AN ABSTRP.CT OF THE THESIS ...r Nelson R. Silva-Sandoval for the denree of Oceanography in Title: presented on laster of Science Aur'ust b, l)77 'JATER MASS STRUCTURE AND CIRCULATION OFF SOUTHERN CHILE Redacted for privacy Abstract Redacted for privacy A detailed analysis of the water mass structure and geostrophic circulation off Southern Chile (L3° 63° S, !)l° t! to the Chilean Cer'st; (hereafter called study area) was performed. 1. It was found that: Potential temperature-salinity relations indicate four d.is- tinct structure types north of the Polar Front Zone in the study area, involving seven identifiable water masses. These water masses arc: Subantarctic Water (SAAW), Antarctic Water (flAW), Equatorial Subsurface Water (ESSW), Western Pacific Subsurface Water (WPSSt!) (a new rerional water mass identified in this study), Antarctic Intermediate Water (MIW), Pacific Deep Water (PDW), and Antarctic Bottom Water (M3Y). 2. A scattergram of dissolved oxygen-salinity maximum pairs identifies two distinct subsurface salinity maxima. The subsurface salinity maximum associated with dissolved oxyoen minimum, establishes the presence of the ESSW as a wedge that penetrates to at least The other subsurface salinity maximum which is nonassociated ° S. 'ith dis- solved oxygen minimum, is traced from at least 162° W to as close to the Chilean Coast as 800 W at 43° S. In this study, this water mass is called the Western Pacific Subsurface Water (WPSSW). 3. Acceleration potential on the 26.8k sigma-8 surface relative. to 3000 db, combined with the analysis of 8-S structures distribution and vertical sections of geostrophic velocity relative to 3000 db, show that the Peru-Chile Undercurrent extends as far south as48° S. 4. Significant linear correlation between surface phosphate or nitrate vs. salinity for t.he study area where the salinity ranges be- tween 33 - 34 0/ show that the relatively low nutrient content of the coastal waters (<300 km) mainly results from mixing oceanic waters with waters of the Archipelago system of Southern Chile. explains only 60 - 70 Two point mixing of the nutrient variability; thus, biological and/or chemical processes may also be important causes of therelatively low nutrient concentrationsof the coastal waters. Water Mass Structure and Circulation off Southern Chile by Nelson R. Silva-Sandoval A THESIS submitted to Oregon State University in partial fulfillment of the requirements for the degree of Master of Science Completed August 4, 1977 Comencement June 1978 APPROVED: Redacted for privacy Redacted for privacy in Charge of Major Redacted for privacy ting Den o?JSchóo1 of Oceanography Redacted for privacy Date thesis is presented Typed by Cheryl M. Schurg for August 4, 1977 Nelson R. SilváSandoval ACKNOWLEDGEMErTS Heth and care are more appreciated if they are offered in a foreign country. Dr. Steve ileshyba was always rich in them, willing to be with me during my good as well as my bad moments. my work were cheerfully given to me. was my home. There is no doubt that His advice and comments on His office was my office, his home I am in debt to him forever and I want here to give him my acknowledgement "desde el fondo de ml corazon." Several other professors from the School of Oceanography were always iflflng to help me during my attendance at Oregon State University. I want to thank Dr. !ayne Burt, Dr. Louis Gordon, Dr. Victor Neal, and Dr. Robert Smith. I want my acknowledgement to be extended to my sponsor, Organiza- tion of American States, without whose help my studies at Oregon State University would not have become a reality. I also want to acknowledge the Universidad Catolica de 'falparaiso-Chile which allowed me to take a leave of absence, making possible my attendance at Oregon State University. Finally, my thesis. I want to thank 1rs. Cheryl Schurg for her care in typing She was the hero of the last minute rush. To my wife Rosi To my son Narcelo and my daughter Erika To my country "Chfle Lindo" TABLE OF CONTENTS Page I. II. INTRODUCTION 1 BACKGROUND 3 2.1 2.2 III. 3.2 Cruises and data Methods of data analysis 3.2.1 Water masses 3.2.2 Distribution of properties on slgma8 surfaces 3.2.3 Geostrophic analysis 3.2.14 Choice of level of no motion 14 5 6 8 10 10 10 11 11 14.1 General 13 4.2 4.3 Subantarctic Water Antarctic Water Equatorial Subsurface Water 24 14.14 14.6 Antarctic Intermediate Water 13 214 33 36 WATER MASS STRUCTURE 1i7 General considerations 5.2 Water structures present in the rejion 47 5.1 VI. 14 DESCRIPTION OF WATER MASSES IN THE STUDY AREA 15 Western Pacific Subsurface Water V. 3 DATA AND METHODS 3.1 IV. Water masses and water mass struc ture Geost rophic circulation 2.2.1 West Wind Drift Division at the Chilean Coast 2.2,2 Peru-Chile Undercurrent 2.2.3 Flow at intermediate, deep and bottom levels 147 GEOSTROPHIC CIRCULATION 6.1 6.2 6.3 6,4 General Flow on Flow on Flow on considerations the sea surface the 26.814 sigma-8 surface the 27.12 sigma-e surface 56 56 58 61 TABLE OF CONTEFITS (Continued) Page 65 Flow In vertical sections The coastal flow Identification of the subsurface coastal flow with the Peru-Chile Undercurrent 6.5.3 Geostrophic flow south of 48° S Geostrophic circulation and water mass structure 6.5.1 6.5.2 6.6 VII. CONCLUDING REI1ARKS BIBLIOGRAPHY 63 63 70 73 74 78 80 LIST OF TABLES Table Page Water mass constituents of e-s structures present in the area north of the Polar Front Zone. LIST OF FIGURES Page Figure The study area, showing locations of SCORPIO (s) 1967 and PIQUERO (P) 1969 oceanographic stations. Letters Pt - F define vertical sections. 2 3 4 5 6 7 8 e-s diagrams of representative stations showing the different water masses present. In the study Depth of the base of seasonal thermocline area. is indicated by stars. 10 15 Salinity distribution on the sea surface, from the SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions. 17 Dissolved oxygen distribution on the sea surface, from the SCORPIO (A) 1967 and PIQUERO (0) 1969 Expeditions. 18 Phosphate distribution on the sea surface, from the SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions. 19 flitrate distribution on the sea surface, from the SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions. 20 Regression of surface phosphate or nitrate with salinity for surface waters of salinity range 34°/, from the SCORPIO 1967 andPIQUERO 1969 Regression equation and correlation Expeditions. coefficient r2 are given. 22 Silicate distribution on the sea surface, from the SCORPIO (A) 1967 and P1QUERO (c,) 1969 Expeditions. 23 Bathymetry in meters of the 26.84 sigma-8 surface, from SCORPIO (A) 1967 and PIQUERO (°) 1969 Expeditions. 11 12 14 Temperature distribution on the sea surface, from the SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions; PFZ marks the Polar Front Zone. 33 9 9 Potential temperature distribution on the 26.84 sigma-8 surface, from SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions. 25 26 Salinity dIstribution on the 26.814 sigma-8 surface, from SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions. 28 LIST OF FIGURES (Continued) Figure 13 14 Page Dissolved oxygen distribution on the 26.81i sigma-B surface, from SCORPIO (A) 1967 and PIQUERO (°) 1969 Expeditions, Phosphate distribution on the 26.84 sigma-B surface, from SCORPIO (A) 1967 and PIQUERO (°) 1969 Expeditions. 15 17 18 19 20 21 30 Nitrate distribution on the 26.84 sigma-B surface, from SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions. 16 29 31 Silicate distribution on the 26.84 sigma-B surface, from SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions, 32 Dissolved oxygen vs. subsurface salinity maximum showing the separate groups of O2_Smax pairs corresponding to two different water masses, from stations north of 55° S of the SCORPIO (5) 1967 and PIQUERO (P) 1969 Expeditions. 34 Superposition of 9-S diagrams along 43° S from 169° W to the Chilean Coast from selected stations.. of SCORPIO 1967, Stars indicate the depth of the base of the seasonal thermocline. 35 Bathymetry in meters of the 27.12 sigma-B surface, from the SCORPIO (A) 1967 and PIQUERO (e) 1969 Expeditions. 37 Potential temperature distribution on the 27.12 sigma-B surface, from the SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions. 38 Salinity distribution on the 27.12 sigma-B surface, from the SCORPIO (A) 1967 and PIQUERO (0) 1969 Expeditions. 39 22 Dissolved oxygen distribution on the 27.12 sigma-B surface, from the SCORPIO (A) 1967 and PIQUERO () 1969 Expeditions. 23 Phosphate distribution on the 27.12 sigma-B surface, from the SCORPIO (A) 1967 and PIQUERO (°) 1969 Expeditions. 42 LIST OF FIGURES (Continued) Figure Page 24 Nitrate distribution on the 27.12 sigma-8 surface, from the SCORPIO (A) 1967 and PIQUERO () 1969 Expeditions, 25 Silicate distribution on the 27.12 sigma-8 surface, from the SCORPIO (A) 1967 and PIQUERO (°) 1969 Expeditions. 26 27 28 29 30 31 32 33 34 Representative stations showing StructureType 44 I from the SCORPIO (s) 1967 and PIQUERO (P) 1969 Expeditions. Stars indicate depths of the base of the seasonal thermocline. 47 Representative stations showing Structure Type II from the SCORPIO (s) 1967 Expedition. Stars indicate depth of the base of the seasonal thermocline. 48 Representative stations showing Structure Type III from the PIQUERO (P) 1969 Expedition. Stars indicate depth of the base of the seasonal thermocline. 49 Representative stations showing Structure Type IV from the PIQUERO (P) 1969 Expedition. Stars mdi'cate depth of the base of the seasonal thermocline. 50 Distribution of 8-S Structure Types north of the Polar Front Zone for the SCORPIO 1967 and PIQUERO 1969 stations in the study area. 51 0-S diagram of the SCORPIO station 5-72 showing the presence of two weak subsurface salinitymaxima at 251 and 399 m. The star marks the base of the seasonal thermocline. 55 DynamIc topography of the sea surface relative to 3000 db, from SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions, 57 Acceleration potential on the 26.84 sigma-8 surface relative to 3000 db, from SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions. 60 Acceleration potential on the 27.12 sigma-B surface relative to 3000 db, from SCORPIO (A) 1967 and PIQUERO (a) 1969 Expeditions. 