Liquid Fuel Hydrocarbon Emissions Mechanisms in Spark-Ignition Engines by Gary B. Landsberg B.S., Mechanical Engineering University of South Alabama, 1998 Submitted to the Department of Mechanical Engineering in Partial Fulfillment of the Requirements for the Degree of Master of Science in Mechanical Engineering at the Massachusetts Institute of Technology June 2000 @ 2000 Massachusetts Institute of Technology All rights reserved Signature of Author Department 6f Mechanical EngTneering May 1, 2000 / Certified by Jokn B. Heywood Sun Jae Professor of Mechanical Engineering Thesis Supervisor Accepted by Ain A. Sonin Chairman, Department Committee on Graduate Students MASSACHUSETTS INSTITUTE OF TECHNOLOGY SEP 2 0 2000 LIBRARIES Liquid Fuel Hydrocarbon Emissions Mechanisms in Spark-Ignition Engines by Gary B. Landsberg Submitted to the Department of Mechanical Engineering May 2000 in Partial Fulfillment of the Requirements for the Degree of Master of Science in Mechanical Engineering ABSTRACT Future regulations, such as the ultra low emissions vehicle (ULEV) specified by the California Air Resources Board (CARB), are placing stricter limits on the allowable hydrocarbon (HC) emissions and make the understanding of the sources of HC emissions of considerable importance. Previous researchers have identified six sources of hydrocarbon emissions: oil layers, deposits, liquid fuel, quenching, crevices, and exhaust valve leakage. The objective of this research was to gain a better understanding of the liquid fuel contribution to hydrocarbon emissions. The purpose of this work was to develop a fundamentally based description of liquid fuel transport into the engine cylinder of a port fuel injected, gasoline fueled, SI engine, and to develop a method of quantifying the liquid fuel contribution to HC emissions. To simulate the liquid fuel flow from the valve seat region into the cylinder, a specially designed injector probe was constructed and used to inject controlled amounts of liquid fuel onto the port wall close to the valve seat. By fueling the engine on a gaseous fuel, either propane or pre-vaporized Indolene, and injecting liquid fuel close to the valve seat, we can examine the effects of liquid fuel entering the cylinder at different circumferential locations around the valve seat. These experiments were carried out with both open and closed valve fuel injection to assess the differences that residual blowback and evaporation produce. The location of liquid fuel around the valve seat was found to have a significant impact on engine-out hydrocarbon emissions. These experiments indicated that for all amounts of liquid fuel injected at the valve seat, the fuel delivered closest to the exhaust valve resulted in the highest engine-out HC's, while the location farthest from the exhaust valve had the lowest HC's. The differences between closed valve and open valve injection showed similar trends for all probe locations, indicating that the blowback during valve overlap has the same impact on mixture preparation and vaporization at all locations. Comparison with other experimental data suggest that the location of liquid fuel in the cylinder after induction into the engine may be a major source of the differences in HC's between the different probe locations around the intake valve. Thesis Advisor: Professor John B. Heywood Title: Sun Jae Professor of Mechanical Engineering 3 (This page was intentionally left blank) 4 Acknowledgments I guess my journey here is over, and as with every journey there were high points and low points along the way. I've done many new things, learned new ideas, and met lots of great people along the way. I would first and foremost like to thank my tour guide (pronounced "advisor"), Professor John B. Heywood, he kept me from getting lost along the way and taught me many of the things I needed to survive. I would also like to thank Professor Wai Cheng for always taking the time to help me fix my electronic gremlins. I could never have gotten my project going without the help of Brian Corkum and Matt Rublewski, I enjoyed working with you both. Brian, thanks for showing Matt how to check to see if a spark plug is sparking. Matt, thanks for showing me what happens when you become the ground for a sparking spark plug (zap zap zap). Of all the people I know, there is only one person who truly understands what I have gone through in the past two years and that is Brian Hallgren (aka. Green Halogen). As my officemate, friend, mountain bike partner, and coconspirator, we have had an adventure nearly everyday, bringing a sense of fun to our otherwise dull days at work. I wish you best of luck on your Ph.D., don't let MIT get to you. One more thing, remember our motto, "it wasn't me, I don't know where it is, you should order one." I would also like to thank everyone in the Sloan Lab past and present. Special thanks to the Engine and Fuels Consortium members for funding this research and providing valuable feedback at our meetings. The Consortium members include: DiamlerChrysler, Ford, General Motors, ExxonMobil, Shell UK, and Volvo Car. There is one person above all others, who helped me through my time here and that is my best friend and wife, Maria. Throughout the past nine years you have given me the courage and confidence that has allowed me to get to where I am. Thank you Maria, for helping me to get through this with my sanity and sense of humor. Coming home to you was (and is) always the best part of my day. I would also like to sincerely thank Annabelle, you have always listened to me, calmed me down after losing my temper, and have stuck by my side everyday for the past six months. I could have never done any of this without the help of my entire family. I would like to thank my parents for always supporting me in all of my endeavors. Brad, thanks for letting me live vicariously through your adventures during my term here. For the next two years when you are in grad school, I will do the same for you. Last but not least I would like to thank all of the people who have helped to get me to MIT. Including the entire engineering faculty at the University of South Alabama, most especially Professors Eugene Odell, Jay Kapat (now at UCF), Lanier Cauley, Ali Engin, and David Hayhurst. When I was about three years old I took a diaper pin stuck it into an electrical socket and discovered electricity. After my mom unplugged me, I thought, "Ouch, I'll never ever do that again ". MIT was a similar experience - I learned a lot of things I'll neverforget. -GL 5 TABLE OF CONTENTS Abstract Acknowledgments Nomenclature List of Tables List of Figures 3 5 8 9 10 CHAPTER 1 INTRODUCTION ..................................................................................... 15 1.1 1.2 1.3 1.4 1.5 1.6 1.7 Mixture Preparation in SI Engines ............................................................. Hydrocarbon Emissions in the Federal Test Procedure ................................ Sources of Hydrocarbon Emissions............................................................. Previous Work on Liquid Fuel Hydrocarbon Emissions................................ Project Scope ............................................................................................. Tables............................................................................................................. Figures ........................................................................................................... CHAPTER 2 EXPERIM ENTAL METHOD .................................................................. 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 Nissan Test Engine ...................................................................................... Nissan Engine Control System ................................................................... Engine M easurement System ....................................................................... In-Cylinder Pressure M easurement............................................................... Hydrocarbon M easurement System............................................................. Labview Data Acquisition Program............................................................. Engine Operating Conditions ....................................................................... Tables............................................................................................................. Figures ........................................................................................................... 15 16 16 17 21 23 25 35 35 35 36 37 37 38 38 41 45 CHAPTER 3 EFFECTS OF ENGINE OPERATING PARAMETERS ON HC.............. 49 3.1 3.2 3.3 3.4 3.5 3.6 3.7 3.8 Factors Affecting Liquid Fuel Distribution ................................................. Intake Airflow Processes ............................................................................. Effects of Spark Timing .............................................................................. Effects of Relative Air/Fuel, Lambda .......................................................... Coolant Temperature Experiments............................................................... Propane and Indolene Fueling ..................................................................... Effects of Fuel Injection Timing ................................................................... Figures ........................................................................................................... 6 49 49 50 51 52 52 53 55 CHAPTER 4 LIQUID FUEL INJECTION PROBE EXPERIMENTS ............................ 4.1 4.2 4.3 4.4 4.5 4.6 4.7 4.8 4.9 4.10 4.11 Overview of Liquid Fuel Injector Probe Experiments ................................... Pre-V aporizing Injector .............................................................................. Liquid Fuel Injector Probe .......................................................................... Liquid Fuel Injector Injection Timing Sweeps ............................................. Fuel Probe Indolene/Propane Fuel Sweeps.................................................. Fuel Probe Fuel Sweeps .............................................................................. Comparison of OVI and CVI with Injector Probes....................................... Experim ental Fuel Probe Comparison with PFI........................................... Discussion .................................................................................................. Tables.............................................................................................................79 Figures ........................................................................................................... CHAPTER 5 SUMMARY AND CONCLUSIONS .......................................................... 5.1 5.2 5.3 5.4 Liquid Fuel Transport into Cylinder .............................................................. Comparison of Liquid Fuel Probes to Standard PFI....................................... Conclusions.................................................................................................. Figures ......................................................................................................... REFEREN CES ................................................................................................................ 7 71 71 71 72 73 74 74 76 77 78 81 105 105 106 106 111 115 NOMENCLATURE BDCC - bottom dead center of compression stroke CFI CVI ECU FID FTP HC MAF MAP - N-IMEP NOX OVI PFI - net indicated mean effective pressure - oxides of nitrogen - open valve injection - port fuel injection SMD TDC - sauter mean diameter - top dead center TDCC - top dead center of compression stroke central fuel injection closed valve injection engine control unit flame ionization detector federal test procedure hydrocarbons mass air flow manifold air pressure 8 LIST OF TABLES Table 1.1 Table 1.2 Table Table Table Table 2.1 2.2 2.3 2.4 Table 4.1 Table 4.2 Engine test matrix used by Stanglmaier [14]............................................... Summary of experimental data on HC emissions during startup, effects of liquid fuel in the cylinder........................................................ 23 N issan engine specifications ......................................................................... National Instruments data acquisition specifications.................................... Data output variables from data acquisition program.................................... Conversion factors for raw voltage input to data acquisition .. sy stem .......................................................................................................... 41 41 43 HC fuel fraction values based on linear regression analysis of experimental data with different assumed Z values...................................... HC fuel fraction values for standard engine operating con ditions..................................................................................................... 9 23 43 79 . 79 LIST OF FIGURES Figure Figure Figure Figure Figure 1.1 1.2 1.3 1.4 1.5 Figure 1.6 Figure 1.7 Figure 1.8 Figure 1.9 Figure 2.1 Figure 2.2 Figure 2.3 Figure 2.4 Federal test procedure, FTP 75 ..................................................................... Steady-state HC emissions flowchart [4]...................................................... Crevices in the combustion chamber [2]........................................................ Effect of crevice volume during warm-up [6]............................................... Plot of total, engine-out HC emissions versus time after coldstart for two standard injection (PFI) and two pre-vaporized injection (PV -CFI) starts [18]........................................................................ Liquid fuel distribution in the port and cylinder during coldstart and warm engine operation [17] ............................................................ Schematic of liquid fuel injector probe used by Stanglmaier [14 ] .................................................................................................................... Liquid fuel injection location for direct injection of fuel used by Stanglm aier [14][15] ................................................................................ Effect of wall wetting location on engine-out HC's, Stanglm aier [14]............................................................................................ 25 25 27 27 29 29 31 31 33 Standard intake runner and intake port geometry for the Nissan . 45 Sentra engine................................................................................................ 45 location ................................. pressure transducer Top-view of in-cylinder 47 Side-view of pressure transducer location [24]............................................. 47 Pressure transducer calibration data............................................................... Figure 3.1 Computed intake backflow distance and volume, 1200 rpm, cylinder displacement volume is 486cc[26]................................................... Figure 3.2 Calculated mass flow rates through intake valve at 0.4, 0.6, and 0.85 B ar MA P, [27] ....................................................................................... Figure 3.3 Intake and exhaust stroke in-cylinder pressure data ..................................... Figure 3.4 Cylinder pressure during intake and exhaust ................................................. Figure 3.5 Spark timing vs. HC with matched N-IMEP for propane and .. In d o len e........................................................................................................ Figure 3.6 Maximum cylinder pressure vs. spark timing with matching of N-IMEP for propane and Indolene Mixtures ................................................. Figure 3.7 Spark timing vs. HC with Nissan injector and propane ................................ Figure 3.8 Nissan Injector and Propane fueled N-IMEP vs. spark timing, w ith M A P = 0.5 bar ....................................................................................... Figure 3.9 Nissan Injector and Propane fueled N-IMEP vs. location of peak cylinder pressure, with MAP = 0.5 bar................................................. Figure 3.10 Location of peak cylinder pressure vs. spark timing ..................................... Figure 3.11 HC vs. Lambda for propane and pre-vaporized Indolene .. experim ents ................................................................................................ Figure 3.12 N-IMEP vs. Lambda for propane and pre-vaporized Indolene...................... 10 55 55 57 57 59 59 61 61 63 63 65 65 Figure 3.13 Effects of Lambda on cyclic variability ........................................................ Figure 3.14 HC engine warm-up experiments for propane and standard N issan injection of Indolene .......................................................................... Figure 3.18 Liquid fuel sweeps with Nissan and BMW injectors, OVI .............. Figure 3.19 Injection timing vs. HC for standard Nissan Injector and the low-flow BMW injector. Injection timing corrected for 175 degree transport delay .................................................................................... Figure Figure Figure Figure 4.1 4.2 4.3 4.4 Figure 4.5 Figure 4.6 Figure 4.7 Figure 4.8 Figure 4.9 Figure 4.10 Figure 4.11 Figure 4.12 Figure 4.13 Figure 4.14 Figure 4.15 Figure Figure Figure Figure Figure Figure Figure 4.16 4.17 4.18 4.19 4.20 4.21 4.22 67 67 69 69 81 Schematic of pre-vaporizing injector............................................................. 81 Air-Assist mass airflow estimation............................................................... 83 Liquid fuel injector probe locations ............................................................... Liquid fuel injection delay through fuel probes, based on liquid 83 fuel probe visualization study ........................................................................ Probe B Liquid fuel probe injection timing sweep, effect of fuel injection timing on HC and N-IMEP, 36% Indolene, balance . 85 P rop ane ......................................................................................................... effect of fuel sweep, Probe B Liquid fuel probe injection timing injection timing on HC and Cyclic Variation of N-IMEP 85 (Covariance), 36% Indolene, balance Propane ............................................ Probe A Liquid fuel probe injection timing sweep, effect of fuel injection timing on HC and N-IMEP, 36% Indolene, 87 balance Propane ............................................................................................ Probe A Liquid fuel probe injection timing sweep, effect of fuel injection timing on HC and Cyclic Variation of N-IMEP 87 (Covariance) , 36% Indolene, balance Propane ............................................ Probe C Liquid fuel probe injection timing sweep, effect of fuel injection timing on HC and N-IMEP, 36% Indolene, balance . 89 P rop an e ......................................................................................................... of fuel sweep, effect timing Probe C Liquid fuel probe injection injection timing on HC and Cyclic Variation of N-IMEP ............................. 89 Comparison of HC's for probes A,B, and C. 36% Indolene, 91 balance Propane ............................................................................................ Comparison of Covariance for probes A,B, and C. 36% 91 Indolene, balance Propane ............................................................................ 93 Indolene/propane fuel sweep CVI................................................................. 93 Indolene/propane fuel sweep OVI ................................................................ Comparison of standard deviations of N-IMEP for liquid fuel . 95 probe sw eep .................................................................................................. Comparison of OVI and CVI HC's for probes A and C............................... 95 97 Liquid fuel probe sweep CVI HC's .............................................................. 97 Liquid fuel probe sweep OVI HC's .............................................................. 99 Effect of liquid fuel on exhaust HC's, CVI ................................................... 99 Effect of liquid fuel on exhaust HC's, OVI ................................................... 101 Effect of liquid fuel probe mass on N-IMEP, CVI ......................................... 101 Effect of liquid fuel probe mass on N-IMEP, OVI ......................................... 11 Figure 4.23 Correlation of N-IMEP with the standard deviation of N-IMEP for all liquid fuel probe sweep data................................................................ Figure 5.1 Figure 5.2 Figure 5.3. CFD Simulation of 4-valve head, at WOT with one intake valve closed, 1500 rpm.[28] Nissan head configuration o v erlay ............................................................................................................. Relative liquid fuel transport mechanisms for probe locations "A " and "C " .................................................................................................... Relative comparison of liquid fuel transport mechanisms for different probe locations ............................................................................... 12 103 111 111 113 (This page was intentionally left blank) 13 (This page was intentionally left blank) 14 CHAPTER 1 INTRODUCTION 1.1 Mixture Preparation in SI Engines Spark Ignition engines are traditionally fueled by liquid fuel (gasoline) vaporizing and being entrained into the airflow entering the engine cylinder. The quality and repeatability of the combustion process in the engine combustion chamber is a function of the fuel-air mixture homogeneity and the mixture fuel-air ratio. This mixing of the fuel and air to produce a burnable mixture is referred to as mixture preparation. Early spark ignition engines were fuel by carburetors where liquid fuel is injected into the intake system at a central location well upstream of the intake valves. The carburetor fuel flow is metered by a venturi tube, which changes the fuel flow depending on intake airflow. More precise fuel control was achieved with the advent of the electronic fuel. Initially, fuel injectors injected fuel upstream of the throttle into the airflow, this type of electronic fuel injection is known as single point injection or central fuel injection (CFI). In more modern engines, each engine cylinder has its own fuel injector and liquid fuel is injected directly into the intake port of each cylinder; this is referred to as multipoint fuel injection or port fuel injection (PFI). Electronic fuel injection metering is controlled using an engine control unit (ECU) which injects the appropriate fuel amount based one or more of the following: mass airflow sensors, manifold intake pressure sensors located in the intake port, throttle position, or a lambda sensor in the exhaust manifold. A more detailed description of these fuel metering systems can be found in [1] and [2]. Regardless of the type of fuel metering system, the liquid fuel must become mixed with the air and evenly distributed into the engine cylinders. Liquid fuel normally enters the airflow in the form of drops. These liquid fuel drops though partially vaporized are deposited onto the port wall and valve forming a fuel film, or transported directly into the engine cylinder. These transport processes are highly dependent on engine temperature, fuel injection location, intake port geometry, fuel injector spray pattern, engine speed, engine load, and fuel properties. Under ideal conditions, all the liquid fuel should be vaporized and mixed uniformly with the air, as the mixture enters the engine cylinder. However, real engines and real operating conditions are not ideal. Previous work has shown that with port fuel injection liquid fuel is deposited on the intake valve and surrounding intake port walls for all operating conditions [3]. 15 1.2 Hydrocarbon emissions in the Federal Test Procedure Federal Regulations require that all passenger vehicle emissions be measured using a standardized test which represents standard driving conditions. In the United States this test is called the Federal Test Procedure or FTP 75. A typical FTP driving cycle for a 90's model Saturn 1.9 L, is shown in Figure 1.1. The first cycle of the FTP (120 seconds) simulates the cold-start and warm-up period of engine operation. During this period, prior to catalyst light-off, tail-pipe HC emissions are high. Several factors contributing to the extra HC emissions are larger crevice volumes, higher gas density in crevices, increased oil absorption, lower exhaust port oxidation, larger quench volume, and substantial liquid fuel on the cylinder walls and in crevices. Hydrocarbon emissions during the first cycle (Bag 1) of the FTP emissions test are the source of 74-94% of the total emissions for FTP test. Previous studies have indicated that liquid fuel in the cylinder may be a major contributor to HC emissions during cold operation. Future regulations, such as the ultra low emissions vehicle (ULEV) specified by the California Air Resources Board (CARB), are placing stricter limits on the allowable HC emissions. Future emissions regulations make the understanding of the sources of HC emissions during cold-start and warm-up of considerable importance. 