Percent Comp CuSO4.5H2O % Composition CuSO4. 5 H2O 1 Cu = 1 (63.55 g) = 63.55 g 1 S = 1 (32.06 g) = 32.06 g 4 O = 4 (16.00 g) = 64.00 g 5 H2O = 5 (18.02 g) = 90.10 g 249.71 g % Composition (Continued) % Cu = 63.55 g/249.71g (100 %) = 25.45 % Cu % S = 32.06 g/249.71 g (100 %) = 12.84 % S % O = 64.00 g/249.71 g (100 %) = 25.63 % O % H2O = 90.10 g/249.71 g (100 %) = 36.08 % H2O Check: Total percentages. Should be equal to 100 % plus or minus 0.01 %. Formulas -- Empirical formula is the empirical formula of a compound. NaCl CaCl2 -- Molecular formula – is the actual ratio of atoms I the compound . C6H12O6 C2H6 The analysis of a rocket fuel showed tht it contained 87.4% nitrogen and 12.6 % hydrogen by weight . Mass spectral analysis showed the fuel to have a molar mass of 32.05 grams . What are the empirical and molecular formulas of the fuel? Empirical Formula Determination from percent 1. Base calculation on 100 grams of compound. 2. Determine moles of each element in 100 grams of compound. 3. Divide each value of moles by the smallest of the values. 4. Multiply each number by an integer to obtain all whole numbers. Formula of a Compound Calculations Determine the empirical and molecular formulas for a deadly nerve gas the gives the following percent analysis . C=39.10 % H=7.67% O=26.11% P=16.82% F=10.30% Molecular Mass =552.3g Empirical Formula Determination 1. Determine moles of each element in the compound. 2. Divide each value of moles by the smallest of the values. 3. Multiply each number by an integer to obtain all whole numbers. Study guide P.68- 71 Q: 3,10,45-47 Calculating Empirical Formulas Determine the empirical formula of a compound that contains 4.151 g Al & 3.692 g O Practice Determine the empirical formula and molecular formula of the following gas. molar mass=184.1g C=39.1% H=7.67% O=26.11% P=16.82% F=10.30% Combustion empirical Combustion data A combustion device was used to determine the empirical formula of a compound containing only carbon ,hydrogen, and oxygen. A 0.6349g sample of the unknown produced 1.603g of CO2 and .2810g H2O. Determine the empirical formula of the compound. A combustion device was used to determine the empirical formula of a compound containing only carbon, hydrogen, and oxygen. A .6349 g sample of the unknown produced 1.603 g of CO2 and .2810 g of H2O. Determine the empirical formula of the compound.