Chemistry 112 First Hour Exam Name:____________ (4 points) Please show all work for partial credit All problems are worth 12 points Please read and sign the following statement: I understand that this test is being given over the course of several days. As a result, I will not discuss the problems on this test with anyone until after Noon on Friday, September 21. Signed: ___________________ Date: ______________ 1A. How many significant figures are in each of the following numbers? .480020 ___6___ 480020 ___5___ .048002x10-5 __5_____ . 1B. Below are the answers to different calculations. Express this number with the correct number of significant figures 67 x 1001 = 67067 _67000____ 13 + 67 = 80 __80.________ Decimal shows good to the 1's place (67x1001)/(13+67) = 838.3375 2. Perform the following unit conversions: 786 ìs to cs 786 footAlbs to cmAkg 786 lbsAin-2 to kgAm-2 840_______ 2 3. Calculate the Molecular mass of the following compounds SnCl4 118.7 + 4(35.45) = 260.5u (NH4)2SO4 2(14.01)+8(1.008) + 32.07 + 4(16.00) = 132.154u Magnesium sulfide (If you don’t know the formula, make one up for partial credit) MgS 24.31+32.07 = 56.38u Bromine pentafluoride (If you don’t know the formula, make one up for partial credit) BrF5 79.90+5(19.00) = 174.9u 4. Complete the following table: Complete Symbol # protons # electrons # neutrons 21 21 24 17 17 18 25 18 29 34 36 45 Note: On the original test I reversed the positions of the atomic number and mass number on the first element, Scandium. I did not take off points for the people who followed my incorrect lead. But one person did correct me and I gave that person a bonus point! 3 5. Balance the following chemical reactions: Na(s) + F2(g) 6NaF(s) 2Na(s) + F2(g) 62NaF(s) Ca3N2(s) + HI(g) 6CaI2(s) + NH3(g) Ca3N2(s) + 6HI(g) 63CaI2(s) + 2NH3(g) C3H6(l) + O2(g) 6 CO2(g) + H2O(g) 2C3H6(l) +9 O2(g) 6 6CO2(g) + 6H2O(g) 6A. In the blank periodic table below please indicate where the following things are found: Inner transition metals XXX Alkaline earth metals YYYY Third period elements ZZZZ 6B. Using the periodic table supplied with this test please identify the following elements (A symbol get you 1 point, a full name, correctly spelled gets you 2 points) Any Halide _Fluorine to Astatine__________ An alkaline earth metal in the second period __Berylium______________ Any three inert gases _Helium to Radon________________ 4 7. Define the following terms: Potential Energy Energy associated with the position of an object in a force field. Element A pure substance that contains only one type of atom. Heterogeneous mixture A mixture of material in which different components can be seen. Solution A homogenous mixture or the combination of solvent and solute. Accuracy How close your answers are to the true value. 8. A tougher question, so I saved it for last. Elemental magnesium has an atomic mass of 24.30u. There are three major isotopes of Mg: 24Mg, 25Mg, and 26Mg. If 76% of elemental magnesium is the 24Mg isotope, what is the % abundance of the other 2 forms? 24.30 = .76(24) + X(25) + Y(26) 1.00=.76 + X + Y 1.00-.76-X =Y Y= .24-X Substituting into the first equation 24.30 = .76(24) + X(25) + (.24-X)(26) 24.30 = 18.24 + 25X + (.24)26 - 26X 24.30 -18.24 -(.24)26) = 25X-26X -.18 = -X 25 Mg = 18% abundance 26 Mg = 6% abundance