Unit Plan By Erik Haigler Lesson 1 Purpose a. Students will be able to understand what parts make up an atom (electrons, protons, neutrons) b. Students will be able to explain how electrons, protons, and neutrons interact in an atom and the charges of each c. Students will be able to identify the atomic number and atomic mass from the periodic table and identify how atomic number increases from left to right and from top to bottom. d. Students will be able to identify and understand isotopes of each element e. Students will be able to find the electrons, protons, and neutrons when given any element on the periodic table (mass required if it is an isotope) Virginia S.O.L’s CH.2 The student will investigate and understand that the placement of elements on the periodic table is a function of their atomic structure. The periodic table is a tool used for the investigations of a) mass number, and atomic number; b) isotopes Materials • Periodic Table • Plastic grocery bag • Scissors • Themselves and a Partner • Desk Science Safety Students should be careful with scissors and put them back after they are done cutting the plastic. Please throw all trash away in the nearest trash can. No Horseplay! Procedure Engage (5min) Show animations and explain that protons and electrons have opposite charges and attract each other. Project the animation Protons and Electrons. www.middleschoolchemistry.com/multimedia/chapter4/lesson1#protons_and_electrons Explain to students that two protons repel each other and that two electrons repel each other. But a proton and an electron attract each other. Another way of saying this is that the same or “like” charges repel one another and opposite charges attract one another. Since opposite charges attract each other, the negatively charged electrons are attracted to the positively charged protons. Tell students that this attraction is what holds the atom together. Project the animation Hydrogen Atom. www.middleschoolchemistry.com/multimedia/chapter4/lesson1#hydrogen_atom Explore (30 min) Students can see evidence of the charges of protons and electrons by doing an activity with static electricity. Question to investigate: What makes objects attract or repel each other? Materials for each group • Plastic grocery bag • Scissors Procedure, part 1 Charged plastic and charged skin 1. Cut 2 strips from a plastic grocery bag so that each is about 2–4 cm wide and about 20 cm long. 2. Hold the plastic strip firmly at one end. Then grasp the plastic strip between the thumb and fingers of your other hand as shown. 3. Quickly pull your top hand up so that the plastic strip runs through your fingers. Do this three or four times. 4. Allow the strip to hang down. Then bring your other hand near it. 5. Write “attract” or “repel” in the chart on the activity sheet to describe what happened. Procedure, part 2 Charged plastic and neutral desk 1. Charge one strip of plastic the same way you did previously. 2. This time, bring the plastic strip toward your desk or chair. 3. Write “attract” or “repel” in the chart. Ask students to make a prediction: What do you think will happen if you charge two strips of plastic and bring them near each other? Procedure, part 3 2 pieces of charged plastic 1. Charge two strips of plastic 2. Slowly bring the two strips of plastic near each other. 3. Write “attract” or “repel” in the chart on the activity sheet. What happened when you brought the two pieces of plastic near each other? The ends of the strips moved away from each other. Use what you know about electrons and charges to explain why this happens. Each strip has extra electrons so they are both negatively charged. Because like charges repel, the pieces of plastic repelled each other. Explain (15 minutes) Introduce students to the periodic table. Project the image Periodic Table. Tell students that this is the periodic table. Explain that each box contains information about a different atom. The periodic table shows all the atoms that everything in the known universe is made from. It’s kind of like the alphabet in which only 26 letters, in different combinations, make up many thousands of words. The 100 or so atoms of the periodic table, in different combinations, make up millions of different of substances Explain the meaning of the numbers and letters in the boxes in the periodic Table. Tell students that the class will focus on the number of protons, electrons, and neutrons in the atoms of each element. Project the image Periodic Table. Explain what the numbers and letters in each box on the periodic table represent. Explain atomic mass. The atomic mass of an element is based on the mass of the protons, neutrons, and electrons of the atoms of that element. The mass of the proton and neutron are about the same, but the mass of the electron is much smaller (about 1/2000 the mass of the proton or neutron). The majority of the atomic mass is contributed by the protons and neutrons. For any element in the periodic table, the number of electrons in an atom of that element always equals the number of protons in the nucleus. But this is not true for neutrons. Atoms of the same element can have different numbers of neutrons than protons. Atoms of the same element with different numbers of neutrons are called isotopes of that element. The atomic mass in the periodic table is an average of the atomic mass of the isotopes of an element. For the atoms of the first 20 elements, the number of neutrons is either equal to or slightly greater than the number of protons. For example, the vast majority of carbon atoms have 6 protons and 6 neutrons, but small percentages have 6 protons and 7 neutrons, and an even smaller percentage have 6 protons and 8 neutrons. Since the majority of carbon atoms have a mass very close to 12, and only a small percentage are greater than 12, the average atomic mass is slightly greater than 12. Proton • Positively charged particle in the nucleus of the atom. • The number of protons in an atom’s nucleus is the atomic number. Electron • Negatively charged particle surrounding the nucleus of the atom. • The number of electrons surrounding the nucleus of an atom is equal to the number of protons in the atom’s nucleus. Neutron • Particle in the nucleus that has almost the same mass as a proton but has no charge. • For the atoms of most elements, the number of neutrons is either equal