10/13/09 Atomic Structure Components of the Atom Parts of the Atom Proton and Neutron Both found in the nucleus Denoted p+ and no Protons have a positive charge while neutrons are neutral. Electrons Found in outer orbitals (e-) Have a negative charge General Atomic Structure 1 10/13/09 Atom Information Atomic Number (Z): Number assigned to each atom denoting the number of protons (Hydrogen is 1 and has 1 proton) Atomic Mass Number (A): Number of protons and neutrons in an atom. Atomic Notation Displaying the atomic number and mass number at the same time. A = neutrons + protons Z = protons Mass Number (A) = p+ + n0 23 11 Na Element Symbol Atomic Number (Z) = # of protons 2 10/13/09 Atomic Variations # of protons determines element. Isotope: atoms of the same element having different masses. Example 12 13 6 6 C C Two isotopes of carbon Atomic Variations Ion: atoms of the same element having different charges. Cation: ion with a positive charge Anion: ion with a negative charge Examples:: 3 10/13/09 Atomic Mass Unit AMU:: 1 amu = 1/12 of the mass of a C-12 atom. It is related to the value on the periodic table. Is an older unit and not part of SI The mole is SI unit. Molar Masses The value on the periodic table is the mass of one mole of that element. 1 mole = 6.022 x 1023 of anything The number of particles in 12g of carbon-12 atoms that are unbound. Atoms, molecules, compounds. Nobel Prize awarded in 1926. Definition accepted in 1980. How much do atoms weigh?? Take a look at your friend the periodic table. What do you notice about the masses? Many atoms have multiple isotopes. This must be accounted for so mass measurements are consistent. 4 10/13/09 Same atom, different mass?? Remember isotopes…atoms (identified by number of protons) can have differing numbers of neutrons. Any atomic sample contains multiple isotopes of that atom…. For example… Average Atomic Masses There are 7 different naturally occurring isotopes of chromium. They vary in atomic mass number from 50 to 63. The mass of each isotope is taken into consideration when calculating average atomic mass. Chromium Isotopes 52Cr = 83.8% Cr = 4.3% 53Cr = 9.5% 54Cr = 2.4 % 61-63 Trace amounts: Cr 50 Using the mass from any one of these would not represent a sample found in nature. 5 10/13/09 Determining Average Masses Weighted Averages are used to find average masses. 63Cu 69.17% 62.92 amu 65Cu 30.83% 64.92 amu 6