1.3 Sources of Hydrocarbon Emissions The six sources of the unburned hydrocarbons: oil layers, deposits, liquid fuel, quenching, crevices, and exhaust valve leakage are the primary focus of the following sections. discussion of liquid fuel hydrocarbons is contained in section 1.4. The Cheng [4] developed a flowchart which outlines the unburned hydrocarbon emissions mechanisms in a spark-ignition engine during steady-state engine operation, this flowchart is shown in Figure 1.2. Currently, the largest source of HC is believed to be crevices in the combustion chamber. Crevices are narrow regions connected to the combustion chamber where unburned gas can escape combustion. Previous research indicates that during steady-state engine operation approximately 5% of the injected fuel escapes initial combustion due to crevices [4]. The crevices in the combustion chamber where HC may escape combustion are the cylinder head gasket crevice, spark plug crevice, valve seat crevice, piston ring pack crevice, and the piston top land crevice as shown 16 in Figure 1.3. The piston top land crevice is the volume between the cylinder wall and piston extending from the piston crown to the top piston compression ring. The piston ring pack crevice is the volume contained in the piston ring grooves and clearances and is believed to account for approximately 85% of the total crevice volume according to Min [5]. Sterlepper conducted several experiments to study the HC emissions during cold-start and warm-up using three different pistons with different crevice volumes [6]. The engine warm-up data shown by Sterlepper's data in Figure 1.4 indicates that the HC emissions during cold-start are virtually independent of crevice volume. However, as the engine warms-up the HC emissions decrease to different steady-state values. Sterlepper states that at start up, the cool wall temperatures cause the flame to quench before reaching the piston crevices. Recent experimental studies on deposits suggest that during steady-state engine operating conditions between 0.2 and 0.5% of the injected fuel was emitted as unburned HC due to deposits [7]. Previously, Cheng et al. estimated this value to be about 1% [4]. Under warm operating conditions the oil layer mechanism accounts for less than 10% of the total HC emissions [8]. Research by Hochgreb and Kaiser suggest that approximately 80% of the desorbed fuel is oxidized when returned to the cylinder [9],[10]. Due to lower temperatures and a corresponding higher absorption of gasoline into the oil layer, the oil layer contribution to HC emissions is expected to be higher at lower temperatures [4][8]. Initially a large amount of fuel is absorbed into the oil reaching a maximum value 50 seconds after cold start [11]. Cheng et al. [4] estimated that under steady-state operation 0.5% of the injected fuel is emitted as unburned HC due to flame quenching at the cylinder walls. During cold engine operation the wall temperatures are cooler and the quench layer is expected to increase in thickness leading to an increase in HC. Experimental studies indicate that 5-7% of the engine out Hydrocarbon emissions may be due to exhaust valve leakage [12][13]. These leaks are likely due to valve and seat distortion due to thermal and other loads; and by deposit flakes being trapped in the valve seat [13]. 1.4 Previous Work on Liquid Fuel Hydrocarbon Emissions Previously, Cheng et al. [4] estimated that 1.2% of the injected fuel is emitted as unburned HC due to liquid fuel in the cylinder. Several researchers have studied the effects of 17 liquid fuel during steady-state engine warm operation and during warm-up [14][15][16][17][18][19]. Min and Kaiser conducted a series of experiments using a pre-vaporizing injector during engine warm-up. Min et al. [16] measured the engine out hydrocarbon emissions for an engine run on pre-vaporized Indolene and normal liquid injection of Indolene. Min found that the HC levels were four times higher during the first 50 seconds of engine operation when using standard port fuel injection compared to pre-vaporized injection. Kaiser et al. [18] conducted an experiment similar to Min's where standard port fuel injection (PFI) and pre-vaporized central fuel injection (PV-CFI) were compared during a 23 'C cold start. In Kaisers' study, special care was taken to inject the same amount of fuel for both injection methods and fuel-rich operation was avoided (this minimizes the effect of fuel control and allows for comparison)[18]. A surprising result of this study was that under light load conditions the fuel preparation can have negligible effect on the engine-out HC as can be seen in Figure 1.5. Imatake and Kudo [17] developed an engine experiment where the intake and exhaust valves are electronically sealed at a specific point during firing operation. The intake port and cylinder are sealed and both the cylinder and port are vented with 200'C air (200'C is the end point of distillation for the given test fuel). This method allows for total vaporization of the fuel, the vented air and vaporized fuel are then sampled with a flame ionization detector (FIID). These researchers found that during warm-up 9 times the injected amount of fuel is stored as a fuel film on the intake port wall (135 mg on port, standard injection is 15 mg per cycle). The corresponding in-cylinder wall wetting was 2.5 times the injected amount. Under steady-state warm conditions (80'C coolant) 3 times the injected amount is stored on the intake port and 0.8 times the injected amount is found in-cylinder wall wetting. Imatake found that, during warm-up, the cylinder contained 37mg of liquid fuel; and 12mg during steady-state operation. The normal injection amount for this study was 15 mg per cylinder. The wall wetting amount in the port and cylinder for cold-start and warm engine operating conditions are shown in Figure 1.6. This same technique was used to study the effects of open valve injection (OVI) vs. closed valve injection (CVI). They found that with open valve injection 18% more of the injected fuel is transported directly into the cylinder resulting in 16% more in-cylinder wall wetting. They also found that with open valve 18 injection there is 7% less port wall wetting but this port wall film has a 12% lower evaporation rate than the port wall film for closed valve injection. Shayler et al. [19] performed a fuel audit on an unmodified Ford Zetec 1.81, 16 valve, four cylinder engine during cold-start. Shayler found that for a 20'C cold start 20 mg and 10mg of liquid fuel are stored in the cylinder during the first 50 and 100 seconds of engine operation (normal injection amount was 20 mg/injection). Fry and Nightingale [20] found that under certain operating conditions a wall film was seen to form in the crevices around the inlet and exhaust valves and the apex of the pent-roof head. This wall film would form during induction and remain unburned throughout the combustion process. This film would then be sucked out of the cylinder during the exhaust blowdown process as liquid fuel. This tendency to form a wall film in this location was stronger for CVI than for OVI for all load and speed conditions studied. Witze and Green at Sandia conducted a visualization study using LIF and Flame-Emission imaging of liquid fuel films and pool fires [21]. The engine setup consisted of a Bowditch piston with a window in the piston crown to provide optical access to 80% of the combustion chamber. The engine head was a standard DOHC with four valves per cylinder, mounted on a single cylinder crankcase. At all engine coolant temperatures 20, 40, and 60 'C there was a significant difference in the distribution of the pool fires for CVI and OVI. CVI generally resulted in larger pool fires below the intake valve squish region, possibly on the piston in some cases. OVI resulted in a wider distribution of pool fires throughout the cylinder but primarily resulted in pool fires between the exhaust valves. This pool fire between the exhaust valves suggest that it is likely that liquid fuel is swept out of the cylinder during the exhaust stroke. Stanglmaier studied the effect of in-cylinder wall wetting location on HC emissions using a specially designed spark plug mounted injector probe [14][15]. This directional probe allowed liquid fuel to be injected onto specific locations within the combustion chamber. This method allows for the quantification of the fate of specific amounts of liquid fuel deposited at different locations within the combustion chamber. This experimental probe is shown in Figure 1.7. The fuel is deposited on the cylinder liner just below the head. This engine test rig set-up consisted of an optically accessible engine that is geometrically identical to a GM Quad-4, 2.26L, 4-valve, 4cylinder engine. The engine was fueled on liquefied petroleum gas (LPG), which is approximately 95% propane, and a small amount of California Phase 2 fuel which was injected through the 19 injector probe. The engine was run slightly lean at X = 1.1, approximately 85% of the fuel was LPG and approximately 15% of the fuel was liquid California Phase 2. These experiments indicated that the location of the liquid fuel within the cylinder has a very significant effect on the engine-out HC. The probe wall wetting locations are shown in Figure 1.8 and the effects of wall wetting location on HC's is summarized in Figure 1.9. The highest HC emissions were found to come from wall wetting at the E-E location, wall wetting on the exhaust side of the cylinder in-between the exhaust valves. The next most significant HC came from wetting of the piston top. The lowest HC came from wall wetting location I-I, wall wetting on the cylinder in-between the intake valves. Stanglmaier suggest that the differences in the HC for the different wall wetting locations can be explained in terms of the physical location of the liquid fuel relative to the exhaust valves. He explains, liquid fuel deposited on the cylinder wall is scraped into the piston top land during the compression stroke and then laid back on the cylinder wall during expansion as a liquid fuel film. Any of this fuel film that survives the combustion and post-flame oxidation process will be scraped into the roll-up vortex during the exhaust stroke. The portions of the roll-up vortex closest to the exhaust valves have a higher chance of be exhausted than the portions of the vortex farther from the exhaust valves [14][15]. Injection timing was varied from 90 degrees before exhaust TDC to 270 degrees ATDC exhaust with both 90*C and for 36'C coolant temperatures. These experiments indicated that HC are only weakly dependent on injection timing for all injection locations for both coolant temperatures. Stanglmaier suggest that the liquid fuel evaporation from the combustion chamber surfaces is a slow process relative to the engine cycle. Yang and Kaiser conducted several engine experiments where the effects of fuel injection droplet size and fuel injection timing were examined [22]. These experiments consisted of three injectors: a production injector Sauter mean diameter (SMD) 300gm, an air-assisted injector SMD 40gm, and an air-forced injector SMD 14gm. They found that the droplet size had a large impact on HC's during open valve injection at lower coolant temperatures. At lower coolant temperatures, the HC's increase by 40% and 80% for A/F = 12.7 and A/F = 16.2 respectively for the standard injector (300 gm). The HC's did not change outside of the experimental error for the air-forced injector (14gm) during open and closed valve injection at the lower coolant temperature (30'C) and the overall HC level was lower for this injector compared to the standard injector. 20 During warm engine operation 89'C coolant the droplet size had a much lower impact on the engine-out HC levels for both OVI and CVI during rich and lean fueling. The standard injector showed no significant change in HC's during fuel rich operation for OVI and CVI. The HC's were 20% higher for OVI vs. CVI injection for fuel lean operation with the standard injector. 1.5 Project Scope The effects of liquid fuel on engine-out HC emission is not well understood at this point. Additionally, the effects of liquid fuel are believed to be of increased importance during cold-start engine operation when the crevice volumes are larger, the quench layer is thicker, and the port and cylinder wall temperatures are lower. The relationship between liquid fuel location in the port and subsequent location in the cylinder on HC emissions is also unclear. The purpose of this work is to develop a fundamentally based description of liquid fuel buildup and transport into the engine and to develop a method of quantifying the liquid fuel contribution to HC emissions. A novel liquid fuel injector probe was developed which deposits controlled amounts of liquid fuel at three precise locations around the intake valve seat. By controlling the amount and location of the injected liquid fuel and measuring the engine-out hydrocarbon (HC) emissions we can estimate the liquid fuel contribution to these emissions. The various injector probe locations allow us to estimate the fate of liquid fuel entering the cylinder from different locations in the port and deposited onto different locations in the cylinder. 21 (This page was intentionally left blank) 22 Part-Load 1500 rpm 1000 rpm 1.1 1.1 M BT MBT 0.345 bar, MAP 2.62 bar, BMEP 11% 18% Idle Speed Lam bda S park Load %Liquid Fuel Table 1.1 Engine test matrix used by Stanglmaier [14] 0-50 seconds 0-100 seconds Min [16], WOT, 900 rpm, PV 4250 ppm C1 4100 ppm C1 Min [16], WOT, 900 rpm, PFI 12000 ppm C1 9750 ppm C1 Kaiser [18], 3.72bmep, 1200 rpm, PV 3250 ppm C1 3025 ppm C1 Kaiser [18], 3.72bmep, 1200 rpm, PFI 4060 ppm C1 3615 ppm C1 Kaiser [18], 0.74bmep, 1200 rpm, PV 2500 ppm C1 2350 ppm C1 Kaiser [18], 0.74bmep, 1200 rpm, PFI 2500 ppm C1 2350 ppm C1 Shayler [19], 0.7 MAP, 2000 rpm PFI 20 mg 10mg Imatake (17], 1200 rpm, 40Nm, open valve inj. 37 mg, 30deg coolant 12 mg, 80 deg coolant Table 1.2 Summary of experimental data on HC emissions during startup, effects of liquid fuel in the cylinder. PV-pre-vaporized fuel, PFI- normal port fuel injection. *- this data is for different steady-state coolant temperatures not for the transient start-up conditions. 