62 LIST OF FIGURES (Continued) Figure 35 Page Geostrophic velocity relative to 3000 db at section Positive values A, from SCORPIO 1967 Expedition. indicate northward flow; negative values indicate Solid horizontal lines represent southward flow. the potential density at which the cores of ESSW (26.84), WPSSW (27.06) and AAIW (27.12) are found; dashed line is the base of the seasonal thermocline (BsT), 36 37 38 39 40 61+ Geostrophic velocity relative to 3000 db at section B, from PIQUE.RO 1969 Expedition. Positive values indicat.e northward flow; negative values indicate Solid horizontal lines represent southward flow. the potential density at which the cores of ESSW (26.84) and AAIW (27.12) are found; dashed line is the base of the seasonal thermocline (BST). 65 Geostrophic velocity relative to 3000 db at section C, from PIQUERO 1969 Expedition. Positive values indicate northward flow; negative values indicate Solid horizontal lines represent the southward flow. potential density at which the core of AAIt4 (27.12) is found; dashed line is the base of the seasonal thermocline (BST). 66 Geostrophic velocity relative to 3000 db at section D, from PIQUERO 1969 Expedition. Positive values indicate northward flow; negative values indicate Solid horizontal lines represent southward flow, the potential density at which the cores of ESSW (26,81+) and AAId (27.12) are found; dashed line is the base of the seasonal therrnocline (BST). 67 Geostrophic velocity relative to 3000 db at section E, from PIQUERO 1969 ExpeditIon. Positive values indicate eastward flow; negative values indicate Solid horizontal lines represent the westward flow. potential density at which the cores of ESSW (26.84) and AAIW (27.12) are found; dashed line is the base of the seasonal thermocline (BST). 68 Geostrophic velocity relative to 3000 db at section Positive values F, from PIQUERO 1969 Expedition. indicate eastward flow; negative values indicate westward flow. Solid horizontal lines represent the potential density at which the cores of ESSW (26.81+) and AAIW (27.12) are found; dashed line is the base of the seasonal thermocline (BST). 69 LIST OF FIGURES (Continued) Figure 41 Page Composite of oceanographic sections showing approximate positions and geostrophic velocities of the core of the Peru-Chile Undercurrent based on STEP 1960 (Wooster and Gilmartin, 1961), MARCHILE VIII 1972 (Sievers and Silva, 1975), SCORPIO 1967 (this study) and PIQUERO 1969 (this study) Expeditions. Respective reference levels are given in the text. 71 Geostrophic velocity profile relative to 2500 db for PIQUERO 1969 stations pairs P-149 P50 and P-50 P-51. Positive values indicate northward flow, negative values indicate southward flow. 72 8-S dia,ram of station P-19. The segment between 714 and 1535 m resembles a structure type IV, while the whole structure corresponds to structure type III. Star marks the base of the seasonal thermocline. 76 I 42 43, WATER MASS STRUCTURE AND CIRCULATION OFF SOUTHERN CHILE I. INTRODUCTION The details of water mass structure anc! circulation of the southernmost extreme of the Eastern Pacific Ocean are poorly known. This area, off Chile, between 350 S and 550 S and east of 900 W, has been included in several studies of circulation and water masses (Gunther, 1936; Reid, 1961; Reid and Arthur, 1975; Warren, 1970, and Wyrtki, 1975). Only the gross characteristics of the regional waters were described because of the large scale geographic ranges of these papers. More specifically, little attention has been paid to a unique feature of this region, namely, that it is the only southern hemisphere coastline where the West Wind Drift (WWD) reaches a solid continental barrier. There is a clear need for improvement of our knowledge of the region. If an inventory of oceanographic expeditions in the area Is performed, a striking reality becomes apparent: even though several cruises have sampled the region there is a great variety in depth of maximum sampling, variables measured and degree of synopticity. Only two major oceanographic cruises have produced a good coverage of the area in the sense of a dense sampling grid. These are the PIQUERO Leg III 1969 (S.I.O., 197k) and the R/V Professor DERYUGIN 1968 (Mamayev, 1973). Neither of these cover the total area off southern Chile, and only PIQUERO Leg III has stations closer than 200 nautical miles to the coast and complete water column sampling. A composite data base of these PIQUERO data plus the 1967 SCORPIO Expedition (s.i.O., 1969) covering from 430 to 63° S and from the coast to 91° W, hereafter called the study area, form the basis for the analysis and results presented in this study. The present study examines the water mass structure present in the water column off southern Chile. It also analyzes the horizontal dis- tribution of physical and chemical characteristics of the Subantarctic Water, Antarctic Water, Equatorial Subsurface Water, Western Pacific Subsurface Water, and Antarctic Intermediate Water. The Western Pacific Subsurface Water is presented as a water mass carried eastward into the area of study by advective processes. This study also treats the geostrophic velocity patterns of this extreme Southeastern Pacific area on vertical and horizontal sections. The southernmost extension of the Peru-Chile Undercurrent is established from a chart of acceleration potential on the 26.84 isopycnal, combined with the analysis of the 8-S structure distribution and vertical sections of geostrophic velocity relative to 3000 db, 3 I I, 2.1 BACKGROUND Water masses and water mass structure The water masses present in the study area have been described in general by authors such as Sverdrup etaL (1942) and Defant (1961). A more detailed study of the distribution, of the water mass characteristics in. the Southern Hemisphere has been done by Taft (1963). He des- cribed the distribution of properties using isentropic analysis on the isanosteres of 125, 100, 80 and 60 cl/ton. Detailed studies of water mass distributions and their characteristics off the Chilean Coast have been prepared by Gunther (1936), Wyrtki (1966; 1967), Brandhorst (1971), Robles etal. (1974), Sievers and Silva (1975), and Silva and Konow (1975). Nevertheless, none of these papers covered the area south of 43° S. Reid (1965) performed an analysis of the Antarctic Intermediate Water distribution in the Pacific Ocean. He also made use of isentropic analysis showing the intermediate water mass distribution and its geostrophic flow on the 80 cl/ton isanostere. The distribution of properties of the Pacific Deep Water (Common Water) (1972). in the Southern Hemisphere south of 40° S was studied by Callahan He also used isentropic analysis, selecting for this purpose the isanosteres of 50 and 30 cl/ton. A detailed analysis of the vertical water mass structure in the Eastern South Pacific was done by Mamayev (1973). He discussed the dif- ferent i-S structures present in the area and elaborated a rather complex classification. Mamayev (1973) described two i-S structure types, one subtype and two transient types for the area between 30° 53° S and 4 800 W - 109° W. Based on his classification system, he presented a 1-S structure distribution chart. 2.2 Geostrophic circulation The geostrophic circulation of the southern part of the Eastern South Pacific Ocean (south of 350 s) has not been described in as much detail as has been done off Peru (Wooster and Gilmartin, 1961; Wyrtkl, 1963; and Zuta and Guillen, 1970), or off northern Chile (Brandhorst, 1971; Robles etal., 1974; and Sievers and Silva, 1975). Nevertheless, this area has been included in several general circulation studies, for instance, by Reid (1961, 1965, 1967b), Wooster and Reid (1963), Warren (1970), Reid arid Arthur (1975), and Wyrtki (1975). West Wind Drift - Division at the Chilean Coast 2.2.1 One of the most outstanding features in the circulation pattern in this area, is the bifurcation of the WWD off southern Chile. The fact that the WWD impinges the South American Continent and divides into a northward and southward branch has been known for a long time, Perez- Ros.ales is cited by Gunther (1936) to have reported in 1857 some thermal observations relative to the characteristics of the Cape Horn Current and the Peru Coastal Current at their commencement off the coast of Chile, Gunther (1936) also cites the textbooks of Hoffmann in 1884 and Somerville In 1923 as describing the WWD division at 4Q0 branches in "the Cape Horn Current flowing to the south S into two the Peru or Humboldt Current to the north." Charts of Pacific Ocean Currents based on ship drift including the area where the WWD reaches the South American Continent have been pre- 5 sented by authors such as Sverdrup etal. (19142) and Defant (1961). These charts present the WWD approaching the coast from the t4-SW and impinging at about 15° S. The geostrophic circulation of the sea surface relative to 1000 db prepared by Reid (1961), shows in a broad way the WWD impingement at 430 of 9Q0 W) from the W-NW. S but with a final approach to the coast (east Wyrtki's (1975) sea surface mean annual dyna- mic topography relative to 1000 db showed a final W-NW flow direction in a fashion similar to that of Reid's (1961). Sandoval (1971) has pre- pared a chart of the sea surface dynamic topography relative to 500 db for the Eastern Pacific Ocean (00 be observed also. 470 s) where this W-NW direction can Nevertheless, some geostrophic velocities inferred from his chart are doubtful (for example 168 cm/sec at 1470 S and 78° w). Silva and Neshyba (1977) prepared a sea surface dynamic chart relative to 500 db using available austral summer data in the region 35° - 56° S, east of 91° W. They found that the W1IID has a final approach from the W-NW reaching the coast off Chiloe Island N 1420 s). They also describe an apparent correlation between the dynamic flow and the bathymetry of the Chile Ridge. 