to or slightly greater than the number of protons. Elaborate (30 minutes) Protons, Neutrons, and Electrons Practice Fill in the blanks in the following activity sheet. Please keep in mind that the isotope represented by each space may NOT be the most common isotope or the one closest in atomic mass to the value on the periodic table. Atomic Symbol B Atomic Number Protons Neutrons Electrons Atomic Mass 6 11 24 31 37 39 29 89 35 43 100 207 Pb 102 89 Mo 70 225 53 81 100 206 159 No Yb 261 172 106 159 Evaluate (10 minutes) Quiz given on the following day similar to activity sheet Lesson 2 Purpose a. Students will be able to identify the family/groups and periods of the periodic table b. Students will be able to understand how each group and period differ and some key vary traits between each group and period that make them similar c. Students will be able to research and create a PowerPoint project to show their understanding of the groups and period of the periodic table Virginia S.O.L’s CH.2 The student will investigate and understand that the placement of elements on the periodic table is a function of their atomic structure. The periodic table is a tool used for the investigations of d) families or groups; e) periods; Materials • Periodic Table • Alien Cards • Laptop Science Safety Students should be careful with laptops and put them back the way they found them at the beginning of class. Please cleanup table and throw all trash away in the nearest trash can. No Horseplay! Procedure Engage (5 minutes) Play the Video https://www.youtube.com/watch?v=zUDDiWtFtEM Explore (20 minutes) Alien Periodic Table Periodic Trends Introduction: An alien community has been discovered and they have a different way of representing the elements on their planet. What would we do if we don’t know the atomic number of the element? What if we don’t know what type of properties are being represented? How can we make predictions? Can you break the Alien Code? Questions: 1. What (Key Similarities and Varying Traits) did you use to distinguish? 2. How many families or groups are there? 3. What (Key Similarities and Varying Traits) did you use to distinguish? 4. How many periods or rows are there? 5. What similarities do this table and the periodic table have in common? 6. What happens to the atomic number and the atomic mass as I go to the right or down the groups? Explain (15 minutes) Have students bring out there periodic table and briefly cover the following topics. Identify important things students need to write down in their notes. Periods Rows of elements are called periods. The period number of an element signifies the highest unexcited energy level for an electron in that element. The number of elements in a period increases as you move down the periodic table because there are more sublevels per level as the energy level of the atom increases. Groups Columns of elements help define element groups. Elements within a group share several common properties. Groups are elements have the same outer electron arrangement. The outer electrons are called valence electrons. Because they have the same number of valence electrons, elements in a group share similar chemical properties. The Roman numerals listed above each group are the usual number of valence electrons. For example, a group V element will have 5 valence electrons. Alkali metals The alkali metals, found in group 1 of the periodic table, are highly reactive metals that do not occur freely in nature. These metals have only one electron in their outer shell. Therefore, they are ready to lose that one electron in ionic bonding with other elements. As with all metals, the alkali metals are malleable, ductile, and are good conductors of heat and electricity. The alkali metals are softer than most other metals. Oxidation Number The oxidation number is the total number of electrons that an atom either gains or losses in order to form a chemical bond with another atom. Alkaline metals The alkaline earth elements are metallic elements found in the second group of the periodic table. All alkaline earth elements have an oxidation number of +2, making them very reactive. The Transition metals The 38 elements in groups 3 through 12 of the periodic table are called "transition metals." As with all metals, the transition elements are both ductile and malleable, and conduct electricity and heat. Their valence electrons are present in more than one shell. This is why they often exhibit several common oxidation states. Other metals The "other metals" elements are located in groups 13, 14, and 15. While these elements are ductile and malleable, they are not the same as the transition elements. These elements, unlike the transition elements, do not exhibit variable oxidation states, and their valence electrons are only present in their outer shell. All of these elements are solid, have a relatively high density, and are opaque. They have oxidation numbers of +3, ±4, and -3. Metalloids Metalloids are the elements found between the boundary that distinguishes metals from nonmetals. Metalloids have properties of both metals and non-metals. Some of the metalloids, such as silicon and germanium, are semi-conductors. Non-metals Non-metals are the elements in groups 14-16 of the periodic table. Non-metals are not able to conduct electricity or heat very well. As opposed to metals, non-metallic elements are very brittle. The non-metals can be gases, such as oxygen and solids, such as carbon. The non-metals have no metallic luster, and do not reflect light. They have oxidation numbers of ±4, -3, and -2. Halogens The halogens are five non-metallic elements found in group 17 of the periodic table. All halogens have 7 electrons in their outer shells, giving them an oxidation number of -1. Noble gases The noble gases are found in group 18 of the periodic table. These elements have an oxidation number of 0. This prevents them from forming compounds readily. All noble gases have 8 electrons in their outer shell, making them stable. Evaluate (45 minutes) Students will make a PowerPoint project where they will work in groups of 2 and from class notes or research they must create their own definition and describe what each family, groups, period, etc. are and elements used to describe them. Lesson 3 Purpose a. Students will be able to identify the trends of the periodic table b. Students