Tuesday, January 22, 2008 • Final Grades • Quick Review • Electron configurations • Types of bonding • Ions and Ionic Compounds • Lewis Structures •Homework for Tuesday Page 436, #18, 20a,d,e, 21-22, 23a,b, 24-27, 28a,b,c, 29 Homework for Wednesday Page 436, #30-38 Lewis Structures Activity WS QUIZ FRIDAY Electron Configurations Give the electron configurations for the following elements: Sodium Sulfur Carbon What about for these ions? Sodium ion (Na+) Aluminum ion (Al3+) Types of Bonding Ionic Bonding - The attraction between ___________________ Between __________ and ________ Involves ____________ of electrons Covalent Bonding - A type of bonding in which atoms ____________ electrons Between two ______________ Involves _________ of electrons equally Polar Covalent Bonding - A ___________ bond in which the electrons are ______ shared equally because one atom attracts the shared electrons _________ than the other atom Ions & Ionic Compounds Charges on Ions Group IA metals always form _________________ Group IIA metals always form ________________ Aluminum in Group IIIA always forms _________ Group VI nonmetals always form ______________ Group VII nonmetals always form _____________ Characteristics of Ionic Compounds High Melting Point Conduct electricity (when dissolved in water) Valence Electrons What are valence electrons? The electrons in the ____________ principal energy level. How many valence electrons do each of the following atoms have? sodium? chlorine? oxygen? Lewis Structures Lewis Structures – A representation of a molecule or polyatomic ion showing how valence electrons are arranged among the atoms in the molecule or ion In a Lewis dot structure for an element, the valence electrons are written as dots surrounding the symbol for the element. Place one dot on each side first, and when all four positions are filled, the remaining dots are paired with one of the first set of dots. A maximum of two dots are placed on each side. Lewis Structures For nonmetals especially, the number of _____________ dots on an isolated atom indicates where covalent bonds can form. • Atoms tend to form bonds in such a way as to satisfy the ______________, having a stable electron configuration of _________ electrons in their outermost shells. – _____________ is an exception, since it is in row 1 and only has the 1s orbital available in the ground state Formation of Ionic Solids • When an element which gives up electrons easily comes in contact with an element that accepts an electron easily an electron may be transferred, yielding a ________________________. . Draw Lewis structure for these examples: Magnesium and oxygen Aluminum and chlorine Sodium and oxygen Lewis Structures Important terminology ________________________ – a pair of electrons that are shared between two atoms forming a covalent or polar covalent bond _____________________________ – Electron pairs in a Lewis structure that are not involved in bonding __________________ – the observation that atoms of nonmetals form the most stable molecules when they are surrounded by eight electrons (to fill their valence orbitals) Lewis Structures Steps for Writing Lewis Structures Step 1: Obtain the sum of the valence electrons from all of the atoms. Do not worry about keeping track of which electrons come from which atoms. It is the total number of valence electrons that is important Step 2: Use one pair of electrons to form a bond between each pair of bound atoms. For convenience, a line (instead of dots) is often used to indicate each pair of bonding electrons Step 3: Arrange the remaining electrons to satisfy the duet rule for hydrogen and the octet rule for each second row element. Chapter 12 Vocabulary Bond Bond Energy Ionic Compound Covalent Compound Polar Covalent Compound Electronegativity Lewis Structure Duet Rule Octet Rule Bonding Pair Lone Pairs Single Bond Double Bond Triple Bond