2,2,2 Peru-Chile Undercurrent The presence of a subsurface poleward flow close to the Chilean Coast-was first described by Gunther (1936). He based his description on the temperature, salinity and oxygen distributions. Wooster and Gilmartin (1961) further describe the poleward subsurface flow between 6° S and 2140 S using both vertica.l sections of geostrophic flow relative to 1000 db and a set of direct measurements by drogues. They further proposed that this flow, which they called the Peru-Chile Undercurrent, should extend at least as far as 41° S, using as a basis a set of north south (along coast) vertical sections of salinity and oxygen. A dynamic topography chart on 200/1000 db was prepared by Wooster and Reid (1963) to analyze the poleward currents in the Eastern Pacific This chart shows the extension of a poleward subsurface flow Ocean. along the Chilean Coast as far south as 40° S. Brandhorst (1971), using isentropic analysis on the 150 and 140 cl/ton isanosteres, described the extension of the Peru-Chile Undercurrent as far as 42° S. He based his results on the distribution of properties of the Equatorial Subsurface Water, rather than geostrophic computations. Vertical sections of geostrophic velocity relative to 1000 db at 24° S and 28° S off the coast of Chile prepared by Sievers and Silva (1975), also show the Peru-Chile Undercurrent. and 5 Flow magnitudes were 10 cm/sec, respectively, which are compatible with those of Wooster and Gilmartin (1961) off Peru. 2.2.3 Flow of intermediate, deep, and bottom levels Dynamic topography charts at intermediate levels have also been prepared by Reid (1965) and by Johnson (1972). The first author des- cribed the Antarctic Intermediate Water flow along the 80 cl/ton isanostere (sigma-t 27.29), while the second showed this. flow along the 27.1 isopycnal. Johnson (1972) showed a general northward flow of the Antarctic Intermediate Water along the Chilean Coast. In Reid's (1965) chart, the situation is not very well defined due to the scarcity of data. Relative to the deep water circulation, Callahan (1972) proposed a deep southward flow along the coast of Chile which carries oxygen poor 7 waters to the Antarctic. This low oxygen water joints the Antarctic Circumpolar Current west of the Drake Passage, flowing through it to the South Atlantic. The dynamic topography maps at 2000/3000 db and 2500/3500 db prepared by Reid and Arthur (1975) are in agreement with Callahan's (1972) proposed flow. The bottom circulation in the Bellinghausen Basin was described by Gordon (1966) based on potential temperature, salinity and oxygen distributions, He pointed out that the flow velocity in the basin is probably moderate in the western (east of East Pacific Ridge) and northern (south of Chile Ridge) sections and weak in its eastern branch (along Southern Chi1e) I I. 3.1 DATA AND METHODS Cruises and data The Leg III of PIQUERO Expedition took place off the southern coast of Chile during January 13 to February 16, 1969. The cruise occupied 51 oceanographic stations including the development of seven current meter arrays in the Drake Passage. Only 43 of these stations were con- sidered in the present study; 8 coastal stations from 40 to omitted because. they lacked nutrient data. 550 S were The 43 PIQUERO stations selected covered the area between 1+5 to 63° S, 91° W to the coast of Chile and they are shown in Figure 1. The current meter data have been analyzed by Reid and NowlIn (1971), and part of their results have been included in the interpretation of the geostrophic velocity profiles. Eleven of the easternmost stations of the section along /+30 S (deeper than 2000 m) of the SCORPIO Expedition (April 30 to May 8, 1967), were added to the PIQUERO Leg III statIon grid to obtain a better coverage to the north (Figure 1). This composite permits construction. of smooth connections between the hydrosections of the two cruises when contours of the different variables are traced, even though the cruises are separated in time by two years and were taken in different seasons (austral summer for PIQUERO and austral autumn for SCORPIO). Additional SCORPIO stations toward the west along 13° S at 93°, lO14, 116°, 127°, 139°, 150°, 162° and 169° W, were used in the analysis of the Western Pacific Subsurface Water Mass. The basic data from both cruises consist in observations of temperature, salinity, dissolved oxygen, and nutrients. Descriptions of the methods and data have been presented in dat.a reports (S.I.O., 1969 900 850 80° 70° 75° 65°W 4 0°S A A SCORPIO f31 4 -S-66 S-68 S-70 j 0 PIQUERO 5-73 S-76 450 000 p-SI P-49 S 0 000 0 0 P P-L5 P-41 500 0' C :° 0 550 0 P35 cc' p37 0 °P-30 P-29 p39 D 0 P-28 oP-18 P-27 P-26 p-g E P-25 op-j °P-20 OP-14 op-21 0 60° oP16 F op-22 op-J3 P-U op-23 P-lb P-Jo . P-9° 1 Figure 1. _____ iii. The study area, showing locations of SCORPIO (s) 1967 and PIQUERO (P) 1969 oceanographic stations. Letters A - F define vertical sections. 10 for SCORPIO and S.I.0., 1971f for PIQUERO), To analyze relationships between horizontal surface mixing and nutrient distribution in coastal. water off Chile, additional data were incorporated from the HUDSON 70 Expedition. These data consist mainly in observaflons of tel nperature, salinity, and dissolved oxygen in the Chilean Archipelago. Some HUDSON 70 oceanographic stations did have additional phosphate, nitrate, and silicate observations (CSS HUDSON, 1970). 3.2 Methods of data analysis Water masses 3.2.1 Water masses were identified using diagrams of potential temperature (0) versus salinity (s) (Helland-Hansen, 1916). The movement or distribution of water masses was studied using Wust's (1935) core method. An additional technique employed to dlsriminate between water masses used oxygen (02) versus S values of 0 values at which they occurred. with the S 2 plots to correlate the specific It will be max shown later this technique provides the basis for identification of the Western Pacific Subsurface Water (wpssw) in the study area. Linear re- gressions of phosphate and nitrate versus salinity were used to examine relationshIps between horizontal surface mixing and nutrient distribut i on. 3.2.2 Distribution of properties on sigma8 surfaces The distribution of water mass properties along surfaces of con- stant potential density is an established method of analyzing horizon- tal advection and mixing (Montaomery, 1937; and Sverdrupetal., 1942), The selection of specific isopycnal surfaces for this purpose involved calculating the averages of the density values associated with salinity maxima or minima, for the PIQUERO and SCORPIO stations within the study A mean sigma-O value of 26.8 area, was obtained for Equatorial Sub- surface Water (ESSW), whfle 27.12 defined Antarctic Intermediate Water (AAIW). Geostrophic analysis 3.2.3 Geostrophic flow patterns at intermediate levels were inferred from distribution of acceleration potential along the Isentropic surfaces described above. On the sea surface, where a specific isopycnal cannot be defined, the horizontal flow pattern was inferred from sea surface dynamic topography computed relative to 3000 db. Vertical sec- tions of geostrophic velocity relative to 3000 db were prepared to complement the information given by horizontal charts of dynamic topography and acceleration potential. Choice of level of no motion 3.2.4 The choice of the level of 3000 db level as a no motion for the computation of the geostrophic velocities is a key decision in this method, In strongly stratified waters, the level of no motion is found at a shallower depth than in more nearly stratified waters (Neumann, 1968), In high latitudes, such as found around the Antarctic Continent, the weakly stratified waters will show a very deep level of no motion. Gordon (1966), for example, indicated that a level of no motion does not exist for zonal flow in the northern and western Drake Passage. He also points out that the level of no motion in the Drake Passage slopes 12 steeply down toward the north, reaching the bottom about half way across the passage. Cabrera-Muro (1977), using the method of Defant (1961), did not find a level of no motion at high latitudes in the South Pacific due to the lack of stratification. Johnson (1972) selected a depth of 2500 m as a level of no motion based on: "the Pacific Deep Water (PDW) considered to be moving gener- ally south, and the AAIW moving north, would have a point of flow re- versal (or level of no motion) between them" Reid (1961, 1965, 1973b), and Reid and Arthur (1975), have used 1000, 2000, 3000, 3500, or 4000 db, as a reference level depending upon the actual value of the feature which they are discussing. Computations of the level of no motion at different latitudes using PIQUERO-SCORPIG data, also leadto similar conclusions to those of Gordon's (1966) and Cabrera-Muro's (1977). South of 550 S, Defant's (1961) method did not indicate the presence of a level of no motion in the water column. Since the study area includes stations where a level of no motion does not exist, or at least can not be defined with Defant's method, an arbitrary depth of 3000 m was selected as a reference level for dynamic computations. The choice of 3000 db was based on: one reference level satisfies the total area Included; (1) No (2) Flow at great- er depths is usually considered to be weaker than at shallower depths; (3) 3000 db is the deepest common standard depth for most of the stations used here; and (4) It is desirable to compare these results with those of Reid and Nowlin (1961) from the PIflUERO data across the Drake Passage Stat ions P-9, 16, 31, 50, 51 and S-69 were not used in this analysis since depths were less than 3000 m. 13 DESCRIPTION OF WATER MASSES IN THE STUDY AREA Iv, ,+.1 General An analysis of all the B-S diagrams for the study area reveals the presence of seven distinct water masses at depths below the seasonal thermocline. These water masses are shown in Figure 2. They are the Subantarctic Water (SAAW) , Antarctic Water (AAw) , Equatorial Subsurface Water (ESSW), Western Pacific Subsurface Water (WPSSW), Antarctic Intermediate Water (AAIW), Pacific Deep Water (PDW), and Antarctic Bottom Water (AABW). Descriptions of the temperature, salinity, dissolved oxygen and nutrient contents of these surface, subsurface, and intermediate waters The deep and bottom water masses, PDW and AABW, are given below. rexpectively, are not described in detail here because the characteris- tics of these deeper waters do not change appreciably over the study area and they already have been described by Gordon Lynn. (1971), and Callahan. (1972). (1966), Reid and The description of the Subantarctic Water includes a discussion of the influence of estuarine waters of the Chilean Coast. The Western Pacific Subsurface Water i.s discussed in detail because this is a new water mass. designation for this region which has resulted from the water mass structure analysis presented in this study. 