will be able to understand the concepts of each periodic trend c. Students will be able to explain how the trend increases or decreases across and up and down the periodic table d. Students will be able to show and understand how understanding the concept and trend are connected Virginia S.O.L’s CH.2 The student will investigate and understand that the placement of elements on the periodic table is a function of their atomic structure. The periodic table is a tool used for the investigations of d) families or groups; e) periods; f) trends including atomic radii, electronegativity, shielding effect, and ionization energy; Materials • Periodic Table • • Alien Cards March Madness Bracket Science Safety Students should be cleanup table at the end of class and throw all trash away in the nearest trash can. No Horseplay! Procedure Engage (5 minutes) Show video and highlight the key points made about properties and trends. https://www.youtube.com/watch?v=O-48znAg7VE#t=226 Explore (20 minutes) Reconnect to the Alien Periodic table, but this time instead of focusing on the table layout focus on trends between the aliens. Draw a connection on how the trends between the aliens and the trends between the elements are not that different. Experiment Overview: In cooperative activity, you will use the 40 cards and construct an Alien Periodic Table. You will arrange the Aliens in some logical pattern so that they form an organized regular block. The resulting table is visually impressive and clearly the meaning of periodic trends. Questions: 1. What multiple trends (Key Similarities and Varying Traits) did you use to distinguish the eight families? 2. What multiple trends (Key Similarities and Varying Traits) did you use to distinguish the five periods? 3. What is at least one trend that you already know on the periodic table? 4. Try to name at least 3 other trends you might know or make up three others? 5. Draw the missing alien from your periodic table! Explain (10-15 minutes) The following trends will be briefly covered and students will take notes then students will draw how the trend moves across period and group on their own periodic table Effective nuclear charge The effective nuclear charge is the net positive charge experienced by an electron in a multielectron atom. The term "effective" is used because the shielding effect of negatively charged electrons prevents higher orbital electrons from experiencing the full nuclear charge by the repelling effect of inner-layer electrons. The effective nuclear charge experienced by the outer shell electron is also called the core charge. It is possible to determine the strength of the nuclear charge by looking at the oxidation number of the atom. - Increase across a period (due to increasing nuclear charge with no accompanying increase in shielding effect). - Decrease down a group (although nuclear charge increases down a group, shielding effect more than counters its effect). Atomic Radius Trends For atoms, the atomic radius is one-half the distance between the nuclei of two atoms is (just like a radius is half the diameter of a circle). However, this idea is complicated by the fact that not all atoms are normally bound together in the same way. Some are bound by covalent bonds in molecules, some are attracted to each other in ionic crystals, and others are held in metallic crystals. Nevertheless, it is possible for a vast majority of elements to form covalent molecules in which two like atoms are held together by a single covalent bond. The covalent radius of these molecules is often referred to as the atomic radius. This distance is measured in picometers. Going through each of the elements of the periodic table, patterns of the atomic radius can be seen. - Atomic radius decreases from left to right within a period. This is caused by the increase in the number of protons and electrons across a period. One proton has a greater effect than one electron; thus, a lot of electrons will get pulled towards the nucleus, resulting in a smaller radius. - Atomic radius increases from top to bottom within a group. This is caused by electron shielding. Ionization Energy Trends Ionization Energy is the amount of energy required to remove an electron from a neutral atom in its gaseous phase. Conceptually, ionization energy is considered the opposite of electronegativity. The lower this energy is, the more readily the atom becomes a cation. Therefore, the higher this energy is, the more unlikely the atom becomes a cation. Generally, elements on the right side of the periodic table have a higher ionization energy because their valence shell is nearly filled. Elements on the left side of the periodic table have low ionization energies because of their willingness to lose electrons and become cations. Thus, ionization energy increases from left to right on the periodic table. Another factor that affects ionization energy is electron shielding. Electron shielding describes the ability of an atom's inner electrons to shield its positively-charged nucleus from its valence electrons. - The ionization energy of the elements within a period generally increases from left to right. This is due to valence shell stability. - The ionization energy of the elements within a group generally decreases from top to bottom. This is due to electron shielding. Elaborate (30 minutes) March Madness is upon us! Your students are probably already working on their next assignment in bracketology, predicting the field for the NCAA Basketball Tournament. Let’s apply the principles of bracketology to the properties of the elements. The competition among the 64 elements is stiff, and there is a wealth of information for students to research, in this “elementary” version of March Madness! Define each of the following properties of the elements and briefly describe any periodic trend in the property across a row or down a column in the periodic table. - Ionization energy, Atomic radius, Effective nuclear charge Evaluate (10 minutes) I will actively evaluate students throughout the bracket exercise. After I will give students an exit slip where they will have give me a definition in their own words of the each trend and be able to draw each trends arrow on a periodic table. Lesson 4 Purpose a. Students will be able to identify the trends of the periodic table b. Students will be able to understand