussion of the HP or the UHP age (emphasis on the singular) of a given unit implies the expectation that all of the HP and UHP metamorphism of a given terrane occurred at the same time. This, in turn, suggests a tectonic model in which the entire terrane was subducted and then metamorphosed at the same time. In contrast to such models, the collective data from this and earlier studies of Franciscan geochronology strongly indicate that HP metamorphism in the Franciscan took place at different times as a result 903 FRANCISCAN COMPLEX, CALIFORNIA of progressive subduction and deep offscraping/ underplating that spanned tens of millions of years. We do not raise this point to suggest that a “one metamorphic age” assessment of other HP and UHP terranes is wrong, but such a model certainly does not apply to the Franciscan, and this issue may be worth revisiting in some other HP and UHP domains. The span of radiometric metamorphic ages of Franciscan HP rocks is from 169 Ma to about 90 Ma (Fig. 18). In addition, some Franciscan HP rocks lacking radiometric ages have yielded fossil and/or detrital zircon ages as young as about 85 Ma and their metamorphism must post-date these ages (Elder and Miller, 1993; Joesten et al., 2004; Tripathy et al., 2005; Unruh et al., in press) (Fig. 18). This span of metamorphism clearly reflects subduction and HP metamorphism over an extended period of time, rather than a single event and subsequent multiple episodes of fluid infiltration and mineral growth or variable cooling, because the protolith ages for the youngest Franciscan HP rocks are about 85 million years younger than the oldest HP metamorphic ages. Thus the HP rocks now exposed in the Franciscan were metamorphosed over a period of time spanning a minimum of 85 million years and reflect the subduction and HP metamorphism of different units of the subduction complex at different times. The age of metamorphism of the coherent units and, by inference, their incorporation into the subduction complex youngs structurally downward, suggesting progressive offscraping/underplating of units during an extended period of subduction (Wakabayashi, 1992, 1999a). High-grade blocks occupy different structural levels within the Franciscan, including levels beneath coherent units metamorphosed up to 85 million years after high-grade metamorphism. This relationship suggests that tectonic and/or sedimentary processes have moved some of these blocks from their original (peak metamorphic) positions within the subduction complex (Wakabayashi, 1992). On the basis of the lack of a thermal overprint and the continuity of U/Pb zircon ages in the Sierran Batholith, Franciscan subduction is believed to have been continuous (Ernst, 1984; Dumitru, 1991; Wakabayashi, 1992). Whether the subduction accretion process was fairly continuous, or whether it was episodic with some periods of subduction erosion (e.g., von Huene and Scholl, 1991), cannot be discerned from the current metamorphic age data. Acknowledgments This work was partially supported by the Donors of the Petroleum Research Fund of the American Chemical Society (grant 25282-AC2). 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