Chemistry 112 First Hour Exam Name:____________ (4 points) Please show all work for partial credit All problems are worth 12 points Please read and sign the following statement: I understand that this test is being given over the course of several days. As a result, I will not discuss the problems on this test with anyone until after Noon on Friday, September 21. Signed: ___________________ Date: ______________ 1A. How many significant figures are in each of the following numbers? 6060 ___3___ .6060 ___4____ .06060x105 __4_____ 1B. Below are the answers to different calculations. Express this number with the correct number of significant figures 13 x .651 = 8.463 ___8.5_______ 13 + 67 = 80 __80.________ (13 and 67 are good to the 1's place) (13+67) /(13 x .651) = 9.4529 __9.5________ 2. Perform the following unit conversions: 34 Gg to mg 34 footAlbs to cmAkg 41 lbsAin-2 to kgAm-2 2 3. Calculate the Molecular mass of the following compounds FeCl3 55.85 + 3(35.45) = 167.2u Mg(NO3)2 24.31 + 2(14.01) + 6(16.00 = 148.33u Lithium fluoride (If you don’t know the formula, make one up for partial credit) LiF = 6.941 + 19.00 =25.941u Sulfur trioxide (If you don’t know the formula, make one up for partial credit) SO3 = 32.07 + 3(16.00) = 80.07u 4. Complete the following table: Complete Symbol # protons # electrons # neutrons 15 15 16 14 14 14 25 22 29 8 10 8 3 5. Balance the following chemical reactions: Mg(s) + O2(g) 6MgO(s) 2Mg(s) + O2(g) 62MgO(s) Ca3N2(s) + HF(g) 6CaF2(s) + NH3(g) Ca3N2(s) + 6HF(g) 63CaF2(s) + 2NH3(g) C6H6(l) + O2(g) 6 CO2(g) + H2O(g) 2C6H6(l) + 15O2(g) 6 12CO2(g) + 6H2O(g) 6A. In the blank periodic table below please indicate where the following things are found: Halides XXX Lanthanides YYYY Fifth period elements ZZZZ 6B. Using the periodic table supplied with this test please identify the following elements (A symbol get you 1 point, a full name, correctly spelled gets you 2 points) Any alkaline earth metal __Beryllium to Radium_______________ A noble gas in the second period _Neon_______________ Any three alkali metals ___Lithium to Francium______________ 4 7. Define the following terms: Intensive properties Properties like density that do not depend on the amount of material. Accuracy How close your values are to the true value. Diatomic A molecule that contains 2 atoms solvent The medium into which a solute will be dispersed. Potential Energy Energy associated with the position of an object in a force field. 8. A tougher question, so I saved it for last. Elemental magnesium has an atomic mass of 24.30u. There are three major isotopes of Mg: 24Mg, 25Mg, and 26Mg. If 78% of elemental magnesium is the 24Mg isotope, what is the % abundance of the other 2 forms? 24.30 = .78(24) + X(25) + Y(26) 1.00=.78 + X + Y 1.00-.78-X =Y Y= .22-X Substituting into the first equation 24.30 = .78(24) + X(25) + (.22-X)(26) 24.30 = 18.72 + 25X + (.22)26 - 26X 24.30 -18.72 -(.22)26) = 25X-26X -.14 = -X 25 Mg = 14% abundance 26 Mg = 8% abundance