1,2 Subantarctic Water The SAAW occupies the surface layer in the whole area of study, north of the Polar Front Zone. tribution (Figure As a surface water, its temperature dis- is dominated by the influence of seasonal varia- 14 15° S-76 S-66 P-24 SAAW lro 26.0 ESSW 2 o o . cD SAAWL 1 5° 8 * .2 w.Pssw AAIW sPDW AA\' 8 J PAAB.W I I. 34.5 %0 34.00/oo coI Ioo Figure 2. 8-s diagrams of reprseritative stations showing the different water masses present in the study area. Depth of the base of seasonal thermocline is indicated by stars. 15 850 90° 800 750 65°W 700 40° A \A A A - 13 4 5C - 13 12 A AA \.. 8 S 5 0 T I 0 0 0 PFZ(3-2 6 Q( T"C Oj 1-I 0 0 Figure 3. Temperature distribution on the sea surface, from the SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions; PFZ marks the Polar Front Zone. 16 tions of solar heating. Since the data was taken during summer and early fall, a seasonal therrnocline was present in the thermal structure. Close to the Chilean coast, relatively low surface salinities are present (Figure 1+). than 31L0 Reid (1969) showed surface waters of salinity less extended as far as 1000 W at i0° S. Figure 4 shows that t.he lowest values, less than 33.69, are located along the coast; these apparently result from coastal runoff. Pickard (1971, 1973), using data from the HUDSON 70 Expedition, demonstrated increasing salinity trends from fresher inside waters of the Chilean fjord region to the oceanic waters offshore. Since the SAAW is in the surface layer, its dissolved oxygen is high (Figure 5). The dissolved oxygen increases towards the Antarctic as a result of the increase in oxygen solubility with decreasing tem- perature, hence the direct correlation between the patterns of isotherm and iso-oxygen contours. Surface phosphate and nitrate values decrease toward the coast, with the lowest values off the Chonos Archipelago (' and 7). 1450 s) (Figures 6 These low values might be explanable as. depletion of phoshate and nitrate from surface waters by phytoplankton and/or mixing of oceanic waters with comparatively lower nutrient estuarine waters.. The first explanation implies that the lowering of phosphate and nitrate would be independent of salinity. The second, on the other hand, would require a covariation between salinity and nutrient content consistent with a two point mixing process. Phosphate and nitrate observations in some of the Chilean fjords and adjacent coastal waters were also made by the HUDSON 70 E.xpediton (CSS HUDSON, 1970). Even though the surface 17 750 800 85° 65°W 700 400 S :. - t t t i b /A33.6 450 33.9 g 33.06 V.. 33.7 500 311 550 0 >34.1 \ 0 0 600 33.9-___ ,9%o 0 - >33.9g. 0 L I Figure i . II .1 I I III It 1 I#i( Salinity distribution on the sea surface, from the SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions. 18 900 800 85° 7 7S 65°W 40 OC 6.0 6.0 6.0 /Jl : 45° :46.t 000. p 000 0 0 0 _---6.S' 5Q0 0 0 - 0 0 0 0 550 00 0 : : 60° 8.0. 0 I I Figure 5. i t . I t i i t I t i i i I i...i t I I t t c Dissolved oxygen distribution on the sea surface, from the SCORPIO (A) 1967 and HQUERO (o) 1969 Expeditions. 19 no qio f0 B5°W 4005 ( - ) /1 L5° - - ,/o10;01 500 ff 0 ((.° \'' 0 550 0 - - - 0 - 0 0 0 0 [!ii POpmoI/! 1.8 1 Figure 6. I I I I LI Ii i I I I t ILc Phosphate distribution on the sea surface, from the SCORPIO (a). 1967 and PIQUERO (o) 1969 ExpeditionS. 20 750 800 85° 700 65°W 4 0°S I A A 6423 A 450 8 4\ ;;' @1 550 0 N - - - - - 60° NO3pmo///' 222L ititi Figure 7. Nitrate distribution on the sea surface, from the SCORP0 () 1967 and PIQUERO (°) 1969 Expeditions. 21 data is highly variable ( pmol/l 0-1 1.3 iimol/I in phosphate, 0 - 14 in nitrate), comparatively Tower phosphate and nitrate contents are the general trend observed in the estuarine region relative to the adjacent coastal waters. Plots of surface phosphate and nitrate vs. salinity show a significant direct linear correlation at the 99 confi- dence level (Figure 8), for the study area where the salinity ranges between 33 3'+°/ (Figure 4) . This dependency supports the second explanation, that is, the low phosphate and nitrate values close to the coast seem to be caused principally by a mixing process between oceanic and estuarine waters. Because of the r2 values (Figure 8), only 7l of the phosphate and 65? of the nitrate variability can be explained by means of the respective linear regressions. Therefore, the biological and/or chemical processes could also account for an important fraction of the observed nutrient variability. The surface silicate content of the SAM in the study area is zero with some exception where the silicate reaches 1-2 pmol/1 (Figure 9). Surface silicate measured by the HUDSON 70 Expedition in the fjord area shows highly variable silicate content (z 1 113 pmolIl). Neverthe- less, it generally shows relatively high values at the heads of the fjords with decreasing values toward the ocean. The above discussion of coastal surface nutrients is general be- cause the data are Hmited. More work should be done on these coastal waters to answer some questions such as: How important are the phos- phate and nitrate depletions by primary producers in this area? How is the high silicate estuarine water, generally present at the head of the estuary, depleted before it reaches the ocean? Biologically? Geo- 15 NO-4 57.3+13.8 S o/ PO =-25.6+O.78S°/.o r2 0.65 J r2O.71 .7 . . 1.0 iii: 1 -a 0 E Icy, III 0 z 0 .. 5 0.5 1 1 33.0 33.5 eol .? 100 Figure 8. 34.0 33.0 33.5 34.0 eo/ . /00 Regression of surface phosphate or nitrate with salinity for surface waters of salinity range 33 -. 34°/oc,, from t.he SCORPIO 1967 and NQUERO 1969 ExRegression equation and correlation coefficient r2 are given. peditions. NJ N.J 23 00 85° 700 75° 80° 65°W 400 S >0>O >0 A A A A\yA A13 0 450 000 0 0 0 0 : . 50° 5",, 0 00 550 0 -4' 0 0 0 0 0 0 0 0 0 00 600 0 5 .._.io 0 I I..' 2525 0 25 <25 0 25 F SiQyrno/// I Figure 9. I I t t Silicate distribution on the sea surface, from the SCORPIO (A) 196] and PQUERO (o) 1969 Expeditions. 24 chemically? Both? L3 Antarctic Water Because of the Polar Front Zone location and the station distribu- tion, only five stations are situated within the Antarctic zone (P-9 to P-13). The vertical temperature structure of the MW is character- ized by a temperature minimum localized at 100 - 150 m, which reaches its lowest value of -1.13° C at station P-JO. The Antarctic surface salinity is lower than that of the Subantarctic zone (Figure If), which is probably the result of ice melting during the summer (Gordon etal., 1977). Due to the low temperatures (Figure 3), the oxygen solubility in this area is higher than that in the Subantarctic. This results in an increase in dissolved oxygen in the MW (Figure 5). The phosphate, nitrate and silicate content in the AAW are relatively high. values above 1.4 prnolfl Surface in phosphate, 18 pmol/1 in nitrate and 15 mo1/l in silicate are observed (Figures 6 to 8). 4I4 Equatorial Subsurface Water Within the study area, the core of the ESSW is characterized by a salinity maximum, an oxygen minimum, a nutrient maximum and a sigma-e of 26.84. The sigma-e surface is deeper along the coast and in the north- ern portion of the study area (Figure 10). It slopes gently upward to- ward the South, intersecting the sea surface at about 58° S. The potential temperature on the 26.84 isopycnaI varies from 60 C to 8°C, with its maximum values off Chiloe Island ( 43° s) (Figure 11). Temperature inversions of the order of 0.1° C above the ESSW salinity maximum are present at stations P-48 and P-I9; similar inversions have 25 850 750 80° 700 65°W 1. O°S A A A A A A\A 44 '-% 250 450 0 0 500 N 200 00 0 o o 't I 150 I ' I ) '. 0 0 100 \ 0 0 0 0 55° $50 00 600 0 Figure 10. Bathyrnetry in meters of the 26.8 sigma-9 surface, from SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions. 26 900 800 85° 7Q0 75 4 QOC >6.5 450 \000 - 6.5 0 0 0 0 500 8.OR a A 7.0 o 0 0 .1 -.. 1.v o ' <6.5 0 ': ' ef- 0 .._o0 0 550 0 ,o \ >6.5 '0' : f 0 v0 .. 0 0 0 00 1 0 eec Figure H. Potential temperature distribution on the 26.8k sigma-9 surface, from SCORPIO (A) '1967 and PIQUERO (o) 1969 Expeditions. 2.7 been described for the ESSW north of 34° S by Silva and Sievers (1974) an.d Sievers and Silva (1975). The description of "warm water" as a characteristic of the ESSW was first given by Gunther (1936). The salinity distribution on the 26.84 isopycnal shows a maximum in the NE portion of the region (Figure 12). The salinity decreases to- wards the south due to mixing with the less saline SAAW and AAIW. of 50° S the ESS South salinity maximum can not be identified. The oxygen content shows a distribution similar to that of the salinity and temperature but exhibits a minimum instead of a maximum (Figure 13) . The lowest values appear near the coast and in the north- ern portion of the study area. Values as low as 1.35 ml/1 were present at 223 m (sigma-e = 26.78) at station S-76. The low oxygen content (<5.0 mill) persist to 52° S; this is a little farther south than the saHnity maximum. The phosphate, nitrate and silicate Content of the ESSW show relatively high values close to the coast and towards the north (Figures 14 to 16). Silva and Konow (1975) have shown that the ESSW nutrient con- tent off the coast of Chile is characterized by a maximum only south of 25° S. This maximum content in the vertical structure originates be- cause of the comparatively lower nutrient values of the 5MW above and the AAIW underneath the ESSW. 25 pmol/l Values of 1,8 pmol/l in phosphate and in nitrate in the maximum persist as far as 52° S. The low oxygen content, high salinity and nutrients are remnant features of the highly oxygen depleted and nutrient enriched waters brought to the south by the poleward Peru-Chile Undercurrent from the eastern tropical areas. 