Warm-up February 12th What is the wavelength of light and portion of the EMS is it on when an electron falls from the: a. 4th to the 2nd energy level? b. 6th-3rd? c. 3rd to 2nd? RULES GOVERNING eCONFIGURATIONS Aufbau principle- an e- occupies the lowestenergy orbital first Pauli exclusion principle- each orbital can hold TWO electrons with opposite spins Hund’s Rule- within a sublevel, place one eper orbital before pairing them Empty bus seat rule! ELECTRON CONFIGURATIONS -arrangement of electrons in an atom Sublevel s p d f orbitals 1 3 5 7 total e2 6 10 14 Energy level Sublevels Total orbitals Total number electrons it can hold 1 s 1 2 2 s,p 4 8 3 s,p,d 9 18 4 s,p,d,f 16 32 5 s,p,d,f 16 32 6 s,p,d,f 16 32 7 s,p,d,f 16 32 Two types of notation for electrons Electron Configuration Notation number of electrons in sublevel is added as a superscript 1s22s22p63s23p64s1 Orbital Notation: an orbital is written as a line each orbital has a name written below it electrons are drawn as arrows (up and down) Electron configuration pattern 1s 2s 2p 3s 3p 3d 4s 4p 4d 4f 5s 5p 5d 5f 6s 6p 6d 6f 7s 7p 7d 7f Electron configuration pattern 1s 2s 2p 3s 3p 3d 4s 4p 4d 4f 5s 5p 5d 5f 6s 6p 6d 6f 7s 7p 7d 7f Electron configurations Follow the pattern in the previous slide and fill maximum number of electrons for each sublevel until you get the number of electrons you should have for the specific atom Example: 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p5 This is an e- configuration for bromine Warm-up February 16th Write the electron configurations for the following elements Aluminum (Al) Chromium (Cr) Yttrium (Y) Orbital diagrams Follow same pattern for e- configurations, but you represent orbitals with lines and electrons with up and down arrows Silicon 1s number of electrons: 14 last electron is in sublevel: 3p 2s 2p 3s 3p Valence Electrons- the electrons in the outermost energy level Chlorine number of electrons: 17 last electron is in sublevel: 3p 1s 2s 2p 3s 3p Sodium 1s number of electrons: 11 last electron is in sublevel: 3s 2s 1s2 2s2 2p6 3s1 2p 3s Bromine 1s 4s number of electrons: 35 last electron is in sublevel: 4p 2s 2p 3s 3d 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p5 3p 4p Argon 1s number of electrons: 18 last electron is in sublevel: 3p 2s 2p 1s2 2s2 2p6 3s2 3p6 3s 3p Noble Gas Notation short hand for larger atoms configuration for the last noble gas is abbreviated by the noble gas’s symbol in brackets Bohr Models Bohr models show only what energy level the electrons are on Order for Filling Sublevels Noble gas configurations (short-cut) Write the noble gas in brackets (the one that comes before the element that you are writing it for) then go to the row that your element is in and write the row number then fill according to the blocks