the concepts of each periodic trend c. Students will be able to explain how the trend increases or decreases across and up and down the periodic table d. Students will be able to show and understand how understanding the concept and trend are connected Virginia S.O.L’s CH.2 The student will investigate and understand that the placement of elements on the periodic table is a function of their atomic structure. The periodic table is a tool used for the investigations of d) families or groups; e) periods; f) trends including atomic radii, electronegativity, shielding effect, and ionization energy; h) chemical and physical properties; and Materials • Periodic Table • Think Pair Share Activity Sheet • 1 die for each group • Index cards with main group element symbols • Periodic Trend War Activity Sheet Science Safety Students should be careful not to lose any of the elements cards or other material used in the game. When finished student should return all items back to the station bucket in which they were found. Students should be cleanup table at the end of class and throw all trash away in the nearest trash can. No Horseplay! Procedure Engage (5 minutes) Show video http://education-portal.com/academy/lesson/electronegativity-trends-among-groupsand-periods-of-the-periodic-table.html#lesson Explore (5 minutes) Students will play a tug of war game and show how the number of valence electrons creates a high electronegativity by adding more students for each electron. Explain (10 minutes) The following trends will be briefly covered and students will take notes then students will draw how the trend moves across period and group on their own periodic table Electron affinity Like the name suggests, electron affinity describes the ability of an atom to accept an electron. Unlike electronegativity, electron affinity is a quantitative measure that measures the energy change that occurs when an electron is added to a neutral gas atom. When measuring electron affinity, the more negative the value, the more of an affinity to electrons that atom has. - With Electron affinity increases from left to right within a period. This is caused by the decrease in atomic radius. - Electron affinity decreases from top to bottom within a group. This is caused by the increase in atomic radius. Chemical Reactivity METALS DOWN a Group: In METALS reactivity INCREASES as you go DOWN a Group because the farther down a Group of metals you go, the easier it is for electrons to be given or taken away, resulting in higher reactivity. ACROSS a Period: In METALS reactivity DECREASES as you go ACROSS a Period because though they still want to give away valence electrons they have more of them to get rid of, which requires more energy. Not as easy to blow off a little steam! NON-METALS UP a Group: In NON-METALS reactivity INCREASES as you go UP a Group because the higher up and to the right atoms are, the higher the electronegativity, resulting in a more vigorous exchange of electrons. Fluorine? A greedy, impatient beast when it comes to electron exchange manners. ACROSS a Period: In NON-METALS reactivity INCREASES as you go ACROSS a Period because (notice how trends repeat?) the closer you get to filling your s- and porbital’s the more motivated you are to do so. Show Cool video of this in action https://www.youtube.com/watch?v=uixxJtJPVXk Elaborate (20 minutes) Think Pair Share Reactivity Video Lab Students are to write down what they thing about the periodic trends, reactivity, then get with partners to discuss Show Cool video of this in action https://www.youtube.com/watch?v=uixxJtJPVXk and then get students to discuss what they saw and how it alters their views. Evaluate (50 minutes) Periodic Table Trend War Purpose: To teach students periodic trends regarding the properties of elements. Materials: 1 die, index cards with main group element symbols written on them (one element per card), a list of trends written on the board numbered from 1 -6. Trends should include such things as ionization energy, electronegativity, atomic radius, electron affinity, reactivity etc... A "wild" category can be included which allows the roller of the dice to choose the trend. Quiz will follow on all trends Lesson 5 Purpose a. Students will be able to identify and show the valence electron configuration (They should already know how to solve the full electron configuration from last unit) b. Students will be able to use their understanding of valence electrons to show orbital notation for each element c. Students will be able to use their understanding of valence electrons, orbital notation, to create a Lew Dot Diagram for each element d. Students will be able to calculate the oxidation numbers from their knowledge of valence electrons and periodic trends Virginia S.O.L’s CH.2 The student will investigate and understand that the placement of elements on the periodic table is a function of their atomic structure. The periodic table is a tool used for the investigations of g) electron configurations, Lewis dot diagrams, valence electrons, and oxidation numbers; Materials 4 periodic tables At least 2 different colored pencils or markers 1 game board divider (binder, book, etc.) 2 Folders and paperclips Science Safety Students should be careful not to lose any of the battleship cars or other material used in the game. When finished student should return all items back to the station bucket in which they were found. Students should be cleanup table at the end of class and throw all trash away in the nearest trash can. No Horseplay! Procedure Engage (5 minutes) Show Video/Intro to today’s lesson https://www.youtube.com/watch?v=ov2ZHoXIBF0 Explore (40 minutes) Quickly in 2 or 3 minutes breakdown valence electrons with the help of the video and do a couple of practice examples as a class. Explain to them, how all transitional elements have two electrons and make sure this makes sense to them. Be sure to answer any question your students might have. PLAY Electron Configuration Battleship Game Rules: 1. You will work with a partner to play Battleship. The goal is to determine where your partner’s ships are on their periodic table. 2. First you need to privately “hide” your seven ships on the periodic table 3. Use a folder or some kind of barrier in order to hide your periodic table. 4. You and your partner will take turns guessing the “coordinates” of the hidden “ships.” 