CHAPTER 1 & 2 Chemistry Matter & Change CHEMISTRY STUDY OF COMPOSITION AND BEHAVIOR OF MATTER “What stuff is made of and how it acts” Organic Chemistry: Study of carbon compounds Inorganic Chemistry: Study of non carbon compounds Analytical Chemistry: Study of composition of substances Physical Chemistry: Study of behavior of substances Biochemistry: Study of the chemistry of living things How Chemistry is Used Pure Chemistry: Knowledge for knowledge’s sake. Research to learn how something works. May lead to and application. Ex: Research for synthetic rubber 1940’s o Applied Chemistry Research directed to a specific goal or application. Ex: Silly Putty 1950’s Scientific Method Systematic problem solving approach Observations Noticing a problem (car won’t start) • Hypothesis (battery dead) Possible explanation • Experiment Procedure used to test the hypothesis (jump start?) Manipulated Variable – Independent Variable Variable you change during an experiment. Responding Variable- Dependent Variable Variable you observe during the experiment Scientific Method Continued THEORY: Tested model that explains WHY an experiment gives certain results. Ex: Atomic Theory LAW: Model of atom has changed over time. Statement that summarizes the results of many observations and experiments. Can be proven and usually is an equation. Ex: Law of Gravity (objects fall at a rate of 9.8 meters per second) PROPERTIES OF MATTER MATTER: Anything that has mass and takes up space MASS: Amount of substance and object contains WEIGHT: Earth’s attraction for an object GRAVITY VOLUME: Amount of space an object takes up PHYSICAL PROPERTY •QUALITY OF A SUBSTANCE that can be analyzed without changing the composition of the substance, Ex: color, odor, density, MP, BP, conductivity CHEMICAL PROPERTY • ability of a substance to undergo a chemical reaction and form new substances Ex: sodium explodes in water, iron nail rusts, wood burns Changes in Matter Change in a substance that does Physical Change: not change composition. Same substance in the beginning and end. Ex: cutting, grinding, tearing, painting, phase change Chemical Change Change in the composition of a substance. Different substance in the end. Ex: burning, rusting, chemical reactions Demo: SUGAR + WATER REACTANTS C12H22O11 + YIELD H2O PRODUCTS C12H22O11 + H2O STARTING AND ENDING MATERIALS ARE THE SAME: PHYSICAL CHANGE DEMO: SUGAR + SULFURIC ACID REACTANTS YIELD PRODUCTS C12H22O11 + H2SO4 12 C + SO3 +12 H2O STARTING AND ENDING MATERIALS ARE DIFFERENT: CHEMICAL CHANGE INDICATORS OF A CHEMICAL CHANGE COLOR CHANGE ODOR CHANGE ENERGY CHANGE FORMATION OF A GAS FORMATION OF A PRECIPITATE- (solid formed from 2 aqueous solutions) NOT EASILY REVERSED What’s happening during a chemical reaction? Only the OUTER SHELL ELECTRONS called (Valence Electrons) of atoms are involved. atoms Combine, break away or rearrange Law of Conservation of Mass Matter is not created or destroyed. Mass reactants = Mass of products Energy Changes Both physical and chemical changes involve energy changes Types of energy include heat, light, bond energy ENDOTHERMIC Needs or requires energy (heat), takes heat in, surroundings feel cooler Energy is a (REACTANT) EXOTHERMIC Gives off or releases energy (heat), gives off heat, feels warmer. Energy is a (PRODUCT) Law of Conservation of Energy Energy is not created or destroyed. Energy of reactants = Energy of products States of Matter Density Movement shape volume D = mass/volume solid Packed very close together, incompressible Packed close liquid together, incompressible Very far apart gas (99%empty space), compressible Vibrate in place Slide past each other Rapid, random straight line definite indefinite indefinite definite definite indefinite Phase Changes HEAT IN (ENDOTHERMIC) MELTING BOILING SOLID ========== LIQUID =========== GAS HEAT OUT (EXOTHERMIC) FREEZING H2O: ICE CONDENSATION WATER * WATER VAPOR *The term VAPOR is used when a substance that is normally a liquid or solid at room temperature is in a gaseous state. Types of Matter Substance (homogeneous) Mixture Definite composition (_________________________) Variable composition (______________________) Separated physically (______________________) Element Compound Homogeneous Heterogeneous Separated chemically (_______________________) One kind of atom Element _____________________ Found on periodic table, H, He ______________________________ solution; one phase Homogeneous (______________________) Same throughout; koolaid, jello _____________________________ Chemical blend Compound ____________________ Not the same Heterogeneous _________________ of 2 or more elements ______________________________ throughout; different phases _____________________________ H O, NaCl, BaSO 2 4 (_____________________________) Chunky soup, salad, soil _____________________________ Comparison of Compound VS Mixture Compound Mixture 1. Chemically combined Physically combined 2. Can only be separated by chemical means. Can be separated physically. 3. Components are present in a Components may be definite proportion by weight present in any proportion 4. Compound has different properties than its individual components. Components in mixture keep their original properties. Chemical Symbols - Every element has a symbol - Symbol consists of 1 or 2 letters, first is capitalized -Some named for Greek and Latin names - Ex: Sodium (Natrium) – Na; Iron (Ferrous) Fe -Chemical Formulas Combination of elements to represent compounds. Ex: C12H22O11 sugar; H2O water Reaction symbols solid (s) * liquid (l) * The following are the only liquids used during a Water, Bromine & Mercury chemical reaction Everything else in a liquid state is an gas (g) gas as a product precipitate ( ) or (ppt.) aqueous (aq) Aqueous Solution ( ) Solid product formed from 2 aqueous solutions Dissolved in water.