Acids, Bases, and Salts I. Properties of Acids Sour taste Change colors of acid-base indicators warm colors– turns litmus paper red Some react with active metals to release H2 Acid + Base → Salt + water Conduct electric current III. Properties of Bases Bitter taste Change colors of acid-base indicators cool colors– turns litmus paper blue Feel slippery React with acids to produce salts and water Conduct electric current Write dissociation equation & balance HCl → 2. HNO3 → 3. NaOH → 4. Mg(OH)2 → 5. NaCl → Note any similarities between the equations 1. IV. ARRHENIUS THEORY Acids, bases, and salts conduct a current when dissolved in water - electrolytes An acid produces H+ in a water solution HCl(g) --> H+(aq) + Cl-(aq) A base produces OH- in a water solution NaOH(cr) --> Na+(aq) + OH-(aq) II. Naming Acids - Binary Binary acid – contains 2 elements; hydrogen and one of the more electronegative elements. Ex. HF 1. Begins with prefix hydro 2. Followed by root of name of second element 3. Ends with suffix -ic hydro – fluor – ic acid H2S II. Naming Acids - oxyacids Compound of hydrogen, oxygen, and a 3rd element that is usually a nonmetal Formula is usually one or more H atoms followed by polyatomic anion Pg. 250 HNO2 – nitrous acid NO2- nitrite HNO3 – nitric acid NO3- nitrate Common industrial – sulfuric, nitric, phosphoric, hydrochloric, acetic Practice problems Pg.250 #’s 18-22 Pg. 596 1a,1b Strong vs. weak Strong acids and bases fully dissociate Weak acids and bases partially dissociate V. BRONSTED-LOWRY THEORY Acid – proton (H+) donor Base – proton acceptor The conjugate base of an acid is the particle that remains after a proton is released by the acid. The conjugate acid of a base is formed when the base receives a proton from an acid. In the reaction NH3(g) + water(l)->NH4 + (aq) + OH-: NH3 is the base, water is the acid, NH4+ is the conjugate acid, and OH- is the conjugate base. H H N N H O H O H H H H H H PRACTICE PROBLEMS Which is the conjugate base / conjugate acid in: H3PO4 + H2O --> H3O+ + H2PO4H3O is the conjugate acid and H2PO4 is the conjugate base. One more, which is the conjugate base / conjugate acid in: H4P2O7 + H2O --> H3O+ + H3P2O7Again H3O is the conjugate acid and H3P2O7- is the conjugate base. BRONSTED-LOWRY Acid Base Reactions HF + H2O → F- + H3O+ Subscripts designate 2 conjugate acid base pairs HF + H2O → F- + H3O+ acid1 base2 base1 acid2 Strength of conjugate acid and base – strong acid – weak conj. Base. Reactions favors direction that produces weaker acids and bases Amphoteric Can act as acid or base (H2O) H2SO4 + H2O → base NH3 + H2O → acid BRONSTED-LOWRY THEORY Monoprotic acid – donates only one proton Polyprotic acid – donates more than one proton Diprotic – donates 2 protons Triprotic – donates 3 protons All polyprotic ionize in steps H3PO4(aq) pg. 601 #3a,3b LEWIS THEORY Lewis focused on an electron transfer rather than a proton transfer. Lewis described an acid as an electron-pair acceptor and a base as an electron-pair donor. An acid or base in Arrhenius theory is the same under the Lewis and Bronsted-Lowry theories. MORE PRACTICE PROBLEMS CLASSIFY THE FOLLOWING SUBSTANCES AS LEWIS ACIDS OR BASES. a. Cl- b. Al+ c. Br- d. I+ a and c = Lewis Base b and d = Lewis Acid