The Composition of Chemical Compounds Dr. Jared Heidinger M.D. Ph.D • When neutral atoms collide, an electron is transferred from one atom to the other • Ions – particles that have an electrical charge due to a transfer of electrons • Monoatomic ions – single atoms that have lost or gained electrons • high reactivity due to unfilled or overfilled electron levels • Cations - + charged ions (metals, formed when they lose an electron) • Anions – neg. charged ions (non-metals, formed when they gain an electron have ide ending) • When an atom loses an electron its charge changes from neutral to positive • eg. Na - 1 electron = Na+ • The Na atom now has 11 protons and 10 electrons. • The sodium atom now has a net positive charge. • When an atom gains an electron its charge changes from neutral to negative • eg. Cl + 1 electron = Cl • The Chlorine atom now has 17 protons and 18 electrons. It has a net neg. charge • Atoms or groups of atoms with a net(overall) negative or positive charge are called ions. • ASSIGN – pg. 68 - #’s 14, 17, 18 • “10-2” Worksheet and “Atomic Structure” side two Ions • Compounds contain two or more elements • Evidence - electrolysis (electro = electrical; lysis = loosen) • Large scale electrolytic cells are used to produce separate water into oxygen and hydrogen gas which can then be used in industry • Industries use this quality for electroplating cars(chrome) • Remember: phys. And chem. charac. Of elements relate directly to the number of protons and electrons its atom contains. Two types of ions: • Monoatomic ions(simple ions) - form from the atoms of an element • eg. Cl forms Cl • Polyatomic ions(complex 3ions) - PO4 ionic compounds • In a chem. Rxn. The #’s of protons and neutrons do not change. • Valence electrons are involved in chemical reactions • for elements to join and become compounds, they must form chemical bonds • chemical bonds: bonds resulting from the forces of attraction between atoms • Ions are attracted to nearby ions of opposite charge. • The force that holds any two oppositely charge ions together is an ionic bond. • In a substance many of these attractions make it possible for the compound to stay together. • This interaction between and + charges gives stability to the substance • This explains why ionic compounds are solids at room temperature Formation of a Compound • When a compound is formed, the sum of the charges must be zero • eg) 1 negative charge + 1 positive charge = zero • so... • eg) When aluminium is in its ionic form it has a charge of (3+) • When chlorine is in its ionic form it has a charge of (1-) • When aluminum and chlorine form an ionic compound the formula is AlCl3 • It is like this because you need 3 chlorine molecules with a (1-) charge to even out the 3+ charge aluminum has. Another example... • Na+ + Cl- ---> NaCl • The ion number tells us how many electrons will be lost or gained by the element.(ion number found on periodic table) • the overall charge of the product must be zero • so if one Na ion has a charge of 1+ in order for it to join the chlorine ion it needs to be balanced by a charge of negative one. • Since one chlorine ion has a charge of negative one only one is needed. Unlike the previous example where 3 chlorine atoms were needed. • The strength of an ionic bond varies, depending upon the kinds of atoms involved. • All ionic compounds share these similar characteristics... ionic compounds: Characteristics • metallic and non-metallic elements • ionic bonding(transfer of electrons) • solutions conduct electricity • solid at room temperature Solubility • If a compound has high solubility it will dissolve in water. • If it is insoluble the compound will form a precipitate(visible pieces of matter, cloudiness in the solution) • Highly soluble ionic compounds can be separated by using a precipitating agent such as alum, to make the soluble compounds removable. Assignment • “Chemistry: Practice Writing formulas” worksheet • “Review of Chapter 2: periodicity, atoms, Ions” Worksheet • “Ions” workSheet (teach how to use key) Covalent Compounds • Non-metal to non-metal • electrons not transferred, they are shared • both atoms attract the electrons, the electrons can’t move to either atom, they find a position in the middle • The bond that forms when electrons are shared is called a covalent bond. • Substances that are formed in this way are called covalent compounds. • Attraction not as strong as an ionic bond. • For this reason, compounds that are made by covalent bonding, are also called molecular compounds • Molecular compounds are generally softer than ionic compounds and exist as gases, liquids, or solids at room temperature. Molecular compounds: characteristics • Usually formed from nonmetallic elements only • covalent bonding (shared electrons, tug-of-war) • solutions will not usually conduct electricity • solid, liquid, gas at room temp. Diatomic and Polyatomic elements • some molecular elements are diatomic and some are polyatomic in their natural form • H2, N2, O2, F2, Cl2, Br2, I2,P4, S8 (Highlight and memorize!!!) Naming Compounds • IUPAC (International Union of Pure and Applied Chemistry) • makes rules and guidelines for all aspects of the study of chemistry • Handout - Chemical Nomenclature Rules for Naming Binary Ionic Compounds(two elements) • includes both elements in the compound • metallic element name appears first. • non-metallic element appears last, and its ending is changed to -ide. Rules continued... • name does not show the charge of the elements in the compound • name is not capitalized, lower case letters are used. • Some compounds have common names (eg. - water) Become familiar with the systematic and common name. Multi-valent ions • some transition metals have two possible charges • eg. Cu has two different ion forms, Cu+ and Cu2+ • this is a multi-valent ion • you must know what charge is being used • The formation of copper(I)chloride looks like this: + • Cu +Cl ---> CuCl • one positive charge is neutralized by one negative charge • The formation of copper(II)chloride looks like this: 2+ • Cu +Cl ---> CuCl2 • The copper ion has two positive charges. • This indicates that there need to be two negative charges added to neutralize it. How do you write the word formula with multivalent compounds? • You must indicate the charge that is being used with roman numerals • CuCl2 - copper(II)chloride • Fe2O3 - iron(III)oxide • “Ionic Naming Practice” • Ionic and Molecular Naming Worksheet Acids • Acid - aqueous hydrogen compound that makes blue litmus paper turn red • ph of less than 7 • hydrogen written first most of the time, unless it comes at the end of a COO- group, like CH3COOH(aq) Naming Acids • refer to chart on the periodic table you received • start by naming the compound as an ionic compound, then check to see if there is an (aq), if there is it is an acid • H2SO4(aq) - hydrogen sulphate --> sulphuric acid • CH3COOH(aq) - hydrogen acetate --> acetic acid Bases • all aqueous solutions of ionic hydroxides (anything dissolved in water that has a hydroxide ion attached) make red litmus turn blue • ph more than 7 Naming Bases • the name of the base is the same as the name of the ionic name • NaOH(aq) - aqueous sodium hydroxide • Ba(OH)2(aq) - aqueous barium hydroxide