5. The game ends when all of one players ships are sunk or after time is called. Explain (10-15 minutes) Review with students what orbitals are and do example problems where students will draw the orbitals and electron within energy level (2n2). There can be a maximum of two electrons in each orbital and each same opposite spins. Only focus on s and p orbitals and teach/remind them of the rules when filling them up. A popular method of representing atoms is through Lewis dot diagrams. In a dot diagram, only the symbol for the element and the electrons in its outermost energy level (valence electrons) are shown. For Lewis dot structures, they are always shown in pairs. This is to indicate that electrons are in separate orbitals within each energy level. There can be a maximum of two electrons in each orbital. This is why the electrons are shown in pairs. When drawing the dot diagram relate it to the orbitals has the dots fill up the same way around the element mention the Octet rule. Using the electron dot diagram and valence electron configuration talk about how metals always lose electrons and nonmetals always gain them. Explain oxidation numbers and how they can be taught easily when you know the number of valence electrons. Show trend of how the groups all have the same number of valence electrons, the same number of dots, and oxidation number. Elaborate (30 minutes) Give the students 6 blank note cards (no lines) and color pencils, markers, etc. Students will have pick 5 elements from the battleship game, evenly distinguished throughout the periodic table, and will create and study card for themselves. On the front students will write the element with the symbol, atomic number, atomic mass, classification, group, period(energy level), protons, neutrons, and electrons. On the back students will draw the Lewis dot diagram and orbital notation and give the oxidation number and valence electron configuration. Evaluate (10 minutes) Chemistry Quiz: Valence Electrons, Electron Configuration, Orbital Notation, and Lewis Dot Structures given at the beginning of the following class Lesson Review/ Test Purpose a. Students will be able to understand what parts make up an atom (electrons, protons, neutrons) b. Students will be able to explain how electrons, protons, and neutrons interact in an atom and the charges of each c. Students will be able to identify the atomic number and atomic mass from the periodic table and identify how atomic number increases from left to right and from top to bottom. d. Students will be able to identify and understand isotopes of each element e. Students will be able to find the electrons, protons, and neutrons when given any element on the periodic table (mass required if it is an isotope) f. Students will be able to identify the family/groups and periods of the periodic table g. Students will be able to understand how each group and period differ and some key vary traits between each group and period that make them similar h. Students will be able to research and create a PowerPoint project to show their understanding of the groups and period of the periodic table i. Students will be able to identify the trends of the periodic table j. Students will be able to understand the concepts of each periodic trend k. Students will be able to explain how the trend increases or decreases across and up and down the periodic table l. Students will be able to show and understand how understanding the concept and trend are connected m. Students will be able to identify and show the valence electron configuration (They should already know how to solve the full electron configuration from last unit) n. Students will be able to use their understanding of valence electrons to show orbital notation for each element o. Students will be able to use their understanding of valence electrons, orbital notation, to create a Lew Dot Diagram for each element p. Students will be able to calculate the oxidation numbers from their knowledge of valence electrons and periodic trends Virginia S.O.L’s CH.2 The student will investigate and understand that the placement of elements on the periodic table is a function of their atomic structure. The periodic table is a tool used for the investigations of a) average atomic mass, mass number, and atomic number; b) isotopes, half lives, and radioactive decay; d) families or groups; e) periods; f) trends including atomic radii, electronegativity, shielding effect, and ionization energy; g) electron configurations, valence electrons, and oxidation numbers; h) chemical and physical properties; and Materials • All supplies used throughout the Unit Science Safety When finished student should return all items back to the station bucket in which they were found. Students should be cleanup table at the end of class and throw all trash away in the nearest trash can. No Horseplay! Procedure Review (30 minutes) Students will be given time to work on their “homework” packet that requires them to review all key definitions and concepts throughout the chapter. It also contains a few practice problems dealing with each concept. Students are to do each problem and evaluate their own performance and knowledge of the subject before choosing which activity/station to do during the last 45 minutes of class. (Students must have made up or taken any Quiz, Lab, Assignment, etc they have missed due to absences or school functions before choosing an activity) Review Part II Options (45 minutes) • Static Electricity with Electrons Protons and Neutrons • Battle Ship Valence Electron Configuration • Periodic Table Trend War • Extra Practice drawing Lewis Dot structures and Orbital Notation • Continue to work on homework packet/study the book Test Day (As long as students need to complete the test ≈ 45 minutes) Give students the test with clear instructions and answer any question they might have about the test questions. When students finish with the test, students will be able to listen to music with headphone, do homework for other classes, take care of any school business, etc. as long as it is quiet and does not distract students taking the test. *Activity Sheets, Quiz’s, Test needed for the Unit Start on the Next Page Protons, Neutrons, and Electrons Practice Fill in the blanks in the following activity sheet. Please keep in mind that the isotope represented