23 (This page was intentionally left blank) 24 .80 300~ iBag 275enf 0 U- en C-) 225200175 150 12510 2 a. I Bag - -20 --20 -40 I-....... _0U 0 1000 500 2000 1500 Time (seconds) Figure 1.1 Federal test procedure, FTP 75 1 Fuel (100%) 91.5% 8.5% Flame converts fuel to CO 2, CO, H2O, H2 etc. , HC Mechanisms 1' Fuel Only - -- q. Fuel SLi 1.2%) Fuel- Air Mixture --- ------ --- Deposits Oil Layers Quenching Crevices (0.5%) (1%) (0.5%) (5.2%) rankcase (0.2%) 2.2% 4 1/3 Oxidized 4. % 5.1% - Recycled - 1.7{% e I Blow-by (0.6%) - Recycled- HC in Residual Unburned j (1.1%) - Recycled - 1/3 Exhaust Oxidation (0.8%) e (0.1%) In-Cylinder Oxidation I 2/3 Oxidized 1.5% '-f Exh. Valve Leakag 2.1% 1/3 - 1.3% :. F Fully Burned Exhaust Engine- out HC (1.4% Figure 1.2 Steady-state HC emissions flowchart [4] 25 di (This page was intentionally left blank) 26 Spark plug thread crevice Lubricating oil absorbtion and desorblon Valve seat crevice Cylinder head gasket crevice Piston ring pack crevices Bulk quenching within flame front for lean mixtures and high turbulence Figure 1.3 Crevices in the combustion chamber [2] 2400 Piston Crevice Volumes 2000 -a- E 0 0.613 cm3 -a- 1.665 cm3 -A- 1.675 cm3 1600 400- E LU800 400 0 0 2 6 4 8 Time (seconds) Figure 1.4 Effect of crevice volume during warm-up [6] 27 10 (This page was intentionally left blank) 28 8000 S I 6000 4000 8000 - I S MID LOAD LICHT LOAD - PFI Ii I C 6000 ~3000 K CF, 2000 LA 0 0 20 100 80 60 40 TIME AFTER COtD START (SEC) 0 20 40 60 80 TIME AFTER COLD START (SEC) b) a) Figure 1.5 Plot of total, engine-out HC emissions versus time after coldstart for two standard injection (PFI) and two pre-vaporized injection (PV-CFI) starts. a) light load- 1200rpm, 0.74 bar BMIEP, fuel flow 0.9 g/sec. b) mid load- 1200rpm, 3.72 bar BMEP, fuel flow 1.75 g/sec [18] 160 140 E P o rt Wetting El Cylinder Wetting 120 100 - 80 P - 60 40 - 20 0 Warm Warm-up Figure 1.6 Liquid fuel distribution in the port and cylinder during coldstart and warm engine operation [17]. 29 too (This page was intentionally left blank) 30 Figure 1.7 Schematic of liquid fuel injector probe used by Stanglmaier [14]. I-I E-I E-E Figure 1.8 Liquid fuel injection location for direct injection of fuel used by Stanglmaier [14][15]. 31 (This page was intentionally left blank) 32 6000 5000 4000 E3000 2000 1000 0 E-E I-E E-1 I-I Piston Top Wetting Location Figure 1.9 Effect of wall wetting location on engine-out HC's, Stanglmaier [14]. 33 (This page was intentionally left blank) 34 CHAPTER 2 EXPERIMENTAL METHOD 2.1 Nissan Test Engine A Nissan SR20DE, 2L production four cylinder spark ignition engine was used for all experiments. The 1991 Nissan Sentra engine has four valves per cylinder and a pent roof head design with direct overhead camshafts. Previous to this study, the engine was modified to run on only one cylinder with the other three cylinders motored. The three motored cylinder intake runners are separated from the intake plenum by a copper plate, the three runners are vented to the atmosphere. The exhaust manifold was also modified to separate the firing cylinder from the three motored cylinders. This setup allows for precise control and measurement of the airflow and exhaust gas of the firing cylinder. The complete engine technical specifications are listed in Table 2.1. The Nissan engine is coupled to a 100HP Dynamatic dynamometer that is capable of motoring the engine or absorbing the engine output when firing. Because of the intake manifold modification, three of the four cylinders are motored at all times. Therefore, even while firing on one cylinder, the engine load must increase to approximately 70% of maximum to overcome the friction of the motored cylinders and produce positive power output. Regardless of load however, the engine speed was maintained with a Digalog controller. The fuel injector and port geometry of the engine used in these experiments is shown in Figure 2.1. The standard injector configuration consist of a 4-hole Nissan injector located approximately 8.5 inches upstream of the intake valve. The injector has a 6 degree view of the intake valve, the standard injector can only see 30%-40% of the total valve surface area. Experiments were carried out to determine the emissions characteristics of the standard fuel injection configuration. 2.2 Nissan Engine Control System The Nissan engine was custom fitted with a 1999 Motec M4 engine control unit. This programmable engine control unit (ECU) allowed for continuous monitoring of all critical engine 35 variables; manifold intake pressure (MAP), coolant temperature, intake air temperature, engine speed, spark timing, fuel injection timing, and fuel injection pulse width. All measurement devices used by the ECU were supplemented by a secondary and pre-existing measurement system already on the Nissan engine. The Motec ECU allowed for 1 degree crank angle resolution for spark timing and fuel injection timing across all operating speeds. Fuel pulse width resolution could be controlled to within 0.1 ms (normal injector pulse width at 0.5 bar MAP is approximately 8 ms). The ECU allowed for the firing cylinder to be fueled with two injectors with different fuel injection pulse widths. The programmable ECU also allowed for real time control of spark timing, fuel injection amount, fuel injection timing. 2.3 Engine Measurement Systems In order to enhance measurement precision of intake mass airflow (MAF) a 55 gallon damping tank was placed ten feet downstream of the mass airflow sensor and six feet upstream of the throttle. The intake airflow was measured using a Kurz, model 505-9A, mass air flow meter and is displayed in units of grams per second. The Intake manifold pressure was measured at the intake plenum entrance using a Data Instruments Model SA pressure sensor. The fuel/air ratio was monitored using two independent universal exhaust gas oxygen sensors; a Horiba Model MEXA-11OX universal exhaust gas oxygen sensor mounted approximately 26 cm downstream of the exhaust port and a GM wide range lambda sensor mounted 30 cm downstream of the exhaust port. The Horiba universal exhaust gas oxygen sensor was used for all fuel metering while the secondary GM lambda sensor served as a check to ensure that the Horiba sensor measurement values did not drift. Engine coolant temperature was controlled through an external heat exchanger, cooled by a chilled water supply. An external oil cooling circuit was also used to maintain the oil sump temperature. The oil and coolant temperature were maintained at 800 C for all experiments with a standard deviation of 1*C. The engine was fitted with a 360 degree optical shaft encoder which outputs one digital five volt pulse every degree of rotation as well as one digital five volt pulse per revolution. The one pulse per revolution signal and the in-cylinder pressure data are used by the data acquisition program to synchronize the data acquisition analysis program with the correct engine cycle 36 position. All data was sampled at a 1 degree interval using the output from a 360' degree per revolution optical shaft encoder as the data acquisition trigger. 2.4 In-Cylinder Pressure Measurement The in-cylinder pressure was measured using a Kistler 6051 piezoelectric pressure transducer located in the cylinder head as show in Figures 2.2 and 2.3. The pressure transducer is mounted in the cylinder head between the intake and exhaust valves of the number four cylinder. The output signal from the pressure transducer was sent to a Kistler model 5010A dual mode charge amplifier, the output signal of this amplifier was then sent to the data acquisition system. In order to get an absolute pressure measurement from the pressure transducer, the pressure must be referenced at one point in the cycle. The in-cylinder pressure was set to be equal to the intake manifold pressure at BDCC. This is the recommended procedure used by Ford Motor Company for low speed operation [23]. The in-cylinder pressure transducer was calibrated with a dead weight tester over the pressure range of 1 to 35 bar to check for linearity. A typical pressure calibration test is shown in Figure 2.4. A further discussion of the in-cylinder pressure measurement system used on this engine can be found in [24]. 2.5 Hydrocarbon Measurement System The Hydrocarbon emissions were measured using a Rosemount Model 402 Hydrocarbon Analyzer. The Hydrocarbon Analysis is based on flame ionization. The engine exhaust was sampled from a ten gallon damping tank located 5 feet downstream of the exhaust port. The sample was then drawn through a heated 15 foot line, the heated line temperature was set at 275'C to prevent HC condensation in the sampling line. The Hydrocarbon Analyzer was calibrated using nitrogen (0 ppm Cl) and propane calibration gas (4536 ppmCl). Two different methods of calibration were utilized: first the calibration gases were fed directly into the analyzer and second, the same calibration gases were fed through the heated sampling line. This calibration technique ensured that no residual hydrocarbons were in the sampling line. To reduce the probability of residual Hydrocarbons in the sampling line the heated line was purged for five minutes with nitrogen at the beginning and end of every experiment. At a fixed operating condition, the engineout hydrocarbon emissions day to day variation was found to be approximately 200 ppmC 1. 37 2.6 Labview Data Acquisition Program The data acquisition system used in all experiments consisted of a Dell Pentium II computer, National Instruments PCI-6025E multi-function 1/0 board, National Instruments BNC2090 BNC connector board, and a custom Labview 5.1 data acquisition program. The specifications for the Data Acquisition board are given in Table 2.2. A Labview Data Acquisition program was written specifically for these experiments. This program was designed with a continuously buffered data acquisition program, allowing the program to sample and process a virtually unlimited number of engine cycles. The program automatically calculated a continuous running average value for the Horiba Lambda sensor, the GM Lambda Sensor, mass airflow (MAF), manifold pressure (MAP), and average in-cylinder pressure based on the formula below. New Average = [(Old Average * (Number of Samples - 1)) + New Value] / (Number of Samples) This program also calculated the net indicated mean effective pressure (N-IMEP) for each engine cycle. The in-cylinder pressure trace was displayed for each engine cycle and the N-IMEP for each engine cycle was also plotted for comparison. The program monitored each engine cycle for possible engine misfires, indicated by a negative N-IMEP. If an engine misfire was detected a warning indicator turns red, and the number of misfires was counted. After the desired number of engine cycles were acquired, the program output an average incylinder cycle pressure trace to a text file. The program also calculated the average N-IMEP, the standard deviation of N-IMEP, peak cylinder pressure, and location of peak pressure. The complete list of program output values is listed in Table 2.3. All input voltages to the data acquisition board were converted to the appropriate units prior to being processed within the data acquisition program. The conversion formulas are listed in Table 2.4. 2.7 Engine Operating Conditions Liquid fuel flow into the engine cylinder is affected by many different engine variables, therefore an experimental test matrix was developed. The review of previous work indicated that the method of fuel injection and fuel targeting play a crucial role in the HC due to liquid fuel [3]. 38 In standard port fuel injection, a liquid fuel film builds up in the intake port and around the valve seat for both open and closed valve injection. The baseline operating condition was chosen to be 1500 rpm with MAP equal to 0.5 bar, this is close to the typical part load operating condition used by the auto industry. Engine speed was not varied for this study because speed should only have a minor impact on liquid fuel hydrocarbons. The spark timing was optimized for maximum brake torque (MBT). MBT is defined as the spark timing which results in maximum N-IMEP and corresponds to peak pressure locations between 130 and 150 ATDC. 39 (This page was intentionally left blank) 40 Engine Type Displacement / Cylinder (cm3 ) Clearance Volume (cm 3) Bore x Stroke (cm) Compression Ratio Intake Valves (34 mm Diameter / 10.2 mm Max Lift) Exhaust Valves (30 mm Diameter / 9.4 mm Max Lift) Valve Overlap Period 4 valve/cylinder DOHC Aluminum Head/Block 500 58.77 8.6 x 8.6 9.5 Open 130 BTDC Close 235' ATDC Open 4830 ATDC Close 7230 ATDC 160 Table 2.1 Nissan engine specifications I/O Board Analog Inputs Resolution Sampling Rate Input Range Analog Ouputs Analog Output Rate Analog Output Range Digital 1/O Counter/Timers National Instruments PCI-6025E 16 single ended/ 8 Differential 12 bits 200 kS/ +/- 0.05 to +/- 10 V 2 10 kS/s +/- 10 V 32 2, 24-bit Table 2.2 National Instruments data acquisition specifications 41 (This page was intentionally left blank) 42 Number of cycles acquired Number of Misfires Average N-tMEP (Bar) Standard Deviation Of N-tMEP (Bar) Maximum Cylinder Pressure (Bar) Location of Maximum Cylinder Pressure Average Mass Airflow (g/s) Average Manifold Pressure (Bar) Average Horiba Lambda Average GM Lambda 2 (deg. AT DC) Table 2.3 Data output variables from data acquisition program Signal input In-Cylinder Pressure Top Dead Center Signal Mass Airflow Manifold Pressure Horiba Lambda Sensor GM Lambda Sensor Slow RD V - Volts V - Volts V - Volts V - Volts V - Volts V - Volts V - Volts Conversion Formula 4.72*V - 0.55 1*V 100*V 0.36*V - 0.35 1*V - 0.55 -0.15 *V^2 -0.11*V + 1.1 -4020*V - 9.24 Output units Bar Volts grams/second Bar Lambda Lambda ppm C1 Table 2.4 Conversion factors for raw voltage input to data acquisition system 43 Average HC (ppm Cl) (This page was intentionally left blank) 44 Figure 2.1 Standard intake runner and intake port geometry for the Nissan Sentra engine Figure 2.2 Top-view of in-cylinder pressure transducer location 45 (This page was intentionally left blank) 46 Kier 6051 3 mm Piston #4 @ TDC Recession = 6 mm +--+ Figure 2.3 Side-view of pressure transducer location [24] 40 35- y= 4.6828x - 0.3831 R2 = 0.9997 3025U) 20U) 15 105 U 0 2 6 4 Volts Figure 2.4 Pressure transducer calibration data 47 8 10 (This page was intentionally left blank) 48 CHAPTER 3 EFFECTS OF ENGINE OPERATING PARAMETERS ON HC 3.1 Factors Affecting Liquid Fuel Distribution Liquid fuel volume and distribution within the cylinder is dependent upon the intake airflow and liquid fuel distribution within the intake port. The intake airflow is determined by: intake port geometry, intake and exhaust valve timing, intake manifold pressure, and engine speed. The liquid fuel distribution in the intake port is dependent upon engine coolant temperature, intake valve temperature, injection timing, fuel injector targeting, injector spray angle, and fuel injector droplet size and velocity. 