28 00 850 80° 75° 700 65°W LU °S A A A A U & t A\A A 450 36.2 00 o 0 000 500 362° 550 <34.1 0 60° Figure 12. Salinity distribution on the 26.81-i.sigma-O surface, from SCORPIO (A) 1967 and PIQUERO (°) 1969 Expeditions. 29 850 7Q0 750 800 65°W £0°S A A!%A A6 - .-... 5.5_'. 450 lJt r I' \ 5Q0 - 0%:::\ 0 0 550 0 \ 0 >6$ 0 0 [eJJ 02m1/l Figure 13. Dissolved oxygen distribution on the 26.84 sigmaO surface, from SCORPIO (A) 1967 and PIQ.UERO (0) 1969 Expeditions - 30 85° 800 75° 700 65°W 4 0°S 450 5Q0 1.6 ° 0 55° 0\ 1' 600 PO4pmo//I Hgure 1-i. Phosphate distribution on the 26.8k sigrna-E3 surface, from SCORHO (A) Expeditions. 967 and PQUERO () 1969 31 10° 85° 80° 75° 700 65°W 4 0°S I 450 50° ° :To: 55° 600 NOJJmoI/I Figure 15. Nitrate distribution on the 26.84 sigma-8 surface, from SCORPIO (A) 1967 and PIQUERO () 1969 Expedluons. 32 800 85° 75° 70° 65° W. L0°S 203 L5° 010 \ " I 15 10 0 E.] 500 5' 0 550 0., 0 0 0 0 0 0 0 0 0 60° Sf02 pmol// Figure 16. Silicate distribution on the 26.81k signi-A surface, from SCORPIO () 1967 and PIQUERO (°) 1969 Expeditions. 33 14.5 Western Pacific Subsurface Water From the B-S diagrams of stations S-66 and S-76 (Figure 2), it can be seen that the small subsurface salinity maximum in station s-66 is a remnant of the major one present in S-76. A superposition of 0-S dia- grams from S-76 towards S-66 (not shown) indicates that this subsurface maximum decreases in intensity westward. ward extension of the ESSW. This would indicate a west- However, some characteristics of the ESSW such as the low oxygen content do not seem to support this interpreta.tion. A plot of the oxygen content. vs. subsurface salinity maximum, for th.ose stations north of 550 S, shows that the 02-S pairs tend to form two groups (Figu.re 17). One group is associated with a high oxygen content (>1k ml/i) and the other with lower oxygen content (<1 mill), The existence of these distinct of clUsters in the 0 2 vs. S max plot in- dicates the presence of two different water masses. A superposition of 0-S diagrams taken from the SCORPIO Expedition (section at 13° s) (S.I.O.,, 1969) from S-30 (169° w) to S-75 (76° w) shows that a subsurface salinity maximum can be traced as far as S70 at 82° 14. It is proposed that this water mass, which is characterized by a subsurface salinity maximum not associated with an oxygen minimum, originates in the southern portion of the Western South Pacific, As the waters located around 170° W move towards the east, surface salinity decreases, probably due to AAW transport across the Polar Front Zone (i.e. ring formation; Joyce and Patterson, 1977) and/or runoff from Southern Chile (Pickard, 1971). This decrease in the surface salinity combined with the presence of low saflnity AMW at intermediate depths causes the formation of a subsurface maximum (Figure 18). U This maximum 34 7.0- P-3 PPL7 WPSSW P-2 6.0- S6 S-7O S-72' S71 5.0- S S-72-- 40- E -P-51 .-P-8 3.0- ESSW --S-7S 2.0- -S-76 1.034.1 Figure 17. .2. .3 ..4 34.5 Dissolved oxygen vs. subsurface salinity maximum showing the separate groups of 0 pairs corresponding to two 550 different water masses, rom stations north of S of the SCORPIO (s) 1967 and HQUERO (P) 1969 Expeditions. 35 0 C,, 0 0 i.t) U) a Lfl th 0 (1) 0 Cl) 15° U' 0 0) - Cl)'? ! t1 .- 0 . o.8 26.0 . 0 5° O27.O 33.5%0 34.O%o 34.5°/oo c.01 /00 Figure 18. Superposition of 0-S diagrams along 13° S from 169° W to the Chilean Coast from selected stations Stars indicate the depth of the of SCORPIO 1967. base of the seasonal thermocline. 36 decreases in intensity eastward due to mixing with the less saline waters located above and below it. Even though the salinity maximum de- creases eastward, the core of the WPSSW increases in density due to temperature decrease. The name of Western. Pacific Subsurface Water (WPSSW) is given to this water mass which in the study area has a mean potential density of 27.06. One notes in Figure 18 that the e-s diagrams for station S-75 (dashed line) departs markedly from the trend of the salinity maximum between station S-30 and S-.70, showing an increase in salinity and a decrease in density. This change is attributed to the presence of the ESSW. A more exhaustive analysis on the properties of the WPSSW is beyond the objectives of this study because of the area involved. Therefore, the WPSSW nutrient characterization as well as its spatial extension is work to be accomplished in the future. 1i.6 Antarctic Intermediate Water North of 550 S the bathymetry of the 27.12 sigma-8, where the AAIW is located, presents rather constant depths of around 600 m (Figure 19). South of 550 S it slopes upwards retching the sea surface south of the Polar Front Zone. The potential temperature has a relatively homogeneous distribution along the 27.12 isopycnal.. Close to the Polar Front Zone, as this water mass shoals, the potential temperature drops rapidly at the rate of about 30 C in 100 km (Figure 20). The salinity of the AAIW in the study area is also fairly uniform, with values between 3.20 and 3'+.25°/ north of 55° S (Ficiure 21). The 37 90° 85° 80° 75° 700 65°W. 4005 450 >600 (OO( .i4° 50° \600 0o / 0 0 ° ep. 0 \ 550 °-';' \J Th200/ 600 'o100 rn FFgure 19. 50 0 0 Bathymetry in meters of the 27.12 sima-O surface, from the SCORPIO () 1967 and PIQUERO () 1969 Exped it ions. 38 )00 750 800 85° 700 65°W. 4Q0 S £ 86.MLJ 450 000 >6.5 0 0 0 0 o 0 o 500 a. - 0 0\ 0 0 0 I. 0 0 550 0 0 / -0 0.. 0 0 4.0 0 0 2.0 0 600 e°c Figure 20. 0j Potential temperature distribution on the 27-12 sigma-9 surface, from the SCORPIO (A) 1967 and PIQUERO (o) 1969 Expeditions. 900 85° 750 80° 7Q0 50W /.0° 5 34.25 AlA A A A 450 000 0 o 0 0 00 0 . 9 <34.25 500 0 0 0 550 iso 600 34123 0 0 Figure 21. Salinity distribution on the 27.12 sigrria-G surface, from the SCORPIO (t) 1967 and PQUERO () 1969 Expeditions. 40 salinity vertical distributions In the three northernmost oceanographic sections A, B and C (not shown), comprise a layer of relatively homogeneous salinity with values between 314.20 and 34.30°/ee. This nearly homogeneous layer, located between 200 and 900 rn, contains the charac- teristic AAIW salinity minimum and becomes shallower and less saline as it approaches the Polar Front Zone. As in the case of potential temperature and salinity, the dissolved oxygen is also fairly uniform (Figure 22). Oxyge.n increases poleward mainly because the water on the 27.12 sigma-O surface is cooler and fresher, increasing oxygen solubiuity. Close to the Chilean coast and between the oxygen poor ESSW above and POW below, the AAIW shows a maximum oxygen content. Beyond the area where the ESSW oxygen minimum is present, the AAIW does not show a relative maximum in dissolved oxygen. Phosphate and nitrate in the AAIW along the 27.12 isopycnal, exhibit nearly homogeneous distributions (Figure 23 and 24). The silicate distribution on the 27.12 sigma-8 is rather different from that of phosphate and nitrate, even though north of 550 S it is also nearly homogeneous (Figure 25). Closer to the Polar Front Zone, silicate dimin- ishes to a minimum (<5 pmol/I) at the Polar Front Zone, increasing again southward. This situation is the result of the use of a fixed mean isentropic surface to describe the AAItI distribution. The 27.12 sigmaO surface represents the core of AAIW in most of the area, but close to the Polar Front Zone it reaches depths lower than 100 m and this is where the SAAW or AAW is located. Therefore, the minimum in silicate on sigma-e 27.12 near the Polar Front Zone can be explained by the presence of low silicate SAAW, whle the increase to the south of the Polar Front 41 9Qo 7Qo 800 650w. I _1 I. 44 A 4 A So 87 / °°ocf) 5L r I- 5f) 0 0 / 0 5001 'o5,' / fo sso/o,/ I - I 0 0 0 0 ° 7.0 I 1. 0 0 0 22. DISSOlVe d OXyg Surf ' fr0 1969 XPed i. d'lsIrjb ,, e SCo10 O the 27 /2 967 100 1,00 S \,tItt,%ptlI't23 3eçoc?\0 otons çSà' U tO 43 900 850 80° 75° 700 65°W. 40 A Z & 45 0 0 0 0 00 O. 0 0 4 0 >25 5 0 0 ° 0 0 00 5! .. 0 0 0 0 BC NO3 pm oil! Figure 2L. Nitrate distribution on the 27.12 sigma-B surface, from the SCORPIO (Li) 1967 and PIQUERO (o) 1969 Exped it ions. I4 900 85° 80° 750 700 65°W. /,00s L 4 A A A L5° <15 F- 15151 A (.3 Ioo :' I 15 500 N:/' °°°:R '><J 550 fl\0oo S Czo15 H 60° $102 simol/I ', Figure 25. Silicate distribution on the 27.12 sigma-S surface, from the SCORPIO (L\) .1967 and PIQtJERO (°) peditions.. 1969 Ex' k5 Zone is explained by the presence of high silicate AAI4. was not evident in t'-' This situation phosphate and nitrate distributions because of the relatively high values of these properties in SAAW in contrast to the silicate. In a similar fashion to oxygen but in an opposite sense, nutrients in the AAIW show a minimum concentration in the vertical structure where the ESSW is present. Reid (l973a) points out that although the nutrients exhibit minima in the vertical, the actual concentrations in the AM'iI are high, as. might be expected from waters of a high latitude origin. These high concentrations define minima only because of the relative higher concentrations of the overlying ESSW carried poleward from the eastern tropical areas (Reid, 1973a) and the high concentrations of the PDW beneath. 46 V. 5.1 WATER MASS STRUCTURE TYPES General considerations When for a given area the temperatures and corresponding salinities of the wate.r column are plotted against each other, the points fall on a characteristic curve showing the structure of the salinity-temperature relationship. This well defined curve is the end result of the vertical mixing processes that different original water masses have experienced during their movement toward the given area. The grouping of similar 8-S curves and the division of the study area into regions with similar types of curves will give important information bearing upon features observed in the circulation patterns. 5.2 Water structures present in the region The PIQUERO-SCORPIO 8-s diagrams of the water column sampled north of the Polar Front Zone, from the seasonal thermocline to the bottom, can be grouped into four different types, each with a more or less characteristic structure. 