by each space may NOT be the most common isotope or the one closest in atomic mass to the value on the periodic table. Atomic Atomic Protons Neutrons Electrons Atomic Mass Symbol Number B 6 11 24 31 37 39 29 89 35 43 100 Pb 207 102 89 Mo 70 225 53 81 206 100 159 No 261 Yb 172 106 159 ALIEN PERIODIC TABLE Periodic Trends Introduction: An alien community has been discovered and they have a different way of representing the elements on their planet. What would we do if we don’t know the atomic number of the element? What if we don’t know what type of properties are being represented? How can we make predictions? Can you break the Alien Code? Background: Most chemistry textbooks report a wealth of numerical data to identify periodic trends in the properties of the elements. Ionization energies, atomic radii, electronegativity, and electron affinities –all are dutifully tabulated and graphed. But what do all the numbers mean? The Modern Periodic Table is based on Periodic Law. This Law states that, physical and chemical properties of elements are a function of their atomic numbers. By using Periodic Law, we can find a variety of trends in both physical and chemical properties. Within each group, all the elements in that column will be exactly the same in some way (Key Similarity) AND must also share some feature that changes regularly as you move down the group (Varying Trait). Similarly, within each period, all the elements in the row must be exactly the same as you move across the period (Key Similarity) AND must also share some feature that changes regularly as you move across the row (the Varying Trait ). Experiment Overview: In cooperative activity, you will use the 40 cards and construct an Alien Periodic Table. You will arrange the Aliens in some logical pattern so that they form an organized regular block. The resulting table is visually impressive and clearly the meaning of periodic trends. Questions: 1. What multiple trends (Key Similarities and Varying Traits) did you use to distinguish the eight families? 2. What multiple trends (Key Similarities and Varying Traits) did you use to distinguish the five periods? 3. What is at least one trend that you already know on the periodic table? 1. 2. 4. Try to name at least 3 other trends you might know or make up three others? 1. 2. 3. 5. Draw the missing alien from your periodic table! It’s Elementary — March Madness March Madness is upon us! Your students are probably already working on their next assignment in bracketology, predicting the field for the NCAA Basketball Tournament. Let’s apply the principles of bracketology to the properties of the elements. The competition among the 64 elements is stiff, and there is a wealth of information for students to research, in this “elementary” version of March Madness! Review of Element Properties Define each of the following properties of the elements and briefly describe any periodic trend in the property across a row or down a column in the periodic table. • Ionization energy • Atomic radius • Effective nuclear charge Tournament Rules Here are the rules for predicting the winners in each round of It’s Elementary—March Madness. In the event of a tie in the properties of two competing elements in any round of the tournament, the element with the larger atomic mass always wins. • First round: Students will find the number of valence electrons of each element, the element with more valence electrons advance to the next round. • Second round: Compare the ionization energy of the elements in each bracket. The element with the higher ionization energy is the winner and advances to the Sweet16. • Third round (Sweet16): Compare the group numbers of the elements—the winner is the element with the larger group number using the international (IUPAC) system (Groups 1–18). • Fourth round: The element with the larger atomic radius wins this round and earns a trip to the Final Four. Use the atomic or covalent radius only • Semifinals (Final Four): Compare the effective nuclear charge(Z-eff) of the two elements, the element with the higher effective nuclear charge advance to the finals • Finals (Finals): Write the full electron configurations for each element, the element with more electrons wins the March Madness Tourney! Electron Configurations ____________________________________________________ ____________________________________________________ March Madness Tourney Winner ______________ Periodic Table Trend War Purpose: To teach students periodic trends regarding the properties of elements. Materials: 1 die, index cards with main group element symbols written on them (one element per card), a list of trends written on the board numbered from 1 -6. Trends should include such things as ionization energy, electronegativity, atomic radius, electron affinity, reactivity etc... A "wild" category can be included which allows the roller of the dice to choose the trend. Playing the game: • Students are placed in groups of 4 -5. • Cards are dealt until each student has the same number of cards. Each student should have about 7 cards per hand. • The dealer begins play by throwing the die. The number of the die determines the trend being played. • After the trend for the hand is determined the dealer plays the first card. Play continues to the left of the dealer. The card with the highest value for the current trend wins. The player who takes the hand rolls the die and makes the next lead. Multiple hands may be played. Note: This game is based on the card game of "War." Rules may vary at the teacher's discretion. Die Roll Code 1- Ionization energy 2- Electronegativity 3- Atomic radius (size) 4- Reactivity (roller choose either metals or non metals) 5- Electron Affinity 6- WILD! (Roller chooses trend) F O Cl I Br N Sb As P Bi Ge B Sn Ni Co Fe Mn Cr V Nb Ta Ti Zr Sc Mg Hf Ca Sr Li Ba Na Ra K Rb Cs Fr Name _________________________________________________ Date ______________ Period _____ Chemistry Quiz Valence Electrons, Electron Configuration, and Lewis Dot Structures 1. How many valence electrons do most atoms need to have a stable configuration? A. 1 C. 8 B. 6 D. 12 2. What are the only elements that naturally have a stable electron configuration? A. the alkali metals C. the actinides B. the halogens D. the Nobel gases 3. How do atoms get a stable electron configuration if they do not naturally have