3.2 Intake Airflow Processes When the intake valve first begins to open, the cylinder pressure is higher than the intake port pressure. This large pressure difference between the cylinder pressure and the intake manifold pressure and the small intake valve gap as the valve begins to open, results in a sonic backflow of exhaust gases into the intake port. This high-speed backflow of hot exhaust gases can redistribute and vaporize the liquid fuel in the intake port, this effect is more significant at lower loads when the pressure difference is higher. Experiments by Almkvist and Dahlberg found that this blowback can blow fuel droplets far back into the intake ports at velocities up to 40 m/s [25]. An engine simulation model developed at MIT estimates the distance which cylinder gas is blown back into the intake port at 1200 rpm [26]. Figure 3.1 indicates that as the intake manifold pressure (MAP) decreases the blowback gas volume and distance increase. Previous experiments by Cheng, estimated the mass flow rates through the intake valve at different intake pressures based on the cylinder pressure data [27]. The three different intake processes can be seen in Figure 3.2. When the blowback process has ended the piston motion induces a forward flow of air into - the cylinder. The intake process continues until after the piston reaches bottom dead center (BDC). The compression stroke then begins to displace the charge mixture in the cylinder. At higher speeds the inertia of the incoming airflow "rams" extra charge into the cylinder after BDC. This allows for a higher volumetric efficiency at higher speeds but results in cylinder charge being 49 displaced as a backflow into the intake port at lower speeds. The intake valve typically closes 40 to 60 *after BDC resulting in a displacement blowback into the intake port at low operating speeds. The intake and exhaust valve timing and resulting in-cylinder pressure data at the standard operating point are plotted in Figures 3.3 and 3.4. By examining the in-cylinder pressure we can estimate approximately where the three intake processes occur at the standard engine operating condition of 1500 rpm and 0.5 bar MAP. The local minimum in the in-cylinder pressure trace at point A, just after EVC is the estimated point where the blowback into the intake port stops and the forward flow induction process begins. The induction process continues until a few degrees after BDC. Approximately 50 after BDC (Point C) the cylinder pressure begins to rise during the compression stroke and charge is displaced into the intake port. As the manifold pressure increases, the initial overlap backflow of gases into the intake port decreases. Increased engine speed reduces the displacement blow back at the end of the intake process. Qualitatively we can see from Figures 3.2 and 3.4 that the overlap and displacement backflows are of approximately the same order of magnitude at the standard operating conditions used in this study. 3.3 Effects of Spark Timing To characterize the HC emissions sensitivity to various operating parameters for this test engine, a test matrix was developed investigating the effects of spark timing, fuel air ratio (lambda), fuel type, and mixture preparation. The effects of spark timing on HC are shown in Figures 3.5 and 3.7, spark timing has a modest impact on HC emissions for the Indolene fuel spark-timing experiments. The propanefueled experiments indicated a slight increase in HC with spark advance. With increasing spark advance the maximum cylinder pressure increases and is located closer to TDC, causing more unburned charge to be stored in the crevices. The spark timing also changes the in-cylinder gas temperatures. The packing of unburned mixture may be of more significance to the propane fueled experiments due to the fully mixed air/fuel charge. A change in spark timing by 5 degrees advanced or retarded causes a 13% increase or decrease in the average maximum cylinder pressure and a shift of this peak pressure by 3.5 degrees for both fuel types. Figures 3.8 and 3.8 indicate that the propane has a maximum N-IMEP when the peak pressure is located around 13 deg. ATDC with a spark timing of 23 BTDC. Indolene fueled spark sweeps indicate a maximum N-IMEP 50 around 15 deg. ATDC corresponding to a spark timing of around 21 deg. BTDC. A second set of propane and Indolene spark timing sweep experiments were controlled by matching the intake manifold pressures for each fuel type. The mass airflow measurements of this experiment revealed that the propane/air displacement causes a 3% decrease in volumetric efficiency and a corresponding to a 5% decrease in N-IMEP. These spark timing experiments indicated that the NIMEP curve is relatively flat near MBT timing and that the HC do not change significantly for spark timing, slightly advanced or retarded from MBT. 3.4 Effects of Relative Air/Fuel Ratio, Lambda The effects of air/fuel ratio on HC emissions for propane and vaporized Indolene were examined by running the engine at fuel rich and fuel lean conditions. The behavior of the HC emissions are distinctly different on the rich and lean sides of stoichiometric engine operation as shown in the HC and N-IMEP vs. Lambda curves shown in Figures 3.11 and 3.12. Under fuel-rich engine conditions (Lambda <1), the HC level increases linearly as the charge mixture moves from stoichiometric to rich engine operation. This is the expected trend as the burning mixture is airlimited, therefore an increase in the required fuel above stoichiometric results in a corresponding increase in HC emissions. The N-IMEP curve shows a slight increase in N-IMEP as the charge mixture becomes slightly fuel rich, with a peak around X=0.95. This peak in N-IMEP is due to dissociation of CO 2 and H2 0 at the high temperatures following combustion, molecular oxygen is present in the burned gases under stoichiometric conditions, so some addition fuel can be added and partially burned [1]. On the lean side of stoichiometric the N-IMEP decreases linearly due to the decreased amount of fuel available for combustion. The HC emissions decrease as the charge becomes fuel-limited until a minimum is reached at X=1.1. An increase in lambda above 1.1 causes an increase in HC as the total burn duration increases and the cyclic variability increases. For a further discussion of the effects of relative air/fuel ratio refer to [1]. The trends in N-IMEP with lambda are identical for propane and pre-vaporized Indolene. There is a slight difference in the slopes of the HC/lambda lines for the propane and the prevaporized Indolene. The difference between the two fuels in terms of HC is believed to be due the different fuel properties of propane and Indolene. It is surprising however that there is not a constant difference in the HC values. This data suggest that the chemical composition and 51 corresponding differences in combustion between Indolene and propane should be considered in the comparison of propane and Indolene experiments. 3.5 Coolant Temperature Experiments Due to the increase in HC levels during cold engine operation, experiments were conducted to characterize the engine under a prolonged engine cold-start/warm-up experiment. These experiments were conducted at the standard engine operating point and the engine coolant temperature was slowly raised to standard engine coolant temperature over a 40 minute period. Two test are shown for each engine fueling condition in Figure 3.14. The engine was fueled with the standard Nissan injector with closed valve injection and with propane. The Nissan injector fueled with liquid Indolene has a much higher HC level at cold operating conditions than at warm engine conditions. The Nissan injector also has a change in the HC/coolant temperature slope around 50'C. For coolant temperatures above 50'C, the propane and Indolene fueled experiments have the same slope. The propane warm-up experiment demonstrates a linear dependence of HC vs. coolant temperature. Because propane is not absorbed into the oil layer and is a gaseous fuel, we cant postulate that the increase in HC with decreasing coolant temperature, for the propane experiment, is primarily due to the increased quench layer thickness, changes in HC oxidation, and increased crevices volumes. The higher HC's, at low coolant temperatures, for the Indolene fueled experiment are believed to be due the increased amount of liquid fuel entering the combustion chamber. 3.6 Propane and Indolene Fueling To examine the emissions impact of running the engine on different stoichiometric mixtures of propane and liquid Indolene a series of "liquid fuel sweep" experiments were done. The engine was initially fueled by gaseous propane then a small amount of liquid Indolene was injected and the propane flow was reduced to maintain a stoichiometric mixture. Figure 3.18 indicated that the HC level was directly proportional to the propane/Indolene mixture. These experiments were done with OVI timing using both the standard Nissan injector and the low-flow BMW injector. 52 3.7 Effects of Fuel Injection Timing By varying the fuel injection timing, the effects of OVI vs. CVI can be examined. The effect of fuel injection timing on HC is shown in Figure 3.19, the data presented in Figure 3.19 consist of the average of two injection timing sweeps for each injector where each data point was the average of 1000 engine cycles. The end of injection at the injector tip is plotted against the actual valve timing. The HC peak before the IVO is indicative of the transport delay of fuel from the injector tip to the intake. valve. There is a clear peak in the HC level for both the Nissan injector and the low-flow BMW injector. This peak is the result of the maximum amount of liquid fuel being transported into the cylinder, both the fuel droplets which are entrained into the intake flow as well as liquid fuel film. Perhaps the more interesting observation that can be made from this figure pertains to the closed valve portions of the graph. Figure 3.19 indicates that there is no significant difference in HC's for "early CVI" (injection just after IVC) and "late CVI" (injection just before IVO). Assuming that the liquid fuel distribution within the intake port is the same for early and late CVI the HC's indicate that there is no significant difference in intake port fuel evaporation for early vs. late CVI. The large difference between open and closed valve injection is due to a variety of factors such as the distribution of liquid fuel within the intake port, amount of evaporation in the port, fuel droplet size, and blowback during IVO. These differences are likely to result in a difference in mixture homogeneity within the cylinder and significantly different distributions of liquid fuel within the cylinder. 53 (This page was intentionally left blank) 54 A 20 300 E - 15 E 4) a 0200 10 0 100 ' ' 0 0 '0 0.2 0.4 0.6 0.8 1 Intake Pressure MAP (bar) Figure 3.1 Computed intake backflow distance and volume, 1200 rpm, cylinder displacement volume is 486cc[261 p= 0.85 atm p =P0.6 atm 0.4 atm 10 CACA: 0W am am. MM W W urn 4M 40 "W -50 0 @vo5 4W VA 0r 50 MW -O MA -O WM 10 MOP 0 OW mm 0 5 2W0 250 BC 10E-3 1050 0 50 too 150 CA Dogr. Figure 3.2 Calculated mass flow rates through intake valve at 0.4, 0.6, and 0.85 Bar MAP, [27] 55 (This page was intentionally left blank) 56 5 4.5 4 3.5 3 (D L(D EVO EVO 2.5 2 1.5 1 EVC 0.5 1VC 0 0.00 0.20 0.40 1.00 0.80 0.60 Cylinder VolumeNmax Figure 3.3 Intake and exhaust stroke in-cylinder pressure data 2 1.8 s\ 1.6 EVO IVO I- .0 a) 1~ 1.41.2 U, U, a) aL. a) V 0 1- Cylinder Pressure Setpoint 0.8 0.6 0.4 AB 0.2 C 0 100 150 200 250 300 350 400 450 500 550 600 Crank Angle (deg ATDC) Figure 3.4 Cylinder pressure during intake and exhaust. Point Aestimated end of blow back, Point B- forward induction, and Point Cend of induction-displacement backflow 57 (This page was intentionally left blank) 58 4000 3500 - 3000 - -*- Indolene -+- 50/50 2500 - --- Propane EL 2000 CL) : 1500 - 1000 - 500 - Retard Advance -p 4- 0-8 -6 -4 -2 0 2 4 6 8 Spark Timing From MBT Figure 3.5 Spark timing vs. HC with matched N-IMEP for propane and Indolene 24 23 ~22 -o- Indolene -+50/50 = 21- -A- Prop ane ~20 S19 E . 18 - W"', 17- Retard 16- 4 - Advance f1 - 15 -8 -6 -4 -2 0 2 4 6 Spark Timing From MBT Figure 3.6 Maximum cylinder pressure vs. spark timing with matching of N-IMEP for propane and Indolene Mixtures 59 8 (This page was intentionally left blank) 60 4000 - * Indolene 3500 - A 3000 - Propane 2500 E a. 2000 CL = 1500 1000 - 500 A A A A AAAAAAA A A Advance - 30o 015 25 20 35 30 Spark Timing (deg BTDC) Figure 3.7 Spark timing vs. HC with Nissan injector and propane 3.2 e Indolene A Propane 3.1 - CL wL 3....