Orbital Diagrams, Electron Configurations, and Dot diagrams Unit 2 (Chapter 13) Rules for filling e- in the e- cloud. Aufbau Principle: Electrons fill lowest energy levels 1st. Pauli Exclusion Principle: An orbital can only hold two e- and they must have opposite spin. (Cannot have the same 4 quantum numbers) Hund’s Rule: Sublevels with multiple orbitals (p, d, f) must fill orbitals one at a time before doubling up. 1s 2s 2p 1. A) Manganese Z = 25 orbital diagram 1s 2s 2p 3s 3p 4s 3d B) electron 1s2 2s2 2p6 3s2 3p6 4s2 3d5 configuration C) Dot diagram Mn Mn 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 7p 3d 4d 5d 6d 7d 4f 5f 5g 6f 6g 6h 7f 7g 7h 7i 2. A) Oxygen orbital diagram Z = 8 B) electron configuration C) Dot diagram 1s 1s2 2s 2p 2s2 O 2p4 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 7p 3d 4d 5d 6d 7d 4f 5f 5g 6f 6g 6h 7f 7g 7h 7i 3. A) Magnesium Z = 12 orbital diagram 1s 2s 2p 3s B) electron 1s2 2s2 2p6 3s2 configuration C) Dot diagram Mg Mg 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 7p 3d 4d 5d 6d 7d 4f 5f 5g 6f 6g 6h 7f 7g 7h 7i 4. A) Iron Z = 26 orbital diagram 1s 2s 2p Make sure you corrected your worksheet 3s 3p 4s 3d B) electron 1s2 2s2 2p6 3s2 3p6 4s2 3d6 configuration C) Dot diagram Fe Fe 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 7p 3d 4d 5d 6d 7d 4f 5f 5g 6f 6g 6h 7f 7g 7h 7i 5. A) Arsenic orbital diagram 1s 2s 2p Z = 33 3s 3p 4s 4p 3d B) electron 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p3 configuration C) Dot diagram As 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 7p 3d 4d 5d 6d 7d 4f 5f 5g 6f 6g 6h 7f 7g 7h 7i 6. A) Neon Z = 10 orbital diagram 1s 2s 2p B) electron 1s2 2s2 2p6 configuration C) Dot diagram Ne 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 7p 3d 4d 5d 6d 7d 4f 5f 5g 6f 6g 6h 7f 7g 7h 7i 7. A) Carbon orbital diagram 1s 2s Z = 6 2p B) electron 1s2 2s2 2p2 configuration C) Dot diagram C C 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 7p 3d 4d 5d 6d 7d 4f 5f 5g 6f 6g 6h 7f 7g 7h 7i 8. A) Tin orbital diagram 1s 2s Z = 50 2p 3s 3p 4s 5s 1s2 2s2 2p6 3s2 3p6 B) electron configuration C) Dot diagram Sn 4p 3d 4d 4s2 3d10 5p 4p6 5s2 4d10 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 7p 3d 4d 5d 6d 7d 5p2 4f 5f 5g 6f 6g 6h 7f 7g 7h 7i c = 9. What is the frequency of light that has a wavelength of 685 nanometers. nano nano = 10-9 so this is 685 x 10-9 m Knowns and unknown c = c = 3.00 x 108 m/s = 3.00 x 108 m/s 685 x 10-9 m = 4.38 x 10 14 1/s ν = ______________ 685 x 10-9 m λ = ______________ 10. What is the energy of a photon of radiation emitted by a radio station broadcasting at 93.7 MHz MHz? Mega (M) = 106 so this is 93.7 x 106 Hz Knowns and unknown E = h h = 6.626 x 10-34 J•s E = (6.626 x 10-34 E = 6.21 x 10-26 J•s) (93.7 x J 106 s-1) 93.7 x 106 Hz ν = ______________ E = ______________