one? A. by splitting their nucleus C. by adding protons to their nucleus B. by chemical bonding D. by losing neutrons 4. What would a sodium atom have to do in order to get eight valence electrons? A. lose 1 valence electron C. lose 7 valence electrons B. gain 1 valence electron D. gain 3 valence electrons 5. What would a chlorine atom have to do in order to get eight valence electrons? A. lose 1 valence electron C. lose 7 valence electrons B. gain 1 valence electron D. gain 3 valence electrons 6. What would an oxygen atom have to do in order to get eight valence electrons? A. lose 2 valence electrons C. lose 3 valence electrons B. gain 2 valence electrons D. gain 3 valence electrons 7. Write the electron configuration notation for an atom of carbon. A. 1s2, 2s2 C. 1s2, 2s2, 2p2 B. 1s2, 2s2, 2p1 D. 1s2, 2s2, 2p6 8. Write the electron configuration notation for an atom of sodium. A. 1s2, 2s2 C. 1s2, 2s2, 2p6, 3s1 B. 1s2, 2s2, 2p4 D. 1s2, 2s2, 2p6, 3s2 9. Write the electron configuration notation for an atom of chlorine. A. 1s2, 2s2, 2p6, 3s1 B. 1s2, 2s2, 2p6, 3s2 C. 1s2, 2s2, 2p6, 3s2,3p3 D. 1s2, 2s2, 2p6, 3s2, 3p5 10. Identify the element that has the following electron configuration: 1s2,2s2,2p5 A. lithium C. nitrogen B. carbon D. fluorine 11. Identify the element in period 2 that contains five electrons in its outermost main energy level. A. beryllium C. nitrogen B. carbon D. oxygen 12. An element has the electron configuration of 1s2, 2s2, 2p6, 3s2, 3p2. What block, group, and period is this element in? A. s-block, group 2, period 3 C. s-block, group 15, period 2 B. p-block, group 14, period 3 D. p-block, group 16, period 4 13. An element that has the electron configuration of 1s2, 2s2, 2p6, 3s2, 3p4 would form which of the following ions? Name _________________________________________________ Date ______________ Period _____ A. 1+ C. 3+ B. 3 D. 214. Among the elements gallium (Ga), bromine (Br), potassium (K), and calcium (Ca), which has the lowest electronegativity? A. Ga C. K B. Br D. Ca 15. Which of the five hypothetical main-group elements below should have the highest electron affinity? E = 2s22p5 G = 4d105s25p5 A. E B. G C. J J = 2s22p2 L = 5d106s26p5 M = 2s22p4 D. L E. M 16. What is the relationship between group number and number of valence electrons in the pblock elements? A. group number = number of valence electrons B. group number minus 10 = number of valence electrons C. group number = number of valence electrons plus 10 D. group number = number of valence electrons times 8 17. The Group 13 element in Period 3 has an outer electron configuration of A. 3s2, 3p1 C. 3s2, 3p3 2 2 B. 3s , 3p D. 3s2, 3p5 18. How many valence electrons does N have?: A. 1 B. 3 C. 5 D. 7 19. Which of the following is the correct Lewis dot structure for the element sodium? 20. Which of the following is the correct Lewis dot structure for the element chlorine? Quiz--Periodic Trends 1. Which of the following is NOT a trend that varies systematically in the periodic table? A. B. C. D. E. electronegativity reactivity ionization energy atomic radius electron affinity 2. The atomic radius of F, Br, and I are 64, 114, and 138 pm respectively. From this information (and not your book) estimate a reasonable atomic radius of Cl. A. B. C. D. E. 53 pm 89 pm 126 pm 162 pm 196 pm 3. Use the periodic table (not any tables in your book) to predict which element has the largest ionization energy. A. B. C. D. E. H He Fr Rn Rh 4. Use the periodic table (not any tables or charts in your book) to predict which element has the largest atomic radius. A. B. C. D. E. H He Fr Rn Rh 5. Use your knowledge of periodic trends to predict which element reacts most vigourosly with water to produce hydrogen gas. A. B. C. D. E. H He Fr Rn Rh 6. Which of the following is a transition element? A. B. C. D. E. H He Fr Rn Rh 7. The element germanium is used in the manufacture of some transistors. What other element might be used for such a purpose? A. B. C. D. E. Ga Se Si Pb Tl 8. For which of the properties does Li have a larger value than potassium? Use the periodic table (not the tables or charts in your text.) A. B. C. D. E. first ionization energy atomic radius ionic radius number of protons molecular weight 9. The energy needed to remove the first electron from an atom is the first ionization energy. The energy needed to remove the second electron from an atom is the second ionization energy. The definition of third and fourth ionization energies is similar. Which of the atoms below would you expect to have the largest 3rd ionization energy? A. B. C. D. E. Na Mg Al Si P 10. Electronegativity tends to increase as you A. B. C. D. go down a column of the periodic table. go from left to right across the periodic table.. go toward the middle of the periodic table. go from the upper left-hand corner to the lower right-hand corner of the periodic table.. E. None of these are correct. Review Quiz Q.1) Why are halogens so highly reactive? A. they have 1 valence electron and want to get rid of it B. they have 1 valence electrons and want 7 more electrons C. they have 7 valence electrons and want 1 more electron D. they have 7 valence electrons and want to get rid of all 7 electrons Q.2) What is the same within a period? A. the number of valence electrons B. the number of orbits/shells C. the reactivity characteristics D. the physical properties (color, melting point, boiling point) Q.3) The element with the lowest ionization energy periodic table is A. Lithium, Li B. Francium, Fr C. Astatine, At D. Fluorine, F Q.4) Which element in period 5 has the largest atomic radii? A. Rubidium, Rb B. Xenon, Xe C. Vanadium, V D. Duborium, Db Q.5) Magneiusm is in the __________ family. A. alkali metal B. alkaline earth metal C. transition metal D. chalcogen E. halogen Q.6) Electronegativity refers to A. the energy needed to excite an electron B. the energy needed to remove an electron C. the energy needed to attract an electron D. the energy needed to release a photon Q.7) _______ is an example of a chalcogen A. Lithium, Li B. Barium, Ba C. Selenium, Se D. Neon, Ne Q.8) The most electronegative element on the periodic table is A. Lithium, Li B. Francium, Fr C. Astatine, At D. Fluorine, F Q.9) Which of the following elements is an alkali metal? A. hydrogen, H B. lithium, Li C. beryllium, Be D. Vanadium, V Q.10) How many valence electrons does Helium (He) have? A. 