The easy way to keep tracks of electrons! ELECTRON CONFIGURATION DO NOW Pick up your paperwork Pick up two handouts Get out Electron Configuration Notes, your Blank Periodic Table, and your green periodic table. RULES Aufbau Principle Each electron occupies the lowest energy orbital available. Electrons are added from the ground state up. Electrons fill in increasing energy order. Pauli Exclusion Principle Each orbital can hold a maximum of only two electrons – one spinning clockwise and one spinning counter clockwise. Hund’s Rule The most stable arrangement of electrons in orbitals is to fill singly and then go back and double up. BLANK PERIODIC TABLE Use this to help determine the different blocks: s, p, d, f BLANK PERIODIC TABLE THE BLOCKS OF THE PERIODIC TABLE ELECTRON CONFIGURATION Includes the principle quantum number, the sublevel and the number of electrons in the sublevel. ELECTRON CONFIGURATION Hydrogen Helium H He 1 2 1s1 1s2 Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon Li Be B C N O F Ne 3 4 5 6 7 8 9 10 1s22s1 1s22s2 1s22s22p1 1s22s22p2 1s22s22p3 1s22s22p4 1s22s22p5 1s22s22p6 ELECTRON CONFIGURATION Sodium Magnesium Aluminum Silicon Phosphorus Sulfur Chlorine Argon Na Mg Al Si P S Cl Ar 11 12 13 14 15 16 17 18 1s22s22p63s1 1s22s22p63s2 1s22s22p63s23p1 1s22s22p63s23p2 1s22s22p63s23p3 1s22s22p63s23p4 1s22s22p63s23p5 1s22s22p63s23p6 Potassium Calcium K Ca 19 20 1s22s22p63s23p64s1 1s22s22p63s23p64s2 ELECTRON HOTEL First determine atomic number Then determine the electron configuration. DO NOW Pick up handout Bright Line Spectra lab due tomorrow 2nd period paperwork revisions due tomorrow. 5th period paperwork revisions due Friday. Get out Electron Configuration Notes, your Blank Periodic Table, and your green periodic table. ELECTRON HOTEL Carbon Sodium Phosphorus Argon Sulfur Neon Aluminum C Na P Ar S Ne Al 6 11 15 18 16 10 13 1s22s22p2 1s22s22p63s1 1s22s22p63s23p3 1s22s22p63s23p6 1s22s22p63s23p4 1s22s22p6 1s22s22p63s23p1 ENERGY FILLING ORDER ARROW DIAGRAM 1s 2s 2p 3s 3p 3d 4s 4p 4d 4f 5s 5p 5d 5f 6s 6p 6d 6f 7s 7p 7d DIAGONAL RULE THE BLOCKS OF THE PERIODIC TABLE TRY BISMUTH, #83 TRY BISMUTH, #83 2 2 6 2 6 2 10 6 1s 2s 2p 3s 3p 4s 3d 4p 2 10 6 2 14 10 3 5s 4d 5p 6s 4f 5d 6p MERCURY, #80 2 2 6 2 6 2 10 6 1s 2s 2p 3s 3p 4s 3d 4p 2 10 6 2 14 10 5s 4d 5p 6s 4f 5d ODDBALLS TO REMEMBER You must memorize only: Chromium, molybdenum, tungsten Copper, silver, Lots of the “f” level elements 6d fills correctly; most f block elements do not fill according to the rulesd. THE BLOCKS OF THE PERIODIC TABLE DO NOW On a piece of paper see if you can do the electron configurations for: Tantalum (Z = 73) Curium (Z=96) ANSWERS Tantalum: 1s22s22p63s23p64s23d104p6 5s24d105p66s24f145d3 Curium: 1s22s22p63s23p64s23d104p6 5s24d105p66s24f145d106p67s25f8 DO NOW Turn in Bright Line Spectra lab Turn in any revised paperwork Pick up both handouts Get out Electron Configuration notes WHAT ARE IONS? Charged particles ANION – atom that has gained electrons and is more negative CATION – atom that has lost electrons and is more positive. So if the number of electrons has changed, then the electron configuration has changed. ELECTRON CONFIGURATION FOR IONS First, write the regular electron configuration for the element. If the ion is positive, take away electrons. If the ion is negative, add electrons to the highest partially filled energy level. EXAMPLES: Na 1s22s22p63s1 Na+1 1s22s22p6 Al Al+3 1s22s22p63s23p1 1s22s22p6 F F-1 H H-1 1s1 1s2 1s22s22p5 1s22s22p6 ION ANSWERS Magnesium 22s22p63s2 Mg 1s 12 +2 1s22s22p6 Mg 12 Lithium 22s1 Li 1s 3 +1 1s2 Li 3 Oxygen 22s22p4 O 1s 8 -2 1s22s22p6 O 8 Iron 22s22p63s23p64s23d6 Fe 1s 26 +3 1s22s22p63s23p64s03d5 Fe 26 EXCITED STATES Atoms that have absorbed energy and are in an excited state have electrons that have moved to a shell level that is higher than what is normal. The electrons that move come from the valence electrons (outermost electrons). A REMINDER ORBITAL DIAGRAMS Another way to symbolize electrons in their energy levels and sublevels. Has three basic symbols: unoccupied orbital orbital with orbital with one electron two electrons RULES TO REMEMBER Pauli Exclusion Principle Each orbital can hold a maximum of only two electrons – one spinning clockwise and one spinning counter clockwise. Hund’s Rule The most stable arrangement of electrons in orbitals is to fill singly and then go back and double up. ORBITAL DIAGRAMS ORBITAL DIAGRAMS TRY SOME Do the orbital diagrams for: SODIUM SULFUR ELECTRON CONFIGURATION SHORTHAND Cannot be used until after the test on Atomic Theory. Start with the noble gas the occurs before the element in question. Then tack on the remaining electron configuration. Example: Sodium 1s22s22p63s1 Shorthand: [Ne] 3s1 Copper 1s22s22p63s23p64s13d10 Shorthand: [Ar] 4s13d10 PRACTICE Calcium 1s22s22p63s23p64s2 shorthand: [Ar]4s2 Oxygen 1s22s22p4 shorthand: [He]2s22p4 VALENCE ELECTRONS These are the electrons in the outermost energy level. Look for the highest principle quantum number and count all the electrons in that level. Sodium Shorthand: 1s22s22p63s1 [Ne] 3s1 valence electrons: 1 VALENCE ELECTRONS Copper Shorthand: Magnesium Chlorine 1s22s22p63s23p64s13d10 [Ar] 4s13d10 valence electrons: 1 1s22s22p63s2 valence electrons: 2 1s22s22p63s23p5 valence electrons: 7 USING THE PERIODIC TABLE AS A SHORTCUT ELECTRON DOT DIAGRAMS The electrons in the outmost level are the ones that are involved in bonding and the ones we really care about (valence electrons). The symbol stands for the nucleus and all the inner electron energy levels. Using the electron configuration for the atom, choose the valence electrons. ELECTRON DOT DIAGRAMS EXAMPLES Sodium 1s22s22p63s1 valence electrons: 1 Na Copper 1s22s22p63s23p64s13d10 valence electrons: 1 Cu Magnesium 1s22s22p63s2 valence electrons: 2 Mg Chlorine 1s22s22p63s23p5 valence electrons: 7 Cl HOMEWORK – START NOW Do electron configuration and orbital diagrams on the front Do electron configuration and electron dot diagrams on the back side Lab tomorrow – bring your logbook.