-...... A A 2.9- A30 2.8 15 20 25 30 35 Spark Timing (deg BTDC) Figure 3.8 Nissan Injector and Propane fueled N-IMEP vs. spark timing, with MAP = 0.5 bar 61 (This page was intentionally left blank) 62 3.2 e Indolene A Propane 3.1 3- z 2.9- 2.8 -0 15 10 5 20 Location of Peak Cylinder Pressure (deg ATDC) Figure 3.9 Nissan Injector and Propane fueled N-IMEP vs. location of peak cylinder pressure, with MAP = 0.5 bar 20 A Indolene A 0 I- e Propane 0) C) -o 154C) 1.. C,, C) e a-L.. 0 eA eA 0 A C) a0 10 + C .2 *6-' C.) 0 -J 5 15 20 25 30 Spark Timing (deg BTDC) Figure 3.10 Location of peak cylinder pressure vs. spark timing 63 35 (This page was intentionally left blank) 64 4000 Pre-Vaporized Indolene AA 3500 - * Propane A A A A 3000 - 2500 E CL 0. 2000 *A 1500 1000 500 0 0.75 0.8 0.85 0.9 0.95 1 1.05 1.1 1.15 1.2 1.25 Lambda Figure 3.11 HC vs. Lambda for propane and pre-vaporized Indolene experiments 3.1 A Pre-Vaporized Indolene e Propane A 3 4 2.9 4 4 S w 2.8 f 2.7 4L 2.6 0.75 0.8 0.85 0.9 0.95 1 1.05 1.1 1.15 1.2 Lambda Figure 3.12 N-IMEP vs. Lambda for propane and pre-vaporized Indolene 65 1.25 (This page was intentionally left blank) 66 15 * Pre-Vaporized Indolene A Propane 104 0) o' s * Ae* A 0 5 0 0.75 0.8 0.85 0.95 0.9 1 1.1 1.05 1.15 1.2 1.25 Lambda Figure 3.13 Effects of Lambda on cyclic variability 6000 55001 '50001 4500 4000 - 3500 - 0. 3000 - E 0. 2500 - 2000 - 1500 - I.. A Op A A AA A A AhAA A AA AAA A~ Propane 1000500 Closed Valve Nissan Injector - 00 20 40 60 80 100 Coolant (deg C) Figure 3.14 HC engine warm-up experiments for propane and standard Nissan injection of Indolene 67 (This page was intentionally left blank) 68 3000 2800 2600 2400 ANissan Injector *BMW Injector "Low-flow" - A 2200 - E 0. CL A 2000 - I A A 1800 1600 - 00 1400 1200 1000 0 100 80 60 40 20 Percent of Required Indolene Figure 3.18 Liquid fuel sweeps with Nissan and BMW injectors, OVI 4000 -i-- Nissan Injector --o-- BMW Injector 3500 Transport Delay 3000 2500 E 2000 GL C) 1500 IVO BMW P.W. 1000 Niss. P.W. 500 . 0 0 I I I . I 100 . I I . 200 I 1 300 .1 1 400 1 1 i 500 I . . I .! I I I . 600 End of Fuel Injection (BTDCC) Figure 3.19 Injection timing vs. HC for standard Nissan Injector and the low-flow BMW injector. Injection timing corrected for 175 degree transport delay. 69 i 700 (This page was intentionally left blank) 70 CHAPTER 4 LIQUID FUEL INJECTOR PROBE EXPERIMENTS 4.1 Overview of Liquid Fuel Injector Probe Experiments To simulate the liquid fuel flow from the valve seat region into the cylinder, a specially designed injector probe was constructed to inject controlled amounts of liquid fuel onto the port wall close to the valve seat. By fueling the engine on a gaseous fuel, either propane or prevaporized Indolene, and injecting liquid fuel close to the valve seat, we can examine the effects of liquid fuel entering the cylinder at different locations around the valve seat. These experiments were carried out with both OVI and CVI to assess the differences that residual blowback and evaporation produce. 4.2 Pre-Vaporizing Injector The effects of operating the engine on two different fuel types (propane and Indolene) simultaneously at differing mixture ratios makes the interpretation of HC data difficult at best. The two most notable problems of operating on two fuel types are the different deposit forming characteristics of the fuels and the negligible absorption of propane into the oil layer. The heavier components of the Indolene fuel have a tendency to form deposits on both the intake valves and in the combustion chamber. Propane, a single component gaseous fuel, did not form any significant deposits on the intake valve and only minor deposits in the combustion chamber. A more significant difference between the fuels is the absorption of fuel into the oil layer. Experiments by Gatellier and Herrier verified that there is no significant absorption of propane into the oil layer [30]. However, Indolene will be absorbed into the oil layer, causing the oil layer to act as a storage medium for unburned fuel. It was found that after running the engine on Indolene for an extended period of time the HC for the next set of propane experiments exhibited a higher than normal level of HC. This higher level of HC's was believed to be due to the fuel stored in the sump oil and desorbing from the oil layer on the cylinder liner. To circumvent these problems with fuel deposits and oil layer effects, a pre-vaporizing gasoline injector was developed and used. 71 The pre-vaporizing injector consist of a low-flow injector mounted at one end of a heated brass tube. An air supply line injects air into the brass tube, inducing a swirling flow through the tube. The liquid fuel injected onto the hot brass surface is evaporated and transported out of the injector via the swirling airflow. This pre-vaporizing injector was based on the design of an earlier pre-vaporizing injector developed at the National Engineering Laboratory in England [31]. The schematic of this injector is shown in Figure 4.1. The swirling airflow was supplied by a pressurized oil free air supply with the air-assist flow rate controlled by a critical flow orifice. The orifice used was an O'Keefe Controls Metal Orifice Number 38. The mass airflow rate was controlled by varying the pressure difference across the critical flow orifice. This mass airflow was checked by running the engine at a fixed manifold pressure (0.5 bar) and varying the mass airflow of the air-assist. The total engine airflow was measured by two different methods: 1) the total airflow was estimated using the fuel mass flow and the lambda measurement, 2) total airflow was estimated by adding the mass airflow measured at the air intake and adding the air-assist mass airflow based the orifice calibration Tables. This experiment to characterize the mass airflow of the air-assist at different supply pressures is shown in Figure 4.2. At the standard air-assist operating point with a supply pressure of 10 psi there is only a 4% difference between the two mass airflow measurement systems for the total airflow. Also note that the HC level for different air-assist supply pressures does not change significantly over the test range. The supply pressure for the air-assist was set at 10 psi (14.5% of total mass airflow) for all pre-vaporized experiments. 4.3 Liquid Fuel Injector Probe The liquid fuel injector probe consist of a low-flow injector connected to a 1/16" inner diameter Teflon tube. Each of the fuel probe tubes were approximately 14" in length and are epoxied to the intake runner wall. The end of the fuel probe tubes were mounted " behind the intake valve seating surface and were aligned such that they were perpendicular to the valve seat. Three injector probe tubes were permanently mounted in the intake port in the locations shown in Figure 4.3. To ensure precise injection timing could be achieved with the liquid fuel injection probes, a series of flow visualization studies were conducted. The visualization experiments consisted of a free hanging 14" Teflon tube injecting liquid fuel into a beaker. The injector was pulsed at a rate 72 of 750 pulses/minute and a fuel pulse width of 2.8 ms, this corresponds to 32% of the total fuel required to fuel the engine at the standard operating point of 1500 rpm, 0.5 bar MAP. A strobe light allowed visualization of the probe flow at different locations in the engine cycle. This visualization study indicated that there is a transport delay of 185 degrees from the start of injection until the liquid fuel begins to exit the fuel probe tip and a 260 degree delay from the end of injection until the liquid fuel stops flowing from the fuel probe tip. Therefore, a signaled injection pulse width of 25 crank angles results in an effective pulse width of 100 crank angles at the fuel probe tip. The results of this visualization study are shown in Figure 4.4. 4.4 Liquid Fuel Probe Injection Timing Sweeps A fuel injection timing sweep was done at each probe location. The engine was fueled with 36% of the required Indolene injected through the fuel probe and the balance of the required fuel was supplied by propane. The actual end of injection is adjusted to match the actual engine cycle position based on the visualization study and the phasing adjustment shown in Figure 4.4. The effects of injection timing on HC's and N-IMEP at the probe "B" location are shown in Figure 4.5. This graph indicates a clear step type increase in HC emissions during open valve injection. The rise and fall time of this step increase is approximately equal to the injection duration. As the fuel injector begins to inject fuel during IVO, the HC's begin to increase. The HC's continue to increase until all the liquid fuel is being injected during open valve injection. The HC's begin decreasing at BDC when the intake airflow ceases. The increase in HC's and corresponding decrease in burned fuel results in a decrease in N-IMEP during open valve injection. This increase in HC and decrease in N-IMEP during OVI was found at all three probe locations as can be seen in Figures 4.5, 4.7, & 4.9. It should also be noted that there is a significant increase in the cyclic variation of N-IMEP during open valve injection. This is shown by the variation in covariance defined as: Covariance = Standard Deviation of N-IMEP *100 Mean N-IMEP Figures 4.6, 8, &10 indicate that the covariance follows closely with the HC emissions trend for all three probe locations and injection timing. The comparison of the HC's for all three probe locations indicate that the average open valve and average closed valve HC's are different for each probe location. This set of injection timing sweep experiments had a large amount of 73 experimental scatter during the open valve portion of the timing sweep. There is however, a clear difference in the closed valve injection HC's between the probe locations. Probe "A" demonstrated the highest HC level during closed valve injection, with probe "C" having the lowest HC's. In comparing the covariance of N-IMEP for the different probe locations we find that the covariance is higher during open valve injection for all three probe locations, as can be seen in Figure 4.12. In examining Figure 4.12 we see that the covariance values are similar for all three probe locations. This injection timing sweep and the probe visualization study verify the accuracy of the liquid fuel injector probe timing. 4.5 Fuel Probe Indolene/Propane Fuel Sweeps The impact of the injected liquid fuel mass was studied by injecting different amounts of liquid fuel to examine the corresponding effect on the HC's at each probe location. This was done for both OVI and CVI and fueling the engine on a combination of propane and Indolene. The result of this fuel sweep for both open and closed valve injection on HC's is shown in Figures 4.13 and 4.14. The closed valve injection of liquid fuel at each probe location shows a linear relationship between HC's and the percent of injected Indolene. This linear relationship was also found when doing a similar fuel sweep with the standard injector (see Figure 3.18). Once again, there is a clear difference in the HC between each probe location with probe "A" having the highest HC's and probe "C" the lowest. Also note that the slope of the HC vs. percent Indolene is different for each probe location. A problem arose when this experiment was carried out for OVI, the engine began misfiring for probe fueling above 22%. At this propane setting we are within the lean misfire limit even if no liquid fuel is being injected. The reasons for the engine misfires at this operating condition remain unclear, and prompted the use of a 100% Indolene fueling with a pre-vaporized injector. 4.6 Fuel Probe Fuel Sweeps The utilization of the pre-vaporized injector in conjunction with the liquid fuel probe closely resembles the fueling in a standard PFI system. By using the same fuel type for both the pre-vaporizing injector and the liquid fuel probe, the interpretation of the experimental data was simplified. The effects of effects of various amounts of fuel being delivered at different 74 circumferential locations around the valve seat were studied by fueling the engine on different proportions of liquid fuel injected at the valve seat at each probe location. The cyclic variability or covariance of these experiments was much lower than the initial propane/Indolene experiments. However, the cyclic variability increased as the proportion of liquid fuel increased and was larger for OVI than for CVI, see Figure 4.15. It should also be noted that there is no significant difference in the cyclic variability between the different probe locations. This indicates that the difference in HC's between the probe locations is due to factors other than differences in cyclic variability. These experiments indicate that for all amounts of liquid fuel injected at the valve seat, the fuel delivered closest to the exhaust valve (probe "A") results in the highest engine-out HC's, while the location farthest from the exhaust valve (probe "C") has the lowest HC's. Figures 4.17 and 4.19 show the effect of liquid fuel injected at the valve seat during CVI. Figures 4.18 and 4.20 show the effect of liquid fuel injected at the valve seat during OVI. A method of interpretation of the experimental probe data was developed based on the mass of the HC's. The following relationship was assumed: MHC/Muel = XHC = y fliq +(1 -y)yvap eq. 1 MHC - mass of engine-out HC's Mfuel - mass of total injected fuel XHC - mass fraction of fuel emitted as HC's y - mass fraction of fuel injected into port as liquid Wfiq - mass fraction of liquid fuel in the cylinder emitted as HC's Nfvap - mass fraction of vaporized fuel emitted as HC's Also realizing that