1 B. 2 C. 7 D. 8 Q.11) Electronegativity __________ as you go down a column because the electrons are ________ to/from the nucleus. A. increases, closer B. decreases, closer C. increases, farther D. decreases, farther Q.12) The alkali metals family has _______ valence electrons. A. 1 B. 2 C. 6 D. 7 E. 8 Q.13) Atomic radius __________ as you go across a period because ________ A. increases, there are more orbits B. increases, the nucleus pulls less on the electrons C. decreases, there are less orbits D. decreases, the nucleus pulls more on the electrons Q.14) Transition metals have _________ valence electrons. A. 1 B. 2 C. 6 D. 8 Q.15) The elements Selenium (Se), Bromine (Br), and Nickel (Ni) are all in A. period 6 B. group 6 C. group 4 D. period 4 Q.16) Which element in group 16 has the largest atomic radius? A. Oxygen, O B. Sulfur, S C. Selenium, Se D. Tellurium, Te E. Polonium, Po F. Ununhexium, Uuh Q.17) Which family is the least reactive? A. alkali metals B. chalcogens C. transition metalsals D. noble gases Q.18) Ionization energy refers to A. the energy needed to excite an electron B. the energy needed to remove an electron C. the energy needed to attract an electron D. the energy needed to release a photon Q.19) Iron, Fe is smaller than Hassium (Hs), primarily because A. iron has fewer neutrons B. iron has a smaller mass C. iron has a smaller atomic number D. iron has fewer orbits Q.20) Which family consists primarily of large, radioactive, man-made elements? A. alkali metals B. transition metals C. lanthanides D. actinides Electron Configuration Battleship(Print Pages Landscape Style) Game Rules: 1. You will work with a partner to play Battleship. The goal is to determine where your partner’s ships are on their periodic table. 2. First you need to privately “hide” your seven ships on the periodic table by highlighting them with a marker. The ship sizes are: a. TWO ships are two places b. TWO ships are three spaces c. TWO ships are four spaces d. One ships are five spaces The ships may be places on the periodic table horizontally (along a period) vertically (along a family), or even diagonally 3. Use a folder or some kind of barrier in order to hide your periodic table. 4. You and your partner will take turns guessing the “coordinates” of the hidden “ships.” You will guess by………… a. First, Student A may guess 3s23p4. You may state either: full configuration or valence configuration. It is best to use different configurations each time to practice all different types. b. Student B will confirm the element saying, Sulfur. After confirmation Student B will say “HIT” (If they hit your battleship) or “MISS”. c. Both students must keep track of all guesses in the following table. 5. The game ends when all of one players ships are sunk or after time is called. Materials 4 periodic tables At least 2 different colored pencils or markers 1 game board divider (binder, book, etc.) 2 Folders and paperclips Electron Configuration Battleship Guess 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. Reply HIT MISS 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. Name Date Class ELECTRONS IN ATOMS A. Multiple Choice Choose the best answer and write its letter on the line. 1. Bohr’s contribution to the development of atomic structure a. was referred to as the “plum pudding model.” b. was the discovery that electrons surround a dense nucleus. c. was proposed that electrons travel in circular orbits around the nucleus. d. is the quantum mechanical model. 2. What is the total number of orbitals in the third principal energy level? a. 1 c. 9 b. 4 d. 3. What is the maximum number of electrons allowed in the third energy level? a. 2 c. 18 b. 8 d. 32 4. What is the maximum number of electrons that can occupy one orbital? a.1 c. 8 b.2 d. 18 5. The electron configuration for fluorine is a. 1s22s22p3. b. 1s22s22p5. c. 1s22s22p6. d. 1s22s22p63s2. 6. The first three electrons that enter into p orbitals must have a. parallel spins. c. low energy levels. b. opposite spins. d. opposite charges. 7. The atom whose electron configuration is 1s22s22p63s23p1 is a. B. c. Al. b. Na. d. Ga. 8. The configuration for the outermost energy level in Ca is a. 3s2. c. 2s1. 2 b. 4s . d. 4s1. 9. The element having the same s and p configurations for principal energy level 3 as the element F has for its principal energy level 2 is a. Na. c. P. b. Al. d. Cl. 10. The frequency and wavelength of all waves are a. directly related. c. unrelated. b. inversely related. d. equal. 11. The SI unit of cycles per second is called a a. photon. c. hertz. b. quantum. d. hund. 12. Among the following groups of atoms, which have the same outer energy level configurations? a. H, He c. Mg, Al, Ca, Ga b. Li, Be, N, Ne d. N, P, As, Bi 13. The wavelength of light with a frequency of 2.50 × 1013 s1 is a. 1.20 × 105 m. c. 1.20 × 105 m. b. 8.33 × 105 m. d. 8.33 × 105 m. 14. Once the electron in a hydrogen atom absorbs a quantum of energy, it a. is now in its ground state. c. has released a photon. b. is now in its excited state (Jumps). d. none of the above B. Problems Solve the following problems in the space provided. Show your work. 15. Write the electron configurations for the following atoms. a. Mg b. P c. Br d. Xe e. Tc 16. Identify the elements described below. a. Configuration = 1s22s22p63s23p4 b. Contains a full second energy level c. Contains the first d electron d. Contains seven electrons in its fourth energy level e. Contains only two electrons in its fifth energy level f. Contains three unpaired electrons in its third energy level g. Contains five electrons in its 3d orbitals h Has its outermost electron in 7s1 C. Chart Sr Mg Ca As F S Name Classification Group/Period Atomic mass Number of protons Number of neutrons Number of electrons Lose or gain electrons Valance electron configuration Number of valance electrons Predicted oxidation number Lewis dot diagram Relative atomic size Relative ionization energy Relative electronegativity Relative electron affinity Relative reactivity Name Classification Group/Period Atomic mass Number of protons Number of neutrons Number of electrons Lose or gain electrons Valance electron configuration Number of valance electrons Predicted oxidation number Lewis dot diagram Relative atomic size Relative ionization energy Relative electronegativity Relative electron affinity Relative reactivity