8-S diagrams representative of each of these structures are shown in Figures 26 to 29. A geographic distribution of stations classified according to these structures is shown, in Figure 3O The water masses present in these structures are given in Table I. TABLE I. Water mass constituents of 8-S structures present in the area north of the Polar Front Zone. Water Masses Structure I II III IV SAAW SAAW SAAW SAAW - ESSW - AAIW - PDW AAIW - PDt4 - AABW* WPSSW AAIW - PDW - AABW* AAW - PDW - AABW *May not be present in some stations showing this characteristic structure. 15°- -S-76 ---'a-- 49 P-48 \J-5OTh 10 100 26.O 10o - .2 P - CD .. ___100 - 5° FIgure 26. from the Representative stations showing Structure Type Stars 1969 Expeditions. 1967 and PQIJERO (P) SCORPIO (s) indicate depths of the base of the seasonal thermocline. I 15° - ,SOm S-67 - - - * S 66 .6 100 26.0 1oo .8 cT$= 27.0 2 / 7 3000. /iI*Loo 0 .8 34.5 %0 34.O'Y00 r0I ,o0 Figure 27. Representative stations showing Structure Type II from Stars indicate depth the SCORPIO (s) 1967 Expedition. of the base of the seasona' thercnocline. 19 150 P-47 S S - a a - 3 7 P-18 1O°-26.o w 1OO 50 L.V 5Orn-N .6 .8 300 -'-600 cT927.O 1500 .2 - 1500 3OOO 6 -J: - 3O0O 000 - 34.O%o 34.5 %o J(Oo Figure 28. Representative stations showing Structure Type III from Stars indicate depth the PIQUERO (P) 1969 Expedition. of the base of the seasonal therniocflne. 50 15°. - - . 2 4 P 23 P-21 100_ o 0 0 50m-- \5Orn ioo7 26.8 jI30 8 (-6o0 .uu =27.O 1500 ,1U0+ 300 600 2 no U - 6 I J 34.00/00 Figure 29. *3000 F P 1.000 .8 I I -: 3.5%o Representative stations showing Structure Type IV from Stars indicate depth the PIQUERO () 1969. Expedition. of the base of the seasonal thermocUne. 51 850 90° ' 400 '-I I I I--i 750 800 I -I I I I I I 1 700 I I I I J 15- 65°W. I I I I I L - 15- ;r27O '::: 4:0 ,28.0 /28.0 : 0 TelIuIIlIIIiI 3&Oso/35.O 0- ., ......... 0 ° V - 340S%o35°0 0 - 27.O 550 :°i : S 60° V STRUCTURE I STRUCTURE/I P-14() CD _ ,cro27.0 : 28.0 ° STRI.ICTLIRE Iii STRUCTURE/V Figure 30. (ri 340 s/oe 35.0 Distribut ion of 8-S structure types north of the Polar Front Zone for the SCORP0 1967 and PIQUERO 1969 Stations in the study area. -- - 52 Some coastal stations are under the influence of the adjacent estuarine system, showing low surface salinity values (Figure 4). This low surface salinity produces a shallow halocline, which has not been considered in the water mass structure analysis. Mamayev (1973) has performed an analysis of 1-S structures of the upper 2500 m in the Eastern South Pacific based on data taken by the R/V Professor DERVUGIN in 1968. His work included the area between 300 and 530 S, 200 nautical miles off Chile and 1100 W, Therefore, there is a region where Mamayev's (1973) study overlaps this study. For this coimion region, Mamayev (1973) described a 1-S structure named Subantarc- tic type I, which corresponds to structure III of this work. He also described a transient type V, 100- 150 km farther to the NW of the study area. This transient type V, structure II in this work, is still present in the study area even though its WPSSW component is very weak. Mamayev (1973) showed that the transient type V extendedwestward as far as 102°W. Farther to the west. he. described a transient type IV which does not show the maximum and minimum salinity content. of the WPSSW and AAIW, showing instead a nearly homogeneous salinity layer. between 300 and 1000 m. The superposition of 0-S diagrams from SCORPIO (Figure 18) shows that structure II [equivalent to Mamayevs (1973) transient type vi extends much farther to the west than 102° W. How- ever, these diagrams do not show a nearly homogeneous salinty layer at subsurface and intermediate levels as shpwn by Mamayev's (1973) transient type IV west of 102° W. Structure II should be considered as ex- tending westward to the point where the surface salinity minimum can not be considered as such. 53 Another study which includes the study region and which considers the water mass structure of the water column is that of Johnson (1972). He described two structures with three water masses in each. Those structures are the basis of his three point vertical mixing analysis. Neither of Johnson's (1972) structures includes the ESSW, even though he recognized the presence of the Peru-Chile Undercurrent and two of his working stations in this area are from SCORPIO Expedition (S-72 and S-76). Basically, Johnson's (1972) two structures correspond to structure III of this study, where the AABW was not included due to the maximum depth he considered (2500 m). Since the ESSW has an important role in the upwelling off the central Chilean Coast (Braridhorst, 1971; and Silva, 1973) and its southernmost extension has not been clearly established, the geographic distribution of structure I will be discussed in detail. As can be ob- served from the water mass structure distribution chart (Figure 30), structure limit. I extends as far south as 48° S with 79° W as its westernmost Its distribution resembles a wedge, with its apex pointing to- ward the south, South of 50° S the ESSW salinity maximum can not be traced, because it has been completely dissipated due to vertical mixing with the less saline SAAW and AAR4. Tiard the west a similar dissipa- tion occurs, nevertheless a slight salinity maximum still persists in This maximum is not some of the remaining stations of sections A and B. a remnant of the ESSW from structure I, but rather Ft belongs to the WPSSW from structure II as has been discussed before. located at the western boundary of structure I , Station S-72, is a good example of such a situation, because of its slight double salinity maximum at 251 and 54 399 m (Figure 31). In addition to the differences In depth and density, the upper salinity maximum in. S-72 is associated with a minimum in oxy- gen, while the lower one is not (See Figure 15, S-72 and 5-72'). This situation can be interpreted as the result of the interleaving of structures I and II in the same oceanographic station. From the above discussion it may be seen that the ESSW, carried southward by the Peru-Chile Undercurrent, spreads as far south as 48° S This result complements that of Wooster and Gilmartin (1961), extending their proposed southernmost limit for the ESSW spreading by about 1000 km. The distribution of structure II has been limited to the west of section A. Nevertheless, some of the stations in section B classified in structure III, could have been classified in structure II. This is because one structure transforms into another by slow mixing of some of the water mass components; therefore, transient or intermediate structures are often present. Structure III is the prevailing structure found in t.he study area. It covers about 75, of the region studied. Structure IV, which includes MW, is found in the neighborhood of the Polar Front. 15°- S-72 2i --'-72.- 4 .6 10°- 26O96 - o .2 177201 4 o i5j: 6 325 -4-399 50 5007" .8 665- 7'698 O27O 864 - 2 / - ./ 1260 w2 ," 2151 ht'3oj5 ' j,B54 361.7-.. .6 no 31 .8 I. I I I 34.0% 1 34.5 %0 eoi 100 Figure 31. e-s diagram of the SCORP!O station S-72 showing the presence of two weak subsurface salinity maxima at 251 and 399 m. The star marks the base of the seasonal thermocl inc. 56 VI. 6.1 GEOSTROPHIC CIRCULATION General considerations Since most ocean currents satisfy geostrophic conditions and until recently direct current measurements have been scarce and difficult to obtain, most classical open ocean current studies are based on geo strophy. As it stated in the Introduction, the flow pattern in the study area is known only in its gross features. Therefore, the need exists for a more detailed study. To improve knowledge of the flow pattern of the study area, this chapter will discuss the geostrophic flow on the sea surface and on the 26.81+ and 27.12 isopycnals, all relative to 3000 db. strophic velocity sections relative to 3000 db will ment the isentropic analysis. Vertical geo- e used to comple- A short discussion on the 8-S structure relative to the geostrophic circulation will be also used to explain some of the flow features. 6,2 Flow on the, sea surface The sea surface can not be represented by a single isopycnal; therefore, It is not possible to apply isentropic analysis to it. Geo- strophic flow at the sea surface must be interpreted from a dynamic height topography map. The sea surface dynamic topography relative to 3000 db (Figure 32) shows a general flow toward the south in the southern half of the study area. This flow corresponds to the southern branch of the .!WD, after its division off South America north of the area of study (Silva and Neshyba, 1977). The coastal part of this poleward flow corresponds to 57 900 750 800 85° 700 65°W. 400 A AU/ 5O %"1:o 0 o$o ! / 550 -1.50 1./.0.. -130 °icn I 60° dynm 1.20 ..- 0 1.00-'-- 0 Figure 32. Dynamic topography of the sea surface relative to 3000 db, from SCORHO (A) 1967 and PiQUERO (o) 1969 Exped it ions. 58 the Cape Horn Current, which also carries southward the less saline and comparatively lower nutrient estuarine water along the coast of Chile. South of 550 S the general surface flow pattern is toward the East with much larger velocities than those of the northern part. eastward flow is This in agreement with generally recognized Antarctic Cir- cumpolar Circulation in this part of the ocean (Sverdrup etal., 1942; Gordon, 1967; and Gordon and Bye, 1972). The main geostrophic flow across the Drake Passage is concentrated north of 58° S, with maximum velocities greater than 30 cm/sec. South of 58° S the geostrophic velocity decreases toward the pole which is in agreement with previous reports of Ostapoff (1961), Gordon (1967), and Reid and Nowlin (1971). 