a certain amount of the liquid fuel entering the cylinder is vaporized prior to combustion, (z - mass fraction of fuel probe "liquid" not vaporized in the cylinder prior to combustion) we can expand equation 1. MHC/Muel = XHC = YZ Whiq +(1-yZ)Wvap 75 eq. 2 The values of 4fiiq and V4vap were estimated by a linear regression analysis of the experimental data based on equation 2 and assumed values for z. Previous work by Meyer [3], suggest that approximately 50% (z = 0.5) of the liquid fuel entering the cylinder is vaporized prior to combustion. The results of this linear regression analysis are given in Table 4.1 for z = 1, 0.5, and 0.1. The mass fraction of injected vaporized fuel emitted as HC's is approximately constant for all probe locations and all z values. By examining the ratio of iq/Wvap we find that during OVI the liquid fuel fractions of probe locations A, B, and C compared to the pre-vaporized liquid fuel fractions are 7 times, 5 times, and 3 times the value of the pre-vaporized liquid fuel fraction. During CVI, the liquid fuel fraction of probe locations A, B, and C are 5 times, 2 times, and 1.3 times the pre-vaporized fuel fraction. This analysis indicates that a given amount of liquid fuel entering the cylinder as liquid at probe location "A" (closest to the exhaust valve) will result in 7 times the engine out HC's of an equal amount of fuel entering the cylinder as vaporized fuel. While a given amount of liquid fuel entering the cylinder as a liquid at probe location "C" (farthest from the exhaust valve) will result in 3 times the HC's of an equal amount of vaporized fuel Table 4.1 also shows the same trend as Figures 17, 18, 19, & 20; probe "A" has the highest mass fraction of fuel emitted as HC's for OVI and CVI, while probe "C" has the lowest mass fraction of fuel emitted as HC's. For comparison purposes the mass fraction of fuel emitted as hydrocarbons for the standard Nissan injector with CVI and OVO and the mass fraction of hydrocarbons with pre-vaporized Indolene fueling are given in Table 4.2. Figures 4.21 and 4.22 compare the N-IMEP vs. percent of fuel injected as liquid. Figure 4.21 indicates that there is no significant change in N-IMEP for CVI with different amounts of injected liquid fuel. Figure 4.22 shows a consistent decrease in N-IMEP with increased amounts of liquid fuel for OVI. The N-IMEP reaches a minimum around 33% of the fuel being injected through the fuel probe, the N-IMEP decreases by 3.3%. This decrease in N-IMEP is believed to be due primarily to the increasing cyclic variability shown in Figure 4.23. 4.7 Comparison of OVI and CVI with Injector Probes The injection timing sweep experiments with the fuel injector probes indicate that there is a distinct step type increase in the HC's during OVI. This also corresponded well with an increase in the cyclic variability or covariance. The differences in HC between OVI and CVI are similar for 76 all the probe locations, the initial interpretation was that this indicated a similar rate of evaporation of fuel at all probe locations for OVI vs. CVI. However, on further examination we find that by comparing "early CVI" just after IVC to "late CVI" there is no significant difference in HC and we can assume no significant difference in evaporation. Stanglmaier [14] also found that with his direct injection fuel probe experiments the HC's were only weakly dependent on injection timing, stating that there is not enough time in the engine cycle for any significant vaporization to occur. The difference between OVI and CVI HC's is believed to be due to blowback from the cylinder just after IVO. This blowback of hot residual gases redistributes the liquid fuel in the intake port and aids in the fuel air mixing process for CVI. The blowback flow velocities around the valve seat will all be approximately equal and therefore have the same effect at all three probe locations. With OVI all of the liquid fuel injected at the valve seat enters the cylinder from one location and leads to a higher (compared to the CVI case) variation the in the fuel/air mixture. This higher variation in the mixture uniformity results in a higher cyclic variability for the OVI compared to CVI. Figure 4.16 compares the HC values for OVI and CVI at probe locations "A" and "C". The difference between the OVI and CVI HC's appears to be the same for all probe locations and indicates that blowback has a similar effect at all three probe locations. 4.8 Experimental Fuel Probe Comparison with PFI A simplified comparison of the experimental probe data can be made with standard port fuel injection using equation 2. Experimental data for the standard Nissan injector with closed valve injection indicated a total engine-out HC fuel fraction of XHC = 0.0157±0.0007. For simplification, the standard Nissan injection is approximated by an average of all three injector probes with OVI. Assuming 50% of the liquid fuel entering the cylinder is vaporized prior to combustion [3]. Using equation 2, an estimate of the amount of liquid fuel entering the cylinder with standard closed valve Nissan injection can be made using the liquid fuel probe data. MHC/Mfuel = XHC = YZ liiq +(1 -yZ)vap XHC = 0.0157 experimental data for standard Nissan injector Wgiq =(WA+VB+WC Vvap = 0.0144 see table 4.1 - vapor HC fuel fraction )/3 = 0.0671 see table 4.1 - liquid HC fuel fraction (z = 0.5) 77 z = 0.5 0.0157 = y(O.5)(0.0144) + (1-y(0.5))(0.0671) based on [3] This analysis indicates that approximately 5% of the total injected fuel mass enters the cylinder as liquid with standard Nissan closed valve fuel injection. Noting that (0.05)(0.5)(0.0671) XHC, liquid = YZfliq= = 0.0017, the mass fraction of total injected fuel exiting the engine as hydrocarbons due to liquid fuel entering the cylinder is estimated. By using the oxidation values in the HC emissions flowchart in Figure 1.2 an estimate of the total injected fuel escaping combustion due to liquid fuel can be obtained. The percent of fuel escaping combustion do to liquid fuel is approximately XHC,liquid(3 12 )( 312 )( 31 2 ) *100%= 0.6%. Previous research indicates that approximately 1.2% of the fuel injected escapes combustion due to liquid fuel [4]. This simplified comparison of the liquid fuel probe experimental data to standard port fuel injection indicates that 0.8-0.2% of the total fuel escapes combustion due to liquid fuel, based on this analysis. These values are only approximate but they indicate that the liquid fuel probe experiments are a realistic approximation of liquid fuel transport into the cylinder of a standard port fueled SI engine. 4.9 Summary The liquid fuel injector probe in conjunction with the pre-vaporized injector is an accurate method for the simulation of the standard PFI system. Strobe visualization of the liquid fuel probe injection and fuel injection timing sweeps have validated the accuracy of the injection timing and control of the liquid fuel injector probe. Both the propane/Indolene and the Indolene-only experiments indicated that there is a distinct difference in the HC behavior at the different fuel probe locations. Location "A" is the highest HC for both OVI and CVI and probe "C" is the lowest. The difference in the HC's between OVI and CVI is similar for all probe locations suggesting that the blowback effect is roughly the same at all locations around the valve. The cyclic variability is also similar for each probe location but higher for OVI than for CVI. 78 Z=1 Fraction Fuel HC Liquid Z=O.5 Liquid HO.Fel.Facton Vapor HC Fuel Fraction Fuel Fraction Vapor HO Z=0.1 Liquid HC Fuel Fraction B-CV 0.0240 A-CV 0.0432 A-CV -B-CV C-CV 0.0171 A-OV 0.0561 B-OV 0.0392 C-OV 0.0270 C-CV A-OV B-OV C-OV . 0. 0.0142i 0.0145. 0.0193 0.0149 0.0975 0.0146 0.0142 B-CV 0.012 0.0149. C-CV 0.019 0.0146. A-OV 0.049 0.0145' A-CV 0.014 0.0648 0.0137 0.0391 0.0149 0.013T7 B-OV 0.064 0.0149 C-OV 0.0139 Table 4.1 HC fuel fraction values based on linear regression analysis of experimental data with different assumed Z values. Z- is defined as the fraction of injected liquid fuel enter cylinder as liquid (Z=O all injected liquid fuel is vaporized prior to combustion). +/- 95% Confidence Interval Average Nissan Injector CVI 0.0157 0.0007 Nissan Injector OVI 0.0211 0.001 Pre-Vaporized Indolene 0.0149 0.0007 Table 4.2 HC fuel fraction values for standard engine operating conditions 79 (This page was intentionally left blank) 80 Low-flow injector 10" heated section LP Air-Assist Heated Brass Tube Figure 4.1 Schematic of pre-vaporizing injector 3500 50 A U) 40 - Based on Fuel Flow and Lambda * Based on MAF and Orifice Mass Flow Tables * HC 3000 2500 0 30 + 0 20 - 2000 E A Standard Operating Condition 10 psi supply pressure 14.5% of Total Airflow A 0. 0 1500 A A 0 1000 u -0 0 10 nA - 500 114- Supply line open to Atmosphere 0 0 0 20 10 30 40 Delta P across Air Assist Orifice Figure 4.2 Air-Assist mass airflow estimation, intake manifold pressure set at 0.5 bar 81 (This page was intentionally left blank) 82 Liquid Fuel Injection locations D H B 4 AJ Intake Exhaust Airflow Intake Exhaust Cross Section D Top View of Cylinder Figure 4.3 Liquid fuel injector probe locations 100 flow rate at injector tip 75 0 L flowrate at probe tip 50 260 degree delay of end of Inj. 25 185 degree delay of start of lnj. 0 0 25 50 75 100 125 150 175 200 225 250 275 300 325 Relative Crank Angle Figure 4.4 Liquid fuel injection delay through fuel probes, based on liquid fuel probe visualization study 83 350 (This page was intentionally left blank) 84 3.4 4000 3500 -A-- Standard Nissan Injector ~~Probe B - HC - - - Probe B - N-IMEP -IVO 3000 - 2500 - 3.2 3 cc 2.8 z E 2000 - Ivo C) ~ p. - 1500 + p. 11-, p.- 1000 P robe nj. Duration 2.6 500 0 0 100 200 400 300 700 600 500 End of Injection Timing (after TDC compression) Figure 4.5 Probe B Liquid fuel probe injection timing sweep, effect of fuel injection timing on HC and N-IMEP, 36% Indolene, balance Propane 20 4000 ---- Probe B - HC 3500 - - - - - Covariance of N-IMEP IVO 15 3000 -e 2500 E C- CL I ' .4 p. ~. 0 2000 s C) p. IV *f* hh4 1500 V ep. 10 ' 4'* '4, 0 -5 1 000 f 500 1L 0 1. 0 100 200 400 300 500 600 40 7 00 End of Injection Timing (after TDC compression) Figure 4.6 Probe B Liquid fuel probe injection timing sweep, effect of fuel injection timing on HC and Cyclic Variation of N-IMEP (Covariance) , 36% Indolene, balance Propane 85 (This page was intentionally left blank) 86 4000 3.4 -r 1 -A- Probe A - HC - - - - 3500 3000 Probe A -N-MEP IvO 3.2 - 2500 - 3 Z 'U E C. 2000 Ivo C. 2.8 -*- 1500 .' 1000 U -U Probe ij. Duration 2.6 500 0 100 0 400 300 200 500 !0 72.4 600 700 End of Injection Timing (after TDC compression) Figure 4.7 Probe A Liquid fuel probe injection timing sweep, effect of fuel injection timing on HC and N-IMEP, 36% Indolene, balance Propane 1 I 4000 20 IvO Probe A - HC Covariance of N-IMEP -A---- 3500 1 15 3000 1 -LU 2500 C- - N" O 0 E 0 E 2000 0 I = 1500 - - - -. 1 *~ - 5 ,'ge * 00 ,,, Probe Inj. Duration 1000 00 14 0 0 100 200 400 300 500 600 7 End of Injection Timing (after TDC compression) Figure 4.8 Probe A Liquid fuel probe injection timing sweep, effect of fuel injection timing on HC and Cyclic Variation of N-IMEP (Covariance) , 36% Indolene, balance Propane 87 (This page was intentionally left blank) 88 4000 3.4 --- - - - 3500 Probe C - HC Probe C -N-IMEP IvO -3.2 3000 2500 E 3 2000 Ivo C) - 1500 - S2.8 - - -. ~--- 1000'[ Probe ij. Duration -2.6 500-2.4 0 0 200 100 400 300 500 600 700 End of Injection Timing (after TDC compression) Figure 4.9 Probe C Liquid fuel probe injection timing sweep, effect of fuel injection timing on HC and N-IMEP, 36% Indolene, balance Propane 20 4000 --3500 Probe C - HC - - - - Covariance of N-IMEP - IvO 15 ^ 3000 I. (U 2500 E 2000 a. C) U , 10 r\/O t z 0 1500 50 1000 0 0 100 200 400 300 500 600 700 End of Injection Timing (after TDC compression) Figure 4.10 Probe C Liquid fuel probe injection timing sweep, effect of fuel injection timing on HC and Cyclic Variation of N-IMEP (Covariance) , 36% Indolene, balance Propane 89 (This page was intentionally left blank) 90 4000 A 3500 + 3000 - 2500 - A-A- A- A A A: eA-AA E 2000 1500 NO - 1000 - -A -- Probe A -Probe B 500 -C-- Probe C - Ivo I- 0 400 300 200 100 500 600 700 End of Injection Timing (after TDC compression) Figure 4.11 Comparison of HC's for probes A,B, and C. 36% Indolene, balance Propane 20 -- A- Probe A -4-Probe B -L- Probe C 15 A IL wU z '4- 0 10 ---V A~ .A 0 -'V 0 5 0 0 100 200 400 300 500 600 End of Injection Timing (after TDC compression) Figure 4.12 Comparison of Covariance for probes A,B, and C. 36% Indolene, balance Propane 91 700 (This page was intentionally left blank) 92 4500 A Probe A 4000 e Probe B n Probe C 3500 A 3000 2500 E .E 2000 A 1500 A 1000 500 0I 10 5 15 20 25 45 40 35 30 50 Percent Indolene Figure 4.13 Indolene/propane fuel sweep, CVI. end of injection 70 deg.after TDCC, 280 deg.before IVO 4500 Probe A .Probe B A A 4000 A A A A I Probe C 3500 3000 E CL) A 2500 1 or more misfires/ 1000 cycles 2000 1500 1000 500 2-4 misfires/ 1000 cycles 0 0 5 10 15 30 25 20 Percent Indolene 35 40 45 Figure 4.14 Indolene/propane fuel sweep OVI, End of Injection at 410 deg. after TDCC, 60 deg. after IVO 93 50 (This page was intentionally left blank) 94 0.45 -A- Probe A Probe B 0.4 - 0.35 - Open Valve -u-Probe C 0.3 - 0.25 - ' CL 0.2 - cc Z S0 0.15 Closed Valve 0.1 0.05 0 0 5 10 15 25 20 30 35 40 45 Percent Indolene from probe, balance is Vaporized Figure 4.15 Comparison of standard deviations of N-IMEP for liquid fuel probe sweep 5000 A Probe A - CV 4500 * Probe C - CV A Probe A - OV 4000 o Probe C - OV 3500 E CL - A 3000 0 A 2500 2000 0 5 10 15 20 1 25 30 35 40 Percent of Liquid Indolene from Probe, balance is Vaporized Figure 4.16 Comparison of OVI and CVI HC's for probes A and C 95 45 (This page was intentionally left blank) 96 5000 A 4500 Probe A * Probe B 4000 m Probe C 3500 3000 UA E 2500 0. U 2000 1500 1000 500 0 0 5 10 15 25 20 30 35 40 45 Percent of Liquid Indolene from Probe, balance is Vaporized Figure 4.17 Liquid fuel probe sweep CVI HC's, end of injection 70 deg. after TDCC, 280 deg. before IVO 5000 A 4500 - Probe A e Probe B A - 4000 m Probe CA 3500 3000 E 2500 20 3 2000 1500 1000 500 0 0 5 10 15 25 20 30 35 40 45 Percent of Liquid Indolene from Probe, balance is Vaporized Figure 4.18 Liquid fuel probe sweep OVI HC's, End of Injection at 410 deg after TDCC, 60 deg. after IVO 97 (This page was intentionally left blank) 98 0.00025 -MA (D 0.0002 N Probe A A U) Probe B - 0 Probe C CLe 0.00015 -L y =2.75E-02x A 0) 0.0001 0 0 y 0.00005 7.77E-03x . 0 0.001 0.004 0.003 0.002 y = 2.33E-03x 0.005 0.006 Mass of Fuel Injected through probe (g/cycle) Figure 4.19 Effect of liquid fuel on exhaust HC's, CVI 0.00025A (n Probe A A Cu 0.0002-- 0 Probe B y = 4.05E-02x * Probe C 0 C. A 0.00015 0 0 mA y = 2.19E-02x 0.0001 y =1.22E-02x 0g 0.00005 00 0 0 0.001 0.003 0.002 0.004 0.005 Mass of Fuel Injected through probe (g/cycle) Figure 4.20 Effect of liquid fuel on exhaust HC's, CVI 99 0.006 (This page was intentionally left blank) 100 3.1 A Probe A * Probe B 0 3.05 A*0 AA A A £ N I- 0 U 3 Cu *Probe U U C . M 0~ w 2.95 z 2.9 2.85 15 20 25 30 40 35 45 Percent of Liquid Indolene from Probe, balance is Vaporized Figure 4.21 Effect of liquid fuel probe mass on N-IMEP, CVI 3.1 A Probe A 5 3.05- Probe B * Probe C A 3. A A wU E 2.95 - AA 2.9 2.85 15 20 25 30 35 40 Percent of Liquid Indolene from Probe, balance is Vaporized Figure 4.22 Effect of liquid fuel probe mass on N-IMEP, OVI 101 45 (This page was intentionally left blank) 102 3.2 3.15 - A 3.1 AAA 3.05 a(CU wn A 3 2.95 y = -0.984x + 3.2639 A 2.9 2.85 2.8 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 Standard Deviation of N-IMEP (bar) Figure 4.23 Correlation of N-IMEP with the standard deviation of NIMEP for all liquid fuel probe sweep data 103 (This page was intentionally left blank) 104 CHAPTER 5 SUMMARY AND CONCLUSIONS 5.1 Liquid Fuel Transport into Cylinder Liquid fuel which is injected into the port is transported into the cylinder in three possible forms; fuel vapor, fuel droplets, or as a fuel film on the port wall. Various researchers have examined this fuel transport from the port to the cylinder [3]. During closed valve injection (CVI) most of the liquid fuel is in the form of a fuel film on the port walls and intake valve prior to IVO. Open valve injection (OVI) results in a smaller mass of liquid fuel stored on the port wall and more liquid fuel transport directly into the cylinder than CVI [17]. The intake airflow causes the injected liquid fuel distribution in the port to be significantly different for OVI injection than CVI. This difference in port fuel distribution has a direct impact on the liquid fuel distribution in the cylinder. A semi-quantitative assessment of the liquid fuel transport into the cylinder can be made using the injector probe location, estimated airflow velocity profiles, port geometry, and combustion chamber design. We recognize three different types of physical transport of fuel into the combustion chamber, 1) fuel which enters the chamber as vapor, 2) droplets which are suspended in the airflow and may evaporate during transport or impinge on combustion chamber surfaces, and 3) a liquid fuel film or puddle, that enters into the combustion chamber as a liquid film attached to the port and combustion chamber walls. Through the visualization study of the fuel injector probes we found that the injector probe deposits the liquid fuel in the form of a puddle on the intake port wall. This puddle is then transported into the cylinder by one of the three basic transport methods described above. By examining the intake velocity profile from a similarly designed 4-valve engine we can estimate the velocity profiles in the Nissan engine during the intake process. Kim and Lee did a CFD analysis of the intake process in a 4-valve head with a head and port geometry very similar to the Nissan engine used in this study. Their CFD simulation was at WOT with one of the intake valves closed. While this CFD simulation is for a higher intake flow rate, the intake flow profile is not expected to be significantly different than our 0.5 Bar MAP experiments. However, intake 105 valve flow profile experiments on a 4-valve head, by Lou and Daneshyar, found that the velocity profiles around the intake valve were independent of flow rate; the velocity magnitudes where found to be almost proportional to flow rate [29]. 5.2 Comparison of Liquid Fuel Probes to Standard PFI To interpret the results of the injector fuel probe experiments a comparison between the fuel probe locations must be made to the liquid fuel distribution in a standard port fuel injection configuration. Meyer [3] found that during OVI the dominant transport mechanism of liquid fuel into the cylinder was fuel droplets transported directly from the injector. The fuel droplets entrained in the airflow will enter the cylinder along the same flow path as the intake airflow. Most of the fuel droplets entrained during OVI will enter the cylinder over the top of the valves where the airflow is highest [3]. OVI results in most of the liquid fuel entering the cylinder at a location that is similar to location "A" of the injector probe. During CVI the liquid fuel will be deposited along the port walls based on injector targeting. The standard injector on the Nissan engine is targeted to deposit liquid fuel on the lower port wall and outer edge of the intake valves. A semi-quantitative comparison can be made between the average of the probe "B" and "C" locations with the standard Nissan injector targeting during CVI. 5.3 Conclusions The purpose of this work was to develop a fundamentally based description of liquid fuel transport into the engine cylinder of a port fuel injected, gasoline fueled, SI engine, and to develop a method of quantifying the liquid fuel contribution to HC emissions. A novel liquid fuel injector probe was developed which deposits controlled amounts of liquid fuel onto three precise circumferential locations around the intake port, just upstream of the intake valve seat. By controlling the amount and location of the liquid fuel injected at the valve seat, during open valve injection, and measuring the engine-out hydrocarbon (HC) emissions an estimate of the contribution to these emissions, due to liquid fuel entering the cylinder, can be made. conclusions from these experiments are as follows: 106 The 1) The impact of the liquid fuel injected at the valve seat was studied by fueling the engine with pre-vaporized Indolene plus different amounts of liquid Indolene injected through the fuel probes. These experiments indicated that the engine-out HC's increase linearly as the proportion of liquid fuel, relative to pre-vaporized fuel, is increased. The rate of increase in HC's is different for each probe location, and is different for closed valve injection (CVI) vs. open valve injection (OVI). 2) The blowback of hot residual gases during valve overlap redistributes the liquid fuel in the intake port and aids in the fuel air mixing process for CVI. The liquid fuel probe experiments show a similar difference between OVI and CVI hydrocarbons at all three probe locations. The blowback flow velocities around the valve seat are approximately equal at all probe locations. At time of injection, the liquid fuel film distribution is similar at all three probe locations. Therefore, the blowback has the same effect at all three probe locations resulting in the constant difference between OVI and CVI, at each probe location. 3) The location of liquid fuel around the valve seat has a significant impact on engine-out hydrocarbon emissions. All the fuel probes were located just upstream of the valve seat and injected liquid fuel film onto the intake port wall in a similar manner. These experiments indicated that for all amounts of liquid fuel injected at the valve seat, the fuel delivered closest to the exhaust valve (probe "A") resulted in the highest engine-out HC's, while the location farthest from the exhaust valve (probe "C") had the lowest HC's. A method of interpretation of the experimental probe data was developed, based on the mass of the HC's, assuming a linear relationship between the mass of liquid fuel injected at the valve seat and the total HC's. The constants of this linear relationship YWq and Yvap were estimated by a linear regression analysis of the experimental data. Examining the ratio of Y/iq/Yvap we find that during OVI the liquid fuel fractions of probe locations A, B, and C compared to the pre-vaporized liquid fuel fractions are 7 times, 5 times, and 3 times the value of the pre-vaporized liquid fuel fraction. During CVI, the liquid fuel fraction of probe locations A, B, and C are 5 times, 2 times, and 1.3 times the pre-vaporized fuel fraction. This analysis indicates that a given amount of liquid fuel entering the cylinder as liquid at 107 probe location "A" (closest to the exhaust valve) will result in 7 times the engine out HC's of an equal amount of fuel entering the cylinder as vaporized fuel. While a given amount of liquid fuel entering the cylinder as a liquid at probe location "C" (farthest from the exhaust valve), will result in 3 times the HC's of an equal amount of vaporized fuel. 4) The difference in HC's at each probe location is due the subsequent distribution of liquid fuel in the cylinder. Stanglmaier [14] studied the effect of in-cylinder wall wetting location on HC emissions using a specially designed spark plug mounted injector probe. His experimental results suggest that the differences in the HC for the different cylinder wall wetting locations can be explained in terms of the physical location of the liquid fuel relative to the exhaust valves. He explains, liquid fuel deposited on the cylinder wall is scraped into the piston top land during the compression stroke and then laid back on the cylinder wall during expansion as a liquid fuel film. Any of this fuel film that survives the combustion and post-flame oxidation process will be scraped into the roll-up vortex during the exhaust stroke. The portions of the roll-up vortex closest to the exhaust valves have a higher chance of being exhausted, and contributing to engine-out HC's, than the portions of the vortex farther from the exhaust valves. Therefore, liquid fuel entering the exhaust side of the cylinder will have a higher probability of being exhausted during the exhaust stroke. Liquid fuel deposited on the intake side of the cylinder has a lower probability of being exhausted [14]. CFD data indicates that liquid fuel deposited on the intake port wall closest to the exhaust valve (probe "A") will enter onto the exhaust side of the cylinder head (onto the exhaust valves, between the exhaust valves, and into the exhaust valve crevices) and onto the exhaust side of the cylinder liner resulting in the highest HC's. Liquid fuel deposited farthest from the exhaust valve (probe "C") will enter onto the intake side of the cylinder and result in lower HC's relative to probe "A". These experiments qualitatively agree with the incylinder liquid fuel injection experiments done by Stanglmaier and Matthew [14][15]. 5) The overall physical conclusions of these experiments are that liquid fuel entering the cylinder increases the engine-out HC's, relative to that fuel entering in vaporized form. The engine-out HC's increase proportionally to the amount of liquid fuel entering the cylinder. 108 By modifying liquid fuel distribution in the intake port and the subsequent distribution of liquid fuel in the cylinder, the impact of liquid fuel entering the cylinder on HC's can be minimized. Liquid fuel entering the cylinder results in less of an increase in HC's if the liquid fuel is deposited farther away from the exhaust valves. The redistribution and vaporization of liquid fuel due to exhaust backflow during CVI further reduces the impact of a given amount of liquid fuel deposited in the intake port. A given amount of fuel deposited at probe location "C" (farthest from the exhaust valve) with CVI results in only 1.3 times the HC's of an equal amount of vaporized fuel, compared to 7 times at the location "A" (closest the exhaust valve) with OVI of liquid fuel. In short, fully vaporizing the fuel results in the lowest HC's. When liquid fuel does reach the valve seat region in the intake port, the lowest HC's are achieved by closed valve injection, with the liquid fuel at the valve seat predominantly on the side of the intake port farthest from the exhaust valves. 109 (This page was intentionally left blank) 110 Figure 5.1 CFD Simulation of 4-valve head, at WOT with one intake valve closed, 1500 rpm.[28] Nissan head configuration overlay. Figure 5.2 Relative liquid fuel transport mechanisms for probe locations "A" and "C" 111 (This page was intentionally left blank) 112 Fuel from Probe C A( Liquid Fuel Fuel enterin Cylinder Vaporized Fuel at Start of Combustion .DVaporized Vaporized Fi-el Film, Liquid Vaporized Fuel DL Liquid Probe A B C Fuel Drops H M IL Fuel Film L M H Vaporization Relative HC H L M M IH |L Figure 5.3. 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