6.3 Flow on the 26.84 sigma-e surface (ESSW) The thermosteric anomaly at the core of the ESSW has been shown by Wooster and Gilmartin (1961) to decrease from 160 cl/ton (sioma-t 26.44) off Peru, to less than 140 cl/ton (sigma-t = 26.65) off central Chile. They suggested that this density increase arises from mixing with water of lower temperature, If one analyzes the meridional sections of salinity off the Peru and Chile coast, prepared by Gunther (1936) or Wooster and Gilmartin (1961) or Silva and Konow (1975), it can be observed that the ESSW core diminishes in salinity and deepens as it moves southward. This could be explained in terms of a more active erosion of the ESSW core due to a stronger vertical mixing at its upper boundary (with SAAW) , than at its lower boundary (with AAIW). The reason for this difference in upper and lower boundary mixing rate can be the relatively hiqher shear in the former compared to that in the latter (see for example, Figure 35). Because of the change in density of the ESSW core as it moves southward along the Chflean Coast, this core can not be represented by a single isopycnal, but by a family of them. The isopycnal of 26.814 represents the mean potential density where the ESSW core is located off southern Chile. Geostrophic. flow on this isopycnal (Figure 33) can be divided into two parts as was done with the sea surface flow. The. southern part, south of 500 S, has a relatively fast geostrophic flow pointing toward the east. This is the continuation at subsurface levels of the Antarctic Circumpolar Current. In the northern part, mainly north of 5Q0 S, the geostrophic flow is significantly slower. The eastern por- tion of the northern area shows a southward flow, while the western portion the general flow is to the north. The poleward flow close to the coast of Chile can be interpreted as a remnant of the Peru-Chile Undercurrent. Nevertheless, a more rigorous explanation of the origin of this poleward flow can be based on an acceleration potential chart which includes a much larger extension to the north of the study area, Reid's (1965) acceleration poten- tial relative to 1000 db on the 125 cl/ton isanostere, which is close to 26,84 sigma-B, shows a poleward flow off Peru and Chile which is not defined south of 36° S. A farther southward extension of this poleward flow may be reasonable, since the available data at that time in this region was very scarce, It is reasonable to connect the poleward flow from Reid's (1965) chart with this study area, thus inferring that the Q0 85° 80° 700 75° 65°W. L 0°S 2.20 - / 6 65° I .. / 2.175# _I H - 2.75 I 1 , 5' 2.175 tr ri fo ol/o\O 50° 2'15 0 010 i 5 5°. 2.00 0 \ 1 70 ° 600 dynm Figure 33. Acce]erdtion potential on the 26.8!! siymaB surface relative to 3000 db, from SCORPIO (A) 1967 and PIQUERO () 1969 Expeditions. [4 Peru-Chile Undercurrent is present at this high latItude. Nevertheless, further evidence is required and will be presented later. 6.4 Flow on the 27.12 sigma-A surface (AAIW) The general circulation on the 27.12 isopycnal (Figure 31+) is very similar to that present on the 26.84 sigma-B surface. Again, main characteristics are the relatively slow flow in the northern portion of the area and a much faster flow in the southern part. North of 550 S the flow direction is not very well defined, but a northward movement can be accepted as the general trend. Reid's (1965) acceleration potential map on 80 cl/ton isanostere (sigma-B = 27.29), which he selected as the AAIW representative, does not show any detail in this area probably due to the scarcity of data. The acceleration potential map on the 27.10 sigma-t surface prepared by Johnson (1972) shows the flow in this region, north of 550 S, with a general northward direction. Nevertheless, the data used by Johnson (1972) for thIs region is also sparse (8 stations located mainly on the periphery of the study area) South of 55 S the flow is well defined toward the east, with relatively high velocites. Again, this flow corresponds to the pre- sence of the Antarctic Circumpolar Current at this level. Since the flow on the 27.12 isopycnal in the vicinity of the Polar Front is directed mainly toward the east, the AAIW formed in the PIQIJERO-SCORPIO area will be carried eastward. Therefore, this area will act mainly as a source region for Pacific AAI'd to the Atlantic Ocean. 62 B° OO 80° 75° 65°W. 70° 40°S A 45° A A \ '1 oc ( \ 50° 55° 5 QO dynm Fi9ure 3+. Acceleration potential on the 27.12 si9ma-A surface relative to 3000 db from SCORPIO (t) 967 and PIQUERO (o) 969 Expeditions 63 6,5 Flow across vertical sections Vertical sections of geostrophic velocity relative to 3000 db are shown in Figures 35 to 40, These vertical sections complement the in- formation given by the horizontal flow on selected isentropic surfaces, showing the geostrophic velocity n the water column across sections perpendicular to the coast (sections A to F in Figure 1). 6.5.1 The coastal flow The coastal subsurface flow associated with the ESSW on the charts of acceleration potential on the 26.84 sigma-e extends as far as 150 km off the coast at section A (43° S) (Figure 35). The flow shows a maxi- mum of 5.9 cm/sec at 250 m depth, which is also the depth at which the salinity maximum of the ESSW is found. In section B (48° s) (Figure 36), the coastal flow shows neither a subsurface maximum nor a decrease in the velocity shear in the subsurface layer associated with the ESSW. Nevertheless, the ESSW salinity maximum is found at station P-48 (see Figure 26) at a depth of 252 m. The maximum velocity of 4.0 cm/sec occurs at the surface at a distance of 140 km offshore; the poleward flow extends to about 400 km offshore, In section C (51° s) (Figure 37), the maximum velocity of the coastal poleward flow is again found at the surface (30 m depth) but at a value of 6.7 cm/sec. offshore, In this section, the flow extends some 300 km From sections C through F the general trend of the coastal flow is to increase in velocity, varying in offshore extent to a niaximum of about 560 km at section F.. SECT/ON S-67 S-66 S-68 I 2Z08 . 5-71 5-72 S-b 4L '4'ftf j3 :\[. o.7fl12S4 / -I-H I II.2I 0.iI' I 27:l2..J-__----- HTH1 +-U-' .i I L S-75 S-76 S-73 5-74 . . J; . I} . :' ( 1 :\ . (:I . . 2000 cr/sec t 1000 500 0 DISTANCE (km) flgure 35. Geostrophic velocity relative to 3000 db at section A, from SCORPIO 1967 Expedition. Positive values indicate northward flow; negative values indicate southward flow. Solid horizontal lines represent the potential density at which the cores of ESSW (26.814), WPSSW (27.06) and MIW (27.12) are found; dshcd line is the base of the seasonal thermocline (BST). 65.. SECTION B P-41 P-h2 IUUU P-43 P-45 P-44 500 P-46 P-47 P-48 0 DISTANCE (kin) Figure 36. Geostrophic velocity relative to 3000 db at section B, from PIQUERO 1969 Expedition. Positive values indicate northward flow; negative values indicate southward flow. Solid horizontal lines represent the potential density at which the cores .f ESSW (26.81+) and AAIW (27.12) are found; dashed line is the base of the seasonal thermcr cUrie (BST). 0 C', -4. 0, 0, 0 0 F C- LUa (I) 0 0) a, C', 0 67 SECTION D 1000 500 0 DS TA N CE I k m) Figure 38. Geostrophic velocity relative to 3000 db at section D, from PtQUERO 1969 Expedition. Positive values indicate northward flow; negative values indicate southward flow. Solid horizontal lines represent the potential density at which the cores of ESSW (26.81+) and AAIW (27.12) are found; dashed line is the base of the seasonal thermo- dine (BST). SECTION E - -- .. fin n__In 0_b DISTANCE (km) Figure 39. Geostrophic velocity relative to 3000 db at section E, from PIQIJERO 1969 Expedition. Positive values indicate eastward flow; negative values indicate westward flow. Solid horizontal lines represent the potential density at which the cores of ESSW (26.84) and AAIW (27.12) are Found; dashed line is. the base of the seasonal thermo dine (BST). 69 SECTION F P-l0 P-li P-12 P-13 P-14 P-iS P-17 cm/sec 1000 500 0 DISTANCE (km) Figure hO. Geostrophic velocity relative to 3000 db at section F, from PIQUERO 1969 Expedition. Positive values indicate eastward flow; negative values indicate westward flow. Solid horizontal lines represent the potential density at which the cores cf ESSW (26.84) and AAIW (27.12> are found; dashed line is the base of the seasonal thermo- dine (BST). 70 6.5.2 Identification of the subsurface coastal flow with the Peru-Chile Undercurrent A central theme of this study is the question of the southernmost extension of the Peru-Chile Undercurrent. In this sense, the coastal flow described in the previous section may now be correlated with previously published data on the Undercurrent along the coasts of Peru and Chile as follows: From 6° to 24° S, STEP Expedition (Wooster and Gflmartin, 1961); reference level 1000 db I From 24° to 28° S, MARCHILE VIII Expedition (Sievers and Silva, 1975) ; reference level 1000 db, - At 35° S, geostrophic flow computed from stations 83 and 84 of section 35° S of the SCORPIO Expedition (S.l.O., 1969); reference level 2000 db. From 43° S to about 57° S, geostrophic flow computed for the study area using SCORPIO and PIQIJERO data; reference level 3000 db. Results from these expeditions and sources are combined in Figure 41. Arrows show the approximate position of the core of the Peru-ChIle Undercurrent from 6° S to the northern limit of the study area using data from the first three of these sources. Within the study area, the Undercurrent is clearly delineated through section A (43° 5), as discussed in the previous section. At latitude 45° S, the PIQUERO Expedition yields a short, near coastal section consisting of three stations, P-49 through P-51 (see Figure 1) Geostrophic flow relative to 2500 db has been computed for this set of stations, and profiles are shownin Figure 42. The profile for flow be- tween P-1+9 and P-50 shows two maxima above 300 m: the first occurs at the surface at a value of 5.7 cm/sec; a second, less pronounced maximum of 2.9 cm/sec occurs at 200 m, The latter is located wIthin the subsur- 71 110° Figure 41. I0O 900 80° 700 60°W Composite of oceanographic sections showing approximate positions and geostrophic velocities of the core of the 1960 (Wooster Peru-Chile Undercurrent. based on STEP and Gilmartin, 1961), tIARCHILE VIII 1972 (Sievers and Silva, 1975), SCORPIO 1967 (this study) and PIQUERO 1969 (this study) Expeditions. Respective reference levels are given in the text. I 72. -4 -6 A U I V cm/sec. 0 -2 I. I. I I. It I I . +2 I. . ¶ P5O-P51 PL9.-P5O\ It 1000 \. E I. IUi a 2000 .. Figure 42. Geostrophic velocity profile relative to 200 db for N50 and P-50 - P-51. PIQUERO 1969 stations pairs P19 Positive values indicate northward flow, negative values indicate southward flow. 73 face salinity maximum of the ESSW. A similar subsurface maximum is found between stations P-50 and P-51. It is, therefore, reasonable to conclude that the Undercurrent still exists at this latitude, 45° S. At J8° S, section B, the subsurface salinity maximum, oxygen minimum, and nutrient max.inium which are characteristic of ESSW water are present at about 250 m depth. However, the geostrophic velocity regime (Figure 36) does not show a subsurface velocity maximum. At 510 S, section C, remnant.s of the low oxygen and high phosphate an.d nitrate still persist, but salinity and silicate do not show a maximum in the vertical distribution. Using the criteria of coincident subsurface velocity maxima and subsurface ESSW characteristics, one must conclude that the Peru-Chile Undercurrent loses its identity around 48° S. How- ever, subsurface flow does exist at section 8, as well as at sections further south, but can not be uniquely identified with the Peru-Chile Undercurrent characteristics. The southernmost extension of the Peru-Chile Undercurrent is not absolutely established in this study. Further work must be done to answer some questions related to the Undercurrent in this area, such as: Does this southern extension undergo seasonal fluctuations? Does the latitude of the WI4D impingement affect its southern and/or western extension? If the WWD impingement off Chile is under the influence of seasonal variations latitudinally, how will this affect the Undercurrent? 6.5.3 Geostrophic flow south of 48° S The increase in the flow velocity in the surface coastal poleward flow or Cape Horn Current, may be the result of influx of runoff water 74 from the adjacent coast, elevating the sea level height and hence the flow velocity. The piling up effect due to the pressure exerted by the WWD against the coast maybe important The relatively high velocities present in sections E and F, is the result of the constriction effect of the Drake Passage to the zonal flow (Gordon and Bye, 1972). The flow across the Drake Passage (Figure 40) follows the pattern described by Reid and Nowlin (1971), as would be expected since they also used PIQIJERO data. Nevertheless, there is a difference between their geostrophic velocity values at the station pair P-15 to P-17 compared to those shown in section F (Figure 40). Even though Reid and Nowlin's (1971) velocity values at this station pair are referred to 3400 db, this can not account for a sea surface velocity difference of 13 cm/sec between the two studies. This difference seems to be the re- sult of a computational error, since their surface value of 36.1 cm/sec could not be obtained by this writer from the corresponding station data set. As a result, the fastest geostrophic velocities are, in fact,. located between the station P-l4 and P-15, and not between P-15 and P-17 as shown by Reid and Nowlin (1961). Direct current measurements near the bottom in the Drake Passage were reported by Reid and Nowlin (1971) to show mean daily speeds ranging from 0.5 to 14.7 cm/sec. These relatively high. speeds at the bottom of the passage are further evidence of the absence ofany given level of no motion For geostrophic computations in this area. 6.6 Geostrophi.c circulation and water mass structure Since the geostrophic circulation is causally linked to the density field distribution, this type of circulation is directly related to the 75 e-s structure present in a given area. At times, circulation features can be more easily explained in terms of 9-S or water mass structure. The eastwardflow south of 570 S(Figures 32 to 34), is dominated by structure IV (FIgure 30). ward bend at station. P-23. This eastward flow shows a sharp south- A detailed analysis of the 0-S structure present at P-23 indicates a transient structure between structures III and IV. This means that. the water column in this sLation still shows remnants of structure III, even though it can be classified as structure IV. Therefore, remnants of characteristics of a northern station are present in the south, giving as a result the observed bend in the flow lines. The clockwise eddy at station P-19 (Figures 32 and 34) seems also to be produced by a transient structure between III and IV (Figure 43). In this station, the e-s structure between 71k and 1535 m resembles more closely structure IV than III. This could be the result of the presence of water which contains a major fraction of cold AAW in its composition. Joyce and Patterson (1977) , In describing a clockwise ring formation at the Polar Front Zone, stated that: withi.n the Polar Front.Zone'the minrnur&' (temperature) "deepens abruptly and erodes splitti.ng into multiple extrema of interleaving Antarctic/Subantarctic waters. Since t.he waters south of the Polar Front Zone are associated withä comparatively lower dynamic height than that of those to the north, t.h.e presence of AAW north of the Polar Front Zone will produce a lesser dynamic height in comparison to that of surrounding waters. Dynamic topography charts of 0/500, 500/1000, 1000/2000 and 2000/3000 db (not shown), indicate the presence of this eddy at all these levels. 76 15°p-.19 - 10°- o Om 0 -'-76 .6 126 8 * Y15O3,/' O27.O - 255 51OIL+.h 817 1737 / 919 - 3157 .6 .8 00 --3871 ', roi , .t0, OL,.0 100 O't.) (00 c,0I qJ,O0 Figure 143. 0-S diagram of station P-19. The segment between 71I and 1535 in resembles a structure type IV, while the whole structure corresponds to structure type HI. Star marks the base of the seasonal therinocline. 77 The highest dynamic difference between adjacent stations ( 10 dyn cm) is found in the 50.0/100 and 1000/2000 db zones which indicates that the segment 500 to 2000 m of the water column is the main contribution to the observed lower relative dynamic height of N19. On the other hand, counterclockwise flow east of the Drake Passage has been described by Gordon etal. (1977). They associated this flow with the presence of SAAW within the Polar Front Zone, The poleward flow on the 26.8'i isopycnal (Figure 33) for the presence of structure off southern Chile. I is responsible Nevertheless, this structure is also present westward of the core of this southward flow. This situation might be the result of horizontal diffusion rather than advect ion. There is no evidence inside the study area of any relatively important flow carrying the WPSSW component of structure II eastward. Thus, the presence of structure II in this area may be interpreted as mainly due to a diffusive phenomenon. Nevertheless, Reid's (1965) ac- celeration potential maps on the 125 and 80 cl/ton isanosteres, show a general eastward flow between o° and 500 S. This flow, which weakens eastward and turns northward around 90° S off Chile, may be responsible for the presence of structure II in this area. 78 VII. CONCLUDING REMARKS To summarize this detailed analysis of the water mass structure and geostrophic circulation of the study area between 13° and 63° S, 91° W to the Chilean Coast, some concluding remarks can bemade: 1. Previous studies of the high salinity, low oxygen poleward flow (Gunther, 1936; Wooster and Gilmartiri, 1961) have placed its southernmost extension at 41° S. This study demonstrates clearly that this limit can be extended to at least as far as 48D S. South of this latitude the subsurface flow can. not be definitely associated with the ESSW characteristics of the Peru-Chile Undercurrent. Further study must be performed to establish whether or not the Peru-Chile Undercurrent's southernmost boundary is subject to seasonal variations. (1) Questions to be answered by future work in the area are: How does the latitude at which the WWD impinges the Chilean Coast affect the southern and/or western extension of the Peru-Chile Undercurrent? and (2) How does the probable seasonal fluctuation in the latitude of impingement of the WWD affect these samefactors? 2. The presence of the WPSSW is proposed in this work as water carried from the extreme Southwestern Pacific Ocean into the study area below the surfacelow salinity water off southernChile. This water mass is characterized by a subsurface salinity maximum, not associated with an oxygen minimum as is the ESSW. Further work has to be performed to establish its nutrient characteristics as well as its spatial dis tribut ion. 3. The low phosphate and nitrate contents of the surface coastal waters off southern Chile, seem to have their origins in the mixture of 79 ocean-waters with estuarine waters. of comparatively less rich nutrient Two point mixing explains-around 60 content. 70 of the nutrient variability of the waters in the study area where the- salinity ranges between 33 34°/, Biological and/or chemical processes may also be important causes of the relatively low nutrient concentrations of thse coastal waters. More interdisciplinary work must be carried -out in order to explain this feature. 1f. The presence of seven water masses in the region of study were established from the 8-S diagrams below the seasonal thermocl me: Subantarctic Water, Antarctic Water, Equato rial Subsurface Water, Western Pacific Subsurface Water, Antarctic intermediateWater, Pacific Deep Water and Bottom Water. 5. Geostrophic flow in the study area can be divided in general into two regions. North of 550 S, where the circulation is relatively slow, with its eastern boundary flow toward the south along the Chilean Coast.- South of 55° S, the circulation is much faster than in the northern portion. The flow has an eastward direction with high velocities characteristic of jhe Antarctic Circumpolar Current in this region. 80 BIBLIOGRAPHY Brandhorst, t4.. 1971. Cond.iciones oceanograficas estivales frente a la costa de Chile. Rev. Blol. Mar., Valpara.iso, 14(3).: 484. Cabrera-Muro, H. 1977. Precise North-South oceanographic transect In the Pacific Ocean. Corvallis., Oregon State Master's Thesis. 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Peru-Callao, Vol. 2, No. 5, pp. 157-324,